CN106634702A - Snail track-resistant POE solar energy packaging adhesive film and preparation method thereof - Google Patents
Snail track-resistant POE solar energy packaging adhesive film and preparation method thereof Download PDFInfo
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- CN106634702A CN106634702A CN201610712824.0A CN201610712824A CN106634702A CN 106634702 A CN106634702 A CN 106634702A CN 201610712824 A CN201610712824 A CN 201610712824A CN 106634702 A CN106634702 A CN 106634702A
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- poe
- solar energy
- packaging adhesive
- vagina
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- 239000002313 adhesive film Substances 0.000 title claims abstract description 45
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 241000237858 Gastropoda Species 0.000 title abstract 4
- 239000004033 plastic Substances 0.000 claims abstract description 16
- 229920003023 plastic Polymers 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 239000004611 light stabiliser Substances 0.000 claims abstract description 10
- 239000002216 antistatic agent Substances 0.000 claims abstract description 6
- 208000031481 Pathologic Constriction Diseases 0.000 claims description 34
- 210000001215 vagina Anatomy 0.000 claims description 34
- 229920001577 copolymer Polymers 0.000 claims description 28
- -1 Polyethylene copolymer Polymers 0.000 claims description 23
- 239000012528 membrane Substances 0.000 claims description 14
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 150000002978 peroxides Chemical class 0.000 claims description 8
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229920001083 polybutene Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 238000003490 calendering Methods 0.000 claims description 4
- 238000007766 curtain coating Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- PYOLJOJPIPCRDP-UHFFFAOYSA-N 1,1,3-trimethylcyclohexane Chemical class CC1CCCC(C)(C)C1 PYOLJOJPIPCRDP-UHFFFAOYSA-N 0.000 claims description 3
- ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 claims description 3
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 claims description 3
- FKMUJSDGDJFLLO-UHFFFAOYSA-N 2-ethylhexyl hydrogen carbonate 2-hydroperoxy-2-methylpropane Chemical class C(OCC(CCCC)CC)(O)=O.C(C)(C)(C)OO FKMUJSDGDJFLLO-UHFFFAOYSA-N 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 3
- 229920002943 EPDM rubber Polymers 0.000 claims description 3
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims description 3
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 238000011160 research Methods 0.000 claims description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 3
- 229940070710 valerate Drugs 0.000 claims description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 150000001451 organic peroxides Chemical class 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 235000006708 antioxidants Nutrition 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000004132 cross linking Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 14
- 230000032683 aging Effects 0.000 description 9
- 241001523405 Limax Species 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 3
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910021419 crystalline silicon Inorganic materials 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical class CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229960000969 phenyl salicylate Drugs 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 2
- UUKZMBSFFPFHSS-UHFFFAOYSA-N 2-(5-chlorobenzotriazol-2-yl)-5-phenylmethoxyphenol Chemical compound C=1C=C(N2N=C3C=C(Cl)C=CC3=N2)C(O)=CC=1OCC1=CC=CC=C1 UUKZMBSFFPFHSS-UHFFFAOYSA-N 0.000 description 1
- LXUJDFITFWBMQT-UHFFFAOYSA-N 2-ethylhexyl hydrogen carbonate Chemical class CCCCC(CC)COC(O)=O LXUJDFITFWBMQT-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- GECNIOWBEXHZNM-UHFFFAOYSA-N hexyl hydrogen carbonate Chemical compound CCCCCCOC(O)=O GECNIOWBEXHZNM-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000036299 sexual function Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The invention relates to a snail track-resistant POE solar energy packaging adhesive film and a preparation method thereof. The packaging adhesive film comprises the following components in parts by weight: 100 parts of POE plastic, 0.05-3 parts of a cross-linking agent, 0.2-0.8 parts of a curing agent, 0.1-1.2 parts of an adhesion agent, 5-90 parts of polar resin, 0.4-1.5 parts of an ultraviolet absorbent, 0.04-1.2 parts of an anti-oxidant, 0.01-0.5 parts of a light stabilizing agent, and 0.01-0.8 parts of an antistatic agent. The snail track-resistant POE solar energy packaging adhesive film guarantees good caking property and crosslinking performances of the POE adhesive film, realizes low water vapour transmittance rate, keeps low residual quantity of the cross-linking agent, reduces the chemical reaction of the POE adhesive film due to packaging of the assembly, effectively increases the heatproof decomposition and yellowing-resistant problems of the POE adhesive film during usage, so as to reduce the possibility of snail track of the solar energy assembly, and prolong the usage life of the assembly.
