CN106633471A - Plastic wood door modified based on argil and preparation method thereof - Google Patents
Plastic wood door modified based on argil and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2497/00—Characterised by the use of lignin-containing materials
- C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a plastic wood door modified based on argil and a preparation method thereof. The preparation method includes the steps that 1, wood powder, bamboo powder, konjac powder, Chinese herbal medicine powder and a coupling agent are mixed to prepare organic powder; 2, polyvinyl chloride, an ethylene-vinyl alcohol copolymer, polyvinyl acetate, trichloroethyl phosphate, vaseline, decabromodiphenyl ether, 1,2-ethylene thiourea, dilauryl thiodipropionate, D-glucosazone, amygdalin, sulfur, argil and the modified organic powder are mixed to obtain a mixed product; 3, the mixed product is mixed with sodium bicarbonate, then foaming treatment is performed, and plasticize-molding is performed to obtain a plastic wood plank; 4, the surface of the plastic wood plank is coated with China wood oil, then drying and machining are performed to obtain the plastic wood door modified based on the argil. The Chinese herbal medicine powder contains cortex meliae, ailanthus altissima leaves, radix stemonae, Chinese yam, folium artemisiae argyi, cacumen biotae and erycibe obtusifolia benth. The plastic wood door made by adopting the method has the advantages of low density, high intensity and fungal resistance.
Description
Technical field
The present invention relates to plastic-wood material, in particular it relates to a kind of modeling timber being modified based on carclazyte and preparation method thereof.
Background technology
Plastic-wood material, is also wood plastic composite, as the term suggests can be regarded as mainly (polypropylene, polyethylene, poly- with plastics
The waste or used plastics of the recovery such as vinyl chloride) it is raw material, it is mixed into new wood by adding the useless strings such as wood powder, rice husk, stalk
Material, then plastic processing, the sheet material produced or the section bar such as Jing extruding, molding, injection moulding；It is mainly used in building
The industries such as material, furniture, logistics packaging.Because plastic-wood material has both the double grading of timber and plastics, plastic-wood material and wooden material
Material is compared and had the advantage that：Water absorption rate is low, is unlikely to deform cracking, Anti-moth-eating, anti-mildew, mechanical performance high, moistureproof, acidproof
Alkali, it is corrosion-resistant, be easy to cleaning.Based on these above-mentioned characteristics cause plastic-wood material can many fields substitute log, plastics and
Aluminium alloy so that it is the following energy-conserving and environment-protective new product of new generation for substituting traditional timber, with extensive market application foreground.
Although for wood materials, the density of plastic-wood material has declined, relative to other lightweight materials
Material, the density of plastic-wood material is still difficult to meet the market demand；In prior art, the general technology for reducing macromolecular material density
Means be by way of foaming, but the material after foaming can cause damage for other performances of material, especially mould wood
The Anti-mildew capability of material.
The content of the invention
It is an object of the invention to provide a kind of modeling timber being modified based on carclazyte and preparation method thereof, is obtained by the method
Modeling timber there is low density, high intensity and antimycotic characteristic, while the preparation method operation is simple, raw material is easy to get, is easy to
Promote.
To achieve these goals, the invention provides it is a kind of based on carclazyte be modified modeling timber preparation method, including：
1) wood powder, bamboo powder, konjaku flour, Chinese herbal medicine powder and coupling agent are mixed modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, ten bromines connection
The double lauryls of phenylate, 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte have with modified
Machine powder is kneaded to obtain mixing thing；
3) foaming process is carried out after mixing thing is mixed with sodium acid carbonate, then plasticizing forming is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines with prepared described modified based on carclazyte
Modeling timber；
Wherein, Chinese herbal medicine powder contains azedarach, tree-of-heaven leaf, the tuber of stemona, Chinese yam, tarragon, cacumen biotae and ergcibe obtusifolia.
Present invention also offers a kind of preparation method of the modeling timber being modified based on carclazyte, should be based on the modeling wood that carclazyte is modified
Door is prepared by above-mentioned preparation method.
