CN106634500A - Insulation coating for glass and application method thereof - Google Patents
Insulation coating for glass and application method thereof Download PDFInfo
- Publication number
- CN106634500A CN106634500A CN201610832373.4A CN201610832373A CN106634500A CN 106634500 A CN106634500 A CN 106634500A CN 201610832373 A CN201610832373 A CN 201610832373A CN 106634500 A CN106634500 A CN 106634500A
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- Prior art keywords
- glass
- water
- insulating mold
- mold coating
- nano
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/216—ZnO
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/116—Deposition methods from solutions or suspensions by spin-coating, centrifugation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an insulation coating for glass and an application method thereof; the insulation coating comprises 10-30% of waterborne modified polyurethane, 10-40% of inorganic nano ceramic resin, 10-50% of nano slurry, 0.05-0.2% of a leveling agent, 0.05-0.2% of a wetting agent, and 12-30% of a solvent; the waterborne modified polyurethane is alkoxy waterborne polyurethane made by modifying silane coupling agent and waterborne polyurethane. The application method comprises: using a glass cleanser to treat glass to be cleaned, flushing with clear water after cleaning until the water on the surface of the glass forms uniform film of water, scraping off water, and wiping the glass with ethanol; 2) applying the coating by rolling, to be specific, applying the insulation coating for glass to the ethanol-wiped glass by rolling. By taking advantage that the insulation coating exhibits high adhesion and high hardness under self-crosslinking reaction at normal temperature, the problems of low cleaning efficiency for glass construction, poor properties of waterborne paint film and short service life are solved.
Description
Technical field
The invention belongs to nano paint technical field, and in particular to a kind of insulating mold coating in use for glass and its application process.
Background technology
The annual new building of China about with 2,000,000,000 squares of speed increasing, but in China's existing building, only 5%
For energy saving building.Except the relevant laws and regulations according to statutory regulation and energy conservation object solve the power conservation requirement of new building
Outward, the reducing energy consumption of existed building would is that a significant problem and a difficult problem to be solved of China's building energy conservation.In glass side
To the research of energy-saving material, the power saving of existed building can be solved, therefore with huge economic and social benefit.
The material that at present glass energy-saving is mainly adopted for：Low-E glass, adhering film to glass and insulating moulding coating.Low-E glass
It is mainly used in new building field, and with irreplaceability.The energy-saving material on existing building glass is applied, mainly
For adhering film to glass and glass coating.Adhering film to glass has that manufacturing cost is high simultaneously, and old due to adhesive after general 2～3 years
Change, film layer occurs warpage, the problem of bubbling.Existing glass heat-insulating coating applies the glass surface in existing building.Oiliness is matched somebody with somebody
Fang Tedian is that paint film property is good, but not environmentally.Water prescription can only normal temperature self-curing drying and forming-film.Current major part glass heat-proof
Water paint is applied in terms of existing building glass, there is that low construction efficiency, film yields be low, paint film adhesion is not enough to
And hardness shows poor problem, has had a strong impact on the actual effect and service life of heat-insulating and energy-saving.
The content of the invention
The present invention proposes a kind of insulating mold coating in use for glass, and the insulating moulding coating is adhered to using the high of self-crosslinking reaction under its normal temperature
Power and high rigidity performance, solve the problems, such as that aqueous paint film property difference is short with service life.
The technical scheme is that what is be achieved in that：
A kind of insulating mold coating in use for glass, calculates by weight percentage, including following components：
Watersoluble modified polyurethane 10～30%, inorganic nano ceramic resin 10～40%, nano pulp 10～50%, levelling
Agent 0.05～0.2%, wetting agent 0.05～0.2% and solvent 12～30%, the watersoluble modified polyurethane is silane coupled
Agent is modified the aqueous polyurethane with alkoxyl for obtaining with aqueous polyurethane.
Further, the nano pulp is tin-antiomony oxide/wolframic acid caesium/zinc oxide composite dispersion.
