CN106634062A - Modifier for filling material and preparation method of modifier - Google Patents

Modifier for filling material and preparation method of modifier Download PDF

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Publication number
CN106634062A
CN106634062A CN201611217888.XA CN201611217888A CN106634062A CN 106634062 A CN106634062 A CN 106634062A CN 201611217888 A CN201611217888 A CN 201611217888A CN 106634062 A CN106634062 A CN 106634062A
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CN
China
Prior art keywords
parts
acid
diatomite
methane
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611217888.XA
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Chinese (zh)
Inventor
贺艺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinzhou Xinghuo Planning Office
Original Assignee
Qinzhou Xinghuo Planning Office
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinzhou Xinghuo Planning Office filed Critical Qinzhou Xinghuo Planning Office
Priority to CN201611217888.XA priority Critical patent/CN106634062A/en
Publication of CN106634062A publication Critical patent/CN106634062A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08Treatment with low-molecular-weight non-polymer organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12Treatment with organosilicon compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a modifier for a filling material and a preparation method of the modifier. The modifier is prepared from the following formula ingredients in parts by mass: 6 to 10 parts of diatomite, 5 to 7 parts of water glass, 10 to 12 parts of glass fiber fabric, 4 to 6 parts of aluminum sulfate, 2 to 4 parts of methane-siliconic acid, 1 to 3 parts of oxidants, 6 to 8 parts of tannic acid, 7 to 9 parts of carbon black, 6 to 10 parts of titanium dioxide, 2 to 4 parts of natural calcium metasilicate, 6 to 8 parts of zinc stearate and 7 to 9 parts of calcium carbonate. The filling material is subjected to modification coating treatment; the quality of the filling material subjected to modification coating is stable; the difference between a water absorption rate and a water content rate is smaller; the compatibility with other ingredients is high; the compatibility of the materials with a formula is greatly expanded; in addition, the filling material prepared by the method has a low water absorption rate, no surface defect and stable quality.