In above-mentioned technical proposal, the present invention causes obtained modeling timber by the synergy of each step and each raw material
With density is low, high intensity and antimycotic characteristic, while the preparation method operation is simple, raw material is easy to get, be easy to promote.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
The specific embodiment of the present invention is described in detail below.It should be appreciated that described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of preparation method of the modeling timber being modified based on carclazyte, including：
1) wood powder, bamboo powder, konjaku flour, Chinese herbal medicine powder and coupling agent are mixed modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, ten bromines connection
The double lauryls of phenylate, 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte have with modified
Machine powder is kneaded to obtain mixing thing；
3) foaming process is carried out after mixing thing is mixed with sodium acid carbonate, then plasticizing forming is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines with prepared described modified based on carclazyte
Modeling timber；
Wherein, Chinese herbal medicine powder contains azedarach, tree-of-heaven leaf, the tuber of stemona, Chinese yam, tarragon, cacumen biotae and ergcibe obtusifolia.
In the step 1 of the present invention) in, the consumption of each material can be selected in wide scope, but in order that be obtained
Modeling timber have more excellent density, intensity and Anti-mildew capability, it is preferable that in step 1) in, relative to 100 weight portions
Wood powder, the consumption of bamboo powder is 50-74 weight portions, and the consumption of konjaku flour is 18-22 weight portions, and the consumption of azedarach is 8-14 weight
Part, the consumption of tree-of-heaven leaf is 2-7 weight portions, and the consumption of the tuber of stemona is 18-27 weight portions, and the consumption of Chinese yam is 16-24 weight portions, is ended
The consumption of leaf is 4-8 weight portions, and the consumption of cacumen biotae is 20-33 weight portions, and the consumption of ergcibe obtusifolia is 34-40 weight portions, is coupled
The consumption of agent is 120-144 weight portions.
In the step 1 of the present invention) in, mixing condition can be selected in wide scope, but in order that obtained modeling
Timber has more excellent density, intensity and Anti-mildew capability, it is preferable that in step 1) in, mixing at least meets following condition：
Mixing temperature is 55-64 DEG C, and incorporation time is 7-10h.
In the step 1 of the present invention) in, the species of coupling agent can be selected in wide scope, but in order that be obtained
Modeling timber have more excellent density, intensity and Anti-mildew capability, it is preferable that in step 1) in, coupling agent be selected from coupling agent
One or more in KH550, coupling agent KH560, coupling agent KH570, coupling agent KH792.
In the step 2 of the present invention) in, the consumption of each material can be selected in wide scope, but in order that be obtained
Modeling timber have more excellent density, intensity and Anti-mildew capability, it is preferable that in step 2) in, relative to 100 weight portions
Polyvinyl chloride, the consumption of ethylene-vinyl alcohol copolymer is 40-54 weight portions, and the consumption of polyvinyl acetate is 38-49 weight portions,
The consumption of TCEP is 10-15 weight portions, and the consumption of vaseline is 40-48 weight portions, and the consumption of decabromodiphenyl oxide is
12-19 weight portions, the consumption of 1,2- ethylene thiourea is 9-17 weight portions, and the consumption of the double lauryls of thio-2 acid is 62-77
Weight portion, the consumption of D-Glucose osazone is 14-22 weight portions, and the consumption of amarogentin is 9-17 weight portions, and the consumption of sulphur is
22-34 weight portions, the consumption of carclazyte is 28-37 weight portions, and the consumption of the organic dust that is modified is 65-80 weight portions.
In the step 2 of the present invention) in, the condition of mixing can be selected in wide scope, but in order that obtained
Modeling timber has more excellent density, intensity and Anti-mildew capability, it is preferable that in step 2) in, mixing at least meets following bar
Part：Melting temperature is 195-205 DEG C, and mixing time is 3-5h.
In the step 3 of the present invention) in, the consumption of raw material can be selected in wide scope, but in order that obtained
Modeling timber has more excellent density, intensity and Anti-mildew capability, it is preferable that in step 3) in, mixing thing and sodium acid carbonate
Weight ratio is 100：5-10.
In the step 3 of the present invention) in, the condition for processing that foams can be selected in wide scope, but in order that system
The modeling timber for obtaining has more excellent density, intensity and Anti-mildew capability, it is preferable that in step 3) in, foaming processes at least full
Be enough to lower condition：Blowing temperature is 125-135 DEG C, and foamed time is 1-3h.
