CN106633429A - Ethylene propylene diene monomer rubber flame-retardant formula - Google Patents
Ethylene propylene diene monomer rubber flame-retardant formula Download PDFInfo
- Publication number
- CN106633429A CN106633429A CN201611072293.XA CN201611072293A CN106633429A CN 106633429 A CN106633429 A CN 106633429A CN 201611072293 A CN201611072293 A CN 201611072293A CN 106633429 A CN106633429 A CN 106633429A
- Authority
- CN
- China
- Prior art keywords
- parts
- ethylene propylene
- propylene diene
- diene monomer
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an ethylene propylene diene monomer rubber flame-retardant formula. The formula material is composed of the following components in parts by mass: 80-140 parts of ethylene propylene diene monomer rubber, 5-18 parts of resin, 1-7 parts of zinc oxide, 1-3 parts of stearic acid, 30-45 parts of N774 carbon black, 40-50 parts of paraffin oil, 150-180 parts of modified magnesium hydroxide, 1-7 parts of silane coupling agent, 2-3 parts of fatty acid mold release agent, 12-19 parts of nano silicate, 1-5 parts of sulfur, 1.5-3.5 parts of accelerator, 3-7 parts of flame retardant and 5-18 parts of composite conditioner. By combining the ethylene propylene diene monomer rubber, resin, zinc oxide, stearic acid, N774 carbon black, paraffin oil, modified magnesium hydroxide, silane coupling agent, fatty acid mold release agent, nano silicate, sulfur, accelerator, flame retardant and composite conditioner, the prepare ethylene propylene diene monomer rubber has flame retardancy, and can satisfy the EPDM (ethylene-propylene-diene monomer) flame-retardant formula according to the high-speed rail standard 5510.
Description
Technical field
The present invention relates to rubber manufacture field, more particularly to a kind of ethylene propylene diene rubber flame-retardant formulations.
Background technology
Ethylene propylene diene rubber is the copolymer of ethene, propylene and a small amount of non-conjugated diene hydrocarbon, is one kind of EP rubbers,
With EPDM（Ethylene Propylene Diene Monomer）Represent, because its main chain is by chemically stable saturated hydrocarbons group
Into, only contain unsaturated double-bond in side chain, therefore the ageing-resistant performance such as its resistance to ozone, heat-resisting, weather-proof is excellent, can be widely used for vapour
The fields such as car part, building water-proof material, electric wire and cable jacket, heat-resistant rubber hose, adhesive tape, automotive sealant.At present in manufacture
During ethylene propylene diene rubber, the ethylene propylene diene rubber for manufacturing is combustible, under special circumstances using easily damage inside
The part of protection.Therefore, design a kind of ethylene propylene diene rubber flame-retardant formulations with fire resistance to be just particularly important.
The content of the invention
For the problem that above-mentioned prior art is present, it is an object of the invention to provide a kind of ethylene propylene diene rubber is fire-retardant matching somebody with somebody
Side, by ethylene propylene diene rubber, resin, zinc oxide, stearic acid, N774 carbon blacks, paraffin oil, modified magnesium hydroxide, silane coupled
The combination of agent, fatty acid releasing agent, nano silicate, sulphur, accelerator, fire retardant and compound blender, prepares and carries
The ethylene propylene diene rubber of fire resistance.
The present invention provides a kind of ethylene propylene diene rubber flame-retardant formulations, and the mass fraction of the formula materials is ethylene-propylene-diene monomer
80 ~ 140 parts of glue, 5 ~ 18 parts of resin, 1 ~ 7 part of zinc oxide, 1 ~ 3 part of stearic acid, 30 ~ 45 parts of N774 carbon blacks, 40 ~ 50 parts of paraffin oil,
150 ~ 180 parts of modified magnesium hydroxide, 1 ~ 7 part of silane coupler, 2 ~ 3 parts of fatty acid releasing agent, nano silicate 12 ~ 19
Part, 1 ~ 5 part of sulphur, 1.5 ~ 3.5 parts of accelerator, 3 ~ 7 parts of fire retardant is combined 5 ~ 18 parts of blender.
