CN106630866A - Hole sealing agent for coal mines - Google Patents

Hole sealing agent for coal mines Download PDF

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Publication number
CN106630866A
CN106630866A CN201610907281.8A CN201610907281A CN106630866A CN 106630866 A CN106630866 A CN 106630866A CN 201610907281 A CN201610907281 A CN 201610907281A CN 106630866 A CN106630866 A CN 106630866A
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CN
China
Prior art keywords
hole
hole sealing
sealing agent
agent
powdery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610907281.8A
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Chinese (zh)
Inventor
柯尚利
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Shaanxi Golden Land Mining Co Ltd
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Shaanxi Golden Land Mining Co Ltd
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Publication date
Application filed by Shaanxi Golden Land Mining Co Ltd filed Critical Shaanxi Golden Land Mining Co Ltd
Priority to CN201610907281.8A priority Critical patent/CN106630866A/en
Publication of CN106630866A publication Critical patent/CN106630866A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/13Methods or devices for cementing, for plugging holes, crevices or the like

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Geology (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention belongs to the field of technologies for sealing drilled holes in coal seams, and particularly relates to a hole sealing agent for carbon dioxide fracturing technologies for coal mines. The hole sealing agent mainly comprises aluminate cement and powdery expansive agents. A weight ratio of the aluminate cement to the powdery expansive agents is 9:1. The hole sealing agent only needs to be uniformly mixed with water to obtain mixtures when used, property change reaction is carried out on raw materials after the mixtures are injected into a drilled hole, the expansive agents are expanded when in contact with the water, the hole sealing agent is gradually thickened, the volume of the hole sealing agent is continuously expanded, the strength of the hole sealing agent is improved, accordingly, the aluminum hole sealing agent can be tightly combined with the drilled hole in a coal mine under the effect of chemical adhesive and is deeply fed into gaps in the edges of the drilled hole, and the gaps can be adhered and sealed and can be prevented from being further spread. Compared with existing materials, the hole sealing agent has the advantages that the hole sealing agent is a safe and effective novel hole sealing material; the tiny gaps can be effectively sealed and can be stopped from being spread, cracking or gas leaking can be prevented after the gaps are sealed, the hole sealing agent is stable in sealing structure and long in duration, the hole sealing expenditure can be saved, and hole sealing effects are high in quality.