Description
Technical field
The present invention relates to a kind of solar energy packaging adhesive film and preparation method thereof, more particularly to a kind of anti-Limax stricture of vagina POE sun
Energy packaging adhesive film and preparation method thereof, belongs to photovoltaic material field.
Background technology
The effect of solar energy packaging adhesive film is solar battery sheet, backboard adhering and sealing, it is to avoid the electricity of encapsulated layer
Pond piece touches air and moisture in air, and solaode is protected.Last century Mo, domestic and international technical staff was once real
Used liquid silicone resin and polyvinyl butyral resin piece (PVB) are tested as encapsulating material, but because price is high, operation is implemented
Condition require that higher, implementation cost is high, physical property is bad and abandoned.It is in the market second using most encapsulating materials
Alkene-vinyl acetate polymer (EVA), however, EVA adhesive film has easy xanthochromia, anti-purple in application process after discovery time length
The shortcomings of outer aging is not enough.
In view of the above-mentioned weak point of EVA adhesive film, finding alternative packaging adhesive film becomes the most important thing.Due to POE modelings
Material is the thermoplastic elastomer (TPE) that in-situ polymerization is realized using the ethylene and octene of metallocene catalyst, abbreviation ethylene-octene copolymerization
Thing (POE), the flexible chain coiled structure of octene and the ethylene chain of crystallization make its existing excellent toughness again as physical crosslinking point
There is good processability.Without unsaturated double-bond in POE plastic molecules structures, with excellent ageing-resistant performance, therefore select
POE glued membranes become following developing direction as encapsulating material.
But no matter EVA or POE as solar panel encapsulating material, use of the solar module in the later stage
Limax stricture of vagina phenomenon occurs, the attractive in appearance of solar panel is affected.The wide dark lines such as finger divide in length and breadth on photovoltaic module
Cloth phenomenon is referred to as Limax stricture of vagina, and this surface occurs in that tiny striped, and its shape causes this existing like Limax crossopodia
The true cause of elephant is then that cell piece surface is oxidized.Although part researcher thinks that the generation of Limax stricture of vagina does not cause component
Power attenuation, but due to the oxidation stain that essence is cell piece grid line that produces of Limax stricture of vagina, and adjoint cell piece it is hidden split and
Higher water vapour permeability, it is hidden to split place's resistance increase in making component power generation process, substantial amounts of heat is produced, cause packaging plastic
Film high-temp. degradation and decomposition, produces xanthochromia, ultimately results in component power rapid decay, and the life-span also reduces.
Although Chinese invention patent (publication number：) and (publication number CN103289582A：CN102850947A) disclose respectively
The POE glued membranes of a kind of bridging property and caking property, realize respectively the more excellent cross-linking properties of POE glued membranes and adhesive property, but
All without reference to the anti-Limax stricture of vagina characteristic of POE packaging adhesive films.
The content of the invention
The purpose of the present invention is for the above-mentioned problems in the prior art, it is proposed that a kind of high temperature resistant, ageing-resistant
Anti- Limax stricture of vagina POE solar energy packaging adhesive films.
The purpose of the present invention can be realized by following technical proposal：A kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, institute
Packaging adhesive film is stated by following parts by weight into being grouped into：POE plastics：100 parts, cross-linking agent：0.05-3 parts, firming agent：0.2-0.8
Part, viscosifier：0.1-1.2 parts, polar resin：5-90 parts, ultraviolet absorber：0.4-1.5 parts, antioxidant：0.04-1.2 parts, light
Stabilizer：0.01-0.5 parts, antistatic additive：0.01-0.8 parts.
