CN106631144A - 圆柱形具有净化空气功能的沸石轻质通孔陶粒 - Google Patents
圆柱形具有净化空气功能的沸石轻质通孔陶粒 Download PDFInfo
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- CN106631144A CN106631144A CN201610846862.5A CN201610846862A CN106631144A CN 106631144 A CN106631144 A CN 106631144A CN 201610846862 A CN201610846862 A CN 201610846862A CN 106631144 A CN106631144 A CN 106631144A
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- Prior art keywords
- zeolite
- lightweight
- air purification
- cylinder
- purification function
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- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 195
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 195
- 239000010457 zeolite Substances 0.000 title claims abstract description 195
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- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 14
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5116—Ag or Au
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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Abstract
本发明公开了一种圆柱形具有净化空气功能的沸石轻质通孔陶粒，其技术方案的要点是，配料由具有净化空气功能的凹凸棒陶土粉、酸化后的沸石、活性白土废渣、白炭黑、活性氧化铝、铝酸钠、十二烷基硫酸钠、可擦洗沸石光触媒喷涂液等组成；将配料进行搅拌、挤压造粒、烘干、焙烧、保温、筛分、浸泡、烘干、筛分、密封包装为圆柱形具有净化空气功能的沸石轻质通孔陶粒；圆柱形具有净化空气功能的沸石轻质通孔陶粒具有比表面积大、堆积密度低、吸湿率高、吸附性能优越、轻质强度好、微孔和大孔为一体的特点，适用于放置在室内、家具橱柜、车辆、飞机、船舶或其它建筑物内，进行吸附和降解甲醛、氨、苯、TVOC等污染物，以达到净化空气的目的。
Description
技术领域
本发明涉及陶粒，具体涉及一种圆柱形具有净化空气功能的沸石轻质通孔陶粒。
背景技术
目前市场上供应的空气净化剂有以下几种类型：吸附型空气净化剂、遮盖型除味产品和分解型除味产品。吸附型空气净化剂是利用活性炭、竹炭、分子筛、矿物质等材料的物理吸附、化学吸附、催化氧化和还原等性能去除污染物的净化产品；遮盖型除味产品是利用芳香烃的香味遮盖空气中的各种异味，很多空气清新剂事实上并没有将异味清除，只是用一种香型将异味掩盖而已；分解型空气净化产品在市面上比较少见。
中国专利授权公告号：CN 103861421 B，授权公告日：2015年11月18日，名称为“一种空气净化剂”，公开了“一种空气净化剂，其制备原料按质量分数含有：硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉，海泡石粉、二氧化钛粉，并采用如下方法制备：1)将硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉，海泡石粉、二氧化钛粉混合；2)将步骤1)所得混合物造粒；3)烘干步骤2)造粒后所得混合物。本发明制得的空气净化剂比表面大而且均匀，对空气中有害物质的吸附分解效果好，是用于室内，车内等封闭空间的环境净化和各种空气净化器的理想选择材料”。
