CN106633763A - PC/ABS material with high binding force and easy to electroplate and preparation method thereof - Google Patents
PC/ABS material with high binding force and easy to electroplate and preparation method thereof Download PDFInfo
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- CN106633763A CN106633763A CN201611012163.7A CN201611012163A CN106633763A CN 106633763 A CN106633763 A CN 106633763A CN 201611012163 A CN201611012163 A CN 201611012163A CN 106633763 A CN106633763 A CN 106633763A
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 229920007019 PC/ABS Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000007747 plating Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims description 8
- 230000003014 reinforcing effect Effects 0.000 claims description 7
- 150000004645 aluminates Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000013329 compounding Methods 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 238000005461 lubrication Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000000956 alloy Substances 0.000 abstract description 7
- 229910045601 alloy Inorganic materials 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 6
- 238000009713 electroplating Methods 0.000 abstract description 5
- 230000003247 decreasing effect Effects 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000005453 pelletization Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a PC/ABS material with high binding force and easy to electroplate and a preparation method thereof. The PC/ABS material is prepared from the following components by a weight ratio: 33.4 to 61.3 percent of PC, 20 to 30 percent of ABS, 15 to 30 percent of modified carbon fiber, 3 to 5 percent of compatilizer, 0.2 to 0.5 percent of dispersant, 0.3 to 1 percent of antioxidant and 0.2 to 0.5 percent of lubricant. The preparation method of the PC/ABS material comprises the following steps of mixing all the components into a mixing agitator according to a proportion to carry out mixing; blending and granulating an obtained mixture through a twin screw extruder. The method provided by the invention is simple, easy and feasible; the dispersion, in a PC/ABS matrix, of the carbon fiber is promoted through the introduction of the compatilizer, so that the excellent electric conduction performance can be given to a PC/ABS alloy composition through a minute quantity of the carbon fiber; the linear expansion coefficient of the composition is decreased; an electroplating procedure can be directly carried out; coarsening, activating and chemical plating procedures are omitted; the electroplating procedure is simplified; a product composition provided by the invention has high mechanical strength; further, the dimensional stability is good.
Description
Technical field
The present invention relates to technical field of polymer materials, and in particular to a kind of PC/ with height adhesion, easily plating
ABS material and preparation method thereof.
Background technology
At present, the enclosure material of office appliance mostly is PC resin, ABS resin or PC/ABS compound resins.But, PC trees
Fat melt viscosity is big, machine-shaping is difficult, and particularly massive article easily produces stress cracking, and chemical proofing is poor, and
Price is higher, and these deficiencies make the application of PC receive a definite limitation；The performance of ABS resin is between engineering plastics and general-purpose plastics
Between, with good impact resistance and processing characteristics, price is also relatively cheap, and is widely applied.But its is heat-resisting
Property, weatherability are poor, and mechanical property is not ideal enough.PC/ABS alloys with PC and ABS as primary raw material are a kind of important engineerings
Plastic alloy, the characteristics of with good processing forming and corrosion resistance and toughness, but its heat resistance, weatherability are poor, mechanics
Performance is not ideal enough.And PC is chief component in PC/ABS alloy materials, this causes PC/ABS electroplating materials point quantity
It is greatly decreased, reduces the performances such as its electrodepositable, binding force of cladding material, it is impossible to which the performance for meeting higher and higher plated item will
Ask.Therefore, a intensity is developed high, easily the PC/ABS materials of plating are just necessary.
The content of the invention
For the problem that prior art is present, it is an object of the invention to provide it is a kind of with height adhesion, easily plating
PC/ABS materials and preparation method thereof.
The present invention is achieved through the following technical solutions above-mentioned purpose：
A kind of PC/ABS materials with height adhesion, easily plating, including following raw material by weight percentage：
PC 33.4-61.3%
ABS 20-30%
Toughness reinforcing compatilizer 3-5%
Modified carbon fiber 15-30%
Dispersant 0.2-1%
Lubricant 0.2-0.5%
Antioxidant 0.3-1%
Preferably, the toughness reinforcing compatilizer is styrene-butadiene-copolymer-maleic anhydride.Phenylethylene-maleic anhydride is total to
Polymers (S-MA) is obtained with a small amount of maleic anhydride monomer reaction by styrene monomer.Maleic anhydride monomer is randomly
It is connected on PS main chains, increased glass transition and heat distortion temperature.The heat change of general styrene-maleic anhydride copolymer product
Shape temperature is above 260 °F.In injection mo(u)lding, even if temperature is more than 550 °F, the performance of this polymer is still quite steady
It is fixed.
