CN106634471A - Eco-friendly coil paint and preparation method - Google Patents
Eco-friendly coil paint and preparation method Download PDFInfo
- Publication number
- CN106634471A CN106634471A CN201611179094.9A CN201611179094A CN106634471A CN 106634471 A CN106634471 A CN 106634471A CN 201611179094 A CN201611179094 A CN 201611179094A CN 106634471 A CN106634471 A CN 106634471A
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- CN
- China
- Prior art keywords
- parts
- cosolvent
- isophorone
- sulfur
- trimethylolpropane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses eco-friendly coil paint and a preparation method. The paint comprises the following components, by mass percentage, 50-55 parts of lauric acid, 50-55 parts of phthalic anhydride, 50-55 parts of trimethylolpropane, 50-55 parts of neopentylene glycol, 15-20 parts of trimellitic anhydride, 15-20 parts of a pH conditioning agent, 15-20 parts of a cosolvent, 5-10 parts of xylene, 5-10 parts of epoxided peanut oil, 5-10 parts of a disiloxane linear aliphatic hydrocarbon emulsion, 1-2 parts of sulfur-water-particle-containing white mineral oil, 1-2 parts of isophorone and 1-2 parts of diacetone alcohol. The coil paint is excellent in impact resistance.
Description
Technical field
The present invention relates to technical field of chemical paint, in particular to a kind of environmentally friendly coiled material paint and preparation method.
Background technology
At present lithotome effect attractive in appearance is embodied to reach in building, often using lithotome or stone-like coating, but
Lithotome also has the shortcomings that natural：Limited by natural crystal color, color and figure line heterogeneity, also cannot turn over after decoration
Newly；It is present in extremely indivedual regions, exploitation and processing difficulties, it is expensive；Bulk density is big, big to body of wall load, uncomfortable
In the decoration of light-weight building, in addition, difficulty of construction is big, especially corner part needs special working process, the gap between stone material
Add seam glue, construction will carry out overall waxing after finishing.At present multiplex stone-like coating replaces lithotome, have true mineral varnish,
The true mineral varnish of sliver, marble paint etc., but their fidelities are low, available color is few, difficulty of construction big, high cost defect.
The content of the invention
For the problems referred to above, the invention provides a kind of environmentally friendly coiled material paint and preparation method.
For achieving the above object, the present invention provides following technical scheme：
A kind of environmentally friendly coiled material paint, is made up of following mass fraction formula components：
50～55 parts of laurate, 50～55 parts of phthalic anhydride, 50～55 parts of trimethylolpropane, 50～55 parts of neopentyl glycol, partially
15～20 parts of benzenetricarboxylic anhydride, 15～20 parts of pH adjusting agent, 15～20 parts of cosolvent, 5～10 parts of dimethylbenzene, epoxy peanut oil 5～
10 parts, 5～10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, 1～2 part of sulfur-bearing water particle White Mineral Oil, 1～2 part of isophorone, dipropyl
1～2 part of keto-alcohol.
Further, it is made up of following mass fraction formula components：
50 parts of laurate, 50 parts of phthalic anhydride, 50 parts of trimethylolpropane, 50 parts of neopentyl glycol, 15 parts of trimellitic anhydride, pH are adjusted
15 parts of agent of section, 15 parts of cosolvent, 5 parts of dimethylbenzene, 5 parts of epoxy peanut oil, 5 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulphurous water
1 part of particle White Mineral Oil, 1 part of isophorone, 1 part of DAA.
Further, it is made up of following mass fraction formula components：
55 parts of laurate, 55 parts of phthalic anhydride, 55 parts of trimethylolpropane, 55 parts of neopentyl glycol, 20 parts of trimellitic anhydride, pH are adjusted
20 parts of agent of section, 20 parts of cosolvent, 10 parts of dimethylbenzene, 10 parts of epoxy peanut oil, 10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing
2 parts of water particle White Mineral Oil, 2 parts of isophorone, 2 parts of DAA.
Further, it is made up of following mass fraction formula components：
53 parts of laurate, 53 parts of phthalic anhydride, 52 parts of trimethylolpropane, 52 parts of neopentyl glycol, 18 parts of trimellitic anhydride, pH are adjusted
18 parts of agent of section, 17 parts of cosolvent, 8 parts of dimethylbenzene, 8 parts of epoxy peanut oil, 7 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulphurous water
1 part of particle White Mineral Oil, 2 parts of isophorone, 1 part of DAA.