上述专利的不足之处是：⑴硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉和海泡石粉没有经过必要的改性处理，很难真正发挥其有效净化空气的作用。⑵所得混合粉体添加20-30％的清水搅拌后采用圆盘造粒机造粒，是一种直径为1.2-1.6mm的圆形颗粒。该发明的混合粉体自身正常含水率大于10％，加水造粒后的圆形颗粒含水率将大于30％，而烘干温度在低于100℃情况下，很难在3个小时内将圆形颗粒烘干。⑶硅藻土、沸石、麦饭石、电气石和海泡石在250～450℃进行热处理加工后，其吸附性能比较好，这是本领域的技术人员共知；该发明的圆形颗粒在低于100℃情况下进行烘干，并不能有效提高净化空气的作用，而且圆形颗粒的抗压强度也很小，用手轻轻一捏，就会将圆形颗粒捏碎为粉未状。
市场上供应的圆球形空气净化剂、分子筛、干燥剂或其它的圆球形颗粒，在造粒过程中是先将粉状配料加工成一种直径小于0.5毫米的小球，然后将配制好的雾状水溶液，喷洒在运转中的造粒机内的小球里，再将粉状配料洒落在湿润的小球的表面，经过多次重复的喷洒雾状水溶液和将粉状配料洒落在湿润的小球的表面，经过一层又一层的包裹，小球的体积不断增大，最终完成造粒的全过程，制备成一种圆球形颗粒，由于圆球形颗粒内部结构非常密实，大大减少了圆球形颗粒有效的比表面积，圆球形颗粒的比重和堆积密度都比较大，直接影响到圆球形颗粒的吸附净化效果。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种圆柱形具有净化空气功能的沸石轻质通孔陶粒。
圆柱形具有净化空气功能的沸石轻质通孔陶粒的配料由具有净化空气功能的凹凸棒陶土粉、酸化后的沸石、粉状沸石发泡剂、活性白土废渣、白炭黑、轻质碳酸钙、轻质氧化镁、活性氧化铝、铝酸钠、空心微珠、熟石膏粉、膨胀珍珠岩和可擦洗沸石光触媒喷涂液组成。
圆柱形具有净化空气功能的沸石轻质通孔陶粒的生产方法：将圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的配料进行搅拌、挤压造粒、烘干、焙烧、保温、筛分、浸泡、烘干、筛分、密封包装为圆柱形具有净化空气功能的沸石轻质通孔陶粒。
具有净化空气功能的凹凸棒陶土粉由高粘凹凸棒石粘土、凹凸棒恒湿调理剂、天然矿物吸附过滤剂、侧柏叶、硅酸铝纤维和聚丙烯酰胺组成，具有较好的粘结性、可塑性、触变性、耐火性和热稳定性，能有效的吸附空气中甲醛、氨和苯等有害物质，保护环境和增进人们的身体健康，本发明选用具有净化空气功能的凹凸棒陶土粉的颗粒细度≤0.074毫米。
天然沸石具有独特的内部结构和晶体化学性质，使其具有吸水、吸附、选择性吸附、离子交换、催化反应、耐酸和耐辐射等优异理化性能，是一种新型的非金属矿物原料。
粉状沸石发泡剂具有发泡能力强、发泡倍数高、单位体积产泡量大、泡沫外膜韧性好不易破碎，泡沫稳定性好、可长时间不消泡、泡沫细腻、在介质内生成的孔洞大小均匀、泌水量低和使用介质的相容性好等优点，本发明选用粉状沸石发泡剂的颗粒细度≤0.074毫米。
活性白土是一种无臭、无味、无毒的白色或米色粉末或颗粒，经脱色以后的活性白土失去了活性即成为活性白土废渣，一些油厂都将这些活性白土废渣丢弃，如果得不到及时处理，活性白土废渣内的脂类有机质发酵后产生霉变和恶臭，不仅资源浪费，污染环境及地下水质，而且易引起火灾，将对社会和企业造成一定的损失；本发明选用活性白土废渣的颗粒细度≤0.149毫米。
白炭黑是一种超微细无机多孔性物质，由于其粒径很小，具有比表面积大、表面吸附力强、化学纯度高、分散性能好、优越的稳定性、补强性、增稠性、附着力和触变性等特异的性能。
轻质碳酸钙颗粒微细、表面较粗糙，比表面积大，轻质碳酸钙还具有不沉降，易分散，光泽好等特性，本发明选用轻质碳酸钙的颗粒细度≤0.074毫米。
轻质氧化镁为白色轻质疏松无定型粉末，无臭无味，无毒，轻质氧化镁所占体积约为重质氧化镁的三倍左右，有高度耐火绝热性能，增强剂、胶粘剂，本发明选用轻质氧化镁的颗粒细度≤0.074毫米。
活性氧化铝是一种多孔性、高分散度的固体材料，有很大的表面积，其微孔表面具备催化作用所要求的特性，如吸附性能、表面活性、优良的热稳定性等，所以被广泛地用作化学反应的催化剂和催化剂载体，本发明选用活性氧化铝的颗粒细度≤0.074毫米。
铝酸钠又名偏铝酸钠，是一种常见化学物品，白色、无臭、无味，呈强碱性的固体，在空气中易吸收水份和二氧化碳，本发明选用铝酸钠的颗粒细度≤0.074毫米。
天然二水石膏又称为生石膏，经过煅烧、磨细可得熟石膏粉，熟石膏有较多的微孔结构，使之具优良的隔音、隔热和防火性能，本发明选用熟石膏粉的颗粒细度≤0.074毫米。
空心微珠外观为灰白色，是一种松散、流动性好的粉体材料，空心微珠比重小、表面光滑、强度大、易分散，本发明选用空心微珠的颗粒细度≤≤0.149毫米。
