CN106633822A - Nylon nanometer material and preparation method thereof - Google Patents
Nylon nanometer material and preparation method thereof Download PDFInfo
- Publication number
- CN106633822A CN106633822A CN201611100883.9A CN201611100883A CN106633822A CN 106633822 A CN106633822 A CN 106633822A CN 201611100883 A CN201611100883 A CN 201611100883A CN 106633822 A CN106633822 A CN 106633822A
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- nylon
- medical stone
- boehmite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a nylon nanometer material and a preparation method thereof. The nylon nanometer material is prepared from the following formula ingredients in parts by mass: 60 to 100 parts of nylon resin, 2 to 3 parts of lubricating agents, 20 to 30 parts of nanometer powder body, 7 to 9 parts of nanometer medical stone, 6 to 8 parts of polyfluortetraethylene, 5 to 15 parts of titanium pigment, 6 to 10 parts of potassium feldspar, 6 to 8 parts of cerium nitrate, 2 to 4 parts of compatilizers, 15 to 25 parts of chopped glass fiber, 5 to 7 parts of modified nanometer boehmite, 5 to 7 parts of polylactic acid and 1 to 2 parts of antioxidants. The nylon nanometer material has the advantages that the pressure-resistant intensity and the antibacterial property of the nylon materials are greatly improved; the operation process is simple; the prepared composite material has excellent performance, and is suitable for industrial production.
Description
Technical field
The present invention relates to artificial material field, in particular to a kind of nylon nano material and preparation method thereof.
Background technology
Nano medical stone be it is a kind of with biologically active, it is apparent for white or grey powder compound mineral, particle diameter 55
～95nm, specific surface area is 30m2/g～80m2/g.With developing rapidly for electronic apparatus and automobile industry, for engineering plastics
Functionalization require gradually step up, especially at the aspect such as mechanical strength and antibiotic property.Nano medical stone has loose structure, filling
The mechanical performance of material can be greatly improved after engineering plastics.In addition nano medical stone powder has stronger suction to pigment and bacterium
Attached ability, makes material have considerable antibiotic property.More traditional addition talcum powder or pearl filler are compared, and nano medical stone is being carried
High compressive strength, while giving material antibiotic property production cost is reduced.Nylon Nanocomposite tool prepared by the present invention
The features such as having resistance to compression, antibacterial, can be applicable to the association areas such as electronic apparatus and purification of water quality.
The content of the invention
The invention provides a kind of nylon nano material and preparation method thereof, of the invention that the anti-of nylon material greatly improved
Compressive Strength and antibiotic property, operating procedure is simple, and prepared composite property is superior, is suitable to industrialized production.
For achieving the above object, the present invention provides following technical scheme：
A kind of nylon nano material and preparation method thereof, is made up of following mass fraction formula components：Nylon resin 60-
100 parts, lubricant 2-3 parts, nano-powder 20-30 parts, nano medical stone 7-9 parts, polytetrafluoroethylene (PTFE) 6-8 parts, titanium dioxide 5-15
Part, potassium feldspar 6-10 parts, cerous nitrate 6-8 parts, compatilizer 2-4 parts, short glass fiber 15-25 parts, modified Nano boehmite 5-7
Part, PLA 5-7 parts, antioxidant 1-2 parts.
Further：It is made up of following mass fraction formula components：60 parts of nylon resin, 2 parts of lubricant, nano-powder 20
Part, 7 parts of nano medical stone, 6 parts of polytetrafluoroethylene (PTFE), 5 parts of titanium dioxide, 6 parts of potassium feldspar, 6 parts of cerous nitrate, 2 parts of compatilizer, chopped glass
15 parts of glass fiber, 5 parts of modified Nano boehmite, 5 parts of PLA, 1 part of antioxidant.
Further：It is made up of following mass fraction formula components：80 parts of nylon resin, 2.5 parts of lubricant, nano-powder 25
Part, 8 parts of nano medical stone, 7 parts of polytetrafluoroethylene (PTFE), 10 parts of titanium dioxide, 8 parts of potassium feldspar, 7 parts of cerous nitrate, 3 parts of compatilizer, be chopped
20 parts of glass fibre, 6 parts of modified Nano boehmite, 6 parts of PLA, 1.5 parts of antioxidant.
Further：It is made up of following mass fraction formula components：100 parts of nylon resin, 3 parts of lubricant, nano-powder 30
Part, 9 parts of nano medical stone, 8 parts of polytetrafluoroethylene (PTFE), 15 parts of titanium dioxide, 10 parts of potassium feldspar, 8 parts of cerous nitrate, 4 parts of compatilizer, be chopped
25 parts of glass fibre, 7 parts of modified Nano boehmite, 7 parts of PLA, 2 parts of antioxidant.