Carbon fiber is a kind of high intensity, the new fiber materials of high modulus fibre of phosphorus content more than 95%.It is by
The organic fibers such as flake graphite crystallite are piled up along fiber axial direction and are formed, and Jing is carbonized and microlite obtained from graphitization processing
Ink material.Carbon fiber " soft outside but hard inside ", quality is lighter than metallic aluminium, but intensity is higher than iron and steel, and with corrosion-resistant, high-modulus
Characteristic, be all important materials in defence and military and civilian aspect.It not only has the intrinsic intrinsic property of material with carbon element, has both again
The soft machinability of textile fabric, is reinforcing fiber of new generation.
Modified carbon fiber of the present invention is the aluminic acid by the PAN base carbon fibres of 95-98% weight and 2%-5% weight
Coupling agent is put into high-speed mixer, and at 100 DEG C, rotating speed is 750-800RPM, is well mixed.
It is further preferred that described aluminate coupling agent is anti-settling Aluminate ASA.
Preferably, the lubricant is alkyd ester lubricant, such as PETS lubricants, and inside and outside lubricity is good, can improve
The heat endurance of product, it is nontoxic.
Preferably, the preferred Hinered phenols antioxidant 1010 of the antioxidant is used as primary antioxidant, phosphite ester kind antioxidant
168 press 1 as synergistic antioxidant, wherein Hinered phenols antioxidant 1010 and phosphite kind antioxidant 168：2 proportionings.Wherein receive
, used as primary antioxidant, phosphite ester kind antioxidant 168 is used as synergistic antioxidant for resistance phenolic antioxidant 1010.
Preferably, the dispersant be ethylene acrylic acid co polymer, the such as 540A of Honeywell Inc. of the U.S..
The above-mentioned preparation method with height adhesion, the PC/ABS materials easily electroplated, comprises the following steps：
(1) raw material is weighed by weight, and each raw material input high-speed mixer and mixing is uniform, and mixing temperature is 55-65 DEG C, is mixed
Sum velocity is 550-600RPM, incorporation time 3-5 minute, obtains compound；
(2) compound Jing double screw extruders are made into material, at 230-260 DEG C, screw speed is for extruder temperature control
450-500RPM, by obtained pellet bar is molded into, and is obtained final product.
Beneficial effects of the present invention：
The characteristics of PC/ABS materials of the present invention have high intensity, easy plating, high tenacity, and moderate cost, size is steady
It is qualitative good, it is a kind of high comprehensive performance, the high alloy of cost performance.And the method for the present invention is simple, compatilizer draws
Enter to promote dispersion of the modified carbon fiber in PC/ABS matrixes so that minimal amount of carbon fiber can give PC/ABS alloy groups
The excellent electric conductivity of compound, reduces the linear expansion coefficient of composition, and can directly carry out electroplating work procedure, eliminates thick
Change, activation, Electroless Plating Procedure, simplify electroplating technology.The overall physical properties of material and the bond properties of material surface are improved,
The integrated cost of material is reduced, the use field of material has been widened.And the present invention in PC/ABS materials in strengthened feelings
Under condition, the light of integral material not being affected thoroughly, dissipating color effect, the resistance to temp effect of its entirety is good, is particularly well-suited to lamp decoration industry.
Specific embodiment
The present invention is explained further with reference to matrix embodiment scheme, but embodiment is not used to present invention composition
Any type of restriction.
Embodiment 1
The modified carbon fiber of the present invention has following methods to prepare：
The modified carbon fiber is to throw the anti-settling Aluminate ASA of the PAN base carbon fibres of 97% weight and 3% weight
Enter in high-speed mixer, at 100 DEG C, rotating speed is 750RPM, is well mixed.
Embodiment 2
Weighing the modified carbon fiber of the embodiment 1 of 15% weight carries out pre-dried, is dried 4 hours at 130 DEG C；So
Afterwards by the PC of 61% weight, the ABS of 20% weight, the toughness reinforcing compatilizer of 3.3% weight, the dispersant of 0.2% weight, 0.2%
The antioxidant of the lubricant of weight and 0.3% weight is added in high-speed mixer, at 55-65 DEG C, is well mixed；To mix
Material afterwards carries out extruding pelletization in double screw extruder, and extruder is divided into 10 areas：One area (230 DEG C), two areas (240
DEG C), 3rd area (240 DEG C), 4th area (245 DEG C), 5th area (250 DEG C), 6th area (250 DEG C), 7th area (245 DEG C), 8th area (250 DEG C),
9th area (245 DEG C), tenth area (260 DEG C)；After particle after extruding pelletization is dried again, it is molded, is prepared survey
Standard batten needed for examination performance.Testing standard and test result are as shown in table 2.