Further, the preparation method of the nano pulp is：Dispersant is added to the water and is stirred, then added again and receive
Rice tin-antiomony oxide powder, nanometer wolframic acid caesium powder, nanometer Zinc oxide powder and defoamer, are ground dispersion, are eventually adding pH
Conditioning agent adjusts pH and obtains final product nano pulp to 8.8～9.2.
Further, calculate according to percetage by weight, the nano pulp each component content is：Nano antimony tin oxide powder 15
～25%, nanometer wolframic acid caesium powder 8～12%, nanometer Zinc oxide powder 1.5～2.5%, dispersant 3～5% and defoamer 0.1
～0.3%, balance of water.
Further, the dispersant is high polymer dispersion.
Further, the dispersant Tech-6300 or BYK190.
Further, the levelling agent is organosilicon levelling agent, and the wetting agent is organosilicon wetting agent, and the solvent is alcohol
Organic solvent.
Further, the alcohol organic solvent is ethanol and ethylene glycol.
The preparation method of insulating mold coating in use for glass of the present invention is：
According to said ratio by watersoluble modified polyurethane, inorganic nano ceramic resin, nano pulp, levelling agent, wetting agent
And solvent adds successively, filter after stirring fully, obtain final product insulating mold coating in use for glass.
It is a further object to provide a kind of application process of insulating mold coating in use for glass, comprises the following steps：
1) cleaning glass is processed：Glass to be cleaned is processed using glass cleaner, after having cleaned clear water is used
It is rinsed totally, until the water of glass surface is in uniform water film, then scrapes eliminating water, then uses ethanol glass；
2) paint rolling applying：By above-mentioned insulating mold coating in use for glass roller coating in step 1) above ethanol glass, according to 1
The standard of kilogram 40～45 squares of glass of coatings carries out roller coating.
Further, the glass cleaner is that cerium oxide throws dispersion liquid, available glass cleaning agent and water according to 3:3:4 ratios
Mixture is formed, the available glass cleaning agent be green umbrella glass cleaner, prestige king's glass cleaner, white cat glass cleaner or
Help clean multifunctional glass water.
Beneficial effects of the present invention：
1st, watersoluble modified polyurethane of the invention be using hydroxyl, amino, epoxy radicals etc. silane coupler with it is aqueous
Active function groups reaction on polyurethane high molecule chain, synthesizes the aqueous polyurethane emulsion with alkoxyl.It is using normal
The lower self-crosslinking reaction of temperature, with the hydroxyl of glass surface polycondensation reaction is carried out, and the self-crosslinking structure of Si-O-Si is generated, so as to have
Good adhesive force and the paint film physical property and resistance to water, especially hardness that substantially improve standard aqueous polyurethane.Enter one
Step improves the hardness of paint film, so as to the paint film for further improving insulating moulding coating is physical by adding inorganic nano ceramic resin
The resistance against physical scratch ability of coating, service life can be caused to be protected.
2nd, nano pulp is added in the component of coating of the invention, especially compound point of tin-antiomony oxide/wolframic acid caesium/zinc oxide
A prose style free from parallelism so that ultraviolet shielded the 99.9% of coating, near-infrared shielding more than 90%, it is seen that light transmission more than 65%, with not shadow
Ring the excellent optical clear heat-proof quality of daylighting and anti-ultraviolet barrier infrared heat.
Specific embodiment
Embodiment 1
Nano pulp is tin-antiomony oxide/wolframic acid caesium/zinc oxide composite dispersion.
The preparation method of nano pulp is：Tech-6300 is added to the water and is stirred, nano tin dioxide is then added again
Antimony powder body, nanometer wolframic acid caesium powder, nanometer Zinc oxide powder and modified polyorganosiloxane, are ground dispersion, finally add ammoniacal liquor to adjust
Section pH obtains final product nano pulp to 9.0.Wherein, nano antimony tin oxide powder 20%, nanometer wolframic acid caesium powder 10%, nano zine oxide
Powder 2%, 4%Tech-6300 and modified polyorganosiloxane 0.2%, balance of water.
