CN106634489A - Alkyd paint with excellent yellowing resistance and preparation method of alkyd paint - Google Patents

Alkyd paint with excellent yellowing resistance and preparation method of alkyd paint Download PDF

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Publication number
CN106634489A
CN106634489A CN201710003756.5A CN201710003756A CN106634489A CN 106634489 A CN106634489 A CN 106634489A CN 201710003756 A CN201710003756 A CN 201710003756A CN 106634489 A CN106634489 A CN 106634489A
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agent
antioxidant
solvent
filler
pigment
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李学全
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Anhui Phoenix Coating Technology Co Ltd
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Anhui Phoenix Coating Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/46Anti-skinning agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention discloses alkyd paint with excellent yellowing resistance and a preparation method of the alkyd paint. The alkyd paint is prepared from the following components in percentage by mass: 55-65% of alkyd resins, 1-5% of pigments, 1-3% of fillers, 0.5-1.5% of aids, 0.5-1.5% of a catalyst, 0.05-0.25% of a wetting agent, 0.05-0.25% of an anti-skining agent, 1.5-3.5% of antioxidant and 25-35% of a solvent. The preparation method comprises the following steps: adding alkyd resins into a mixer, stirring, adding aids, pigments, an antioxidant and fillers, stirring for 20-30 minutes, adding one of the solvents so as to obtain a mixture; adding the mixture into a grinding machine for grinding; adding a dryer, the wetting agent and the anti-skining agent into the ground mixture, stirring for 20-30 minutes, adding the residual solvents for adjusting the viscosity, stirring for 20-30 minutes, and packaging after detection qualification, so as to obtain the product. The alkyd paint disclosed by the invention has the advantages of high yellowing resistance, excellent overall performance and the like.

Description

Good alkyd paint of a kind of anti-yellowing property and preparation method thereof
Technical field
The present invention relates to the processing technique field of alkyd paint, specifically a kind of good alkyd paint of anti-yellowing property and its Preparation method.
Background technology
Alkyd paint calls alkyd resin coating or phthalic resin coating, is mainly made up of alkyd resin, is domestic at present raw The maximum class coating of yield, it is plentiful hard, durable with low price, simple, film less demanding to construction environment of constructing Property and weatherability preferably, the advantages of ornamental and protectiveness is all relatively good.
Alkyd resin be with polyalcohol, polyacid and aliphatic acid as primary raw material, it is obtained by polycondensation reaction Because synthetic technology is ripe, raw material is easy to get, resin coating film good combination property, alkyd resin has become synthetic resin to a kind of polymer One of most wide kind of middle consumption maximum, purposes.
At present, alkyd paint is widely used, but existing alkyd paint generally existing non-oxidizability difference is scarce Fall into, in use for some time, be very easy to the defect for xanthochromia occur, the using effect of alkyd is also just poor, how to produce Go out the good alkyd paint of a anti-yellowing property to become one of current important research topic.
The content of the invention
The invention aims to solve the easy xanthochromia of alkyd paint in prior art, the defect of using effect difference, there is provided one Plant good alkyd paint of anti-yellowing property and preparation method thereof to solve the above problems.
To achieve these goals, technical scheme is as follows:The invention discloses a kind of anti-yellowing property is good Alkyd paint, according to mass percent, is prepared from the following components:Alkyd resin 55%-65%, pigment 1%-5%, filler 1%-3%, Auxiliary agent 0.5%-1.5%, drier 0.5%-1.5%, wetting agent 0.05%-0.25%, anti skinning agent 0.05%-0.25%, antioxidant 1.5%-3.5%, solvent 25%-35%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 56%-64%, pigment 2%-4%, filler 1.2%-2.8%, auxiliary agent 0.6%-1.4%, drier 0.6%- 1.4%th, wetting agent 0.06%-0.24%, anti skinning agent 0.06%-0.24%, antioxidant 1.6%-3.4%, solvent 26%-34%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 60%, pigment 3%, filler 2%, auxiliary agent 1%, drier 1%, wetting agent 0.2%, anti skinning agent 0.2%, Antioxidant 2.6%, solvent 30%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 65%, pigment 1%, filler 1%, auxiliary agent 1.5%, drier 0.5%, wetting agent 0.25%, anti skinning agent 0.25%th, antioxidant 1.5%, solvent 29%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 55%, pigment 5%, filler 1%, auxiliary agent 1.5%, drier 1.5%, wetting agent 0.05%, anti skinning agent 0.05%th, antioxidant 3.5%, solvent 32.4%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 62%, pigment 4%, filler 2%, auxiliary agent 0.8%, drier 0.2%, wetting agent 0.05%, anti skinning agent 0.05%th, antioxidant 3.5%, solvent 27.4%.