Embodiment 3
Weighing the modified carbon fiber of the embodiment 1 of 27% weight carries out pre-dried, is dried 4 hours at 130 DEG C；So
Afterwards by the PC of 41% weight, the ABS of 28% weight, the toughness reinforcing compatilizer of 3.3% weight, the dispersant of 0.2% weight, 0.2%
The antioxidant of the lubricant of weight and 0.3% weight is added in high-speed mixer, at 55-65 DEG C, is well mixed；To mix
Material afterwards carries out extruding pelletization in double screw extruder, and extruder is divided into 10 areas：One area (230 DEG C), two areas (240
DEG C), 3rd area (240 DEG C), 4th area (245 DEG C), 5th area (250 DEG C), 6th area (250 DEG C), 7th area (245 DEG C), 8th area (250 DEG C),
9th area (245 DEG C), tenth area (260 DEG C)；After particle after extruding pelletization is dried again, it is molded, is prepared survey
Standard batten needed for examination performance.Testing standard and test result are as shown in table 2.
Embodiment 4
Weighing the modified carbon fiber of the embodiment 1 of 25% weight carries out pre-dried, is dried 4 hours at 130 DEG C；So
Afterwards by the PC of 44.5% weight, the ABS of 25% weight, the toughness reinforcing compatilizer of 4.2% weight, the dispersant of 0.3% weight,
The antioxidant of the lubricant of 0.5% weight and 0.5% weight is added in high-speed mixer, at 55-65 DEG C, is well mixed；
Material after mixing is carried out in double screw extruder extruding pelletization, extruder is divided into 10 areas：One area (230 DEG C), two
Area's (240 DEG C), 3rd area (240 DEG C), 4th area (245 DEG C), 5th area (250 DEG C), 6th area (250 DEG C), 7th area (245 DEG C), 8th area
(250 DEG C), 9th area (245 DEG C), tenth area (260 DEG C)；After particle after extruding pelletization is dried again, it is molded,
Prepare the standard batten needed for test performance.Testing standard and test result are as shown in table 2.
Embodiment 5
Weighing the modified carbon fiber of the embodiment 1 of 30% weight carries out pre-dried, is dried 4 hours at 130 DEG C；So
Afterwards by the PC of 33.5% weight, the ABS of 30% weight, the toughness reinforcing compatilizer of 5% weight, the dispersant of 0.5% weight, 0.5%
The antioxidant of the lubricant of weight and 0.5% weight is added in high-speed mixer, at 55-65 DEG C, is well mixed；To mix
Material afterwards carries out extruding pelletization in double screw extruder, and extruder is divided into 10 areas：One area (230 DEG C), two areas (240
DEG C), 3rd area (240 DEG C), 4th area (245 DEG C), 5th area (250 DEG C), 6th area (250 DEG C), 7th area (245 DEG C), 8th area (250 DEG C),
9th area (245 DEG C), tenth area (260 DEG C)；After particle after extruding pelletization is dried again, it is molded, is prepared survey
Standard batten needed for examination performance.Testing standard and test result are as shown in table 2.
Embodiment 2-5 of table 1 is raw materials used and ratio
The embodiment 2-5 products obtained therefrom the performance test results of table 2
Consolidated statement 2 as can be seen that the PC/ABS materials of the present invention have intensity it is high, easily plating, high tenacity the characteristics of, and
Moderate cost, is a kind of high comprehensive performance, the high alloy of cost performance.
Above example is preferably embodiment, all changes according to done by technical solution of the present invention of the invention, is produced
When raw function fails to exceed the scope of technical solution of the present invention, protection scope of the present invention is belonged to.
Claims (10)
1. it is a kind of with height adhesion, the PC/ABS materials of easily plating, it is characterised in that including it is following by weight percentage
Raw material：
PC 33.4-61.3%
ABS 20-30%
Toughness reinforcing compatilizer 3-5%
Modified carbon fiber 15-30%
Dispersant 0.2-1%
Lubricant 0.2-0.5%
Antioxidant 0.3-1%.