Description

A kind of hole sealing agent for colliery
Technical field
The invention belongs to coal bed drilling blocking technology field, and in particular to a kind of hole sealing agent for colliery.
Background technology
In the last few years, with the increasingly complexity of China's coal-mine mining environment, each colliery also increasingly weighs to gas preventing and control Depending on, wherein, it is an important means for preventing gas to the in advance extraction of coal-bed gas, the effect of pre- extraction is better, extraction Than higher, the environment in exploitation is better, and the possibility that accident occurs is also lower.It is right in the links of gas drainage under suction The closure drilled in extraction is again one of key point link.Therefore, new colliery skill of the country in the regulation of in August, 2009 In art safety standard, the closure that extraction drills mandatory provision, at least up to 8 meters of closure distance are carried out.
Drill in prior art after cutting, carry out next step operation after needing to be closed again.For example, coal seam is being surveyed After spy, need to be blocked, be easy to later exploitation.
Traditional method for sealing is to inject yellow mud toward drilling, due to the restriction of yellow mud itself, effectively will can not be bored Hole closure is closely knit, and in addition yellow mud is difficult to use mechanized operation, needs to put into substantial amounts of manpower and materials, and engineering progress is slow, gesture Project progress must be affected.For this purpose, both at home and abroad many scholars have made intensive studies to this problem, major progress is achieved. A Wang Yu outstanding persons of CN 101318802 et al. are in patent《Hole sealing agent for seismic exploration and preparation method thereof》In propose with inorganic material Material carries out sealing of hole, wherein be distinctly claimed burning CaO content for 40%-97%, because burning CaO is bulking substances, and content mistake The materials such as rock, coal may more crushed, the purpose of expected sealing of hole is not reached.The A Yang Sheng of CN 102733844 it is strong et al. Patent《A kind of hole sealing structure and method for sealing and sealing of hole expanding cement》In efficiently solve sealing of hole imprecision, gas leakage etc. and ask Topic, but wherein require to twine flexible fabric outward respectively at gas pumping pipe both ends, then expanding cement is coated on flexible fabric, it is quiet 10-15min is treated, Grouting Pipe is inserted on front plug after its solidification.In the case where drilling hole amount is less, the method has can Row.If drilling hole amount is more, reduced using the efficiency of construction of the method, this will certainly extend the engineering time, affect engineering Progress.
The content of the invention
In order to solve the above problems, the present invention is studied the composition and proportioning of hole sealing agent, has made a kind of use In the hole sealing agent in colliery.
The technical solution used in the present invention is:A kind of hole sealing agent for colliery, it is characterised in that:The hole sealing agent is mainly wrapped Include aluminate cement, powdery swelling agent, Chemical Felter.
The aluminate cement, the weight proportion of powdery swelling agent are:9: 1, the aluminate cement, powdery swelling agent, The weight error of Chemical Felter is within ± 4%.
The optimization of the present invention, according to a kind of hole sealing agent for colliery described above, it is characterised in that:The powdery is swollen Swollen dose is included in alumite plumping agent, sulphoaluminate expander, calcium oxide swelling agent, calcium oxide-calcium sulphoaluminate composite expanding agent One or more.
The optimization of the present invention, according to a kind of hole sealing agent for colliery described topmost, it is characterised in that:It is described Chemical Felter include bentonite and epoxy adhesive, polyurethane adhesive, amino resins binding agent in one kind or It is various.
The optimization of the present invention, a kind of hole sealing agent for colliery according to the top, it is characterised in that:The sealing of hole The using method of agent is to complete according to the following steps:
(4) coal mine drilling or blast hole periphery water-wet;
(5) hole sealing agent adds water and stirs, and the weight proportion of the hole sealing agent and water is 1: (1.5~3);
(6) hole sealing agent for tempering is rapidly injected to coal mine drilling or blast hole, sealing filling is closely knit, air tight, Up to sealing of hole effect after 10~15min.
The further optimization of the present invention, according to a kind of hole sealing agent for colliery described above, it is characterised in that:It is described Coal mine drilling or explosion bore dia >=50mm, hole sealed borehole length >=300mm;Drilling or explosion bore dia≤10mm, hole envelope Hole length is >=450mm;The coal mine drilling or explosion 10~50mm of bore dia, hole 300~450mm of sealed borehole length.
Compared with prior art, its effect is the present invention:The present invention adopts such scheme, when using, as long as by hole sealing agent Mix well with water, after injection hole, generation property becomes and reacts between raw material, swelling agent water-swellable, hole sealing agent gradually retrogradation, and volume is not Disconnected expansion, intensity enhancing, under Chemical Felter effect so that aluminate cement is tightly combined with coal mine drilling, and deeply bores In bore edges gap, gap bonding is blocked, prevent gap from further expanding and prolong.The present invention is a kind of safely and effectively new sealing of hole Material, compared with conventional material, can effectively block micro gap, and prevent gap expansion and prolong, gas leakage of not ftractureing after closure, closure Stability Analysis of Structures, duration length saves sealing of hole funds, and sealing of hole effect quality is high.
Specific embodiment
In order that the technological means of the present invention, creation characteristic, reached purpose and effect are easy to understand, in conjunction with concrete Embodiment, is further elaborated to the present invention.
Embodiment one:A kind of hole sealing agent for colliery, the hole sealing agent is made up of following components proportioning by weight:Aluminium 9 parts of acid salt cement, 1 part of powdery swelling agent, the aluminate cement, powdery swelling agent, Chemical Felter weight error ± Within 4%.
The powdery swelling agent be alumite plumping agent, calcium oxide swelling agent, its alumite plumping agent, calcium oxide swelling agent Parts by weight proportioning is 1: 1.
The Chemical Felter includes bentonite and epoxy adhesive, its bentonite and epoxy adhesive weight Number proportioning is 0.8: 1.
Embodiment two:A kind of hole sealing agent for colliery, the hole sealing agent is made up of following components proportioning by weight:Aluminium 9 parts of acid salt cement, 1 part of powdery swelling agent, 1 part of Chemical Felter, the aluminate cement, powdery swelling agent, Chemical Felter Weight error within ± 4%.
The powdery swelling agent is calcium oxide-calcium sulphoaluminate composite expanding agent.
The Chemical Felter includes bentonite and polyurethane adhesive, its bentonite and polyurethane adhesive parts by weight Proportioning is 1: 1.
Embodiment three:A kind of hole sealing agent for colliery, the hole sealing agent is made up of following components proportioning by weight:Aluminium 10 parts of acid salt cement, 1 part of powdery swelling agent, the aluminate cement, powdery swelling agent, Chemical Felter weight error ± Within 4%.
The powdery swelling agent is sulphoaluminate expander, calcium oxide swelling agent, and its sulphoaluminate expander, calcium oxide are swollen Swollen dose of parts by weight proportioning is 1: 1.
The Chemical Felter includes bentonite and polyurethane adhesive, its bentonite and amino resins weight of binder part Number proportioning is 0.5: 1.
The technical indicator of a kind of hole sealing agent for colliery that the present invention is prepared is:
Outward appearance:Gray powder;
Water content:Less than 2%;Fineness:
120 eye mesh screen parts by weight are not through less than 10%, through 100 eye mesh screen parts by weight more than 80%;
Compression strength after sealing of hole is:5~10MPa;
Presetting period:Less than 10 minutes.
The using method of the hole sealing agent that above-described embodiment one, two, three is prepared is,
Complete according to the following steps:
(1) coal mine drilling or blast hole periphery water-wet;
(2) hole sealing agent adds water and stirs, and the weight proportion of the hole sealing agent and water is 1: (1.5~3);
(3) hole sealing agent for tempering is rapidly injected to coal mine drilling or blast hole, sealing filling is closely knit, air tight, Up to sealing of hole effect after 15~60min.
The coal mine drilling or explosion bore dia >=50mm, hole sealed borehole length >=300mm;Drilling or explosion bore dia ≤ 10mm, hole sealed borehole length is >=450mm;The coal mine drilling or explosion 10~50mm of bore dia, hole sealed borehole length 300~ 450mm。
Hole sealing agent and water are mixed by 5: 1 after stirring evenly, in rapid injection hole, the initial set in 5 minutes, in 10~15 minutes Gain in strength is most fast.At 3~5 times, the expansion multiple is volume after expansion and hole sealing agent volume ratio for expansion multiple control, plus The fewer curing rate of the water yield is faster, and expansion multiple is reduced, and intensity is big.Intensity when volume increases to 3 times when 30 minutes can reach More than 3MPa.And the micro gap formed in boring procedure is blocked, material entirety densification has reached good sealing effectiveness, This hole sealing agent is nontoxic, harmless, low cost, and environment is not interfered with after use.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry It should be appreciated that the present invention is not restricted to the described embodiments, the description in above-described embodiment and specification is only the present invention to personnel Preference, the present invention is not limited by above-mentioned preference, without departing from the spirit and scope of the present invention, of the invention Can also there are various changes and modifications, these changes and improvements are both fallen within the scope of protection of present invention.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (5)

