CN106626669A - High-weather-resistant and abrasion-resistant polyvinyl chloride floor - Google Patents

High-weather-resistant and abrasion-resistant polyvinyl chloride floor Download PDF

Info

Publication number
CN106626669A
CN106626669A CN201611049781.9A CN201611049781A CN106626669A CN 106626669 A CN106626669 A CN 106626669A CN 201611049781 A CN201611049781 A CN 201611049781A CN 106626669 A CN106626669 A CN 106626669A
Authority
CN
China
Prior art keywords
layer
pvc flooring
wear
resistant
resisting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611049781.9A
Other languages
Chinese (zh)
Inventor
徐诚
徐洪
蒋晓璐
陈向荣
程晔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG GREEN NEW MATERIALS CO Ltd
Original Assignee
ZHEJIANG GREEN NEW MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG GREEN NEW MATERIALS CO Ltd filed Critical ZHEJIANG GREEN NEW MATERIALS CO Ltd
Priority to CN201611049781.9A priority Critical patent/CN106626669A/en
Publication of CN106626669A publication Critical patent/CN106626669A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/712—Weather resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/744—Non-slip, anti-slip
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire

Abstract

The invention discloses a high-weather-resistant and abrasion-resistant polyvinyl chloride floor. The high-weather-resistant and abrasion-resistant polyvinyl chloride floor comprises a polyvinyl chloride floor layer and a protection layer in a thickness ratio of 40 to 1, wherein the protection layer is formed by coextruding an abrasion-resistant surface layer, a function layer, an abrasion-resistant modified layer and a bonding layer in a thickness ratio of 1 to 3 to 1 to 1; the abrasion-resistant surface layer is made of a fluorine-containing high polymer; the function layer is made by mixing the fluorine-containing high polymer, a filling agent and a functional aid in a ratio of (20-100) to (0-40) to (0.5-40); an abrasion-resistant middle layer is made of a fluorine-containing high polymer; the bonding layer is a pressure-sensitive adhesive; the protection layer is laminated and bonded with the polyvinyl chloride floor layer through one side of the bonding layer. The high-weather-resistant and abrasion-resistant polyvinyl chloride floor has the advantages of environmental friendliness, high abrasion resistance, high weather resistance, ultrahigh impact resistance and ultrahigh skid resistance.