Further improvement is that：The mass fraction of the formula materials be 100 parts of ethylene propylene diene rubber, 10 parts of resin, oxygen
5 parts of zinc of change, 1 part of stearic acid, 40 parts of N774 carbon blacks, 50 parts of paraffin oil, 160 parts of modified magnesium hydroxide, 2 parts of silane coupler,
2 parts of fatty acid releasing agent, 15 parts of nano silicate, 1.5 parts of sulphur, 2.8 parts of accelerator, 5 parts of fire retardant is combined blender
8 parts.
Further improvement is that：The paraffin oil is 300# paraffin oils.
Further improvement is that：The resin is 1801 resins.
The invention has the beneficial effects as follows：By ethylene propylene diene rubber, resin, zinc oxide, stearic acid, N774 carbon blacks, paraffin
Oil, modified magnesium hydroxide, silane coupler, fatty acid releasing agent, nano silicate, sulphur, accelerator, fire retardant and multiple
The combination of blender is closed, the ethylene propylene diene rubber with fire resistance is prepared, the EPDM resistances of high ferro standard 5510 can be met
Combustion formula.
Specific embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, the embodiment
It is only used for explaining the present invention, does not constitute limiting the scope of the present invention.
The present embodiment provides a kind of ethylene propylene diene rubber flame-retardant formulations, and the mass fraction of the formula materials is EPDM
100 parts of rubber, 10 parts of resin, 5 parts of zinc oxide, 1 part of stearic acid, 40 parts of N774 carbon blacks, 50 parts of paraffin oil, modified magnesium hydroxide
160 parts, 2 parts of silane coupler, 2 parts of fatty acid releasing agent, 15 parts of nano silicate, 1.5 parts of sulphur, accelerator 2.8
Part, 5 parts of fire retardant is combined 8 parts of blender.The paraffin oil is 300# paraffin oils.The resin is 1801 resins.By ternary
EP rubbers, resin, zinc oxide, stearic acid, N774 carbon blacks, paraffin oil, modified magnesium hydroxide, silane coupler, fatty acid
The combination of releasing agent, nano silicate, sulphur, accelerator, fire retardant and compound blender, prepares with fire resistance
Ethylene propylene diene rubber, can meet the EPDM flame-retardant formulations of high ferro standard 5510.
Claims (4)
1. a kind of ethylene propylene diene rubber flame-retardant formulations, it is characterised in that：The mass fraction of the formula materials is ethylene-propylene-diene monomer
80 ~ 140 parts of glue, 5 ~ 18 parts of resin, 1 ~ 7 part of zinc oxide, 1 ~ 3 part of stearic acid, 30 ~ 45 parts of N774 carbon blacks, 40 ~ 50 parts of paraffin oil,
150 ~ 180 parts of modified magnesium hydroxide, 1 ~ 7 part of silane coupler, 2 ~ 3 parts of fatty acid releasing agent, 12 ~ 19 parts of nano silicate,
1 ~ 5 part of sulphur, 1.5 ~ 3.5 parts of accelerator, 3 ~ 7 parts of fire retardant is combined 5 ~ 18 parts of blender.
2. ethylene propylene diene rubber flame-retardant formulations as claimed in claim 1, it is characterised in that：The mass fraction of the formula materials
For 100 parts of ethylene propylene diene rubber, 10 parts of resin, 5 parts of zinc oxide, 1 part of stearic acid, 40 parts of N774 carbon blacks, 50 parts of paraffin oil, it is modified
160 parts of magnesium hydroxide, 2 parts of silane coupler, 2 parts of fatty acid releasing agent, 15 parts of nano silicate, 1.5 parts of sulphur, accelerator
2.8 parts, 5 parts of fire retardant is combined 8 parts of blender.
