CN106633219A - Formula of super-heat-resistant natural damping rubber - Google Patents

Formula of super-heat-resistant natural damping rubber Download PDF

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Publication number
CN106633219A
CN106633219A CN201611068780.9A CN201611068780A CN106633219A CN 106633219 A CN106633219 A CN 106633219A CN 201611068780 A CN201611068780 A CN 201611068780A CN 106633219 A CN106633219 A CN 106633219A
Authority
CN
China
Prior art keywords
parts
rubber
vulcuren
sulphur
damping rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611068780.9A
Other languages
Chinese (zh)
Inventor
吕晓刚
吴喜林
王磊
王化勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Jituo Rubber Technologies Co Ltd
Original Assignee
Wuhu Jituo Rubber Technologies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Jituo Rubber Technologies Co Ltd filed Critical Wuhu Jituo Rubber Technologies Co Ltd
Priority to CN201611068780.9A priority Critical patent/CN106633219A/en
Publication of CN106633219A publication Critical patent/CN106633219A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention aims at providing a formula of super-heat-resistant natural damping rubber. By adding an amine type accelerator VULCUREN into Thailand smoke sheet rubber No. 3, the thermal ageing resistance degree of natural rubber is greatly improved, the condition of using at 120 DEG C can be met, and the thermal fatigue damage can reach 300,000 times without breaking; N330 carbon black, naphthenic oil, zinc oxide, stearic acid and sulphur are also added for performing cooperative interaction and guaranteeing the performance; an anti-aging agent BLE, an anti-aging agent MB, a scorch retarder CTP and coumarone resin are added, so that the service life is guaranteed, and the obtained rubber has good cohesive property.