Description

A kind of wear-resisting PVC flooring of high durable
Technical field
The present invention relates to a kind of wear-resisting PVC flooring of high durable.
Background technology
PVC flooring is popular a kind of novel light body floor decorative material in the world today, also referred to as " light Body ground material ".It is a kind of very popular product of Japan and Korea S in American-European and Asia, fashionable foreign countries, in initially entering from the beginning of the eighties State market, so far big and medium-sized cities at home obtained universal accreditation, using widely, such as family, hospital, The various places such as school, office building, factory, public place, supermarket, business, stadiums.But existing PVC flooring is organic to be waved Body of getting angry is more, maintenance is inconvenient, easily stain the defects such as trace intolerant to chemical reagent such as the tincture of iodine, limits PVC flooring Range of application.
The content of the invention
In order to solve above technical problem, it is wear-resisting that the present invention provides a kind of high durable, the wear-resisting high durable for being difficult trace PVC flooring.
A kind of wear-resisting PVC flooring of high durable of the invention, including thickness ratio is 40:1 PVC flooring layer And protective layer, the protective layer is 1 by thickness ratio:3:1:1 wearing coat, functional layer, wear-resisting intermediate layer and tack coat co-extrusion Form, the wearing coat is fluorine-containing polymer, the functional layer be fluorine-containing polymer, filler and functional aid with 20～ 100:0～40:0.5～40 ratio is mixed, and the wear-resisting intermediate layer is fluorine-containing polymer, and the tack coat is pressure-sensitive Glue；The protective layer is connected by the side of tack coat with PVC flooring lamination system bonding.
Further, the fluorine-containing polymer is fluorinated ethylene propylene, ethylene-tetrafluoroethylene, polytetrafluoroethylene (PTFE)-perfluor Propyl vinyl ether, Kynoar, polytetrafluoroethylene (PTFE), polytetrafluoroethylene (PTFE)-perfluoro methyl vinyl ether, polyethylene chlorine trifluoro second The blend of one or more in alkene, polychlorotrifluoroethylene, polytetrafluoroethylene (PTFE)-hexafluoropropene-vinylidene fluoride.
Further, the filler is the one kind in titanium dioxide, silica, barium sulfate or calcium carbonate.
Further, the functional aid include ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer, One or more in light stabilizer or antistatic additive.
Further, the pressure sensitive adhesive is in acrylic pressure-sensitive adhesivee, silicone pressure sensitive adhesive or polyurethanes pressure sensitive adhesive One kind.
Further, the PVC flooring layer includes compound compact-type PVC flooring, composite foamed type polychlorostyrene One kind in vinyl flooring or homogeneous penetrating PVC flooring.
The fluorine-containing polymer molecule interchain arrangement that wearing coat and wear-resisting intermediate layer use in the application is tight, has again stronger Hydrogen bond, therefore with good chemical resistance, heat-resisting quantity, oxidative resistance, weatherability, the radiance of resistance to ray outside, also It is excellent resistance to for having herein as the wearing coat of outer layer with properties such as piezoelectricity, dielectricity, pyroelectricities Grind and be difficult trace effect.
Functional layer includes that uvioresistant, high tenacity, antioxygen resist cold electrostatic, light due to adding functional aid and have in the application The function such as heat endurance is good, adds as the case may be different functionalities auxiliary agent to make it have difference in functionality；Add filling simultaneously Agent is used to provide the blending between fluorine-containing polymer and functional aid.
The tack coat of the application is pressure sensitive adhesive, for compacting bonding PVC flooring, more than realization compacting under 50N pressure Bonding.
The PVC flooring that a kind of high durable of the present invention is wear-resisting has the advantages that：
1st, environmental protection：Protective layer is made using environment-protecting asepsis material, while being can to completely cut off the release of PVC flooring layer Organic matter volatilization (release of VOC)；
2nd, high-wearing feature：Transparent protective film of the protective layer based on fluorine-containing polymer, it is covered in PVC flooring layer On make the wear-resisting grade of PVC flooring improve more than 30% than highest polyvinyl chloride grade on the market, service life is reachable More than 10 years, so and its suitable for places such as the big hospital of flow of the people, school, office building, market, supermarket, the vehicles；
3rd, high-weatherability：Fluorine-containing polymer chemical stability in protective layer is high, can resist photooxidation hydrothermal aging, extends general The service life of logical PVC flooring layer.
4th, high resiliency and superpower impact resistance：Soft texture, elasticity are good, there is good elastic extensive under the impact of weight Multiple, more preferably, its comfortable foot feeling is referred to as " material soft gold " to coiled material floor soft texture elasticity, while the PVC flooring With very strong impact resistance, for heavy impact destruction has very strong elasticity to recover, damage is not resulted in；While the polychlorostyrene second Alkene floor can reduce to greatest extent in the face of human body injury, and disperse impact to foot, personnel fall down and injury ratio Rate is greatly reduced compared with other floors.
5th, it is superpower anti-skidding：Protective layer has special skid resistance, compared with common earth material, the pin in the case of viscous water Sense is more puckery, more difficult to slide into, i.e., more chance water is more puckery, and resistance to wet and slippery grade can reach R10, therefore require in public safety higher Public place such as airport, hospital, kindergarten, school etc. are first-selected floor decorative materials.
6th, high soil resistance：Fluorine-containing polymer in antifouling surface layer is a kind of chemical inert material, is resistant to most of chemical solution The erosion (including the tincture of iodine reagent for easily polluting of traditional PVC flooring) of agent；Anti acid alkali performance can be excellent, is 1～14 to PH Chemical agent 72h in leave no trace.
Description of the drawings
Fig. 1 is a kind of structural representation of the wear-resisting PVC flooring of high durable of the invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Embodiment 1
