CN106634110A - Fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material - Google Patents
Fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material Download PDFInfo
- Publication number
- CN106634110A CN106634110A CN201611106994.0A CN201611106994A CN106634110A CN 106634110 A CN106634110 A CN 106634110A CN 201611106994 A CN201611106994 A CN 201611106994A CN 106634110 A CN106634110 A CN 106634110A
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- Prior art keywords
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- coating material
- wall thermal
- thermal insulating
- heat insulation
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- 239000000463 material Substances 0.000 title claims abstract description 58
- 238000005260 corrosion Methods 0.000 title claims abstract description 26
- 238000009413 insulation Methods 0.000 title claims abstract description 18
- 238000002955 isolation Methods 0.000 title abstract 5
- 239000003973 paint Substances 0.000 title abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000839 emulsion Substances 0.000 claims abstract description 24
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 21
- 239000000919 ceramic Substances 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 poly(butylene succinate) Polymers 0.000 claims abstract description 15
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims abstract description 14
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 claims abstract description 14
- 239000003822 epoxy resin Substances 0.000 claims abstract description 14
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001913 cellulose Substances 0.000 claims abstract description 13
- 229920002678 cellulose Polymers 0.000 claims abstract description 13
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 11
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 11
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 2
- 229920002545 silicone oil Polymers 0.000 claims abstract 2
- 238000000576 coating method Methods 0.000 claims description 44
- 239000011248 coating agent Substances 0.000 claims description 42
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 24
- 238000000465 moulding Methods 0.000 claims description 23
- 230000007797 corrosion Effects 0.000 claims description 22
- 238000004079 fireproofing Methods 0.000 claims description 19
- 230000003628 erosive effect Effects 0.000 claims description 18
- 229920002554 vinyl polymer Polymers 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 13
- 239000005011 phenolic resin Substances 0.000 claims description 13
- 229920001568 phenolic resin Polymers 0.000 claims description 13
- 229910000077 silane Inorganic materials 0.000 claims description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
- 229940106691 bisphenol a Drugs 0.000 claims description 12
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 12
- 229920000447 polyanionic polymer Polymers 0.000 claims description 12
- 239000004631 polybutylene succinate Substances 0.000 claims description 12
- 229920002961 polybutylene succinate Polymers 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 125000005340 bisphosphate group Chemical group 0.000 claims description 9
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- RFXSFVVPCLGHAU-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1.OC1=CC=CC=C1 RFXSFVVPCLGHAU-UHFFFAOYSA-N 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 238000002474 experimental method Methods 0.000 abstract description 2
- 239000003063 flame retardant Substances 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- LAUIXFSZFKWUCT-UHFFFAOYSA-N [4-[2-(4-phosphonooxyphenyl)propan-2-yl]phenyl] dihydrogen phosphate Chemical compound C=1C=C(OP(O)(O)=O)C=CC=1C(C)(C)C1=CC=C(OP(O)(O)=O)C=C1 LAUIXFSZFKWUCT-UHFFFAOYSA-N 0.000 abstract 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000002245 particle Substances 0.000 description 5
- 238000004321 preservation Methods 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
Abstract
The invention discloses a fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material, which is prepared from the following raw materials in parts by weight: 40 to 60 parts of epoxy resin, 10 to 20 parts of molybdenum-modified phenolic resin, 5 to 10 parts of poly(butylene succinate), 10 to 20 parts of EVA emulsion, 3 to 12 parts of hydroxyl silicone oil, 20 to 30 parts of ceramic hollow microspheres, 10 to 20 parts of silicon dioxide hollow spheres, 5 to 10 parts of triallyl isocyanurate, 3 to 8 parts of polyanionic cellulose, 8 to 15 parts of propylene glycol, 5 to 15 parts of hydrotalcite powder, 1 to 3 parts of sodium polyacrylate, 2 to 6 parts of polyvinyl pyrrolidone, 6 to 12 parts of ethylene glycol diglycidyl ether, 0.5 to 1.5 parts of 2,5-di-tert-butylhydroquinone, 5 to 15 parts of vinyl tris(beta-methoxyethoxy) silane, 2 to 5 parts of tetraphenyl bisphenol A diphosphate and 15 to 30 parts of deionized water. The fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material belongs to a wall body heat insulation and thermal isolation paint material obtained through experiments for multiple times, and has the advantages that the good thermal isolation and heat insulation performance is realized; meanwhile, good flame retardant and fireproof performance, weather resistant performance and anti-corrosion performance are realized.
Description
Technical field
The present invention relates to insulation material technical field, and in particular to a kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion
Material.