Further：Preparation method of the present invention has following steps：
Step one, by nylon resin, nano medical stone, antioxidant, lubricant and compatilizer proportional assignment；
Step 2, nano medical stone is carried out in modified Nano boehmite 10～35min of surface treatment；
Step 3, medical stone and step (1) that above-mentioned steps (2) process is obtained are placed in high-speed mixer dispersion；
Step 4, by after dispersion raw material add surplus stock be well mixed after by extruder extrude；
Step 5, raw material Jing after melting, plasticizing, extrusion, cooling, pelletizing and packaging, finished product.
The invention has the beneficial effects as follows：
1st, the present invention greatly improved the compression strength and antibiotic property of nylon material；
2nd, operating procedure is simple, and prepared composite property is superior, is suitable to industrialized production.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of nylon nano material is made up of following mass fraction formula components：Nylon resin 60-100 parts, lubricant 2-3
Part, nano-powder 20-30 parts, nano medical stone 7-9 parts, polytetrafluoroethylene (PTFE) 6-8 parts, titanium dioxide 5-15 parts, potassium feldspar 6-10 parts,
Cerous nitrate 6-8 parts, compatilizer 2-4 parts, short glass fiber 15-25 parts, modified Nano boehmite 5-7 parts, PLA 5-7 parts,
Antioxidant 1-2 parts.
Embodiment two：
A kind of nylon nano material is made up of following mass fraction formula components：60 parts of nylon resin, 2 parts of lubricant, receive
20 parts of ground rice body, 7 parts of nano medical stone, 6 parts of polytetrafluoroethylene (PTFE), 5 parts of titanium dioxide, 6 parts of potassium feldspar, 6 parts of cerous nitrate, compatilizer 2
Part, 15 parts of short glass fiber, 5 parts of modified Nano boehmite, 5 parts of PLA, 1 part of antioxidant.
Embodiment three：
A kind of nylon nano material is made up of following mass fraction formula components：80 parts of nylon resin, 2.5 parts of lubricant,
It is 25 parts of nano-powder, 8 parts of nano medical stone, 7 parts of polytetrafluoroethylene (PTFE), 10 parts of titanium dioxide, 8 parts of potassium feldspar, 7 parts of cerous nitrate, compatible
3 parts of agent, 20 parts of short glass fiber, 6 parts of modified Nano boehmite, 6 parts of PLA, 1.5 parts of antioxidant.
Example IV：
A kind of nylon nano material is made up of following mass fraction formula components：100 parts of nylon resin, 3 parts of lubricant, receive
30 parts of ground rice body, 9 parts of nano medical stone, 8 parts of polytetrafluoroethylene (PTFE), 15 parts of titanium dioxide, 10 parts of potassium feldspar, 8 parts of cerous nitrate, compatilizer
4 parts, 25 parts of short glass fiber, 7 parts of modified Nano boehmite, 7 parts of PLA, 2 parts of antioxidant.
Embodiment five：
A kind of preparation method preparation method of nylon nano material comprises the steps：
Step one, by nylon resin, nano medical stone, antioxidant, lubricant and compatilizer proportional assignment；
Step 2, nano medical stone is carried out in modified Nano boehmite 10～35min of surface treatment；
Step 3, medical stone and step (1) that above-mentioned steps (2) process is obtained are placed in high-speed mixer dispersion；
Step 4, by after dispersion raw material add surplus stock be well mixed after by extruder extrude；
Step 5, raw material Jing after melting, plasticizing, extrusion, cooling, pelletizing and packaging, finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of nylon nano material, it is characterised in that：It is made up of following mass fraction formula components：
Nylon resin 60-100 parts, lubricant 2-3 parts, nano-powder 20-30 parts, nano medical stone 7-9 parts, polytetrafluoroethylene (PTFE) 6-
8 parts, titanium dioxide 5-15 parts, potassium feldspar 6-10 parts, cerous nitrate 6-8 parts, compatilizer 2-4 parts, short glass fiber 15-25 parts, change
Property nm boehmite 5-7 part, PLA 5-7 parts, antioxidant 1-2 parts.
2. a kind of nylon nano material according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
60 parts of nylon resin, 2 parts of lubricant, 20 parts of nano-powder, 7 parts of nano medical stone, 6 parts of polytetrafluoroethylene (PTFE), titanium dioxide 5
Part, 6 parts of potassium feldspar, 6 parts of cerous nitrate, 2 parts of compatilizer, 15 parts of short glass fiber, 5 parts of modified Nano boehmite, PLA 5
Part, 1 part of antioxidant.