As shown in Figure 1, a kind of wear-resisting PVC flooring of high durable of the present embodiment, including thickness ratio is 40:1 answers Compact-type PVC flooring layer 1 and protective layer are closed, protective layer is 1 by thickness ratio:3:1:It is 1 wearing coat 2, functional layer 3, resistance to Mill intermediate layer 4 and tack coat 5 are co-extruded, and wearing coat 2 is fluorine-containing polymer Kynoar and polytetrafluoroethylene (PTFE) with 100:0 ～10 ratio is mixed, and functional layer 3 is Kynoar, titanium dioxide and functional aid with 20～100:0～20:0.5 ～40 ratio is mixed, and functional aid is with 0.5～3 with ultraviolet absorber and toughener:0～10 ratio mixing and Into wear-resisting intermediate layer 4 is fluorine-containing polymer Kynoar, and tack coat 5 is acrylic pressure-sensitive adhesivee；Protective layer passes through tack coat 5 side is connected with the compacting bonding of compound compact-type PVC flooring layer 1.
Embodiment 2
As shown in Figure 1, a kind of wear-resisting PVC flooring of high durable of the present embodiment, including thickness ratio is 40:1 answers Expansion type PVC flooring layer 1 and protective layer are closed, protective layer is 1 by thickness ratio:3:1:It is 1 wearing coat 2, functional layer 3, resistance to Mill intermediate layer 4 and tack coat 5 are co-extruded, and wearing coat 2 is fluorine-containing polymer fluorinated ethylene propylene and ETFE with 100:5～ 10 ratio is mixed, and functional layer 3 is fluorinated ethylene propylene, silica and functional aid with 20～100:0～40: 0.5～20 ratio is mixed, and functional aid is with 1～3 with antioxidant and cold-resistant agent:4～10 ratio is mixed, Wear-resisting intermediate layer 4 is fluorine-containing polymer fluorinated ethylene propylene, and tack coat 5 is polyurethanes pressure sensitive adhesive；Protective layer is by bonding The side of layer 5 is connected with the compacting bonding of composite foamed type PVC flooring layer 1.
Embodiment 3
As shown in Figure 1, a kind of wear-resisting PVC flooring of high durable of the present embodiment, including thickness ratio is 40:1 it is same The saturating heart PVC flooring layer 1 of matter and protective layer, protective layer is 1 by thickness ratio:3:1:It is 1 wearing coat 2, functional layer 3, wear-resisting Intermediate layer 4 and tack coat 5 are co-extruded, and wearing coat 2 is fluorine-containing polymer polytetrafluoroethylene (PTFE)-perfluoro propyl vinyl ether, MFA With ECTFE with 100:0～3:2～5 ratio is mixed, and functional layer 3 is polytetrafluoroethylene (PTFE)-perfluoro propyl vinyl ether, sulphur Sour barium and functional aid are with 40～100:0～40:0.5～20 ratio is mixed, and functional aid is with UV absorption Agent and heat stabilizer are with 1～5:1～5 ratio is mixed, and wear-resisting intermediate layer 4 is fluorine-containing polymer polytetrafluoroethylene (PTFE)-perfluor Propyl vinyl ether, tack coat 5 is silicone pressure sensitive adhesive；Protective layer is by the side of tack coat 5 and homogeneous penetrating polychlorostyrene second The compacting bonding of alkene floor layer 1 is connected.
Embodiment 4
As shown in Figure 1, a kind of wear-resisting PVC flooring of high durable of the present embodiment, including thickness ratio is 40:1 answers Compact-type PVC flooring layer 1 and protective layer are closed, protective layer is 1 by thickness ratio:3:1:It is 1 wearing coat 2, functional layer 3, resistance to Mill intermediate layer 4 and tack coat 5 are co-extruded, and wearing coat 2 is fluorine-containing polymer polychlorotrifluoroethylene and polytetrafluoroethylene (PTFE)-hexafluoro Propylene-vinylidene fluoride is with 100:3～5 ratio is mixed, and functional layer 3 is polychlorotrifluoroethylene, calcium carbonate and feature Auxiliary agent is with 40～100:0～20:0.5～20 ratio is mixed, functional aid be with light stabilizer or antistatic additive with 0.5～4:1～10 ratio is mixed, and wear-resisting intermediate layer 4 is fluorine-containing polymer polychlorotrifluoroethylene, and tack coat 5 is organic Silicon class pressure sensitive adhesive；Protective layer is connected by the side of tack coat 5 with the compacting bonding of compound compact-type PVC flooring layer 1.
The quality measurements of above example are as shown in the table：
Data above shows to have using a kind of wear-resisting PVC flooring of high durable of above example following beneficial Effect：
1st, environmental protection：Protective layer is made using environment-protecting asepsis material, while being can to completely cut off the release of PVC flooring layer Organic matter volatilization (release of VOC)
2nd, high-wearing feature：Transparent protective film of the protective layer based on fluorine-containing polymer, it is covered in PVC flooring layer On make the wear-resisting grade of PVC flooring improve more than 30% than highest polyvinyl chloride grade on the market, service life is reachable More than 10 years, so and its suitable for places such as the big hospital of flow of the people, school, office building, market, supermarket, the vehicles；
3rd, high-weatherability：Fluorine-containing polymer chemical stability in protective layer is high, can resist photooxidation hydrothermal aging, extends general The service life of logical PVC flooring layer.
4th, high resiliency and superpower impact resistance：Soft texture, elasticity are good, there is good elastic extensive under the impact of weight Multiple, more preferably, its comfortable foot feeling is referred to as " material soft gold " to coiled material floor soft texture elasticity, while the PVC flooring With very strong impact resistance, for heavy impact destruction has very strong elasticity to recover, damage is not resulted in；While the polychlorostyrene second Alkene floor can reduce to greatest extent in the face of human body injury, and disperse impact to foot, personnel fall down and injury ratio Rate is greatly reduced compared with other floors.
5th, it is superpower anti-skidding：Protective layer has special skid resistance, compared with common earth material, the pin in the case of viscous water Sense is more puckery, more difficult to slide into, i.e., more chance water is more puckery, and resistance to wet and slippery grade can reach R10, therefore require in public safety higher Public place such as airport, hospital, kindergarten, school etc. are first-selected floor decorative materials.
6th, high soil resistance：Fluorine-containing polymer in antifouling surface layer is a kind of chemical inert material, is resistant to most of chemical solution The erosion (including the tincture of iodine reagent for easily polluting of traditional PVC flooring) of agent；Anti acid alkali performance can be excellent, is 1～14 to PH Chemical agent 72h in leave no trace.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (6)