Preferably, described pigment is using the one kind in carbon black, titanium dioxide, described filler adopts coarse whiting, described Auxiliary agent adopts organoclay, described drier to adopt cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt With methyl ethyl ketoxime, using hypophosphorous acid, the one kind of coating in antioxidant 168, described solvent is adopted described antioxidant No. 200 industrial napthas.
Preferably, the invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, concrete step It is rapid as follows:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 55-75r/min 2-8min is mixed, auxiliary agent, pigment, antioxidant and filler is subsequently adding, under the rotating speed of 1100-1300r/min 20- is stirred 30min, is then initially charged half solvent, and under the rotating speed of 1100-1300r/min 5-10min is stirred, and obtains compound;
(2), grinding:Add mixture in grinder and be ground, grind 20-30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, in 1100-1300r/ 20-30min is stirred under the rotating speed of min, being subsequently adding remaining solvent carries out the regulation of viscosity, turning in 1100-1300r/min The lower stirring 20-30min of speed, after detection is qualified, packaging.
The present invention has compared to existing technology advantages below:
By adding filler, can effectively increase the volume of product, reduce production cost, and because filler adopts coarse whiting, Coarse whiting is also named " calcium-magnesium powder ", and main component is the carbonate of calcium and magnesium, and stability preferably, by adding auxiliary agent organoclay, is adding During work, organoclay can effectively play sludge proof effect, by adding drier, can play the oxygen for accelerating paint film Change, be polymerized, be dried, reach the purpose of quick-drying, by adding wetting agent silicone oil, silicone oil is a kind of different polymerization degree chain structure Polysiloxane, silicone oil has remarkable heat resistance, electrical insulating property, weatherability, hydrophobicity, physiological inertia and less surface Tension force, additionally with low viscosity-temperature coefficient, higher resistance to compression, additionally by addition antioxidant hypophosphorous acid, hypophosphorous acid It is colourless oil liquid or deliquescent crystallization, is strong reductant, antioxygenic property is good, therefore the alkyd paint for preparing has Excellent antioxygenic property, is less prone to the defect of xanthochromia, and weatherability, electrical insulating property and heat resistance are relatively good.
Specific embodiment
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by following components preparation Into:Alkyd resin 55%-65%, pigment 1%-5%, filler 1%-3%, auxiliary agent 0.5%-1.5%, drier 0.5%-1.5%, wetting agent 0.05%-0.25%, anti skinning agent 0.05%-0.25%, antioxidant 1.5%-3.5%, solvent 25%-35%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 56%-64%, pigment 2%-4%, filler 1.2%-2.8%, auxiliary agent 0.6%-1.4%, drier 0.6%- 1.4%th, wetting agent 0.06%-0.24%, anti skinning agent 0.06%-0.24%, antioxidant 1.6%-3.4%, solvent 26%-34%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 60%, pigment 3%, filler 2%, auxiliary agent 1%, drier 1%, wetting agent 0.2%, anti skinning agent 0.2%, Antioxidant 2.6%, solvent 30%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 65%, pigment 1%, filler 1%, auxiliary agent 1.5%, drier 0.5%, wetting agent 0.25%, anti skinning agent 0.25%th, antioxidant 1.5%, solvent 29%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 55%, pigment 5%, filler 1%, auxiliary agent 1.5%, drier 1.5%, wetting agent 0.05%, anti skinning agent 0.05%th, antioxidant 3.5%, solvent 32.4%.