3. a kind of nylon nano material according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
80 parts of nylon resin, 2.5 parts of lubricant, 25 parts of nano-powder, 8 parts of nano medical stone, 7 parts of polytetrafluoroethylene (PTFE), titanium dioxide
10 parts, 8 parts of potassium feldspar, 7 parts of cerous nitrate, 3 parts of compatilizer, 20 parts of short glass fiber, 6 parts of modified Nano boehmite, PLA 6
Part, 1.5 parts of antioxidant.
4. a kind of nylon nano material according to claim 1, it is characterised in that：By following mass fraction formula components group
Into：
100 parts of nylon resin, 3 parts of lubricant, 30 parts of nano-powder, 9 parts of nano medical stone, 8 parts of polytetrafluoroethylene (PTFE), titanium dioxide 15
Part, 10 parts of potassium feldspar, 8 parts of cerous nitrate, 4 parts of compatilizer, 25 parts of short glass fiber, 7 parts of modified Nano boehmite, PLA 7
Part, 2 parts of antioxidant.
5. a kind of a kind of preparation method of nylon nano material according to claim 1, it is characterised in that：Including following step
Suddenly：
Step one, by nylon resin, nano medical stone, antioxidant, lubricant and compatilizer proportional assignment；
Step 2, nano medical stone is carried out in modified Nano boehmite 10～35min of surface treatment；
Step 3, medical stone and step (1) that above-mentioned steps (2) process is obtained are placed in high-speed mixer dispersion；
Step 4, by after dispersion raw material add surplus stock be well mixed after by extruder extrude；
Step 5, raw material Jing after melting, plasticizing, extrusion, cooling, pelletizing and packaging, finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611100883.9A CN106633822A (en) | 2016-12-05 | 2016-12-05 | Nylon nanometer material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611100883.9A CN106633822A (en) | 2016-12-05 | 2016-12-05 | Nylon nanometer material and preparation method thereof |
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| CN106633822A true CN106633822A (en) | 2017-05-10 |
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| CN201611100883.9A Pending CN106633822A (en) | 2016-12-05 | 2016-12-05 | Nylon nanometer material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383742A (en) * | 2017-09-15 | 2017-11-24 | 安徽江淮汽车集团股份有限公司 | A kind of antibacterial AES composite material and preparation method thereof |
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| US20080161482A1 (en) * | 2006-12-29 | 2008-07-03 | Diamond Polymer Science Co., Ltd | Functional material powder, method for fabricating the same and functional staple fiber containing the same |
| CN103965617A (en) * | 2013-01-29 | 2014-08-06 | 合肥杰事杰新材料股份有限公司 | Nylon nanometer composite material and preparing method thereof |
| CN104004349A (en) * | 2014-06-06 | 2014-08-27 | 宁波伊德尔新材料有限公司 | Antibacterial nylon/nano composite material and preparation method thereof |
| CN104250435A (en) * | 2013-06-26 | 2014-12-31 | 合肥杰事杰新材料股份有限公司 | Medical stone modified nylon microsphere material, its preparation method and its application in 3D printing |
| CN105504799A (en) * | 2016-01-20 | 2016-04-20 | 惠州市华聚塑化科技有限公司 | Nylon composite material |
-
2016
- 2016-12-05 CN CN201611100883.9A patent/CN106633822A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080161482A1 (en) * | 2006-12-29 | 2008-07-03 | Diamond Polymer Science Co., Ltd | Functional material powder, method for fabricating the same and functional staple fiber containing the same |
| CN103965617A (en) * | 2013-01-29 | 2014-08-06 | 合肥杰事杰新材料股份有限公司 | Nylon nanometer composite material and preparing method thereof |
| CN104250435A (en) * | 2013-06-26 | 2014-12-31 | 合肥杰事杰新材料股份有限公司 | Medical stone modified nylon microsphere material, its preparation method and its application in 3D printing |
| CN104004349A (en) * | 2014-06-06 | 2014-08-27 | 宁波伊德尔新材料有限公司 | Antibacterial nylon/nano composite material and preparation method thereof |
| CN105504799A (en) * | 2016-01-20 | 2016-04-20 | 惠州市华聚塑化科技有限公司 | Nylon composite material |
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| 刘西文 等: "《塑料挤出工培训教程》", 31 January 2013, 印刷工业出版社 * |
| 广西医药企业管理协会仓储管理养护技术研究会: "《危险物品化学试剂安全储存养护手册》", 31 July 1992, 广西师范大学出版社 * |
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| CN107383742A (en) * | 2017-09-15 | 2017-11-24 | 安徽江淮汽车集团股份有限公司 | A kind of antibacterial AES composite material and preparation method thereof |
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