1. the wear-resisting PVC flooring of a kind of high durable, it is characterised in that：It is 40 including thickness ratio:1 PVC flooring Layer and protective layer, the protective layer is 1 by thickness ratio:3:1:1 wearing coat, functional layer, wear-resisting intermediate layer and tack coat are common Squeeze and form, the wearing coat is fluorine-containing polymer, the functional layer is fluorine-containing polymer, filler and functional aid with 20 ～100:0～40:0.5～40 ratio is mixed, and the wear-resisting intermediate layer is fluorine-containing polymer, and the tack coat is pressure-sensitive Glue；The protective layer is connected by the side of tack coat with PVC flooring lamination system bonding.
2. the wear-resisting PVC flooring of a kind of high durable according to claim 1, it is characterised in that：It is described fluorine-containing high poly- Thing be fluorinated ethylene propylene, ethylene-tetrafluoroethylene, polytetrafluoroethylene (PTFE)-perfluoro propyl vinyl ether, Kynoar, poly- four PVF, polytetrafluoroethylene (PTFE)-perfluoro methyl vinyl ether, polyethylene chlorotrifluoroethylene, polychlorotrifluoroethylene, polytetrafluoroethylene (PTFE)- The blend of one or more in hexafluoropropene-vinylidene fluoride.
3. the wear-resisting PVC flooring of a kind of high durable according to claim 1, it is characterised in that：The filler is One kind in titanium dioxide, silica, barium sulfate or calcium carbonate.
4. the wear-resisting PVC flooring of a kind of high durable according to claim 1, it is characterised in that：The feature is helped Agent includes the one kind or several in ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer, light stabilizer or antistatic additive Kind.
5. the wear-resisting PVC flooring of a kind of high durable according to claim 1, it is characterised in that：The pressure sensitive adhesive is One kind in acrylic pressure-sensitive adhesivee, silicone pressure sensitive adhesive or polyurethanes pressure sensitive adhesive.
6. the wear-resisting PVC flooring of a kind of high durable according to claim 1, it is characterised in that：The polyvinyl chloride Floor layer includes compound compact-type PVC flooring, composite foamed type PVC flooring or homogeneous penetrating PVC flooring In one kind.
CN201611049781.9A 2016-11-24 2016-11-24 High-weather-resistant and abrasion-resistant polyvinyl chloride floor Pending CN106626669A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611049781.9A CN106626669A (en) 2016-11-24 2016-11-24 High-weather-resistant and abrasion-resistant polyvinyl chloride floor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611049781.9A CN106626669A (en) 2016-11-24 2016-11-24 High-weather-resistant and abrasion-resistant polyvinyl chloride floor