珍珠岩经膨胀而成为一种轻质、多功能新型材料，具有表观密度轻、导热系数低、化学稳定性好等特点，本发明选用膨胀珍珠岩的颗粒细度≤0.074毫米。
可擦洗沸石光触媒喷涂液喷涂在建筑物或装饰材料表面，在光的照射下，可以持续不断的吸附和降解甲醛、氨、苯、甲苯、二甲苯、TVOC等污染物，并具有极强的杀菌、除臭、防霉、防污自洁和净化空气的功能。
本发明通过下述技术方案予以实现：
1、圆柱形具有净化空气功能的沸石轻质通孔陶粒的配料按重量百分比由下列组分组成：圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品55～95％和可擦洗沸石光触媒喷涂液5～45％。
2、圆柱形具有净化空气功能的沸石轻质通孔陶粒的生产方法：⑴先将可擦洗沸石光触媒喷涂液放入浸泡池里，再将圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品缓慢加入浸泡池内的可擦洗沸石光触媒喷涂液中，圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品内外的微孔，不断的吸入可擦洗沸石光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗沸石光触媒喷涂液的圆柱形具有净化空气功能的沸石轻质通孔陶粒，输送到低温回转式烘干炉中进行烘干，烘干温度控制在150～180℃，烘干时间控制在1～3小时；⑶将低温烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆柱形具有净化空气功能的沸石轻质通孔陶粒的成品。
3、圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉10～45％、酸化后的沸石5～35％、粉状沸石发泡剂2～15％、活性白土废渣2～10％、白炭黑1～8％、轻质碳酸钙0.5～5％、轻质氧化镁0.5～5％、活性氧化铝0.5～5％、铝酸钠0.5～5％、空心微珠0.5～5％、熟石膏粉0.5～5％、膨胀珍珠岩0.5～5％和水10～40％。
4、圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的生产方法：⑴将圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆柱形具有净化空气功能的沸石轻质通孔陶粒的混合物；⑵将圆柱形具有净化空气功能的沸石轻质通孔陶粒的混合物输送到挤压造粒机中，挤压造粒为圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料，圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料中心的大孔为通孔；⑶将圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在200～250℃，烘干时间控制在1～4小时；⑷将烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，焙烧时间控制在1～3小时；⑸将焙烧后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料，输入不锈钢圆筒库中保温，保温时间控制在24～72小时；⑹将保温冷却后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品。
5、具有净化空气功能的凹凸棒陶土粉的生产方法是：⑴将具有净化空气功能的凹凸棒陶土粉的配料混合后输入粉碎机中进行粉碎，粉碎后的混合物颗粒细度小于0.5毫米；⑵将粉状混合物加入浸泡陈腐池中用水进行浸泡陈腐处理为半成品，浸泡陈腐时间控制在7～30天；⑶将半成品输入真空挤出机中挤压成圆柱形条状物，圆柱形条状物的直径控制在2～10毫米；⑷将圆柱形条状物输入到水泥晒场进行晾晒，晾晒后的圆柱形条状物含水量小于15％；⑸将晾晒后的圆柱形条状物输入磨机中进行磨粉为粉状物，粉状物的颗粒细度小于0.074毫米。
具有净化空气功能的凹凸棒陶土粉的配料按重量百分比由下列组分组成：高粘凹凸棒石粘土35～60％、凹凸棒恒湿调理剂10～35％、天然矿物吸附过滤剂5～20％、侧柏叶2～15％、硅酸铝纤维1～5％和聚丙烯酰胺0.1～3％。
具有净化空气功能的凹凸棒陶土粉是采用由本发明人于2011年2月25日申请的“具有净化空气功能的凹凸棒陶土粉”，中国专利授权公告号为：CN 102173743 B，授权公告日：2012年7月25日。
