CN106634742A - Self-prepared glue and preparation method thereof - Google Patents
Self-prepared glue and preparation method thereof Download PDFInfo
- Publication number
- CN106634742A CN106634742A CN201611122714.5A CN201611122714A CN106634742A CN 106634742 A CN106634742 A CN 106634742A CN 201611122714 A CN201611122714 A CN 201611122714A CN 106634742 A CN106634742 A CN 106634742A
- Authority
- CN
- China
- Prior art keywords
- raw material
- ethyl ketone
- graininess
- methyl ethyl
- mass fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J155/00—Adhesives based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09J123/00 - C09J153/00
- C09J155/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09J127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J169/00—Adhesives based on polycarbonates; Adhesives based on derivatives of polycarbonates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides self-prepared glue and a preparation method thereof. The method comprises the following steps of adding a granular injection molding raw material and methyl ethyl ketone into a stirring container according to respective preset mass fractions; stirring methyl ethyl ketone and the granular injection molding raw material by overturning the stirring container, and besides diluting the granular injection molding raw material with the methyl ethyl ketone until the granular injection molding raw material is diluted to be fluid with methyl ethyl ketone. When the self-prepared glue prepared in the invention is used for bonding products, the phenomenon of whitening cannot be generated.
Description
Technical field
The present invention relates to glue technical field, more specifically, is related to a kind of self-control glue and preparation method thereof.
Background technology
At present, in the manufacturing process of electronic product, for plastic products often use technique for sticking, pass through
By two adhering components together, such as fore shell and the back cover of earphone are formed outside earphone various types of glue by technique for sticking
Shell.But can there is following technical problem in the different parts of bonding plastics product in existing glue：
After the glue solidifies, it may appear that albinism, the outward appearance of electronic product finished product is had a strong impact on, reduce user to electronics
The perception of product.
The content of the invention
In view of the above problems, it is an object of the invention to provide a kind of self-control glue and preparation method thereof, existing to solve
Glue occurs after solidification the problem of albinism.
On the one hand, the self-control glue that the present invention is provided, including：
By the Methylethyl that the graininess injection raw material and mass fraction that mass fraction is 10%-30% is 70%-90%
Ketone is mixed, and graininess injection raw material is fluid state with the mixture of methyl ethyl ketone；Wherein, graininess injection raw material bag
Include any one in acrylonitrile-butadiene-styrene copolymer, Merlon, polypropylene and polyvinyl chloride.
On the other hand, the preparation method of the self-control glue that the present invention is provided, including：
Graininess injection raw material and methyl ethyl ketone are added in stirring container according to each predetermined mass fraction；
Methyl ethyl ketone is stirred with graininess injection raw material by overturning stirring container, meanwhile, methyl ethyl ketone
Graininess injection raw material is diluted, till graininess injection raw material is diluted to fluid state by methyl ethyl ketone.
Compared with prior art, self-control glue that the present invention is provided and preparation method thereof, is prepared by the preparation method
Glue after solidification, can will not produce albinism while adhesive strength is ensured.
In order to realize above-mentioned and related purpose, the one or more aspects of the present invention include the spy that will be explained in below
Levy.Description below and accompanying drawing are described in detail some illustrative aspects of the present invention.However, these aspects are indicated only
It is some modes in the various modes for can use principle of the invention.Additionally, it is contemplated that including all these aspects with
And their equivalent.
Description of the drawings
By reference to below in conjunction with the explanation of accompanying drawing, and with being more fully understood to the present invention, the present invention other
Purpose and result will be more apparent and should be readily appreciated that.In the accompanying drawings：
Fig. 1 is the schematic flow sheet of the preparation self-control glue according to the present invention.
In all of the figs identical label indicates similar or corresponding feature or function.
Specific embodiment
In the following description, for purposes of illustration, in order to provide the comprehensive understanding to one or more embodiments, explain
Many details are stated.It may be evident, however, that these embodiments can also be realized in the case of without these details.
In other examples, for the ease of describing one or more embodiments, known structure and equipment are illustrated in block form an.
The self-control glue that the present invention is provided, mainly by the graininess injection raw material and quality that mass fraction is 10%-30%
Fraction is mixed for the methyl ethyl ketone of 70%-90%, and graininess injection raw material is eventually mixed into stream with methyl ethyl ketone
Body state；Wherein, graininess injection raw material can select acrylonitrile-butadiene-styrene copolymer, Merlon, polypropylene
With any one in polyvinyl chloride.Describe the proportioning group of present invention self-control glue in detail with several specific embodiments below
Into.