Present invention also offers a kind of preparation method of the modeling timber being modified based on carclazyte, should be based on the modeling wood that carclazyte is modified
Door is prepared by above-mentioned preparation method.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
1) at 60 DEG C, by wood powder, bamboo powder, konjaku flour, azedarach powder, tree-of-heaven leaf powder, tuber of stemona powder, yam flour, Folium Artemisiae Argyi powder,
Cacumen biotae powder, ergcibe obtusifolia powder, coupling agent (coupling agent KH550) are according to 100：64：20：12：5：22：20：5：27：38：134 weight
Amount is than carrying out mixing 8h modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, ten bromines connection
The double lauryls of phenylate, 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte have with modified
Machine powder is according to 100：45：44：13：42：16：14：67：18：13：28：32：70 weight ratio kneads 4h to obtain at 200 DEG C
To mixing thing；
3) by mixing thing and sodium acid carbonate according to 100：8 weight is then plastified into than mixing the 2h that foams at 130 DEG C
Type is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines with prepared described modified based on carclazyte
Modeling timber A1.
Embodiment 2
1) at 55 DEG C, by wood powder, bamboo powder, konjaku flour, azedarach powder, tree-of-heaven leaf powder, tuber of stemona powder, yam flour, Folium Artemisiae Argyi powder,
Cacumen biotae powder, ergcibe obtusifolia powder, coupling agent (coupling agent KH570) are according to 100：50：18：8：2：18：16：4：20：34：120 weight
Amount is than carrying out mixing 7h modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, ten bromines connection
The double lauryls of phenylate, 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte have with modified
Machine powder is according to 100：40：38：10：40：12：9：62：14：9：22：28：65 weight ratio kneads 3h to obtain at 195 DEG C
Mixing thing；
3) by mixing thing and sodium acid carbonate according to 100：5 weight is then plastified into than mixing the 1h that foams at 125 DEG C
Type is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines with prepared described modified based on carclazyte
Modeling timber A2.
Embodiment 3
1) at 64 DEG C, by wood powder, bamboo powder, konjaku flour, azedarach powder, tree-of-heaven leaf powder, tuber of stemona powder, yam flour, Folium Artemisiae Argyi powder,
Cacumen biotae powder, ergcibe obtusifolia powder, coupling agent (coupling agent KH792) are according to 100：74：22：14：7：27：24：8：33：40：144 weight
Amount is than carrying out mixing 10h modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, ten bromines connection
The double lauryls of phenylate, 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte have with modified
Machine powder is according to 100：54：49：15：48：19：17：77：22：17：34：37：80 weight ratio kneads 5h to obtain at 205 DEG C
To mixing thing；
3) by mixing thing and sodium acid carbonate according to 100：10 weight is then moulded than mixing the 1-3h that foams at 135 DEG C
Chemical conversion type is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines with prepared described modified based on carclazyte
Modeling timber A3.
Comparative example 1
Method according to embodiment 1 carries out that modeling timber B1, except for the difference that, step 1 is obtained) in azedarach powder, smelly is not used
Chinese toon leaf powder.
Comparative example 2
Method according to embodiment 1 carries out that modeling timber B2, except for the difference that, step 1 is obtained) in tuber of stemona powder, Chinese yam is not used
Powder.
Comparative example 3
Method according to embodiment 1 carries out that modeling timber B3, except for the difference that, step 1 is obtained) in Folium Artemisiae Argyi powder, arbor-vitae is not used
Ye Fen, ergcibe obtusifolia powder.
Comparative example 4
Method according to embodiment 1 carries out that modeling timber B4, except for the difference that, step 2 is obtained) in D-Glucose osazone is not used.
Comparative example 5
Method according to embodiment 1 carries out that modeling timber B5, except for the difference that, step 2 is obtained) in amarogentin is not used.
Comparative example 6
Method according to embodiment 1 carries out that modeling timber B6, except for the difference that, step 2 is obtained) in 1,2- ethylidene sulphur is not used
Urea.
Comparative example 7
Method according to embodiment 1 carries out that modeling timber B7, except for the difference that, step 3 is obtained) in sodium acid carbonate is not used.
Detection example 1
1) density (Kg/m of above-mentioned modeling timber is detected3) and impact resistance (KJ/m2)；
2) (the cfu/dm of total plate count 1 on the surface of above-mentioned modeling timber is detected2), then above-mentioned modeling timber is placed in into air wet
Spend for 60%, temperature is to place 7 days in 40 DEG C of environment, then (the cfu/dm of total plate count 2 on the surface of detection modeling timber2),
Concrete outcome is shown in Table 1.