Embodiment 2
Nano pulp is tin-antiomony oxide/wolframic acid caesium/zinc oxide composite dispersion.
The preparation method of nano pulp is：BYK190 is added to the water and is stirred, nano antimony tin oxide is then added again
Powder, nanometer wolframic acid caesium powder, nanometer Zinc oxide powder and modified polypropene acid polymer, are ground dispersion, are eventually adding
Ammoniacal liquor adjusts pH and obtains final product nano pulp to 8.9.Wherein, nano antimony tin oxide powder 22%, nanometer wolframic acid caesium powder 8%, nanometer
Zinc oxide powder 3%, 3%BYK190 and modified polyorganosiloxane 0.3%, balance of water.
Embodiment 3
Insulating mold coating in use for glass
Calculate by weight percentage, filling a prescription is：Watersoluble modified polyurethane 30%, inorganic nano ceramic resin 12%, enforcement
The nano pulp 40%, 0.1%Tech-233 of example 1,0.1%8000th, ethanol 12.8% and ethylene glycol 5%, the water
Property modified polyurethane be that silane coupler and aqueous polyurethane are modified the aqueous polyurethane with alkoxyl for obtaining.
Embodiment 4
Insulating mold coating in use for glass
Calculate by weight percentage, filling a prescription is：Watersoluble modified polyurethane 36%, inorganic nano ceramic resin 14%, enforcement
The nano pulp 30%, 0.1%Tech-233 of example 1,0.1%8000th, ethanol 13.8% and ethylene glycol 6%, the water
Property modified polyurethane be that silane coupler and aqueous polyurethane are modified the aqueous polyurethane with alkoxyl for obtaining.
Embodiment 5
Insulating mold coating in use for glass
Calculate by weight percentage, filling a prescription is：Watersoluble modified polyurethane 42%, inorganic nano ceramic resin 16%, enforcement
The nano pulp 20%, 0.1%Tech-233 of example 2,0.1%8000th, ethanol 14.8% and ethylene glycol 7%, the water
Property modified polyurethane be that silane coupler and aqueous polyurethane are modified the aqueous polyurethane with alkoxyl for obtaining.
Embodiment 6
A kind of application process of insulating mold coating in use for glass, comprises the following steps：
1) cleaning glass is processed：Glass to be cleaned is rooted out after the obvious foreign matter on surface using blade, after sprinkling dilution
Glass cleaning solution (cerium oxide throws dispersion liquid, available glass cleaning agent and water according to 3:3:4 ratio mixtures are formed, available glass
Cleaning agent is white cat glass cleaner), after simple scouring, shave；Spoon water again, by glass cleaning surface have it is hydrophilic
The moisture film uniformity that property should be presented is finished judging whether cleaning.If it is not, then carrying out homemade glass to uneven local location
Glass rinse agent grinding process, until the water of glass surface is in uniform water film, then scrapes eliminating water, then uses ethanol glass；
2) paint rolling applying：By above-mentioned insulating mold coating in use for glass roller coating in step 1) above ethanol glass, according to 1
The standard of kilogram 40～45 squares of glass of coatings carries out roller coating.
Embodiment 7
The insulating mold coating in use for glass roller coating that embodiment 3～5 is obtained is adopted and divided on the thick ordinary white glass of 5mm
Light photometer UV-2700 tests the optical transmittance of film sample block, the results are shown in Table 1：
The optical transmittance of the insulating mold coating in use for glass of 1 embodiment of table 3～5
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (10)
1. a kind of insulating mold coating in use for glass, it is characterised in that calculate by weight percentage, including following components：
Watersoluble modified polyurethane 10～30%, inorganic nano ceramic resin 10～40%, nano pulp 10～50%, levelling agent
0.05～0.2%, wetting agent 0.05～0.2% and solvent 12～30%, the watersoluble modified polyurethane is silane coupler
The aqueous polyurethane with alkoxyl for obtaining is modified with aqueous polyurethane.