2. it is according to claim 1 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that the increasing
Tough compatilizer is styrene-butadiene-copolymer-maleic anhydride.
3. it is according to claim 1 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that described to change
Property carbon fiber be that the aluminate coupling agent of the PAN base carbon fibres of 95-98% weight and 2%-5% weight is put into mixer
In, at 100 DEG C, it is well mixed.
4. it is according to claim 3 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that described
Mixer is high-speed mixer, and rotating speed is 750-800RPM.
5. it is according to claim 3 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that described
Aluminate coupling agent is anti-settling Aluminate ASA.
6. it is according to claim 1 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that the profit
Lubrication prescription is alkyd ester lubricant.
7. it is according to claim 1 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that described anti-
Oxygen agent is Hinered phenols antioxidant 1010 and phosphite kind antioxidant 168 by weight 1:2 compoundings.
8. it is according to claim 1 with height adhesion, the PC/ABS materials easily electroplated, it is characterised in that described point
Powder is ethylene acrylic acid co polymer.
9. according to any one of claim 1-8 with height adhesion, the preparation side of easy PC/ABS materials of plating
Method, it is characterised in that comprise the following steps：
(1) raw material is weighed by weight, and each raw material input high-speed mixer and mixing is uniform, and mixing temperature is 55-65 DEG C, during mixing
Between 3-5 minutes, obtain compound；
(2) compound Jing double screw extruders extrusion makes material, and extruder temperature is molded into obtained pellet at 230-260 DEG C
Bar, obtains final product.
10. it is according to claim 9 with height adhesion, the preparation method of easy PC/ABS materials of plating, its feature
It is that the mixing velocity in step (1) is 550-600RPM；The screw speed of extruder is 450-500RPM in step (2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201611012163.7A CN106633763B (en) | 2016-11-17 | 2016-11-17 | A kind of PC/ABS materials and preparation method thereof that there is height binding force, be easily electroplated |
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| CN201611012163.7A CN106633763B (en) | 2016-11-17 | 2016-11-17 | A kind of PC/ABS materials and preparation method thereof that there is height binding force, be easily electroplated |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250660A (en) * | 2017-12-22 | 2018-07-06 | 万华化学集团股份有限公司 | A kind of plating grade PC/ABS alloy materials and preparation method thereof |
| CN108822556A (en) * | 2018-05-31 | 2018-11-16 | 镇江高美新材料有限公司 | A kind of conducting liquid silicone rubber compound and its manufacturing method |
| CN109735078A (en) * | 2018-11-23 | 2019-05-10 | 金旸（厦门）新材料科技有限公司 | A kind of efficient conduction PC/ABS alloy material and preparation method thereof |
| CN112778692A (en) * | 2020-12-31 | 2021-05-11 | 广东国恩塑业发展有限公司 | Reinforced ABS (acrylonitrile-butadiene-styrene) composition with low expansion coefficient and preparation method thereof |
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| CN102719073A (en) * | 2012-07-03 | 2012-10-10 | 上海锦湖日丽塑料有限公司 | Electroplating poly carbonate (PC)/acrylonitrile butadiene styrene (ABS) alloy composition and preparation method thereof |
| CN103044886A (en) * | 2012-12-26 | 2013-04-17 | 安徽科聚新材料有限公司 | Preparation method and application of PC/ABS alloy |
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| CN108822556A (en) * | 2018-05-31 | 2018-11-16 | 镇江高美新材料有限公司 | A kind of conducting liquid silicone rubber compound and its manufacturing method |
| CN109735078A (en) * | 2018-11-23 | 2019-05-10 | 金旸（厦门）新材料科技有限公司 | A kind of efficient conduction PC/ABS alloy material and preparation method thereof |
| CN112778692A (en) * | 2020-12-31 | 2021-05-11 | 广东国恩塑业发展有限公司 | Reinforced ABS (acrylonitrile-butadiene-styrene) composition with low expansion coefficient and preparation method thereof |
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Denomination of invention: A PC/ABS material with high adhesion and easy electroplating, and its preparation method Effective date of registration: 20231204 Granted publication date: 20181109 Pledgee: Jiangmen Rural Commercial Bank Co.,Ltd. Hetang sub branch Pledgor: GUANGDONG DOSN TECHNOLOGY CO.,LTD. Registration number: Y2023980069080 |