3. ethylene propylene diene rubber flame-retardant formulations as claimed in claim 1 or 2, it is characterised in that：The paraffin oil is 300# stones
Wax oil.
4. ethylene propylene diene rubber flame-retardant formulations as claimed in claim 1 or 2, it is characterised in that：The resin is 1801 resins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072293.XA CN106633429A (en) | 2016-11-29 | 2016-11-29 | Ethylene propylene diene monomer rubber flame-retardant formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072293.XA CN106633429A (en) | 2016-11-29 | 2016-11-29 | Ethylene propylene diene monomer rubber flame-retardant formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633429A true CN106633429A (en) | 2017-05-10 |
Family
ID=58813048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611072293.XA Pending CN106633429A (en) | 2016-11-29 | 2016-11-29 | Ethylene propylene diene monomer rubber flame-retardant formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633429A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385014A (en) * | 2018-09-30 | 2019-02-26 | 芜湖集拓橡胶技术有限公司 | A kind of flame-retardant rubber pipe |
| CN110003543A (en) * | 2019-04-09 | 2019-07-12 | 扬州华通橡塑有限公司 | A kind of rail traffic seal ball-valve of resistance to extremely low temperature rubber and preparation method thereof |
| CN112898689A (en) * | 2021-01-27 | 2021-06-04 | 青岛博锐智远减振科技有限公司 | Halogen-free environment-friendly flame-retardant rubber material and preparation method thereof |
| WO2021153234A1 (en) * | 2020-01-31 | 2021-08-05 | Nok株式会社 | Flame-retardant rubber composition |
| CN113717474A (en) * | 2021-09-09 | 2021-11-30 | 东莞世纪创造绝缘有限公司 | EPDM flame-retardant rubber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131088A (en) * | 2011-11-30 | 2013-06-05 | 天津昕中和胶业有限公司 | Unsaturated carboxylic acid metal salt modified ethylene-propylene-diene monomer (EPDM) and preparation method thereof |
| CN105086167A (en) * | 2014-05-15 | 2015-11-25 | 舟山坚久橡塑制业有限公司 | Environment-friendly type edge-easily-torn EPDM gasket rubber compound with high flame retardancy and preparation method thereof |
| CN105400086A (en) * | 2015-12-21 | 2016-03-16 | 潍坊市宏源防水材料有限公司 | Flame-retardant EPDM waterproof coiled material, and production method thereof |
| CN105968591A (en) * | 2016-07-15 | 2016-09-28 | 株洲时代新材料科技股份有限公司 | Flame-retardant shock-absorption EPDM vulcanized rubber and preparation method thereof |
-
2016
- 2016-11-29 CN CN201611072293.XA patent/CN106633429A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131088A (en) * | 2011-11-30 | 2013-06-05 | 天津昕中和胶业有限公司 | Unsaturated carboxylic acid metal salt modified ethylene-propylene-diene monomer (EPDM) and preparation method thereof |
| CN105086167A (en) * | 2014-05-15 | 2015-11-25 | 舟山坚久橡塑制业有限公司 | Environment-friendly type edge-easily-torn EPDM gasket rubber compound with high flame retardancy and preparation method thereof |
| CN105400086A (en) * | 2015-12-21 | 2016-03-16 | 潍坊市宏源防水材料有限公司 | Flame-retardant EPDM waterproof coiled material, and production method thereof |
| CN105968591A (en) * | 2016-07-15 | 2016-09-28 | 株洲时代新材料科技股份有限公司 | Flame-retardant shock-absorption EPDM vulcanized rubber and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385014A (en) * | 2018-09-30 | 2019-02-26 | 芜湖集拓橡胶技术有限公司 | A kind of flame-retardant rubber pipe |
| CN110003543A (en) * | 2019-04-09 | 2019-07-12 | 扬州华通橡塑有限公司 | A kind of rail traffic seal ball-valve of resistance to extremely low temperature rubber and preparation method thereof |
| WO2021153234A1 (en) * | 2020-01-31 | 2021-08-05 | Nok株式会社 | Flame-retardant rubber composition |
| JP7420839B2 (en) | 2020-01-31 | 2024-01-23 | Nok株式会社 | Flame retardant rubber composition |