1. a kind of hole sealing agent for colliery, it is characterised in that:The hole sealing agent mainly includes aluminate cement, powdery swelling agent.
The aluminate cement, powdery swelling agent:9: 1, the aluminate cement, the weight error of powdery swelling agent are ± 4% Within.
2. a kind of hole sealing agent for colliery according to claim 1, it is characterised in that:The powdery swelling agent includes bright One kind in aluminite swelling agent, sulphoaluminate expander, calcium oxide swelling agent, calcium oxide-calcium sulphoaluminate composite expanding agent or It is various.
3. a kind of hole sealing agent for colliery according to claim 1, it is characterised in that:The Chemical Felter includes swollen Profit soil and epoxy adhesive, polyurethane adhesive, amino resins binding agent in one or more.
4. a kind of hole sealing agent for colliery according to claim 1, it is characterised in that:The using method of the hole sealing agent To complete according to the following steps:
(1) coal mine drilling or blast hole periphery water-wet;
(2) hole sealing agent adds water and stirs, and the weight proportion of the hole sealing agent and water is 5: 1;
(3) hole sealing agent for tempering is rapidly injected to coal mine drilling or blast hole, sealing filling is closely knit, air tight, 10~ Up to sealing of hole effect after 15min.
5. a kind of hole sealing agent for colliery according to claim 4, it is characterised in that:The coal mine drilling or explosion Bore dia >=50mm, hole sealed borehole length >=300mm;Drilling or explosion bore dia≤10mm, hole sealed borehole length is >=450mm; The coal mine drilling or explosion 10~50mm of bore dia, hole 300~450mm of sealed borehole length.
CN201610907281.8A 2016-10-18 2016-10-18 Hole sealing agent for coal mines Pending CN106630866A (en)