Embodiment one
The self-control glue that the present embodiment one is provided, its composition is made up of graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 10%, and the mass fraction of methyl ethyl ketone is 90%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
Graininess injection raw material in embodiment one includes acrylonitrile-butadiene-styrene copolymer, Merlon, gathers
The composition of any one in propylene and polyvinyl chloride, i.e. graininess injection is single, it is impossible to be the mixture of aforementioned different materials.
In addition, it is necessary to explanation, the self-control glue mixed by Merlon and methyl ethyl ketone can only be to poly- carbon
The product of acid esters material carries out bonding, and in the same manner, the self-control glue mixed by polyvinyl chloride and methyl ethyl ketone can only be to poly-
The product of vinyl chloride material carries out bonding.
The self-control glue that the present invention is provided only is made up of graininess injection raw material and methyl ethyl ketone both compositions, due to
The characteristics of molecular structure of graininess injection raw material, bonding can only be carried out to the product of same molecular structure, if using by poly- carbon
The self-control glue that acid esters and methyl ethyl ketone are mixed carries out bonding, then non-binding effect to the product of polyvinyl chloride material.
Adhering object to making glue by oneself in following embodiments is suitable in the same manner.
The reason for existing glue produces albinism is that the molecular structure of glue composition and the hydrone in air are produced
Raw reaction, so as to albinism, but the present invention occur in this several constituent for making by oneself involved by glue will not be with hydrone
Reaction is produced, albinism also would not occur.
In each following embodiments, the constituent of graininess injection raw material is identical with embodiment one, each enforcement
Difference between example is that graininess injection raw material is different with the proportioning of methyl ethyl ketone.
Embodiment two
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 13%, and the mass fraction of methyl ethyl ketone is 87%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
Embodiment three
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 16%, and the mass fraction of methyl ethyl ketone is 84%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
Example IV
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 20%, and the mass fraction of methyl ethyl ketone is 80%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
Embodiment five
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 24%, and the mass fraction of methyl ethyl ketone is 76%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
Embodiment six
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 28%, and the mass fraction of methyl ethyl ketone is 72%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state..
Embodiment seven
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 22%, and the mass fraction of methyl ethyl ketone is 78%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state..
Embodiment eight
The self-control glue that the present embodiment two is provided, its composition includes：Graininess injection raw material and methyl ethyl ketone, wherein,
The mass fraction of graininess injection raw material is 30%, and the mass fraction of methyl ethyl ketone is 70%, graininess injection raw material and first
Base ethyl ketone is mixed according to respective mass fraction, and the mixture of final graininess injection raw material and methyl ethyl ketone is in stream
Body state.
The above is described in detail the constituent of the self-control glue of present invention offer, below to the preparation of self-control glue
Method is illustrated.
Fig. 1 shows the flow process for preparing self-control glue of the invention.
As shown in figure 1, the flow process of glue is made in the preparation that the present invention is provided by oneself, including：
Step S1：Graininess injection raw material and methyl ethyl ketone are added to into stirring according to each predetermined mass fraction to hold
In device.
Wherein, the mass fraction of graininess injection raw material is 10%-30%, and the mass fraction of methyl ethyl ketone is 70%-
90%, specific proportioning can flexibly determine according to the needs of actual application environment, such as：
When the mass fraction of graininess injection raw material is 10%, the mass fraction of methyl ethyl ketone is 90%.
When the mass fraction of graininess injection raw material is 13%, the mass fraction of methyl ethyl ketone is 87%.
When the mass fraction of graininess injection raw material is 16%, the mass fraction of methyl ethyl ketone is 84%.
When the mass fraction of graininess injection raw material is 20%, the mass fraction of methyl ethyl ketone is 80%.
When the mass fraction of graininess injection raw material is 24%, the mass fraction of methyl ethyl ketone is 76%.
When the mass fraction of graininess injection raw material is 28%, the mass fraction of methyl ethyl ketone is 72%.
When the mass fraction of graininess injection raw material is 22%, the mass fraction of methyl ethyl ketone is 78%.
When the mass fraction of graininess injection raw material is 30%, the mass fraction of methyl ethyl ketone is 70%.
Graininess injection raw material can be acrylonitrile-butadiene-styrene copolymer, Merlon, polypropylene and polychlorostyrene
Any one in ethene, is mixed with methyl ethyl ketone.
Step S2：Methyl ethyl ketone is stirred with graininess injection raw material by overturning stirring container, meanwhile, methyl
Ethyl ketone is diluted to graininess injection raw material, is until graininess injection raw material is diluted to fluid state by methyl ethyl ketone
Only.
In order to fully stir methyl ethyl ketone and graininess injection raw material, at least one stirring is put in stirring container
Ball, when stirring container is overturn, by stirring motion of the ball in stirring container, by methyl ethyl ketone and graininess injection raw material
It is sufficiently mixed together.