The present invention realizes the good adhesive property of POE glued membranes by regulating and controlling materials composition and various auxiliary agent proportionings, relatively low
Water vapour permeability, relatively low cross-linking agent residual volume is real so as to prepare a kind of high temperature resistant, ageing-resistant POE packaging adhesive films
Existing its anti-Limax stricture of vagina performance.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the polar resin is that polar group grafting changes
Sexual function resin.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the polar group graft modification functional resin
For Research of Grafting Malaic Anhydride Onto Polyethylene copolymer, polycthylene grafted sulfonic acid copolymer, polycthylene grafted acryhic copolymer, poly- third
Alkene grafted maleic anhydride copolymer, polypropylene grafted glycidyl methacrylate copolymer, polybutene grafted maleic anhydride
Copolymer, polybutene grafted propylene acid copolymer, EPDM grafted maleic anhydride copolymers, POE grafted maleic anhydride copolymers,
One or more in POE grafted propylene acid copolymers, POE grafted methacrylic acid ester copolymers.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the cross-linking agent be cumyl peroxide, two
Acyl group organic peroxide, 2,5- dimethyl -2,5 pairs (t-butyl peroxy) hexane, 1,1- (double tert-butyl peroxides) 3,3,5-
Trimethyl-cyclohexane, peroxidized t-butyl perbenzoate, triphenyl methane -4,4- triisocyanates, tert-butyl hydroperoxide -3,5,5-
Tri-methyl hexanoic acid ester, dibenzoyl peroxide, two (4- chlorobenzene formacyls) peroxide, two (2,4 dichloro benzene formoxyls)
Peroxide, two (4- methyl benzoyls) peroxide, normal-butyl -4,4- two (tert-butyl hydroperoxide) valerate, ethyl -3,
One or more in 3- bis- (tert-butyl hydroperoxide) butyrate, tert-butyl hydroperoxide -2- ethylhexyl carbonates.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the firming agent is tert-butyl hydroperoxide 2- second
Base hexyl carbonate.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, described viscosifier are alkyl phenolic resin SP-
134。
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, described antistatic additive is anion antistatic
Agent, the anionic antistatic agents include in alkylsulfonate, alkylbenzenesulfonate, alkyl sulfate, alkylphosphonate
Plant or various.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the ultraviolet absorber be UV-770,2- (2 '-
Hydroxyl -4 '-benzoxy phenyl) -5 chloro- 2H- benzotriazole, UV-360, UV-571, UV-539, one kind of 1010 DL TP or
It is various.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the antioxidant is four [β-(3,5- bis- tertiary fourths
Base -4- hydroxy phenyls) propanoic acid] pentaerythritol ester, antioxidant 1010, antioxidant DNP, antioxidant 1076, antioxidant TPP, antioxygen
One or more of agent DLTP, antioxidant CA.
In above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, the light stabilizer be 5- dimethyl oxazolidines-
2,4- diketone, 4- (tolysulfonyl amido) -2,2,6,6- tetramethyl piperidines, phenyl salicylate, phenylpropyl alcohol triazole, Tinuvin
119th, one or more of triazine hindered amine condensation polymer 3346.
Further object is that providing a kind of above-mentioned preparation side of anti-Limax stricture of vagina POE solar energy packaging adhesive films
Method, the method comprising the steps of：
S1, by proportioning by each raw material mix homogeneously, be added to melting mixing extruding pelletization in extruder, obtain plastics
Grain；
S2, by plastic grain obtained above through extruder extrusion, curtain coating, calendering film forming, obtain POE solaodes
Packaging adhesive film.
In the preparation method of above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, extruder in step S1
Each section of temperature is 40 DEG C -120 DEG C.
In the preparation method of above-mentioned a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, injection machine in step S3
Each section of temperature is 50 DEG C -110 DEG C.
Compared with prior art, the present invention is not on the premise of production cost is improved, it is ensured that the good caking property of POE glued membranes
And cross-linking properties, relatively low water vapour permeability is realized, relatively low cross-linking agent residual quantity reduces component because of encapsulation problem etc.
There is chemical reaction in the POE glued membranes for causing, in use resistance to thermal decomposition and color inhibition are asked to effectively raise POE glued membranes
Topic, so as to reduce the possibility of solar components Limax stricture of vagina generation, extends the service life of component.
Specific embodiment
The specific embodiment of the present invention is the following is, technical scheme is further described, but the present invention is simultaneously
It is not limited to these embodiments.