| EP4098695A4 (en) * | 2020-01-31 | 2024-03-06 | Nok Corp | Flame-retardant rubber composition |
| CN112898689A (en) * | 2021-01-27 | 2021-06-04 | 青岛博锐智远减振科技有限公司 | Halogen-free environment-friendly flame-retardant rubber material and preparation method thereof |
| CN112898689B (en) * | 2021-01-27 | 2023-01-13 | 青岛博锐智远减振科技有限公司 | Halogen-free environment-friendly flame-retardant rubber material and preparation method thereof |
| CN113717474A (en) * | 2021-09-09 | 2021-11-30 | 东莞世纪创造绝缘有限公司 | EPDM flame-retardant rubber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106633429A (en) | Ethylene propylene diene monomer rubber flame-retardant formula | |
| CN102977605B (en) | A kind of silicone rubber crosslinking fire-resistant cable material and preparation method thereof | |
| CN102382358A (en) | Halogen-free flame-retardant cable sheath material for railway locomotive and manufacturing method for halogen-free flame-retardant cable sheath material | |
| CN103146081B (en) | A kind of can the high flame retardant elastomeric material and preparation method thereof of extrusion moulding | |
| CN102272209B (en) | Flame retardant rubber and manufacturing method thereof, and flame protection pad using flame retardant rubber and manufacturing method thereof | |
| CN103819758A (en) | Flame-retardant fire-resistant rubber composition and preparation method thereof, and flame-retardant fire-resistant rubber wrapping tape | |
| WO2017070893A1 (en) | Ceramic silicone rubber, preparation method and use thereof | |
| CN106916438B (en) | A kind of halogen-free flameproof anti-dripping melt Thermoplastic polyurethane elastomer material and preparation method thereof | |
| CN1465616A (en) | Magnetsium hydroxide halogen-free polythene flame redardant composite material | |
| CN104194100A (en) | High-performance rubber material for cable sheaths | |
| CN101928427B (en) | Low-smoke halogen-free flame-retardant insulating rubber with rated voltage of 750V for single-core cable for railway vehicles | |
| CN103351518A (en) | Polyethylene cable material and preparation method thereof | |
| CN110684270A (en) | Preparation method of irradiation crosslinking polyolefin insulation material for locomotive | |
| CN102408620A (en) | Environment-friendly sheath material for cable and preparation method thereof | |
| CN105931718B (en) | A kind of high reliability flexible mineral insulation cable | |
| CN106479190A (en) | A kind of fire-resisting ceramic silicone rubber that can be used for middle temperature sulfuration and preparation method thereof | |
| CN108034126B (en) | Halogen-free flame-retardant polyolefin composite material and preparation method thereof | |
| CN104927177A (en) | Halogen-free low-smoke flame-retardant and arc-resistance rubber insulation material and preparation method | |
| CN102675754B (en) | Halogen-free flame-retardant ethylene-propylene-diene monomer rubber material and preparation method thereof | |
| CN105602075A (en) | High-flame-retardant modified phenolic resin cable material | |
| KR20140110139A (en) | Power cable with low-temperature resistance and oil resistance | |
| CN103087368A (en) | High-efficiency low-smoke inflaming retarding oil resisting cable material | |
| CN102977289A (en) | City track EPDM (ethylene propylene diene monomer) medium-voltage insulation material and its preparation method | |
| CN105419117A (en) | High-performance EPDM (ethylene-propylene-diene monomer) rubber pipe | |
| CN105111599A (en) | Flame-retardant automobile rubber sealing strip |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |
|
| RJ01 | Rejection of invention patent application after publication |