Description

A kind of super heat-resisting natural damping rubber formula
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of super heat-resisting natural damping rubber formula.
Background technology
Rubber is elastomeric macromolecular compound.It is divided into two kinds of natural rubber and synthetic rubber.Natural rubber is from rubber Extract in the plants such as gum, Russian dandelion and be processed into after colloid;Synthetic rubber is then obtained by the aggregated reaction of various monomers.Rubber Product is widely used in industry or life each side.In prior art, the elongation of No. three smoke sheet rubbers of Thailand can be up to 2000%, pulling force reaches nearly 20MPA, with good elastic and good insulating properties, plasticity, water proof trapping, tension and the spy such as wear-resisting Point, but also need to No. three smoke sheet rubbers of Thailand and there is super heat-resisting performance.Therefore solving this problem just seems very necessary.
The content of the invention
To solve the above problems, the present invention provides a kind of super heat-resisting natural damping rubber formula, by using No. three cigarettes of Thailand Piece glue adds amine type accelerator VULCUREN, significantly improves natural gum heat-proof aging degree, can meet 120 DEG C and use bar Part, while Under Thermal Fatigue Damage can reach 300,000 times not breaking, also adds N330 carbon blacks, naphthenic oil, zinc oxide, stearic acid, sulphur and enters Row coordinate interaction ensure performance, also add antioxidant BLE, antioxidant MB, anti-scorching agent CTP, coumarone indene resin ensure the life-span, can Make rubber that there is good caking property;Solve produced problem in background technology.
It is an object of the invention to provide a kind of super heat-resisting natural damping rubber formula, includes the component material of following mass fraction:
No. three smoke sheet rubber 90-110 parts of Thailand,
N330 carbon black 45-55 parts,
Naphthenic oil 3-7 parts,
Zinc oxide 3-7 parts,
Stearic acid 1-3 parts,
Sulphur 0.3-0.7 parts,
Amine type accelerator VULCUREN 1-3 parts,
Antioxidant BLE 2-5 parts,
Antioxidant MB 2-5 parts,
Anti-scorching agent CTP 1-3 parts,
Coumarone indene resin 5-10 parts.
Further improvement is that:The amine type accelerator VULCUREN is double (N, the N'- bisbenzothiazole carbamyls of 1,6- Two sulphur)-hexane.
Further improvement is that:Include the component material of following mass fraction:
100 parts of the smoke sheet rubber of Thailand three,
50 parts of N330 carbon blacks,
5 parts of naphthenic oil,
5 parts of zinc oxide,
1 part of stearic acid,
0.5 part of sulphur,
1.5 parts of amine type accelerator VULCUREN,
3 parts of antioxidant BLE,
3 parts of antioxidant MB,
2 parts of anti-scorching agent CTP,
7 parts of coumarone indene resin.
The beneficial effect of the present invention:The present invention using No. three smoke sheet rubbers of Thailand by adding amine type accelerator VULCUREN, significantly improves natural gum heat-proof aging degree, 120 DEG C of use conditions can be met, while Under Thermal Fatigue Damage is reachable Do not break to 300,000 times, also adding N330 carbon blacks, naphthenic oil, zinc oxide, stearic acid, sulphur carries out coordinating interaction to ensure performance, also adds Plus antioxidant BLE, antioxidant MB, anti-scorching agent CTP, coumarone indene resin ensure the life-span, rubber can be made to have good caking property.
Specific embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, the embodiment It is only used for explaining the present invention, does not constitute limiting the scope of the present invention.
Embodiment one
The present embodiment provides a kind of super heat-resisting natural damping rubber formula, includes the component material of following mass fraction:
90 parts of the smoke sheet rubber of Thailand three,
45 parts of N330 carbon blacks,
3 parts of naphthenic oil,
3 parts of zinc oxide,
2 parts of stearic acid,
0.3 part of sulphur,
1 part of amine type accelerator VULCUREN,
2 parts of antioxidant BLE,
2 parts of antioxidant MB,
1 part of anti-scorching agent CTP,
5 parts of coumarone indene resin.
Embodiment two
The present embodiment provides a kind of super heat-resisting natural damping rubber formula, includes the component material of following mass fraction:
100 parts of the smoke sheet rubber of Thailand three,
50 parts of N330 carbon blacks,
5 parts of naphthenic oil,
5 parts of zinc oxide,
1 part of stearic acid,
0.5 part of sulphur,
1.5 parts of amine type accelerator VULCUREN,
3 parts of antioxidant BLE,
3 parts of antioxidant MB,
2 parts of anti-scorching agent CTP,
7 parts of coumarone indene resin.
Embodiment three
The present embodiment provides a kind of super heat-resisting natural damping rubber formula, includes the component material of following mass fraction:
110 parts of the smoke sheet rubber of Thailand three,
55 parts of N330 carbon blacks,
7 parts of naphthenic oil,
7 parts of zinc oxide,
3 parts of stearic acid,
0.7 part of sulphur,
3 parts of amine type accelerator VULCUREN,
5 parts of antioxidant BLE,
5 parts of antioxidant MB,
3 parts of anti-scorching agent CTP,
10 parts of coumarone indene resin.
Above example amine type accelerator VULCUREN is double (sulphur of N, N'- bisbenzothiazole the carbamyl two)-hexanes of 1,6-.
Above example significantly improves day by adding amine type accelerator VULCUREN using No. three smoke sheet rubbers of Thailand So glue heat-proof aging degree, can meet 120 DEG C of use conditions, while Under Thermal Fatigue Damage can reach 300,000 times not breaking, also add N330 carbon blacks, naphthenic oil, zinc oxide, stearic acid, sulphur carry out coordinating interaction to ensure performance, also add antioxidant BLE, prevent old Agent MB, anti-scorching agent CTP, coumarone indene resin ensure the life-span, rubber can be made to have good caking property.