Publications (1)

Publication Number Publication Date
CN106626669A true CN106626669A (en) 2017-05-10

Family

ID=58812892

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611049781.9A Pending CN106626669A (en) 2016-11-24 2016-11-24 High-weather-resistant and abrasion-resistant polyvinyl chloride floor

Country Status (1)

Country Link
CN (1) CN106626669A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180142115A1 (en) * 2016-11-24 2018-05-24 Zhejiang Green New Materials Co.,LTD High stain resistance and easy cleaning polyvinyl chloride floor and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101163762A (en) * 2005-04-19 2008-04-16 杜邦三井氟化物有限公司 Fluororesin coating film
CN101619615A (en) * 2009-04-24 2010-01-06 麦道地板（苏州）有限公司 Veneering water-proofing multi-layer solid wood floor
CN105291499A (en) * 2015-10-15 2016-02-03 浙江歌瑞新材料有限公司 PE or PVC base material decoration film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101163762A (en) * 2005-04-19 2008-04-16 杜邦三井氟化物有限公司 Fluororesin coating film
CN101619615A (en) * 2009-04-24 2010-01-06 麦道地板（苏州）有限公司 Veneering water-proofing multi-layer solid wood floor
CN105291499A (en) * 2015-10-15 2016-02-03 浙江歌瑞新材料有限公司 PE or PVC base material decoration film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180142115A1 (en) * 2016-11-24 2018-05-24 Zhejiang Green New Materials Co.,LTD High stain resistance and easy cleaning polyvinyl chloride floor and preparation process thereof
US10662345B2 (en) * 2016-11-24 2020-05-26 Zhejiang Green New Materials Co., Ltd. High stain resistance and easy cleaning polyvinyl chloride floor and preparation process thereof

Similar Documents

Publication Publication Date Title
CN104263259B (en) A kind of low melting point high-adhesive-strength TPU hot melt adhesive film and preparation method thereof
CN104736654B (en) It is used in particular for coating the pressure sensitive adhesive material of electronic building brick
CN1964843B (en) Multi-layer polymer film
CN106784097A (en) A kind of transparent solar components backboard of high water resistant and foreboard
CN106626649A (en) Polyvinyl chloride floor resistant to stain and easy to clean as well as preparation process of polyvinyl chloride floor
CN105038033A (en) PVC (polyvinyl chloride) plastic floor
CN105196778A (en) Decorative film
CN106626669A (en) High-weather-resistant and abrasion-resistant polyvinyl chloride floor
CN106677453A (en) Weather-proof polyvinyl chloride wallpaper and preparation process thereof
CN104351998A (en) Chemical protective clothing fabric
CN103261312A (en) Fluoropolymer-based film for photovoltaic application
CN106903955A (en) It is a kind of to can be used for the structure of composite membrane of Building Skin and its application
CN107459942A (en) A kind of self-adhering-type EPDM waterproof rolled sheet
CN207683059U (en) Polymer compound film and waterproof roll
CN105754280A (en) Recyclable self-cleaning reflective high polymer roof waterproof roll and preparation method thereof
CN206157060U (en) Energy -concerving and environment -protective colored resistance to compression doubling glass
CN105295257A (en) Scraping-resisting super wear-resisting PVC (polyvinyl chloride) transparent sheet and manufacturing method thereof
CN104497915B (en) Binding resin for multilayer coextruded hoses
CN110641109A (en) Anti-wicking mildew-proof weather-proof membrane material and preparation method thereof
CN206475520U (en) A kind of Novel tent fabric
CN102585715A (en) Colored EVA (Ethylene Vinyl-Acetate copolymer) interlayer rubber sheet
CN211172922U (en) PVC floor
CN207014887U (en) A kind of wear-resistant antibacterial ageing resistance polypropylene film
CN202237005U (en) Composite multilayer gymnastics mat
CN105525735A (en) Environment-friendly nontoxic plastic floorboard

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170510

RJ01 Rejection of invention patent application after publication