Background technology
Heat preserving and insulating material can block the transmission of hot-fluid, play heat-insulated and/or insulation, greatly buffer temperature change
Effect.Being applied to the insulating mold coating material of body of wall can in a large number save materials for wall, improve wall insulation performance, save money
Source, reduces environmental pollution.Because the insulating mold coating material of body of wall is mainly used in surface of wall, need to undergo day for a long time
The erosion of the conditions such as solarization, the temperature difference, steam, air-flow, therefore thermal insulation coatings material on the market, generally existing cracking come off it is hidden
Suffer from, in work progress, need add using anticracking grout grid cloth to make up the defect of this respect, to reach body of wall is acted on
The effect of heat-insulation and heat-preservation, and existing thermal insulation coatings Flame Retardancy is not good, and smog is also easy to produce in the combustion environment, using steady
It is qualitative poor.
The content of the invention
It is not enough for prior art, the invention provides a kind of have good heat-insulation and heat-preservation, fire protection flame retarding and corrosion resistant
Erosion/rodent wall thermal insulating insulating moulding coating material.
The present invention solve the technical scheme that adopts of above-mentioned technical problem for：A kind of heat-insulated painting of wall thermal insulating of fireproofing corrosion resistant erosion
Material material, including the raw material of following parts by weight：40 ~ 60 parts of epoxy resin, 10 ~ 20 parts of Mo-phenolic resin, poly-succinic fourth two
5 ~ 10 parts of alcohol ester, 10 ~ 20 parts of EVA emulsions, 3 ~ 12 parts of hydroxy silicon oil, 20 ~ 30 parts of ceramic hollow microballon, hollow silica ball 10
~ 20 parts, 5 ~ 10 parts of Triallyl isocyanurate, 3 ~ 8 parts of polyanion cellulose, 8 ~ 15 parts of propane diols, hydrotalcite powder 5 ~ 15
Part, 1 ~ 3 part of Sodium Polyacrylate, 2 ~ 6 parts of PVP, 6 ~ 12 parts of ethylene glycol diglycidylether, the special fourths of 2,5- bis-
0.5 ~ 1.5 part of base hydroquinones, 5 ~ 15 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Bisphosphate 2
~ 5 parts, 15 ~ 30 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm.
Further, the average grain diameter of the ceramic hollow microballon is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is comprised the following steps：
1）Raw material is on the waiting list according to the parts by weight；
2）Epoxy resin, Mo-phenolic resin, hydroxy silicon oil, poly butylene succinate, EVA emulsions, propane diols are placed in into reaction
In kettle, 50 DEG C are warming up to after stirring；
3）Nitrogen protection will be led in reactor, and add Triallyl isocyanurate, 1 ~ 2h of insulated and stirred at 70 ~ 80 DEG C；
It is subsequently adding vinyl three ('beta '-methoxy ethyoxyl) silane, 1 ~ 2h of insulated and stirred；Add the deionized water of half amount and be incubated
0.5 ~ 1h of high-speed stirred, discharging, obtains mixed emulsion material；
4）Remaining deionized water is placed in reactor, PVP and ethylene glycol diglycidylether is added,
Stir at 60 ~ 70 DEG C, add ceramic hollow microballon, hollow silica ball, polyanion cellulose, hydrotalcite powder and
Sodium Polyacrylate, insulation high-speed stirred to uniform state adds the mixed emulsion material and 2,5- di-tert-butyl of step 3 gained to benzene
Diphenol and tetraphenyl（Bisphenol-A）Bisphosphate, 1 ~ 2h of insulated and stirred obtains just coating material；
5）The clipped mulser of first coating material of step 4 gained is processed into 0.5 ~ 1h, discharging obtains the wall thermal insulating of the present invention
Insulating moulding coating material.
Compared with prior art, what the present invention possessed has the beneficial effect that：
The present invention is obtained for a kind of Jing many experiments has good heat preservation and insulation, while preferable fire-retardant fireproof can be kept
The wall thermal insulating insulating moulding coating material of property, weatherability and corrosion resistance；Processing is easy to use, good with the interface compatibility of body of wall,
Tack is excellent, and interior over a long time after coating is not in cracking obscission, while coating material system stability is good；Can apply
In exterior surface of wall, being equally applicable for pipeline etc. needs the equipment surface of heat-insulation and heat-preservation.
Specific embodiment
With reference to specific embodiment, the present invention is described further.
