CN106626343A - Ultra-wide polyvinyl chloride thin film blow-molding device - Google Patents

Ultra-wide polyvinyl chloride thin film blow-molding device Download PDF

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Publication number
CN106626343A
CN106626343A CN201611077577.8A CN201611077577A CN106626343A CN 106626343 A CN106626343 A CN 106626343A CN 201611077577 A CN201611077577 A CN 201611077577A CN 106626343 A CN106626343 A CN 106626343A
Authority
CN
China
Prior art keywords
polyvinyl chloride
core
melt
ultra
wide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611077577.8A
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Chinese (zh)
Inventor
刘东升
杨卫民
焦志伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Green Chemical (beijing) Technology Co Ltd
Beijing University of Chemical Technology
Original Assignee
Green Chemical (beijing) Technology Co Ltd
Beijing University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Green Chemical (beijing) Technology Co Ltd, Beijing University of Chemical Technology filed Critical Green Chemical (beijing) Technology Co Ltd
Priority to CN201611077577.8A priority Critical patent/CN106626343A/en
Publication of CN106626343A publication Critical patent/CN106626343A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/28Shaping by stretching, e.g. drawing through a die; Apparatus therefor of blown tubular films, e.g. by inflation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0018Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/86Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
    • B29C48/865Heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets

Abstract

The invention discloses an ultra-wide polyvinyl chloride thin film blow-molding device and belongs to the field of plastic machinery. The ultra-wide polyvinyl chloride thin film blow-molding device is mainly composed of n precision polyvinyl chloride extruders, a film blowing machine head, a film tube, a reversed-V-shaped plate, traction rollers, guiding rollers, air rings and a rolling-up device. Distribution runners and spiral runners are evenly distributed on the cylindrical outer surface of a core mold. The center of the core mold is provided with a venthole. Polyvinyl chloride is subjected to melt plastification through the n precision polyvinyl chloride extruders to be a melt, and the melt enters between the core mold and a core mold sleeve. N melt distribution inlets corresponding to the core mold sleeve are formed in the lower portion of the core mold, and each melt distribution inlet is evenly distributed into the m spiral runner through the corresponding distribution runner. Parts of the n*m spiral runner overlap with one other to converge upward to be annular mouth model gaps. Different melt inlets are evenly distributed, and appropriate spiral lead angles of the spiral runners are selected, so that overheating decomposition of the polyvinyl chloride in the flowing process is avoided, and non-uniformity, caused by shortening of the annular runner length, of the thickness of annular performs is compensated.