Table 1
By above-described embodiment, comparative example and detection example, the modeling timber of present invention offer has that density is low, high intensity
With antimycotic characteristic.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, the present invention range of the technology design in, various simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of embodiments of the present invention, as long as it is without prejudice to this
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (9)
1. it is a kind of based on carclazyte be modified modeling timber preparation method, it is characterised in that include：
1) wood powder, bamboo powder, konjaku flour, Chinese herbal medicine powder and coupling agent are mixed modified organic dust is obtained；
2) by polyvinyl chloride, ethylene-vinyl alcohol copolymer, polyvinyl acetate, TCEP, vaseline, decabromodiphenyl oxide,
The double lauryls of 1,2- ethylene thioureas, thio-2 acid, D-Glucose osazone, amarogentin, sulphur, carclazyte are modified organic with described
Powder is kneaded to obtain mixing thing；
3) foaming process is carried out after the mixing thing is mixed with sodium acid carbonate, then plasticizing forming is with prepared plastic wood sheet；
4) by the external coating tung oil of the plastic wood sheet, then it is dried, machines that the modeling being modified based on carclazyte is obtained
Timber；
Wherein, the Chinese herbal medicine powder contains azedarach, tree-of-heaven leaf, the tuber of stemona, Chinese yam, tarragon, cacumen biotae and ergcibe obtusifolia.
2. preparation method according to claim 1, it is characterised in that in step 1) in, relative to described in 100 weight portions
Wood powder, the consumption of the bamboo powder is 50-74 weight portions, and the consumption of the konjaku flour is 18-22 weight portions, the use of the azedarach
Measure as 8-14 weight portions, the consumption of the tree-of-heaven leaf is 2-7 weight portions, the consumption of the tuber of stemona is 18-27 weight portions, the mountain
The consumption of medicine is 16-24 weight portions, and the consumption of the tarragon is 4-8 weight portions, and the consumption of the cacumen biotae is 20-33 weight
Part, the consumption of the ergcibe obtusifolia is 34-40 weight portions, and the consumption of the coupling agent is 120-144 weight portions.
3. preparation method according to claim 2, it is characterised in that in step 1) in, the mixing at least meets following
Condition：Mixing temperature is 55-64 DEG C, and incorporation time is 7-10h.
4. preparation method according to claim 2, it is characterised in that in step 1) in, the coupling agent is selected from coupling agent
One or more in KH550, coupling agent KH560, coupling agent KH570, coupling agent KH792.
5. the preparation method according to any one in claim 1-4, it is characterised in that in step 2) in, relative to 100
The polyvinyl chloride of weight portion, the consumption of the ethylene-vinyl alcohol copolymer is 40-54 weight portions, the polyvinyl acetate
Consumption be 38-49 weight portions, the consumption of the TCEP is 10-15 weight portions, and the consumption of the vaseline is 40-
48 weight portions, the consumption of the decabromodiphenyl oxide is 12-19 weight portions, and the consumption of 1, the 2- ethylene thioureas is 9-17 weight
Part, the consumption of the double lauryls of the thio-2 acid is 62-77 weight portions, and the consumption of the D-Glucose osazone is 14-22 weight
Part, the consumption of the amarogentin is 9-17 weight portions, and the consumption of the sulphur is 22-34 weight portions, the consumption of the carclazyte
For 28-37 weight portions, the consumption of the modified organic dust is 65-80 weight portions.
6. preparation method according to claim 5, it is characterised in that in step 2) in, the mixing at least meets following
Condition：Melting temperature is 195-205 DEG C, and mixing time is 3-5h.
7. preparation method according to claim 5, it is characterised in that in step 3) in, the mixing thing and sodium acid carbonate
Weight ratio be 100：5-10.
8. the preparation method according to claim 6 or 7, it is characterised in that in step 3) in, the foaming processes at least full
Be enough to lower condition：Blowing temperature is 125-135 DEG C, and foamed time is 1-3h.
9. it is a kind of based on carclazyte be modified modeling timber preparation method, it is characterised in that it is described based on carclazyte be modified modeling timber
It is prepared by the preparation method described in any one in claim 1-8.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610881375.2A CN106633471A (en) | 2016-10-10 | 2016-10-10 | Plastic wood door modified based on argil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610881375.2A CN106633471A (en) | 2016-10-10 | 2016-10-10 | Plastic wood door modified based on argil and preparation method thereof |
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| CN103396620A (en) * | 2013-07-15 | 2013-11-20 | 安徽省振云塑胶有限公司 | PVC (Polyvinyl Chloride) plastic-wood foaming material |
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Non-Patent Citations (1)
| Title |
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| "《中药大辞典 第二版 上下册》" * |
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Application publication date: 20170510 |
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