Embodiment 1：A kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion, including the raw material of following parts by weight：
50 parts of epoxy resin, 15 parts of Mo-phenolic resin, 8 parts of poly butylene succinate, 15 parts of EVA emulsions, 7 parts of hydroxy silicon oil, ceramics
25 parts of cenosphere, 15 parts of hollow silica ball, 7 parts of Triallyl isocyanurate, 6 parts of polyanion cellulose, the third two
11 parts of alcohol, 10 parts of hydrotalcite powder, 2 parts of Sodium Polyacrylate, 4 parts of PVP, 9 parts of ethylene glycol diglycidylether,
1 part of 2,5- ditert-butylhydro quinones, 10 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Diphosphonic acid
3 parts of ester, 22 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm, the ceramic hollow microballon it is flat
Particle diameter is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is comprised the following steps：
1）Raw material is on the waiting list according to the parts by weight；
2）Epoxy resin, Mo-phenolic resin, hydroxy silicon oil, poly butylene succinate, EVA emulsions, propane diols are placed in into reaction
In kettle, 50 DEG C are warming up to after stirring；
3）Nitrogen protection will be led in reactor, and add Triallyl isocyanurate, insulated and stirred 1.5h at 75 DEG C；Then
Add vinyl three ('beta '-methoxy ethyoxyl) silane, insulated and stirred 1.5h；Add the deionized water of half amount and be incubated at a high speed
Stirring 45min, discharging obtains mixed emulsion material；
4）Remaining deionized water is placed in reactor, PVP and ethylene glycol diglycidylether is added,
Stir at 65 DEG C, add ceramic hollow microballon, hollow silica ball, polyanion cellulose, hydrotalcite powder and gather
PAA, insulation high-speed stirred to uniform state adds the mixed emulsion material and 2,5- di-tert-butyl of step 3 gained to benzene two
Phenol and tetraphenyl（Bisphenol-A）Bisphosphate, insulated and stirred 1.5h obtains just coating material；
5）The clipped mulser of first coating material of step 4 gained is processed into 45min, discharging obtain the wall thermal insulating of the present invention every
Hot coating material.
Embodiment 2：A kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion, including the raw material of following parts by weight：
40 parts of epoxy resin, 10 parts of Mo-phenolic resin, 5 parts of poly butylene succinate, 10 parts of EVA emulsions, 3 parts of hydroxy silicon oil, ceramics
20 parts of cenosphere, 10 parts of hollow silica ball, 5 parts of Triallyl isocyanurate, 3 parts of polyanion cellulose, the third two
8 parts of alcohol, 5 parts of hydrotalcite powder, 1 part of Sodium Polyacrylate, 2 parts of PVP, 6 parts of ethylene glycol diglycidylether, 2,
0.5 part of 5- ditert-butylhydro quinones, 5 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Bisphosphate
2 parts, 15 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm, the ceramic hollow microballon it is flat
Particle diameter is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is comprised the following steps：
1）Raw material is on the waiting list according to the parts by weight；
2）Epoxy resin, Mo-phenolic resin, hydroxy silicon oil, poly butylene succinate, EVA emulsions, propane diols are placed in into reaction
In kettle, 50 DEG C are warming up to after stirring；
3）Nitrogen protection will be led in reactor, and add Triallyl isocyanurate, insulated and stirred 2h at 70 DEG C；Then plus
Enter vinyl three ('beta '-methoxy ethyoxyl) silane, insulated and stirred 2h；Add the deionized water of half amount and be incubated high-speed stirred
1h, discharging, obtains mixed emulsion material；
4）Remaining deionized water is placed in reactor, PVP and ethylene glycol diglycidylether is added,
Stir at 60 DEG C, add ceramic hollow microballon, hollow silica ball, polyanion cellulose, hydrotalcite powder and gather
PAA, insulation high-speed stirred to uniform state adds the mixed emulsion material and 2,5- di-tert-butyl of step 3 gained to benzene two
Phenol and tetraphenyl（Bisphenol-A）Bisphosphate, insulated and stirred 2h obtains just coating material；
5）The clipped mulser of first coating material of step 4 gained is processed into 1h, the wall thermal insulating that discharging obtains the present invention is heat-insulated
Coating material.