Embodiment 1-4：
POE plastics, cross-linking agent, firming agent, viscosifier, polarity tree are weighed according to composition component and its parts by weight in table 1
Fat, ultraviolet absorber, antioxidant, light stabilizer, antistatic additive in being placed in stainless steel, are uniformly mixed with blender.Its
In, polar resin is Research of Grafting Malaic Anhydride Onto Polyethylene copolymer, and cross-linking agent is cumyl peroxide, and firming agent is the tert-butyl group
Peroxidating 2- ethylhexyl carbonates, viscosifier are alkyl phenolic resin SP-134, and antistatic additive is alkylsulfonate, ultraviolet suction
Receipts agent is UV-770, and antioxidant is four [β-(3,5- di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol esters, and light stabilizer is
5- dimethyl oxazolidine -2,4- diketone.
Said mixture is added to into melting mixing extrusion plastic rope in extruder, extruder temperature is controlled each
The temperature of section is 40 DEG C～120 DEG C, is then cut into plastic grain.
Above-mentioned resulting plastic grain is required according to the width and thickness and shape decorative pattern of required glued membrane, Jing
Extruder extrusion, curtain coating, calendering carry out film forming, then pack.Extruder temperature control each section temperature be 50 DEG C～
110℃.Finished product sample is taken, is tested, test result is shown in Table 2, table 3.
Comparative example 1：
With reference to table 1：POE plastics, cross-linking agent, firming agent, ultraviolet suction are weighed according to constituent in table 1 and its parts by weight
Agent is received, antioxidant, light stabilizer in being placed in stainless steel, is uniformly mixed with blender.Wherein, polar resin is poly- second
Alkene grafted maleic anhydride copolymer, cross-linking agent is cumyl peroxide, and firming agent is tert-butyl hydroperoxide 2- ethylhexyl carbon
Acid esters, viscosifier are alkyl phenolic resin SP-134, and ultraviolet absorber is UV-770, and antioxidant is four [β-(3,5- bis- tertiary fourths
Base -4- hydroxy phenyls) propanoic acid] pentaerythritol ester, light stabilizer be 5- dimethyl oxazolidine -2,4- diketone.
Said mixture is added to into melting mixing extrusion plastic rope in extruder, extruder temperature is controlled each
The temperature of section is 40 DEG C～120 DEG C, is then cut into plastic grain.
Above-mentioned resulting plastic grain is required according to the width and thickness and shape decorative pattern of required glued membrane, Jing
Extruder extrusion, curtain coating, calendering carry out film forming, then pack.Extruder temperature control each section temperature be 50 DEG C～
110℃.Finished product sample is taken, is tested, test result is shown in Table 2, table 3.
Table 1
The peel test force of POE and backboard is according to the testing standards of GB/T 2790.
The peel test force of POE and glass is according to the testing standards of GB/T 2790.
The specific insulation of POE is tested according to GB/T1410-2006 testing standards.
The light transmission rate of POE is tested according to GB/T2410 testing standards.
The ultraviolet ageing yellowness index power of the test of POE is according to IEC61215/IEC61730 testing standards.
Double 85 aging yellowness index power of the tests of POE are according to IEC61215/IEC61730 testing standards.
Table 2
Draw from table 2, increased peeling force after cross-linking agent, polar resin, viscosifier and be obviously improved, light transmittance is substantially not
Become, do not affect the light transmission of glued membrane, it is ultraviolet to be mutually due for promotion with double 85 aging yellowness index.
For the impact to comparing component power, taking 5 conventional crystalline silicon photovoltaic modulies carries out performance test, and double 85 is aging
The data tested after test 240h, conventional polycrystalline body silicon photovoltaic module supreme ultra-clear glasses layer for stacking gradually under including, first
EVA adhesive film layer, solaode lamella, the second EVA adhesive film layer, backsheet layer.Then 5 conventional crystalline silicon photovoltaic modulies are carried out
I/V is tested, and test result is as shown in table 3.
Table 3
Draw in component there are obvious anti-PID effects from table 3, this is due to present invention achieves POE glued membranes are excellent
Light transmission, ageing-resistant, resistance to oxidation and relatively low water vapour permeability, so as to realize the anti-Limax stricture of vagina effect of POE glued membranes.