Further：Preparation method of the present invention has following steps：
Step one：Laurate, phthalic anhydride, trimethylolpropane, neopentyl glycol are added into reactor reaction, is reacted 30 minutes
Afterwards, refluxing xylene is added, is warming up to 200～220 DEG C and reacts 1.5～2 hours, make intermediate blend 1；
Step 2:Trimellitic anhydride is added in intermediate blend 1,150～160 DEG C of reactions 1.5～2 is then cooled to little
When, make intermediate blend 2；
Step 3:PH adjusting agent and cosolvent are added in intermediate blend 2, its ph value is adjusted to into 5～7, be subsequently adding
Water, makes intermediate blend 3；
Step 4:Intermediate blend 3, dimethylbenzene is added into stirring mixing 30～45 minutes in mixer, ring is subsequently adding
Oxygen peanut oil, silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle White Mineral Oil, isophorone and DAA continue to stir
1.5～2 hours, make finished product.
The invention has the beneficial effects as follows：
1. the coiled material paint of the present invention has preferable impact resistance；
2. the coiled material paint of the present invention has weatherability；
3. the coiled material paint of the present invention have can reach higher hardness number
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of environmentally friendly coiled material paint, is made up of following mass fraction formula components：50～55 parts of laurate, phthalic anhydride 50～55
Part, 50～55 parts of trimethylolpropane, 50～55 parts of neopentyl glycol, 15～20 parts of trimellitic anhydride, 15～20 parts of pH adjusting agent,
15～20 parts of cosolvent, 5～10 parts of dimethylbenzene, 5～10 parts of epoxy peanut oil, 5～10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body,
1～2 part of sulfur-bearing water particle White Mineral Oil, 1～2 part of isophorone, 1～2 part of DAA.
Embodiment two：
A kind of environmentally friendly coiled material paint, is made up of following mass fraction formula components：50 parts of laurate, 50 parts of phthalic anhydride, three hydroxyl first
50 parts of base propane, 50 parts of neopentyl glycol, 15 parts of trimellitic anhydride, 15 parts of pH adjusting agent, 15 parts of cosolvent, 5 parts of dimethylbenzene, epoxy
5 parts of peanut oil, 5 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, 1 part of sulfur-bearing water particle White Mineral Oil, 1 part of isophorone, DAA 1
Part.
Embodiment three：
A kind of environmentally friendly coiled material paint, is made up of following mass fraction formula components：55 parts of laurate, 55 parts of phthalic anhydride, three hydroxyl first
55 parts of base propane, 55 parts of neopentyl glycol, 20 parts of trimellitic anhydride, 20 parts of pH adjusting agent, 20 parts of cosolvent, 10 parts of dimethylbenzene, ring
10 parts of oxygen peanut oil, 10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, 2 parts of sulfur-bearing water particle White Mineral Oil, 2 parts of isophorone, dipropyl
2 parts of keto-alcohol.
Example IV：
A kind of environmentally friendly coiled material paint, is made up of following mass fraction formula components：53 parts of laurate, 53 parts of phthalic anhydride, three hydroxyl first
52 parts of base propane, 52 parts of neopentyl glycol, 18 parts of trimellitic anhydride, 18 parts of pH adjusting agent, 17 parts of cosolvent, 8 parts of dimethylbenzene, epoxy
8 parts of peanut oil, 7 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, 1 part of sulfur-bearing water particle White Mineral Oil, 2 parts of isophorone, DAA 1
Part.
Embodiment five：
A kind of environmentally friendly coiled material paint its preparation method comprises the steps：
Step one：Laurate, phthalic anhydride, trimethylolpropane, neopentyl glycol are added into reactor reaction, is reacted 30 minutes
Afterwards, refluxing xylene is added, is warming up to 200～220 DEG C and reacts 1.5～2 hours, make intermediate blend 1；
Step 2:Trimellitic anhydride is added in intermediate blend 1,150～160 DEG C of reactions 1.5～2 is then cooled to little
When, make intermediate blend 2；
Step 3:PH adjusting agent and cosolvent are added in intermediate blend 2, its ph value is adjusted to into 5～7, be subsequently adding
Water, makes intermediate blend 3；
Step 4:Intermediate blend 3, dimethylbenzene is added into stirring mixing 30～45 minutes in mixer, ring is subsequently adding
Oxygen peanut oil, silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle White Mineral Oil, isophorone and DAA continue to stir
1.5～2 hours, make finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of environmentally friendly coiled material paint, it is characterised in that：It is made up of following mass fraction formula components：
50～55 parts of laurate, 50～55 parts of phthalic anhydride, 50～55 parts of trimethylolpropane, 50～55 parts of neopentyl glycol, inclined benzene three
15～20 parts of acid anhydrides, 15～20 parts of pH adjusting agent, 15～20 parts of cosolvent, 5～10 parts of dimethylbenzene, 5～10 parts of epoxy peanut oil,
5～10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, 1～2 part of sulfur-bearing water particle White Mineral Oil, 1～2 part of isophorone, DAA 1
～2 parts.