Embodiment 3：A kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion, including the raw material of following parts by weight：
60 parts of epoxy resin, 20 parts of Mo-phenolic resin, 10 parts of poly butylene succinate, 20 parts of EVA emulsions, 12 parts of hydroxy silicon oil, pottery
30 parts of porcelain cenosphere, 20 parts of hollow silica ball, 10 parts of Triallyl isocyanurate, 8 parts of polyanion cellulose, third
15 parts of glycol, 15 parts of hydrotalcite powder, 3 parts of Sodium Polyacrylate, 6 parts of PVP, ethylene glycol diglycidylether 12
Part, 1.5 parts of 2,5- ditert-butylhydro quinones, 15 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Two
5 parts of phosphate, 30 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm, the ceramic hollow microballon it is flat
Particle diameter is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is comprised the following steps：
1）Raw material is on the waiting list according to the parts by weight；
2）Epoxy resin, Mo-phenolic resin, hydroxy silicon oil, poly butylene succinate, EVA emulsions, propane diols are placed in into reaction
In kettle, 50 DEG C are warming up to after stirring；
3）Nitrogen protection will be led in reactor, and add Triallyl isocyanurate, insulated and stirred 1h at 80 DEG C；Then plus
Enter vinyl three ('beta '-methoxy ethyoxyl) silane, insulated and stirred 1h；Add the deionized water of half amount and be incubated high-speed stirred
0.5h, discharging, obtains mixed emulsion material；
4）Remaining deionized water is placed in reactor, PVP and ethylene glycol diglycidylether is added,
Stir at 70 DEG C, add ceramic hollow microballon, hollow silica ball, polyanion cellulose, hydrotalcite powder and gather
PAA, insulation high-speed stirred to uniform state adds the mixed emulsion material and 2,5- di-tert-butyl of step 3 gained to benzene two
Phenol and tetraphenyl（Bisphenol-A）Bisphosphate, insulated and stirred 1h obtains just coating material；
5）The clipped mulser of first coating material of step 4 gained is processed into 0.5h, discharging obtain the wall thermal insulating of the present invention every
Hot coating material.
Embodiment 4：A kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion, including the raw material of following parts by weight：
40 parts of epoxy resin, 20 parts of Mo-phenolic resin, 5 parts of poly butylene succinate, 20 parts of EVA emulsions, 3 parts of hydroxy silicon oil, ceramics
30 parts of cenosphere, 10 parts of hollow silica ball, 10 parts of Triallyl isocyanurate, 3 parts of polyanion cellulose, the third two
15 parts of alcohol, 5 parts of hydrotalcite powder, 3 parts of Sodium Polyacrylate, 2 parts of PVP, 12 parts of ethylene glycol diglycidylether,
0.5 part of 2,5- ditert-butylhydro quinones, 15 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Two phosphorus
2 parts of acid esters, 30 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm, the ceramic hollow microballon it is flat
Particle diameter is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is with embodiment 1.
Embodiment 5：A kind of wall thermal insulating insulating moulding coating material of fireproofing corrosion resistant erosion, including the raw material of following parts by weight：
55 parts of epoxy resin, 12 parts of Mo-phenolic resin, 6 parts of poly butylene succinate, 19 parts of EVA emulsions, 5 parts of hydroxy silicon oil, ceramics
23 parts of cenosphere, 18 parts of hollow silica ball, 7 parts of Triallyl isocyanurate, 7 parts of polyanion cellulose, the third two
10 parts of alcohol, 12 parts of hydrotalcite powder, 2 parts of Sodium Polyacrylate, 3 parts of PVP, 10 parts of ethylene glycol diglycidylether,
1 part of 2,5- ditert-butylhydro quinones, 12 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）Diphosphonic acid
4 parts of ester, 20 parts of deionized water.
Further, the average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm, the ceramic hollow microballon it is flat
Particle diameter is 10 ~ 15 μm.
A kind of wall thermal insulating insulating moulding coating material of described fireproofing corrosion resistant erosion, its preparation method is with embodiment 1.
Jing is tested, a kind of wall thermal insulating insulating moulding coating material coating institute of fireproofing corrosion resistant erosion obtained by above-described embodiment 1-5
Form coating surface smooth, hardness is more than 3H, 0 grade of adhesive force, compression strength is more than 20Mpa, and the heat-insulated temperature difference is more than 15 DEG C, leads
Hot coefficient is less than 0.07w/mk.
Above-described embodiment is only the better embodiment of the present invention, and its specific descriptions can not be interpreted as to patent of the present invention
The restriction of scope, as long as the technical scheme that those skilled in the art are obtained in the form of equivalent or equivalent transformation, all falls within
Within protection scope of the present invention.