Preferably, the invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, by with the following group Divide and be prepared from:Alkyd resin 62%, pigment 4%, filler 2%, auxiliary agent 0.8%, drier 0.2%, wetting agent 0.05%, anti skinning agent 0.05%th, antioxidant 3.5%, solvent 27.4%.
Preferably, described pigment is using the one kind in carbon black, titanium dioxide, described filler adopts coarse whiting, described Auxiliary agent adopts organoclay, described drier to adopt cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt With methyl ethyl ketoxime, using hypophosphorous acid, the one kind of coating in antioxidant 168, described solvent is adopted described antioxidant No. 200 industrial napthas.
Preferably, the invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, concrete step It is rapid as follows:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 55-75r/min 2-8min is mixed, auxiliary agent, pigment, antioxidant and filler is subsequently adding, under the rotating speed of 1100-1300r/min 20- is stirred 30min, is then initially charged half solvent, and under the rotating speed of 1100-1300r/min 5-10min is stirred, and obtains compound;
(2), grinding:Add mixture in grinder and be ground, grind 20-30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, in 1100-1300r/ 20-30min is stirred under the rotating speed of min, being subsequently adding remaining solvent carries out the regulation of viscosity, turning in 1100-1300r/min The lower stirring 20-30min of speed, after detection is qualified, packaging.
Embodiment 1
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, is prepared from the following components:Alcohol Acid resin 60%, pigment 3%, filler 2%, auxiliary agent 1%, drier 1%, wetting agent 0.2%, anti skinning agent 0.2%, antioxidant 2.6%, Solvent 30%.
Described pigment adopts carbon black, described filler to adopt coarse whiting, described auxiliary agent to adopt organoclay, and described urging is dry Agent adopts cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxidant Using hypophosphorous acid, described solvent adopts No. 200 industrial napthas.
The invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, comprises the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 60r/min 6min, is subsequently adding auxiliary agent, pigment, antioxidant and filler, and 25min is stirred under the rotating speed of 1200r/min, then first adds Enter half solvent, under the rotating speed of 1200r/min 8min is stirred, obtain compound;
(2), grinding:Add mixture in grinder and be ground, grind 25min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, 1200r/min's 25min is stirred under rotating speed, being subsequently adding remaining solvent carries out the regulation of viscosity, stirred under the rotating speed of 1200r/min 25min, after detection is qualified, packaging.
Embodiment 2
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, is prepared from the following components:Alcohol It is acid resin 65%, pigment 1%, filler 1%, auxiliary agent 1.5%, drier 0.5%, wetting agent 0.25%, anti skinning agent 0.25%, anti-oxidant Agent 1.5%, solvent 29%.
Using in titanium dioxide, described filler adopts coarse whiting to described pigment, and described auxiliary agent adopts organoclay, described Drier adopts cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxygen Agent adopts coating antioxidant 168, described solvent to adopt No. 200 industrial napthas.
The invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, comprises the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 55r/min 2min, is subsequently adding auxiliary agent, pigment, antioxidant and filler, and 30min is stirred under the rotating speed of 1100r/min, then first adds Enter half solvent, under the rotating speed of 1300r/min 10min is stirred, obtain compound;
(2), grinding:Add mixture in grinder and be ground, grind 30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, 1100r/min's 30min is stirred under rotating speed, being subsequently adding remaining solvent carries out the regulation of viscosity, stirred under the rotating speed of 1100r/min 20min, after detection is qualified, packaging.
Embodiment 3
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, is prepared from the following components:Alcohol It is acid resin 55%, pigment 5%, filler 1%, auxiliary agent 1.5%, drier 1.5%, wetting agent 0.05%, anti skinning agent 0.05%, anti-oxidant Agent 3.5%, solvent 32.4%.
Described pigment adopts carbon black, described filler to adopt coarse whiting, described auxiliary agent to adopt organoclay, and described urging is dry Agent adopts cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxidant Using coating antioxidant 168, described solvent adopts No. 200 industrial napthas.
The invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, comprises the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 75r/min 8min, is subsequently adding auxiliary agent, pigment, antioxidant and filler, and 20min is stirred under the rotating speed of 1300r/min, then first adds Enter half solvent, under the rotating speed of 1300r/min 10min is stirred, obtain compound;
(2), grinding:Add mixture in grinder and be ground, grind 30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, 1300r/min's 20min is stirred under rotating speed, being subsequently adding remaining solvent carries out the regulation of viscosity, stirred under the rotating speed of 1300r/min 20min, after detection is qualified, packaging.
Embodiment 4
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, is prepared from the following components:Alcohol It is acid resin 62%, pigment 4%, filler 2%, auxiliary agent 0.8%, drier 0.2%, wetting agent 0.05%, anti skinning agent 0.05%, anti-oxidant Agent 3.5%, solvent 27.4%.
Described pigment adopts carbon black, described filler to adopt coarse whiting, described auxiliary agent to adopt organoclay, and described urging is dry Agent adopts cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxidant Using hypophosphorous acid, described solvent adopts No. 200 industrial napthas.
The invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, comprises the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 65r/min 6min, is subsequently adding auxiliary agent, pigment, antioxidant and filler, and 22min is stirred under the rotating speed of 1150r/min, then first adds Enter half solvent, under the rotating speed of 1150r/min 6min is stirred, obtain compound;
(2), grinding:Add mixture in grinder and be ground, grind 26min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, 1150r/min's 20min is stirred under rotating speed, being subsequently adding remaining solvent carries out the regulation of viscosity, stirred under the rotating speed of 1150r/min 22min, after detection is qualified, packaging.
Embodiment 5
The invention discloses a kind of good alkyd paint of anti-yellowing property, according to mass percent, is prepared from the following components:Alcohol Acid resin 63%, pigment 4%, filler 1.2%, auxiliary agent 0.8%, drier 1.4%, wetting agent 0.24%, anti skinning agent 0.06%, antioxygen Agent 2.6%, solvent 26.7%.
Described pigment adopts carbon black, described filler to adopt coarse whiting, described auxiliary agent to adopt organoclay, and described urging is dry Agent adopts cobalt iso-octoate, described wetting agent to adopt silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxidant Using hypophosphorous acid, described solvent adopts No. 200 industrial napthas.
The invention also discloses a kind of preparation method of the good alkyd paint of above-mentioned anti-yellowing property, comprises the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 55r/min 5min, is subsequently adding auxiliary agent, pigment, antioxidant and filler, and 30min is stirred under the rotating speed of 1100r/min, then first adds Enter half solvent, under the rotating speed of 1100r/min 10min is stirred, obtain compound;
(2), grinding:Add mixture in grinder and be ground, grind 30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, 1300r/min's 20min is stirred under rotating speed, being subsequently adding remaining solvent carries out the regulation of viscosity, stirred under the rotating speed of 1300r/min 20min, after detection is qualified, packaging.
Table 1 is the testing result of the alkyd paint good to anti-yellowing property obtained in embodiment 1-5, and particular technique index is shown in Table 1
Table 1
As shown in Table 1, the comprehensive comparison of the good alkyd paint of anti-yellowing property of the present invention is excellent.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry The simply present invention of the personnel it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and specification Principle, without departing from the spirit and scope of the present invention the present invention also have various changes and modifications, these change and Improvement is both fallen within the range of claimed invention.The protection domain of application claims by appending claims and its Equivalent is defined.

Claims (8)

1. the good alkyd paint of a kind of anti-yellowing property, it is characterised in that:According to mass percent, it is prepared from the following components: Alkyd resin 55%-65%, pigment 1%-5%, filler 1%-3%, auxiliary agent 0.5%-1.5%, drier 0.5%-1.5%, wetting agent 0.05%-0.25%, anti skinning agent 0.05%-0.25%, antioxidant 1.5%-3.5%, solvent 25%-35%.
2. the good alkyd paint of a kind of anti-yellowing property according to claim 1, it is characterised in that:According to mass percent, It is prepared from the following components:Alkyd resin 56%-64%, pigment 2%-4%, filler 1.2%-2.8%, auxiliary agent 0.6%-1.4%, urge dry Agent 0.6%-1.4%, wetting agent 0.06%-0.24%, anti skinning agent 0.06%-0.24%, antioxidant 1.6%-3.4%, solvent 26%- 34%。
3. the good alkyd paint of a kind of anti-yellowing property according to claim 1, it is characterised in that:According to mass percent, It is prepared from the following components:Alkyd resin 60%, pigment 3%, filler 2%, auxiliary agent 1%, drier 1%, wetting agent 0.2%, anti-caking Skin agent 0.2%, antioxidant 2.6%, solvent 30%.