2. a kind of environmentally friendly coiled material paint according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
50 parts of laurate, 50 parts of phthalic anhydride, 50 parts of trimethylolpropane, 50 parts of neopentyl glycol, 15 parts of trimellitic anhydride, pH adjusting agent
15 parts, 15 parts of cosolvent, 5 parts of dimethylbenzene, 5 parts of epoxy peanut oil, 5 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle
1 part of White Mineral Oil, 1 part of isophorone, 1 part of DAA.
3. a kind of environmentally friendly coiled material paint according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
55 parts of laurate, 55 parts of phthalic anhydride, 55 parts of trimethylolpropane, 55 parts of neopentyl glycol, 20 parts of trimellitic anhydride, pH adjusting agent
20 parts, 20 parts of cosolvent, 10 parts of dimethylbenzene, 10 parts of epoxy peanut oil, 10 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle
2 parts of sub- White Mineral Oil, 2 parts of isophorone, 2 parts of DAA.
4. a kind of environmentally friendly coiled material paint according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
53 parts of laurate, 53 parts of phthalic anhydride, 52 parts of trimethylolpropane, 52 parts of neopentyl glycol, 18 parts of trimellitic anhydride, pH adjusting agent
18 parts, 17 parts of cosolvent, 8 parts of dimethylbenzene, 8 parts of epoxy peanut oil, 7 parts of silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle
1 part of White Mineral Oil, 2 parts of isophorone, 1 part of DAA.
5. the preparation method of a kind of environmentally friendly coiled material paint according to claim 1, it is characterised in that：Comprise the steps：
Step one：Laurate, phthalic anhydride, trimethylolpropane, neopentyl glycol are added into reactor reaction, after reacting 30 minutes, plus
Enter refluxing xylene, be warming up to 200～220 DEG C and react 1.5～2 hours, make intermediate blend 1；
Step 2:Trimellitic anhydride is added in intermediate blend 1,150～160 DEG C is then cooled to and is reacted 1.5～2 hours,
Make intermediate blend 2；
Step 3:PH adjusting agent and cosolvent are added in intermediate blend 2, its ph value is adjusted to into 5～7, be subsequently adding water, made
Into intermediate blend 3；
Step 4:Intermediate blend 3, dimethylbenzene is added into stirring mixing 30～45 minutes in mixer, epoxy flower is subsequently adding
Oil generation, silica ether straight chain aliphatic hydrocarbons emulsified body, sulfur-bearing water particle White Mineral Oil, isophorone and DAA continue to stir 1.5～2
Hour, make finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179094.9A CN106634471A (en) | 2016-12-19 | 2016-12-19 | Eco-friendly coil paint and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179094.9A CN106634471A (en) | 2016-12-19 | 2016-12-19 | Eco-friendly coil paint and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634471A true CN106634471A (en) | 2017-05-10 |
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ID=58834902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611179094.9A Pending CN106634471A (en) | 2016-12-19 | 2016-12-19 | Eco-friendly coil paint and preparation method |
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| Country | Link |
|---|---|
| CN (1) | CN106634471A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236397A (en) * | 2017-06-22 | 2017-10-10 | 合肥永泰新型建材有限公司 | A kind of environmental protection paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627899A (en) * | 2012-04-13 | 2012-08-08 | 阜新恒通氟化学有限公司 | Preparation process for fluorine-containing high light paint |
| CN103555161A (en) * | 2013-10-18 | 2014-02-05 | 陆君军 | Preparation method of environment-friendly water-based alkyd paint |
| CN104072739A (en) * | 2014-06-23 | 2014-10-01 | 西安经建油漆股份有限公司 | Hydrolysis resisting aqueous alkyd resin and preparation method thereof |
-
2016
- 2016-12-19 CN CN201611179094.9A patent/CN106634471A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627899A (en) * | 2012-04-13 | 2012-08-08 | 阜新恒通氟化学有限公司 | Preparation process for fluorine-containing high light paint |
| CN103555161A (en) * | 2013-10-18 | 2014-02-05 | 陆君军 | Preparation method of environment-friendly water-based alkyd paint |
| CN104072739A (en) * | 2014-06-23 | 2014-10-01 | 西安经建油漆股份有限公司 | Hydrolysis resisting aqueous alkyd resin and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236397A (en) * | 2017-06-22 | 2017-10-10 | 合肥永泰新型建材有限公司 | A kind of environmental protection paint and preparation method thereof |
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Application publication date: 20170510 |