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Application Number Priority Date Filing Date Title
CN201610907281.8A CN106630866A (en) 2016-10-18 2016-10-18 Hole sealing agent for coal mines

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Application Number Priority Date Filing Date Title
CN201610907281.8A CN106630866A (en) 2016-10-18 2016-10-18 Hole sealing agent for coal mines

Publications (1)

Publication Number Publication Date
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863244A (en) * 2018-08-14 2018-11-23 山西潞安晋安矿业工程有限责任公司 A kind of coal mine hole sealing agent and preparation method thereof, application method
CN110926292A (en) * 2019-12-16 2020-03-27 安徽理工大学 Water-leakage-proof sand hole sealing bag for coal mine blasting and using method thereof
CN112250384A (en) * 2020-10-20 2021-01-22 陕西煤业化工技术研究院有限责任公司 High-expansion quick-setting inorganic mining hole sealing material and preparation method thereof
CN113248197A (en) * 2021-05-07 2021-08-13 河南工程学院 Waste incineration fly ash based flexible gas hole sealing material and preparation method thereof
CN113670491A (en) * 2021-08-17 2021-11-19 中国矿业大学 Chemical expansion rubber-pushing type hollow capsule geostress meter and method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844902A (en) * 2010-05-14 2010-09-29 河南工程学院 High-strength expandable mine sealing material capable of being solidified quickly
CN103849362A (en) * 2014-02-18 2014-06-11 六盘水师范学院 Formula of coal-bed gas extraction drilling-sealing material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844902A (en) * 2010-05-14 2010-09-29 河南工程学院 High-strength expandable mine sealing material capable of being solidified quickly
CN103849362A (en) * 2014-02-18 2014-06-11 六盘水师范学院 Formula of coal-bed gas extraction drilling-sealing material and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863244A (en) * 2018-08-14 2018-11-23 山西潞安晋安矿业工程有限责任公司 A kind of coal mine hole sealing agent and preparation method thereof, application method
CN108863244B (en) * 2018-08-14 2021-06-11 山西潞安晋安矿业工程有限责任公司 Coal mine hole sealing agent and preparation method and use method thereof
CN110926292A (en) * 2019-12-16 2020-03-27 安徽理工大学 Water-leakage-proof sand hole sealing bag for coal mine blasting and using method thereof
CN110926292B (en) * 2019-12-16 2021-09-10 淮南矿业(集团)有限责任公司 Water-leakage-proof sand hole sealing bag for coal mine blasting and using method thereof
CN112250384A (en) * 2020-10-20 2021-01-22 陕西煤业化工技术研究院有限责任公司 High-expansion quick-setting inorganic mining hole sealing material and preparation method thereof
CN112250384B (en) * 2020-10-20 2022-04-26 陕西煤业化工技术研究院有限责任公司 High-expansion quick-setting inorganic mining hole sealing material and preparation method thereof
CN113248197A (en) * 2021-05-07 2021-08-13 河南工程学院 Waste incineration fly ash based flexible gas hole sealing material and preparation method thereof
CN113670491A (en) * 2021-08-17 2021-11-19 中国矿业大学 Chemical expansion rubber-pushing type hollow capsule geostress meter and method

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Application publication date: 20170510