Claims (3)

1. a kind of super heat-resisting natural damping rubber formula, it is characterised in that:Include the component material of following mass fraction:
No. three smoke sheet rubber 90-110 parts of Thailand,
N330 carbon black 45-55 parts,
Naphthenic oil 3-7 parts,
Zinc oxide 3-7 parts,
Stearic acid 1-3 parts,
Sulphur 0.3-0.7 parts,
Amine type accelerator VULCUREN 1-3 parts,
Antioxidant BLE 2-5 parts,
Antioxidant MB 2-5 parts,
Anti-scorching agent CTP 1-3 parts,
Coumarone indene resin 5-10 parts.
2. as claimed in claim 1 a kind of super heat-resisting natural damping rubber formula, it is characterised in that:The amine type accelerator VULCUREN is double (sulphur of N, N'- bisbenzothiazole the carbamyl two)-hexanes of 1,6-.
3. as claimed in claim 1 a kind of super heat-resisting natural damping rubber formula, it is characterised in that:Include following mass fraction Component material:
100 parts of the smoke sheet rubber of Thailand three,
50 parts of N330 carbon blacks,
5 parts of naphthenic oil,
5 parts of zinc oxide,
1 part of stearic acid,
0.5 part of sulphur,
1.5 parts of amine type accelerator VULCUREN,
3 parts of antioxidant BLE,
3 parts of antioxidant MB,
2 parts of anti-scorching agent CTP,
7 parts of coumarone indene resin.
CN201611068780.9A 2016-11-29 2016-11-29 Formula of super-heat-resistant natural damping rubber Pending CN106633219A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611068780.9A CN106633219A (en) 2016-11-29 2016-11-29 Formula of super-heat-resistant natural damping rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611068780.9A CN106633219A (en) 2016-11-29 2016-11-29 Formula of super-heat-resistant natural damping rubber

Publications (1)

Publication Number Publication Date
CN106633219A true CN106633219A (en) 2017-05-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611068780.9A Pending CN106633219A (en) 2016-11-29 2016-11-29 Formula of super-heat-resistant natural damping rubber

Country Status (1)

Country Link
CN (1) CN106633219A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107090102A (en) * 2017-05-16 2017-08-25 天纳克汽车工业(苏州)有限公司 A kind of high-temperature resistant rubber formula and preparation method thereof
CN107163313A (en) * 2017-07-03 2017-09-15 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation technology
JP7354509B2 (en) 2019-11-21 2023-10-03 Toyo Tire株式会社 Rubber composition for covering steel cords and pneumatic tires

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1850894A (en) * 2006-05-18 2006-10-25 刘树炯 Laminated tread cushion rubber composition
EP2733167A1 (en) * 2012-11-20 2014-05-21 The Goodyear Tire & Rubber Company Rubber composition and tire
CN104130464A (en) * 2014-07-23 2014-11-05 泰州市罡杨橡塑有限公司 Temperature-resistant natural rubber composition for damping member
CN105542264A (en) * 2016-01-19 2016-05-04 山东美晨先进高分子材料科技有限公司 Natural rubber composition of temperature-resistant high-elasticity vibration-reduction product

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1850894A (en) * 2006-05-18 2006-10-25 刘树炯 Laminated tread cushion rubber composition
EP2733167A1 (en) * 2012-11-20 2014-05-21 The Goodyear Tire & Rubber Company Rubber composition and tire
CN104130464A (en) * 2014-07-23 2014-11-05 泰州市罡杨橡塑有限公司 Temperature-resistant natural rubber composition for damping member
CN105542264A (en) * 2016-01-19 2016-05-04 山东美晨先进高分子材料科技有限公司 Natural rubber composition of temperature-resistant high-elasticity vibration-reduction product

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
董凌波,吕丹丹: "交联剂WY988在天然橡胶胶料中的应用研究", 《橡胶科技》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107090102A (en) * 2017-05-16 2017-08-25 天纳克汽车工业(苏州)有限公司 A kind of high-temperature resistant rubber formula and preparation method thereof
CN107163313A (en) * 2017-07-03 2017-09-15 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation technology
CN107163313B (en) * 2017-07-03 2019-02-22 宁波华恒底盘零件有限公司 A kind of shock-absorbing sleeve and its preparation process
JP7354509B2 (en) 2019-11-21 2023-10-03 Toyo Tire株式会社 Rubber composition for covering steel cords and pneumatic tires

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Application publication date: 20170510

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