Description

A kind of filler modifying agent and preparation method thereof
Technical field
The present invention relates to modifying agent technical field, in particular to a kind of filler modifying agent and preparation method thereof.
Background technology
Flyash, silicon ash, slag, building waste, wood chip, glass bead etc. be organic and inorganic filler is widely used building materials In (magnesite material, cement products etc.) product, play reduction density, increase toughness, reduce the effect such as cracking, reduces cost, and And twice laid, energy-conserving and environment-protective are realized, meet Green energy-saving buildings development topic.Yet with filler autogenous extensively, contain The performance differences such as water rate, water absorption rate are larger, easily cause quality of item unstable.
During filler use, it may appear that the phenomenon with the bonding component poor compatibility such as magnesite material, cement, or even go out Existing filler and cement modifier make a difference slip operability chemical reaction phenomenon.Cause material group in such as whipping process Poly-, slip water requirement difference is big, the fluctuation of core modifying agent proportioning is big, slip setting time is unstable, the loose, product in product local A series of problems, such as surface defect.Product quality is had a strong impact on, product percent of pass is reduced, standardization, large-scale production is hindered.
The content of the invention
The invention provides a kind of filler modifying agent and preparation method thereof, of the invention that filler is modified at cladding Reason, the packing quality after the parcel that is modified is stable, water absorption rate and moisture content difference are less, good with other component compatibilities, greatly The compatibility of material and formula is expanded;And the filler water absorption rate of use present invention preparation is little, surface zero defect, and quality is steady It is fixed.
For achieving the above object, the present invention provides following technical scheme:
A kind of filler modifying agent and preparation method thereof, is made up of following mass fraction formula components:Diatomite 6-10 parts, Waterglass 5-7 parts, glass-fiber-fabric 10-12 parts, aluminum sulfate 4-6 parts, methane-siliconic acid 2-4 parts, oxidant 1-3 parts, tannic acid 6-8 parts, carbon Black 7-9 parts, titanium dioxide 6-10 parts, natural calcium metasilicate 2-4 parts, zinc stearate 6-8 parts, calcium carbonate 7-9 parts.
Further:It is made up of following mass fraction formula components:6 parts of diatomite, 5 parts of waterglass, 10 parts of glass-fiber-fabric, sulfuric acid 4 parts of aluminium, 2 parts of methane-siliconic acid, 1 part of oxidant, 6 parts of tannic acid, 7 parts of carbon black, 6 parts of titanium dioxide, 2 parts of natural calcium metasilicate, stearic acid 6 parts of zinc, 7 parts of calcium carbonate.
Further:It is made up of following mass fraction formula components:8 parts of diatomite, 6 parts of waterglass, 11 parts of glass-fiber-fabric, sulfuric acid 5 parts of aluminium, 3 parts of methane-siliconic acid, 2 parts of oxidant, 7 parts of tannic acid, 8 parts of carbon black, 8 parts of titanium dioxide, 3 parts of natural calcium metasilicate, stearic acid 7 parts of zinc, 8 parts of calcium carbonate.
Further:It is made up of following mass fraction formula components:10 parts of diatomite, 7 parts of waterglass, 12 parts of glass-fiber-fabric, sulphur 6 parts of sour aluminium, 4 parts of methane-siliconic acid, 3 parts of oxidant, 8 parts of tannic acid, 9 parts of carbon black, 10 parts of titanium dioxide, 4 parts of natural calcium metasilicate, tristearin 8 parts of sour zinc, 9 parts of calcium carbonate.
Further:Preparation method comprises the steps:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by diatomite, waterglass, glass-fiber-fabric, aluminum sulfate, methane-siliconic acid, tannic acid, carbon black, titanium dioxide, it is natural partially Calcium silicates, zinc stearate, calcium carbonate stir prepared semi-finished product;
Step 3, by obtained in step 2 semi-finished product add oxidant be well mixed, under the conditions of 50~80 DEG C, be dried to and contain Water rate < 20%.
The invention has the beneficial effects as follows:The present invention is modified cladding process to filler, the packing quality after the parcel that is modified Stable, water absorption rate and moisture content difference are less, good with other component compatibilities, are greatly expanded material compatible with formula Property;And the filler water absorption rate of use present invention preparation is little, surface zero defect, and steady quality.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of filler modifying agent is made up of following mass fraction formula components:Diatomite 6-10 parts, waterglass 5-7 parts, Glass-fiber-fabric 10-12 parts, aluminum sulfate 4-6 parts, methane-siliconic acid 2-4 parts, oxidant 1-3 parts, tannic acid 6-8 parts, carbon black 7-9 parts, titanium white Powder 6-10 parts, natural calcium metasilicate 2-4 parts, zinc stearate 6-8 parts, calcium carbonate 7-9 parts.
Embodiment two:
A kind of filler modifying agent is made up of following mass fraction formula components:6 parts of diatomite, 5 parts of waterglass, glass-fiber-fabric 10 parts, 4 parts of aluminum sulfate, 2 parts of methane-siliconic acid, 1 part of oxidant, 6 parts of tannic acid, 7 parts of carbon black, 6 parts of titanium dioxide, natural calcium metasilicate 2 Part, 6 parts of zinc stearate, 7 parts of calcium carbonate.
Embodiment three:
A kind of filler modifying agent is made up of following mass fraction formula components:8 parts of diatomite, 6 parts of waterglass, glass-fiber-fabric 11 parts, 5 parts of aluminum sulfate, 3 parts of methane-siliconic acid, 2 parts of oxidant, 7 parts of tannic acid, 8 parts of carbon black, 8 parts of titanium dioxide, natural calcium metasilicate 3 Part, 7 parts of zinc stearate, 8 parts of calcium carbonate.
Example IV:
A kind of filler modifying agent is made up of following mass fraction formula components:10 parts of diatomite, 7 parts of waterglass, glass 12 parts of cloth, 6 parts of aluminum sulfate, 4 parts of methane-siliconic acid, 3 parts of oxidant, 8 parts of tannic acid, 9 parts of carbon black, 10 parts of titanium dioxide, natural metasilicic acid 4 parts of calcium, 8 parts of zinc stearate, 9 parts of calcium carbonate.
Embodiment five:
A kind of preparation method of filler modifying agent comprises the steps:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by diatomite, waterglass, glass-fiber-fabric, aluminum sulfate, methane-siliconic acid, tannic acid, carbon black, titanium dioxide, it is natural partially Calcium silicates, zinc stearate, calcium carbonate stir prepared semi-finished product;
Step 3, by obtained in step 2 semi-finished product add oxidant be well mixed, under the conditions of 50~80 DEG C, be dried to and contain Water rate < 20%.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of filler modifying agent, it is characterised in that:It is made up of following mass fraction formula components:
Diatomite 6-10 parts, waterglass 5-7 parts, glass-fiber-fabric 10-12 parts, aluminum sulfate 4-6 parts, methane-siliconic acid 2-4 parts, oxidant 1- 3 parts, tannic acid 6-8 parts, carbon black 7-9 parts, titanium dioxide 6-10 parts, natural calcium metasilicate 2-4 parts, zinc stearate 6-8 parts, calcium carbonate 7- 9 parts.
2. a kind of filler modifying agent according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
6 parts of diatomite, 5 parts of waterglass, 10 parts of glass-fiber-fabric, 4 parts of aluminum sulfate, 2 parts of methane-siliconic acid, 1 part of oxidant, 6 parts of tannic acid, carbon Black 7 parts, 6 parts of titanium dioxide, 2 parts of natural calcium metasilicate, 6 parts of zinc stearate, 7 parts of calcium carbonate.
3. a kind of filler modifying agent according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
8 parts of diatomite, 6 parts of waterglass, 11 parts of glass-fiber-fabric, 5 parts of aluminum sulfate, 3 parts of methane-siliconic acid, 2 parts of oxidant, 7 parts of tannic acid, carbon Black 8 parts, 8 parts of titanium dioxide, 3 parts of natural calcium metasilicate, 7 parts of zinc stearate, 8 parts of calcium carbonate.
4. a kind of filler modifying agent according to claim 1, it is characterised in that:By following mass fraction formula components group Into:
10 parts of diatomite, 7 parts of waterglass, 12 parts of glass-fiber-fabric, 6 parts of aluminum sulfate, 4 parts of methane-siliconic acid, 3 parts of oxidant, 8 parts of tannic acid, 9 parts of carbon black, 10 parts of titanium dioxide, 4 parts of natural calcium metasilicate, 8 parts of zinc stearate, 9 parts of calcium carbonate.
5. a kind of a kind of preparation method of filler modifying agent according to claim 1, it is characterised in that:Including following step Suddenly:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by diatomite, waterglass, glass-fiber-fabric, aluminum sulfate, methane-siliconic acid, tannic acid, carbon black, titanium dioxide, natural metasilicic acid Calcium, zinc stearate, calcium carbonate stir prepared semi-finished product;
Step 3, by obtained in step 2 semi-finished product add oxidant be well mixed, under the conditions of 50~80 DEG C, be dried to moisture content < 20%.
CN201611217888.XA 2016-12-26 2016-12-26 Modifier for filling material and preparation method of modifier Pending CN106634062A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611217888.XA CN106634062A (en) 2016-12-26 2016-12-26 Modifier for filling material and preparation method of modifier