2. insulating mold coating in use for glass according to claim 1, it is characterised in that the nano pulp is tin-antiomony oxide/tungsten
Sour caesium/zinc oxide composite dispersion.
3. insulating mold coating in use for glass according to claim 2, it is characterised in that the preparation method of the nano pulp is：
Dispersant is added to the water and is stirred, nano antimony tin oxide powder, nanometer wolframic acid caesium powder, nano zine oxide are then added again
Powder and defoamer, are ground dispersion, are eventually adding pH adjusting agent regulation pH and obtain final product nano pulp to 8.8～9.2.
4. insulating mold coating in use for glass according to claim 3, it is characterised in that calculate according to percetage by weight, it is described to receive
Rice ＆ peanut milk material each component content is：Nano antimony tin oxide powder 15～25%, nanometer wolframic acid caesium powder 8～12%, nano zine oxide
Powder 1.5～2.5%, dispersant 3～5% and defoamer 0.1～0.3%, balance of water.
5. the insulating mold coating in use for glass according to Claims 2 or 3, it is characterised in that the dispersant is high molecular polymerization
Thing dispersant.
6. insulating mold coating in use for glass according to claim 5, it is characterised in that the dispersant Tech-6300 or
BYK190。
7. insulating mold coating in use for glass according to claim 1 and 2, it is characterised in that the levelling agent is organosilicon levelling
Agent, the wetting agent is organosilicon wetting agent, and the solvent is alcohol organic solvent.
8. insulating mold coating in use for glass according to claim 7, it is characterised in that the alcohol organic solvent is ethanol and second two
Alcohol.
9. a kind of application process of the insulating mold coating in use for glass as described in claim 1 to 8 any one, it is characterised in that bag
Include following steps：
1) cleaning glass is processed：Glass to be cleaned is processed using glass cleaner, is carried out with clear water after having cleaned
Rinse well, until the water of glass surface is in uniform water film, then scrape eliminating water, then use ethanol glass；
2) paint rolling applying：By the insulating mold coating in use for glass roller coating described in claim 1 to 7 any one in step 1) through ethanol
Above cleaning glass window, according to the standard of 1 kilogram of coatings, 40～45 squares of glass roller coating is carried out.
10. the application process of insulating mold coating in use for glass according to claim 9, it is characterised in that the glass cleaner
For cerium oxide dispersion liquid, available glass cleaning agent and water are thrown according to 3:3:4 ratio mixtures are formed, and the available glass cleaning agent is
Green umbrella glass cleaner, prestige king's glass cleaner, white cat glass cleaner help clean multifunctional glass water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610832373.4A CN106634500A (en) | 2016-09-19 | 2016-09-19 | Insulation coating for glass and application method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610832373.4A CN106634500A (en) | 2016-09-19 | 2016-09-19 | Insulation coating for glass and application method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634500A true CN106634500A (en) | 2017-05-10 |
Family
ID=58852332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610832373.4A Pending CN106634500A (en) | 2016-09-19 | 2016-09-19 | Insulation coating for glass and application method thereof |
Country Status (1)
| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108058500A (en) * | 2017-06-30 | 2018-05-22 | 施莹莺 | A kind of surface treatment method and its treatment fluid for improving water resistance |
| CN112625577A (en) * | 2020-12-23 | 2021-04-09 | 海安浩驰科技有限公司 | Preparation process and application of ultrahigh-transmittance blue-light-free and white-fog-free nano heat-insulating coating |
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|---|---|---|---|---|
| CN108058500A (en) * | 2017-06-30 | 2018-05-22 | 施莹莺 | A kind of surface treatment method and its treatment fluid for improving water resistance |
| CN112625577A (en) * | 2020-12-23 | 2021-04-09 | 海安浩驰科技有限公司 | Preparation process and application of ultrahigh-transmittance blue-light-free and white-fog-free nano heat-insulating coating |
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Application publication date: 20170510 |
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