The effect above just because of POE glued membranes causes the anti-PID abilities of component to be improved, and extends the service life of component.
In above-described embodiment and its alternative, the consumption of cross-linking agent can also for 0.05 part, 0.5 part, 1.5 parts, 2.5
Part, 3 parts；Cross-linking agent can also be diacyl organic peroxide, 2,5- dimethyl -2,5 pairs (t-butyl peroxy) hexane, 1,1-
(double tert-butyl peroxides) 3,3,5- trimethyl-cyclohexanes, peroxidized t-butyl perbenzoate, the Carbimide .s of triphenyl methane -4,4- three
Ester, tert-butyl hydroperoxide -3,5,5 Trimethylhexanoic acid ester, dibenzoyl peroxide, two (4- chlorobenzene formacyls) peroxidating
Thing, two (2,4 dichloro benzene formoxyl) peroxide, two (4- methyl benzoyls) peroxide, (the tertiary fourths of normal-butyl -4,4- two
Base peroxidating) valerate, ethyl -3,3- two (tert-butyl hydroperoxide) butyrate, tert-butyl hydroperoxide -2- ethylhexyl carbonates
Ester.
In above-described embodiment and its alternative, the consumption of firming agent can also be 0.2 part, 0.7 part, 0.8 part.
In above-described embodiment and its alternative, the consumption of viscosifier can also for 0.1 part, 0.3 part, 0.7 part, 0.8
Part, 0.9 part, 1.1 parts, 1.2 parts.
In above-described embodiment and its alternative, the consumption of polar resin can also for 5 parts, 10 parts, 15 parts, 25 parts,
30 parts, 35 parts, 45 parts, 50 parts, 55 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85 parts, 90 parts；Polar resin can also be polyethylene
Grafting sulfonic acid copolymer, polycthylene grafted acryhic copolymer, polypropylene grafted maleic anhydride copolymer, polypropylene grafted methyl
Glycidyl acrylate copolymer, polybutene grafted maleic anhydride copolymer, polybutene grafted propylene acid copolymer, EPDM connect
Branch copolymer-maleic anhydride, POE grafted maleic anhydride copolymers, POE grafted propylene acid copolymers, POE grafted methacrylic acids
Ester copolymer.
In above-described embodiment and its alternative, the consumption of antistatic additive can also for 0.01 part, 0.03 part, 0.05
Part, 0.15 part, 0.25 part, 0.35 part, 0.4 part, 0.45 part, 0.5 part, 0.55 part, 0.65 part, 0.7 part, 0.75 part, 0.8 part；
Antistatic additive can also be alkylbenzenesulfonate, alkyl sulfate, alkylphosphonate.
In above-described embodiment and its alternative, the consumption of ultraviolet absorber can also for 0.4 part, 0.6 part, 0.7 part,
0.9 part, 1.2 parts, 1.4 parts, 1.5 parts；Ultraviolet absorber can also be 2- (2 '-hydroxyl -4 '-benzoxy phenyl) -5 chloro- 2H-
Benzotriazole, UV-360, UV-571, UV-539,1010DL TP.
In above-described embodiment and its alternative, the consumption of antioxidant can also for 0.04 part, 0.07 part, 0.09 part,
0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1.1 parts, 1.2 parts；Antioxidant may be used also
Think antioxidant 1010, antioxidant DNP, antioxidant 1076, antioxidant TPP, anti-oxidant DLTP, antioxidant CA.
In above-described embodiment and its alternative, the consumption of light stabilizer can also for 0.01 part, 0.03 part, 0.04
Part, 0.05 part, 0.06 part, 0.07 part, 0.08 part, 0.09 part, 0.1 part, 0.2 part, 0.5 part；Light stabilizer can also be (right for 4-
Tosyl amido) -2,2,6,6- tetramethyl piperidines, phenyl salicylate, phenylpropyl alcohol triazole, Tinuvin119, triazine hindered amine
Condensation polymer 3346.