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Application Number Priority Date Filing Date Title
CN201611217888.XA CN106634062A (en) 2016-12-26 2016-12-26 Modifier for filling material and preparation method of modifier

Publications (1)

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CN106634062A true CN106634062A (en) 2017-05-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116875133A (en) * 2023-08-10 2023-10-13 唐山科鸿新材料有限公司 Diatomite-containing heat-insulating coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1781871A (en) * 2004-11-30 2006-06-07 李丰凡 Environment friendly composite material and its preparing method
CN103553700A (en) * 2013-10-29 2014-02-05 新疆华莎能源股份有限公司 Environment-friendly magnesium oxide foaming material
CN105293991A (en) * 2015-10-16 2016-02-03 卓达新材料科技集团威海股份有限公司 Modifying agent for filler and preparation method of filler

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1781871A (en) * 2004-11-30 2006-06-07 李丰凡 Environment friendly composite material and its preparing method
CN103553700A (en) * 2013-10-29 2014-02-05 新疆华莎能源股份有限公司 Environment-friendly magnesium oxide foaming material
CN105293991A (en) * 2015-10-16 2016-02-03 卓达新材料科技集团威海股份有限公司 Modifying agent for filler and preparation method of filler

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116875133A (en) * 2023-08-10 2023-10-13 唐山科鸿新材料有限公司 Diatomite-containing heat-insulating coating and preparation method thereof

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