It should be noted that while methyl ethyl ketone and graininess injection raw material is stirred, methyl ethyl ketone can to
Granular injection raw material is diluted, and dilutes while stirring, until graininess injection raw material is diluted to flow-like by methyl ethyl ketone
Till state, stop upset stirring container, complete the preparation for making glue by oneself.
Self-control glue is methyl ethyl ketone and the mixed mixture in fluid state of graininess injection raw material.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, all should contain
Cover within protection scope of the present invention.Therefore, protection scope of the present invention described should be defined by scope of the claims.
Claims (10)
1. it is a kind of to make glue by oneself, it is characterised in that by graininess injection raw material and mass fraction that mass fraction is 10%-30%
Methyl ethyl ketone for 70%-90% is mixed, and the graininess injection raw material is with the mixture of the methyl ethyl ketone
Fluid state；Wherein, the graininess injection raw material include acrylonitrile-butadiene-styrene copolymer, Merlon, poly- third
Any one in alkene and polyvinyl chloride.
2. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
10%, the mass fraction of the methyl ethyl ketone is 90%.
3. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
13%, the mass fraction of the methyl ethyl ketone is 87%.
4. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
16%, the mass fraction of the methyl ethyl ketone is 84%.
5. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
20%, the mass fraction of the methyl ethyl ketone is 80%.
6. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
24%, the mass fraction of the methyl ethyl ketone is 76%.
7. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
28%, the mass fraction of the methyl ethyl ketone is 72%.
8. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
22%, the mass fraction of the methyl ethyl ketone is 78%.
9. self-control glue as claimed in claim 1, it is characterised in that the mass fraction of the graininess injection raw material is
30%, the mass fraction of the methyl ethyl ketone is 70%.
10. as described in any one in claim 1-9 self-control glue preparation method, it is characterised in that include：
Graininess injection raw material and methyl ethyl ketone are added in stirring container according to each predetermined mass fraction；
The methyl ethyl ketone is stirred with the graininess injection raw material by overturning the stirring container, meanwhile, institute
State methyl ethyl ketone to be diluted the graininess injection raw material, until the graininess is molded original by the methyl ethyl ketone
Till material is diluted to fluid state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122714.5A CN106634742A (en) | 2016-12-08 | 2016-12-08 | Self-prepared glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122714.5A CN106634742A (en) | 2016-12-08 | 2016-12-08 | Self-prepared glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106634742A true CN106634742A (en) | 2017-05-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201611122714.5A Pending CN106634742A (en) | 2016-12-08 | 2016-12-08 | Self-prepared glue and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1172837A (en) * | 1996-07-19 | 1998-02-11 | B.F.谷德里奇公司 | Low volatile organic solvent based adhesive |
| US20020010257A1 (en) * | 1998-06-30 | 2002-01-24 | Eastman Chemical Company | Adhesion-promoting primer compositions for polyolefin substrates |
| CN1880399A (en) * | 2005-06-16 | 2006-12-20 | 鸿富锦精密工业（深圳）有限公司 | Thermally conductive glue and method of manufacturing same |
| CN101191044A (en) * | 2007-09-30 | 2008-06-04 | 潘成钢 | Water-proof adhesive |
| CN102344770A (en) * | 2010-08-03 | 2012-02-08 | 福建振云塑业股份有限公司 | Formula and preparation method of adhesive for polyvinyl chloride pipeline system |
-
2016
- 2016-12-08 CN CN201611122714.5A patent/CN106634742A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1172837A (en) * | 1996-07-19 | 1998-02-11 | B.F.谷德里奇公司 | Low volatile organic solvent based adhesive |
| US20020010257A1 (en) * | 1998-06-30 | 2002-01-24 | Eastman Chemical Company | Adhesion-promoting primer compositions for polyolefin substrates |
| CN1880399A (en) * | 2005-06-16 | 2006-12-20 | 鸿富锦精密工业（深圳）有限公司 | Thermally conductive glue and method of manufacturing same |
| CN101191044A (en) * | 2007-09-30 | 2008-06-04 | 潘成钢 | Water-proof adhesive |
| CN102344770A (en) * | 2010-08-03 | 2012-02-08 | 福建振云塑业股份有限公司 | Formula and preparation method of adhesive for polyvinyl chloride pipeline system |
Non-Patent Citations (2)
| Title |
|---|
| 史江恒等: "《新编实用化学配方手册（下册）》", 30 November 2004, 中国建材工业出版社 * |
| 里见英一: "《塑料制品设计》", 31 August 1991, 中国石化出版社 * |
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Application publication date: 20170510 |