Claims (5)
1. the wall thermal insulating insulating moulding coating material that a kind of fireproofing corrosion resistant loses, it is characterised in that including the raw material of following parts by weight：
40 ~ 60 parts of epoxy resin, 10 ~ 20 parts of Mo-phenolic resin, 5 ~ 10 parts of poly butylene succinate, 10 ~ 20 parts of EVA emulsions, hydroxyl
3 ~ 12 parts of silicone oil, 20 ~ 30 parts of ceramic hollow microballon, 10 ~ 20 parts of hollow silica ball, Triallyl isocyanurate 5 ~ 10
Part, 3 ~ 8 parts of polyanion cellulose, 8 ~ 15 parts of propane diols, 5 ~ 15 parts of hydrotalcite powder, 1 ~ 3 part of Sodium Polyacrylate, polyvinyl pyrrole
2 ~ 6 parts of pyrrolidone, 6 ~ 12 parts of ethylene glycol diglycidylether, 0.5 ~ 1.5 part of 2,5- ditert-butylhydro quinones, vinyl three
5 ~ 15 parts of ('beta '-methoxy ethyoxyl) silane, tetraphenyl（Bisphenol-A）2 ~ 5 parts of bisphosphate, 15 ~ 30 parts of deionized water.
2. the wall thermal insulating insulating moulding coating material that a kind of fireproofing corrosion resistant according to claim 1 loses, it is characterised in that：Including
The raw material of following parts by weight：50 parts of epoxy resin, 15 parts of Mo-phenolic resin, 8 parts of poly butylene succinate, EVA emulsions 15
Part, 7 parts of hydroxy silicon oil, 25 parts of ceramic hollow microballon, 15 parts of hollow silica ball, 7 parts of Triallyl isocyanurate, poly- the moon
6 parts of ion fiber element, 11 parts of propane diols, 10 parts of hydrotalcite powder, 2 parts of Sodium Polyacrylate, 4 parts of PVP, second two
9 parts of alcohol diglycidyl ether, 1 part of 2,5- ditert-butylhydro quinones, 10 parts of vinyl three ('beta '-methoxy ethyoxyl) silane, four
Phenyl（Bisphenol-A）3 parts of bisphosphate, 22 parts of deionized water.
3. the wall thermal insulating insulating moulding coating material that a kind of fireproofing corrosion resistant according to claim 1 and 2 loses, it is characterised in that：
The average grain diameter of the hollow silica ball is 0.5 ~ 1.5 μm.
4. the wall thermal insulating insulating moulding coating material that a kind of fireproofing corrosion resistant according to claim 1 and 2 loses, it is characterised in that：
The average grain diameter of the ceramic hollow microballon is 10 ~ 15 μm.
5. described in claim 1 or 2 a kind of fireproofing corrosion resistant erosion wall thermal insulating insulating moulding coating material preparation method, its feature
It is to comprise the following steps：
1）Raw material is on the waiting list according to the parts by weight；
2）Epoxy resin, Mo-phenolic resin, hydroxy silicon oil, poly butylene succinate, EVA emulsions, propane diols are placed in into reaction
In kettle, 50 DEG C are warming up to after stirring；
3）Nitrogen protection will be led in reactor, and add Triallyl isocyanurate, 1 ~ 2h of insulated and stirred at 70 ~ 80 DEG C；
It is subsequently adding vinyl three ('beta '-methoxy ethyoxyl) silane, 1 ~ 2h of insulated and stirred；Add the deionized water of half amount and be incubated
0.5 ~ 1h of high-speed stirred, discharging, obtains mixed emulsion material；
4）Remaining deionized water is placed in reactor, PVP and ethylene glycol diglycidylether is added,
Stir at 60 ~ 70 DEG C, add ceramic hollow microballon, hollow silica ball, polyanion cellulose, hydrotalcite powder and
Sodium Polyacrylate, insulation high-speed stirred to uniform state adds the mixed emulsion material and 2,5- di-tert-butyl of step 3 gained to benzene
Diphenol and tetraphenyl（Bisphenol-A）Bisphosphate, 1 ~ 2h of insulated and stirred obtains just coating material；
5）The clipped mulser of first coating material of step 4 gained is processed into 0.5 ~ 1h, discharging obtains the wall thermal insulating of the present invention
Insulating moulding coating material.
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| CN201611106994.0A CN106634110A (en) | 2016-12-06 | 2016-12-06 | Fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material |
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| CN111662599A (en) * | 2020-05-11 | 2020-09-15 | 江苏理想空间装饰工程股份有限公司 | Sound-insulation heat-preservation self-cleaning wall paint and preparation method thereof |
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| CN111662599A (en) * | 2020-05-11 | 2020-09-15 | 江苏理想空间装饰工程股份有限公司 | Sound-insulation heat-preservation self-cleaning wall paint and preparation method thereof |
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