高粘凹凸棒石粘土是采用提高凹凸棒石粘土粘度的加工工艺生产的凹凸棒石粘土，从矿区开采的凹凸棒石粘土，需要经过30～120天的自然风化；改性处理方法是：以重量百分比计算，取自然风化后的凹凸棒石粘土94～98％，均匀加入2～6％碳酸钠，共同输入浸泡池中，加入清水进行浸泡陈化，浸泡时间为72～120小时；取浸泡后的凹凸棒石粘土，输入搅拌机中进行搅拌，并将搅拌后的凹凸棒石粘土，经挤压机挤成薄片，其厚度控制在0.5～2毫米，将凹凸棒石粘土薄片，进行晾晒，晾晒后的凹凸棒石粘土薄片，其含水量≤15％；配料以重量百分比计算：晾晒后的凹凸棒石粘土94～98％、高吸水树脂0.5～5％和纤维素0.5～3％，将上述配料进行搅拌，搅拌均匀后输入磨机中进行磨粉，颗粒细度≤0.074毫米；
上述生产工艺是采用由本发明人于2005年6月20日申请的“提高凹凸棒石粘土粘度的加工工艺”，中国专利授权公告号为：CN 1317067C，授权公告日：2007年5月23日。
高粘凹凸棒石粘土的检测方法：取28.0g凹凸棒石粘土粉试样，加入高速搅拌机的悬浮液杯中，再加入372g水，将悬浮液杯置于高速搅拌机上，在11000转/分钟的转速下搅拌20分钟，再将经过高速搅拌试样悬浮液倒入250mL的烧杯中，使用NDJ-1型旋转粘度计测试悬浮液的粘度，测试粘度值≥2200 mPa•s为高粘凹凸棒石粘土。
6、酸化后的沸石配料按重量百分比由下列组分组成：酸化后的沸石半成品90～98％、速溶硅酸钠0.1～5％、聚乙烯醇0.1～5％、羟丙基甲基纤维素0.01～3％和碳酸钠0～3％；酸化后的沸石的生产方法：将酸化后的沸石配料输入磨机中磨粉，颗粒细度≤0.074毫米，磨粉后的粉状物为酸化后的沸石。
酸化后的沸石半成品的生产方法：⑴将沸石混合物的配料输入已经运转的搅拌机中搅拌，再将稀盐酸缓慢加入沸石混合物中进行酸化处理；⑵将酸化处理后的沸石混合物，通过对辊机挤压为沸石片状物，沸石片状物的厚度≤3毫米；⑶将沸石片状物输送到回转式烘干炉内焙烧，焙烧时间为1～3小时，焙烧温度控制在300～400℃，焙烧后的沸石片状物含水量≤2％，焙烧后的沸石片状物为酸化后的沸石半成品。
沸石片状物的配料按重量百分比由下列组分组成：沸石混合物75～95％和稀盐酸5～25％；沸石混合物的配料按重量百分比由下列组分组成：沸石68～92％、凹凸棒石粘土5～30％和氧化镁0.1～3％；稀盐酸的配料按重量百分比由下列组分组成：浓度为37%的浓盐酸1～25％和水75～99％。
酸化后的沸石是采用由本发明人于2014年06月01日申请的“酸化后的沸石”，中国专利授权公告号为：CN 103979573B，授权公告日：2016年02月17日。
7、粉状沸石发泡剂配料按重量百分比由下列组分组成：活性凹凸棒石粘土45～95％、十二烷基硫酸钠1～35％、过碳酸钠1～25％、聚丙烯酸钠0.01～5％、焦磷酸钠0.01～5％和聚萘甲醛磺酸钠盐0.01～5％；粉状沸石发泡剂的生产方法：将粉状沸石发泡剂配料输入搅拌机中进行搅拌，搅拌均匀后输入磨机中进行磨粉，颗粒细度≤0.074毫米。
粉状沸石发泡剂是采用由本发明人于2013年05月26日申请的“粉状沸石发泡剂”，中国专利授权公告号为：CN 103265213B，授权公告日：2014年09月24日。
8、可擦洗沸石光触媒喷涂液的配料按重量百分比由下列组分组成：酸化后的沸石5～15％、高粘凹凸棒石粘土2～8％、纳米二氧化钛1～5％、白炭黑1～5％、纳米载银抗菌粉0.5～5％、纳米氧化镁0.5～5％、纳米二氧化锆0～5％、纳米氧化铝0～5％、纳米氧化锌0～5％、聚乙烯醇0.5～5％、聚乙二醇0.1～3％、聚二甲基硅氧烷0.1～2％和去离子水50～82％；
可擦洗沸石光触媒喷涂液的生产方法：⑴将可擦洗沸石光触媒喷涂液的配料输入已经运转的高速分散机中进行强力搅拌、分散和乳化，然后输入三辊研磨机中研磨为可擦洗沸石光触媒喷涂液的半成品；⑵将可擦洗沸石光触媒喷涂液的半成品输入胶体磨中，再次进行分散、乳化、粉碎、均质、消泡和研磨；⑶研磨后的可擦洗沸石光触媒喷涂液中固体颗粒的粒度≤0.01毫米，罐装为可擦洗沸石光触媒喷涂液。
可擦洗沸石光触媒喷涂液是采用由本申请人于2016年07月29日申请的“可擦洗沸石光触媒喷涂液”，中国专利申请号为：201610612738.2。
本发明中所述含水量百分比为重量百分比，浓度为37%的浓盐酸百分比为重量百分比。
本发明中的沸石经过酸化处理后，形成疏松多孔的海绵体，使吸附和阳离子交换等特性得以发挥，而且当沸石晶体结构中的水受热逸出后，通道和孔穴更加空旷，相应内表面积更加巨大，使沸石表现出强烈的吸附性。