4. the good alkyd paint of a kind of anti-yellowing property according to claim 1, it is characterised in that:According to mass percent, It is prepared from the following components:Alkyd resin 65%, pigment 1%, filler 1%, auxiliary agent 1.5%, drier 0.5%, wetting agent 0.25%, Anti skinning agent 0.25%, antioxidant 1.5%, solvent 29%.
5. the good alkyd paint of a kind of anti-yellowing property according to claim 1, it is characterised in that:According to mass percent, It is prepared from the following components:Alkyd resin 55%, pigment 5%, filler 1%, auxiliary agent 1.5%, drier 1.5%, wetting agent 0.05%, Anti skinning agent 0.05%, antioxidant 3.5%, solvent 32.4%.
6. the good alkyd paint of a kind of anti-yellowing property according to claim 1, it is characterised in that:According to mass percent, It is prepared from the following components:Alkyd resin 62%, pigment 4%, filler 2%, auxiliary agent 0.8%, drier 0.2%, wetting agent 0.05%, Anti skinning agent 0.05%, antioxidant 3.5%, solvent 27.4%.
7. according to the alkyd paint that a kind of arbitrary described anti-yellowing property of claim 1-6 is good, it is characterised in that:Described pigment Using the one kind in carbon black, titanium dioxide, described filler adopts coarse whiting, described auxiliary agent to adopt organoclay, described drier Using cobalt iso-octoate, described wetting agent adopts silicone oil, described anti skinning agent to adopt methyl ethyl ketoxime, described antioxidant to adopt With the one kind in hypophosphorous acid, coating antioxidant 168, described solvent is using No. 200 industrial napthas.
8. according to a kind of preparation method of the good alkyd paint of the arbitrary described anti-yellowing property of claim 1-6, it is characterised in that: Comprise the following steps that:
(1), dispensing:According to above-mentioned mass percent, alkyd resin is added in batch mixer, stirred under the rotating speed of 55-75r/min 2-8min is mixed, auxiliary agent, pigment, antioxidant and filler is subsequently adding, under the rotating speed of 1100-1300r/min 20- is stirred 30min, is then initially charged half solvent, and under the rotating speed of 1100-1300r/min 5-10min is stirred, and obtains compound;
(2), grinding:Add mixture in grinder and be ground, grind 20-30min;
(3), allotment detection:Drier, wetting agent, anti skinning agent are added in the compound after grinding, in 1100-1300r/ 20-30min is stirred under the rotating speed of min, being subsequently adding remaining solvent carries out the regulation of viscosity, turning in 1100-1300r/min The lower stirring 20-30min of speed, after detection is qualified, packaging.
CN201710003756.5A 2017-01-04 2017-01-04 Alkyd paint with excellent yellowing resistance and preparation method of alkyd paint Pending CN106634489A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462267A (en) * 2021-06-07 2021-10-01 上海涂固安高科技有限公司 Formula of high-temperature-resistant alkyd aluminum powder anti-scratch paint

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245219A (en) * 2008-02-29 2008-08-20 浙江天女集团制漆有限公司 Alkyd paint with low content of VOC and manufacture method thereof
CN102174291A (en) * 2011-02-11 2011-09-07 中国电力科学研究院 Organosilicon-modified alkyd resin paint composite and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245219A (en) * 2008-02-29 2008-08-20 浙江天女集团制漆有限公司 Alkyd paint with low content of VOC and manufacture method thereof
CN102174291A (en) * 2011-02-11 2011-09-07 中国电力科学研究院 Organosilicon-modified alkyd resin paint composite and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462267A (en) * 2021-06-07 2021-10-01 上海涂固安高科技有限公司 Formula of high-temperature-resistant alkyd aluminum powder anti-scratch paint

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Application publication date: 20170510