Specific embodiment described herein is only explanation for example spiritual to the present invention.Technology neck belonging to of the invention
The technical staff in domain can be made various modifications to described specific embodiment or supplement or substituted using similar mode, but and
Do not deviate by the spirit of the present invention or surmount scope defined in appended claims.
It is skilled to this area although having made a detailed description and being cited some specific embodiments to the present invention
For technical staff, as long as it is obvious that can make various changes without departing from the spirit and scope of the present invention or correct.
Claims (10)
1. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films, it is characterised in that the packaging adhesive film is by following parts by weight composition
Composition：POE plastics：100 parts, cross-linking agent：0.05-3 parts, firming agent：0.2-0.8 parts, viscosifier：0.1-1.2 parts, polarity tree
Fat：5-90 parts, ultraviolet absorber：0.4-1.5 parts, antioxidant：0.04-1.2 parts, light stabilizer：0.01-0.5 parts, antistatic
Agent：0.01-0.8 parts.
2. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 1, it is characterised in that the polarity tree
Fat is polar group graft modification functional resin.
3. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 2, it is characterised in that the polar group
Group's graft modification functional resin is Research of Grafting Malaic Anhydride Onto Polyethylene copolymer, polycthylene grafted sulfonic acid copolymer, polycthylene grafted
It is acrylic copolymer, polypropylene grafted maleic anhydride copolymer, polypropylene grafted glycidyl methacrylate copolymer, poly-
Butylene grafted maleic anhydride copolymer, polybutene grafted propylene acid copolymer, EPDM grafted maleic anhydride copolymers, POE grafting
One or more in copolymer-maleic anhydride, POE grafted propylene acid copolymers, POE grafted methacrylic acid ester copolymers.
4. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 1, it is characterised in that the cross-linking agent
It is (double for cumyl peroxide, diacyl organic peroxide, 2,5- dimethyl -2,5 pairs (t-butyl peroxy) hexane, 1,1-
Tert-butyl peroxide) 3,3,5- trimethyl-cyclohexanes, peroxidized t-butyl perbenzoate, triphenyl methane -4,4- triisocyanates,
Tert-butyl hydroperoxide -3,5,5 Trimethylhexanoic acid ester, dibenzoyl peroxide, two (4- chlorobenzene formacyls) peroxide,
Two (2,4 dichloro benzene formoxyl) peroxide, two (4- methyl benzoyls) peroxide, (tert-butyl groups of normal-butyl -4,4- two
Peroxidating) valerate, ethyl -3,3- two (tert-butyl hydroperoxide) butyrate, in tert-butyl hydroperoxide -2- ethylhexyl carbonates
One or more.
5. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 1, it is characterised in that characterized in that,
The firming agent is tert-butyl hydroperoxide 2- ethylhexyl carbonates.
6. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 1, it is characterised in that described thickening
Agent is alkyl phenolic resin SP-134.
7. a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 1, it is characterised in that described is anti-quiet
Electric agent is anionic antistatic agents, and the anionic antistatic agents include alkylsulfonate, alkylbenzenesulfonate, alkylsurfuric acid
One or more in ester, alkylphosphonate.
8. a kind of preparation method of anti-Limax stricture of vagina POE solar energy packaging adhesive films, it is characterised in that methods described includes following step
Suddenly：
S1, by proportioning by each raw material mix homogeneously, be added to melting mixing extruding pelletization in extruder, obtain plastic grain；
S2, by plastic grain obtained above through extruder extrusion, curtain coating, calendering film forming, obtain POE solar cell packages
Glued membrane.
9. the preparation method of a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 8, it is characterised in that
The temperature of each section of extruder is 40 DEG C -120 DEG C in step S1.
10. the preparation method of a kind of anti-Limax stricture of vagina POE solar energy packaging adhesive films according to claim 8, it is characterised in that
The temperature of each section of extruder is 50 DEG C -110 DEG C in step S3.
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| WO2022057139A1 (en) * | 2020-09-18 | 2022-03-24 | 苏州赛伍应用技术股份有限公司 | Solder strip carrier film, preparation method therefor, and application thereof |
| CN116200131A (en) * | 2023-03-24 | 2023-06-02 | 通威太阳能（成都）有限公司 | Modified polyvinyl butyral adhesive film, preparation method thereof and solar cell module |
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