具有净化空气功能的凹凸棒陶土粉内有大量的微孔和活性炭，具有较好的粘结性、可塑性、触变性、耐火性和热稳定性，能有效的吸附空气中甲醛、氨和苯等有害物质。
采用具有净化空气功能的凹凸棒陶土粉为主要原料，生产圆柱形具有净化空气功能的沸石轻质通孔陶粒，充分发挥了具有净化空气功能的凹凸棒陶土粉的有效功能。
粉状沸石发泡剂在搅拌混合为圆柱形具有净化空气功能的沸石轻质通孔陶粒混合物时，将会产生一定量的气泡，有利于增加圆柱形具有净化空气功能的沸石轻质通孔陶粒内部的孔隙率。
活性白土废渣在焙烧过程中，活性白土废渣内的脂类和有机质共同参加圆柱形具有净化空气功能的沸石轻质通孔陶粒的焙烧，提高了燃烧气流的热量，不但能节省能源，还有利于圆柱形具有净化空气功能的沸石轻质通孔陶粒的内部能完全烧透，增加圆柱形具有净化空气功能的沸石轻质通孔陶粒内部的孔隙率，以确保圆柱形具有净化空气功能的沸石轻质通孔陶粒的质量。
白炭黑、轻质氧化镁、活性氧化铝和铝酸钠能提高圆柱形具有净化空气功能的沸石轻质通孔陶粒的吸附能力，增加圆柱形具有净化空气功能的沸石轻质通孔陶粒的颗粒强度。
轻质碳酸钙、熟石膏粉、空心微珠和膨胀珍珠岩能降低圆柱形具有净化空气功能的沸石轻质通孔陶粒的堆积密度，增加圆柱形具有净化空气功能的沸石轻质通孔陶粒内部的孔隙率。
吸入可擦洗沸石光触媒喷涂液的圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品，经过烘干后为圆柱形具有净化空气功能的沸石轻质通孔陶粒，在光的照射下，圆柱形具有净化空气功能的沸石轻质通孔陶粒可以持续不断的吸附和降解甲醛、氨、苯和TVOC等污染物，并具有极强的杀菌、除臭、防霉、防污自洁和净化空气的功能。
挤压造粒后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料含水率大于30％，直接输送到回转式焙烧炉中高温焙烧，在高温焙烧过程中，陶粒毛坯料的表面先开始烧结固化，而内部的水蒸汽很难快速蒸发出来，陶粒毛坯料将会产生爆裂，而且也不能将陶粒毛坯料内部烧透。
本发明先将圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式烘干炉中缓慢进行预烘干，烘干温度控制在150～250℃，再将烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，可以确保在焙烧过程中将圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料烧透，不会产生爆裂。
焙烧后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料内在温度仍然高达700℃以上，将焙烧后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输入不锈钢圆筒库中保温，可以利用自身的余热，继续对圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料均匀加热，不但能确保将圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料内部完全烧透，还能起到均匀散布热量的作用，以提高圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料的内在质量。
圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料表面和内部有大量的微孔，是一种开口孔，开口孔不仅彼此贯通还与外界相通，圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料中心的大孔是一种通孔，有利于在焙烧过程中，能够将陶粒内部完全烧透，并能增加陶粒的有效比表面积、强度和降低堆积密度。
圆柱形具有净化空气功能的沸石轻质通孔陶粒具有比表面积大、堆积密度低、吸湿率高、吸附性能优越、外观造型美观无异味、轻质强度好、微孔和大孔为一体的特点，圆柱形具有净化空气功能的沸石轻质通孔陶粒在干燥状态下没有粉尘，可以吸附空气中大量的甲醛、氨、苯和TVOC等污染物，长年浸泡在水中也不会产生崩解。
吸入可擦洗沸石光触媒喷涂液的圆柱形具有净化空气功能的沸石轻质通孔陶粒，是在吸附的基础上进行降解，全面提高了圆柱形具有净化空气功能的沸石轻质通孔陶粒吸附和净化空气的能力。
圆柱形具有净化空气功能的沸石轻质通孔陶粒经过长时间的使用，吸附一定量的污染物后，沸石光触媒降解能力开始下降，会呈现出饱和状态，采用90～100℃的热水，将已经处于饱和状态的圆柱形具有净化空气功能的沸石轻质通孔陶粒进行反冲洗，清洗粘附在圆柱形具有净化空气功能的沸石轻质通孔陶粒内外的沸石光触媒薄膜或微粒，清洗干净后，将新配制的可擦洗沸石光触媒喷涂液，喷涂或浸泡到圆柱形具有净化空气功能的沸石轻质通孔陶粒内外，并进行烘干或晒干，可以继续发挥圆柱形具有净化空气功能的沸石轻质通孔陶粒净化空气的作用。
清洗下来的微粒废渣可以用于种植吊兰、芦荟、虎尾兰、袖珍椰子、常春藤和绿萝等绿色植物，微粒废渣内没有分解的殘留物将会被吊兰、芦荟、虎尾兰等绿色植物缓慢吸附分解，不会产生新的污染。
圆柱形具有净化空气功能的沸石轻质通孔陶粒适用于放置在室内、家具橱柜、车辆、飞机、船舶、地铁、隧道、高速公路隔音板、军事设施、装饰材料、公共场所或其它建筑物内，进行吸附和降解甲醛、氨、苯、TVOC等污染物，以达到长时间净化空气的目的。
附图说明
图1是圆柱形具有净化空气功能的沸石轻质通孔陶粒示意图，图2是圆柱形具有净化空气功能的沸石轻质通孔陶粒A-A剖面图。
如图所示：1是圆柱形具有净化空气功能的沸石轻质通孔陶粒，2是圆柱形具有净化空气功能的沸石轻质通孔陶粒的通孔。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、圆柱形具有净化空气功能的沸石轻质通孔陶粒1的配料按重量百分比由下列组分组成：圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品82％和可擦洗沸石光触媒喷涂液18％。
2、圆柱形具有净化空气功能的沸石轻质通孔陶粒1的生产方法：⑴先将可擦洗沸石光触媒喷涂液放入浸泡池里，再圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品缓慢加入浸泡池内的可擦洗沸石光触媒喷涂液中，圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品内外的微孔，不断的吸入可擦洗沸石光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗沸石光触媒喷涂液的圆柱形具有净化空气功能的沸石轻质通孔陶粒1，输送到低温回转式烘干炉中进行烘干，烘干温度控制在160～180℃，烘干时间控制在2小时；⑶将低温烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒1输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆柱形具有净化空气功能的沸石轻质通孔陶粒1的成品。
3、圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉32％、酸化后的沸石12％、粉状沸石发泡剂5％、活性白土废渣4％、白炭黑4％、轻质碳酸钙3％、轻质氧化镁3％、活性氧化铝3％、铝酸钠2％、空心微珠2％、熟石膏粉2％、膨胀珍珠岩1％和水27％。
4、圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品的生产方法：⑴将圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆柱形具有净化空气功能的沸石轻质通孔陶粒1的混合物；⑵将圆柱形具有净化空气功能的沸石轻质通孔陶粒1的混合物输送到挤压造粒机中，挤压造粒为圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料，圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料中心的大孔为通孔2；⑶将圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在220～240℃，烘干时间控制在2小时；⑷将烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～920℃，焙烧时间控制在1小时；⑸将焙烧后的圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料，输入不锈钢圆筒库中保温，保温时间控制在48小时；⑹将保温冷却后的圆柱形具有净化空气功能的沸石轻质通孔陶粒1毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆柱形具有净化空气功能的沸石轻质通孔陶粒1半成品。
Claims (3)
1.一种圆柱形具有净化空气功能的沸石轻质通孔陶粒，其特征在于，圆柱形具有净化空气功能的沸石轻质通孔陶粒的配料按重量百分比由下列组分组成：圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品55～95％和可擦洗沸石光触媒喷涂液5～45％；
所述圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉10～45％、酸化后的沸石5～35％、粉状沸石发泡剂2～15％、活性白土废渣2～10％、白炭黑1～8％、轻质碳酸钙0.5～5％、轻质氧化镁0.5～5％、活性氧化铝0.5～5％、铝酸钠0.5～5％、空心微珠0.5～5％、熟石膏粉0.5～5％、膨胀珍珠岩0.5～5％和水10～40％；
圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的生产方法：⑴将圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆柱形具有净化空气功能的沸石轻质通孔陶粒的混合物；⑵将圆柱形具有净化空气功能的沸石轻质通孔陶粒的混合物输送到挤压造粒机中，挤压造粒为圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料，圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料中心的大孔为通孔；⑶将圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在200～250℃，烘干时间控制在1～4小时；⑷将烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，焙烧时间控制在1～3小时；⑸将焙烧后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料，输入不锈钢圆筒库中保温，保温时间控制在24～72小时；⑹将保温冷却后的圆柱形具有净化空气功能的沸石轻质通孔陶粒毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品；
所述可擦洗沸石光触媒喷涂液的配料按重量百分比由下列组分组成：酸化后的沸石5～15％、高粘凹凸棒石粘土2～8％、纳米二氧化钛1～5％、白炭黑1～5％、纳米载银抗菌粉0.5～5％、纳米氧化镁0.5～5％、纳米二氧化锆0～5％、纳米氧化铝0～5％、纳米氧化锌0～5％、聚乙烯醇0.5～5％、聚乙二醇0.1～3％、聚二甲基硅氧烷0.1～2％和去离子水50～82％；
可擦洗沸石光触媒喷涂液的生产方法：⑴将可擦洗沸石光触媒喷涂液的配料输入已经运转的高速分散机中进行强力搅拌、分散和乳化，然后输入三辊研磨机中研磨为可擦洗沸石光触媒喷涂液的半成品；⑵将可擦洗沸石光触媒喷涂液的半成品输入胶体磨中，再次进行分散、乳化、粉碎、均质、消泡和研磨；⑶研磨后的可擦洗沸石光触媒喷涂液中固体颗粒的粒度≤0.01毫米，罐装为可擦洗沸石光触媒喷涂液。
2.根据权利要求1所述的圆柱形具有净化空气功能的沸石轻质通孔陶粒，其特征在于，具有净化空气功能的凹凸棒陶土粉的颗粒细度≤0.074毫米，酸化后的沸石的颗粒细度≤0.074毫米,活性白土废渣的颗粒细度≤0.149毫米，轻质碳酸钙的颗粒细度≤0.074毫米，轻质氧化镁的颗粒细度≤0.074毫米，活性氧化铝的颗粒细度≤0.074毫米，铝酸钠的颗粒细度≤0.074毫米，空心微珠的颗粒细度≤0.149毫米，熟石膏粉的颗粒细度≤0.074毫米，膨胀珍珠岩的颗粒细度≤0.074毫米。
3.根据权利要求1所述的圆柱形具有净化空气功能的沸石轻质通孔陶粒，其特征在于，圆柱形具有净化空气功能的沸石轻质通孔陶粒的生产方法：⑴先将可擦洗沸石光触媒喷涂液放入浸泡池里，再将圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品缓慢加入浸泡池内的可擦洗沸石光触媒喷涂液中，圆柱形具有净化空气功能的沸石轻质通孔陶粒半成品内外的微孔，不断的吸入可擦洗沸石光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗沸石光触媒喷涂液的圆柱形具有净化空气功能的沸石轻质通孔陶粒，输送到低温回转式烘干炉中进行烘干，烘干温度控制在150～180℃，烘干时间控制在1～3小时；⑶将低温烘干后的圆柱形具有净化空气功能的沸石轻质通孔陶粒输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆柱形具有净化空气功能的沸石轻质通孔陶粒的成品。
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