Description

A kind of ultra-wide polyvinyl chloride film blow molding apparatus
Technical field
The present invention relates to a kind of ultra-wide polyvinyl chloride (PVC) film blow molding apparatus, for ultra-wide, (fabric width is more than 5-6 rice) polyvinyl chloride film preparation, belong to field of plastic machinery.
Background technology
Polyvinyl chloride is unique non-petroleum dependent form resin in five big general-purpose plastics, is hindered extensively, certainly with raw material sources Combustion, good heat preservation performance, it is cheap the advantages of.The Apparent con- sumption of polyvinyl chloride in 2014, up to 16,000,000 tons, is to be only second to poly- second The second largest general-purpose plastics of alkene.Film is the important product form of polyvinyl chloride, is widely used in the fields such as medical treatment, packaging, special It, due to polyvinyl chloride good heat insulating, good translucency, good weatherability, lower-price characteristic, is to prepare agriculture greenhouse film not to be Optimal material.Modern agriculture is required more than 20 meters the fabric width of awning film mostly, and the polyvinyl chloride that at present prepared by technology Film fabric width is up to 5-6 rice so that application of the polyvinyl chloride in agriculture greenhouse film field is severely limited.
The version of head mainly has core method and the big class of spiral flow Dow process two in existing blown film device.Polyvinyl chloride heat Stability is poor, and the easy thermal decomposition excessively of process is carbonized and produces hydrogen-chloride etching process equipment, and technique controlling difficulty is very big.Polychlorostyrene Ethene prepares wide cut and the technical difficulty of ultra-wide film is as follows:(1) core method melt flow length, is suitable for polyvinyl chloride film Preparation, but be difficult to ensure that the uniformity of ring flow, be only suitable for the blow molding of little fabric width polyvinyl chloride film;(2) spiral Runner method can effectively ensure the uniformity of ring flow by the annular channel of long flow process, be adapted to the system of big fabric width film Standby, existing more than 20 meters of polyethylene film and ethene-vinyl acetate polymers (EVA) film are prepared using this version , but because its flow process is very long, polyvinyl chloride is easily decomposed phenomenon in runner, thus this method is not suitable for polyvinyl chloride The production of film.Patent ZL200910180067.7 discloses a kind of large-scale scale polymer product extrusion molding device and technique, main If melt planet pump is divided into into multiply by one stream, re-segmenting enters head branch flow passage with uniform pressure, to realize The uniformity of high-precision control stream, but melt not only needs to also need to flow through point through the distribution of melt planet pump in device Branch flow passage, the flow process reached between mouth mold from after extruder is longer, is not suitable for the production of polyvinyl chloride film.
Accurate polyvinyl chloride extruder is that precise control is carried out to screw speed by servomotor, realizes extrusion polychlorostyrene second The yield and pressure remained steady of alkene, it is shorter that its plasticizing process compares general extruder, it is ensured that what polyvinyl chloride was plastified completely Do not decompose simultaneously.
The content of the invention
It is an object of the invention to overcome above technological deficiency, there is provided a kind of ultra-wide polyvinyl chloride film blow molding dress Put, the processing technology for being suitable for pvc material is required and realizes the preparation of ultra-wide polyvinyl chloride film, i.e., comprehensive spiral The advantage of runner and accurate polyvinyl chloride extruder, short distance completes evenly distributing for melt.
In order to realize object above, the present invention is employed the following technical solutions:A kind of ultra-wide polyvinyl chloride film is blow molded into Type device, mainly by n platforms precision polyvinyl chloride extruder, blown-film die, membrane tube, collapser, carry-over pinch rolls, guide roller, vane and Wrap-up is constituted, and has core and core sleeve in blown-film die, and the gap between core and core sleeve is the passage of melt, Distribution runner and helical flow path are evenly equipped with the cylindrical outer surface of core, there are passage, n platforms precision polyvinyl chloride in the center of core Extruder has corresponding with accurate polyvinyl chloride extruder by flange and the core sleeve connection of blown-film die on core sleeve N melt inlet, polyvinyl chloride becomes melt into core and core Jing after n platforms precision polyvinyl chloride extruder fusion plastification Between sleeve;Core bottom arranges n melt corresponding with core sleeve and distributes entrance, and the cylindrical outer surface of core is provided with and melts The corresponding n components of body entrance match somebody with somebody runner, and each the allocated uniform flow passage of melt distribution entrance is distributed into m head helical flow paths, in core N × m heads helical flow path part is overlapped on mould merges into upwards annular die gap;Melt is Jing after the extrusion of annular die gap Move upwards in the presence of carry-over pinch rolls, passage and the lower inflation of vane effect form membrane tube, membrane tube Jing collapser in Jing cores Draw in, under guide roller effect wrap-up and final molding are entered.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, the quantity of helical flow path is preferably 4 Integral multiple, the lead angle of helical flow path is 30-60 °, the corresponding central angle of chord length of helical flow path within 180 °, specifically Determined by handpiece size, it is ensured that material will not decompose because thermal history is long and be limited.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, melt inlet, distribution runner and spiral shell Eddy flow road is all located on core, it is to avoid runner junction is rough and cause buildup to be decomposed when being arranged on different parts.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, it is characterised in that:It is arranged on core The accurate adjustable accurate polyvinyl chloride dedicated extruder of the external flow of melt inlet of bottom, each melt inlet connects an essence Close polyvinyl chloride extruder, all porch flow into the melt flow of distribution runners and adjust to identical.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, distribute the sectional area phase everywhere of runner Same or edge is extruded upwards direction and is slightly compressed, and sectional area of the melt inlet sectional area score with runner for being arranged on core bottom is omited It is big or identical.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, are arranged on core sleeve heater Can be electrical heating, or electromagnetic induction heating.
During work, core and core sleeve are heated to temperature required, and ensure the uniformity of temperature.Open extruder, Per platform, accurate polyvinyl chloride extruder all distributes entrance and distribution runner and is fed forward the material for having plastified simultaneously by melt It is even to be distributed into m parts and enter to helical flow path.Logistics Jing helical flow path is fed forward and topmost forms polyvinyl chloride in core Blowing material base.It is in uneven thickness if there is material base ring, can be solved by the flow of adjustment precision polyvinyl chloride extruder Certainly.
From above technical scheme, the present invention has the advantage that compared with prior art:(1) play helical flow path to exist The unique advantage of blow molding super large fabric width film, but by evenly distributing different entrance and choosing appropriate helical flow path Lead angle make helical flow path contraction in length avoid polyvinyl chloride in flow process cross thermally decompose, Jing test understand, spiral shell Rotation flow channel length can shorten to original 40-65%;(2) by accurate polyvinyl chloride extruder and evenly distribute runner realize it is right The Effective Regulation of mass flow in helical flow path, makes up the thickness of the annular material base brought due to shortening annular flow channel length not Uniformity.
Description of the drawings
Fig. 1 is a kind of process chart of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention;
Fig. 2 is a kind of core flow passage structure figure of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention;
Fig. 3 is a kind of blown-film die and extruder of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention Distribution schematic diagram.
In figure:1- precision polyvinyl chloride extruders, 2- blown-film dies, 3- membrane tubes, 4- collapsers, 5- carry-over pinch rolls, 6- is oriented to Roller, 7- vanes, 8- wrap-ups, 9- cores, 10- core sleeves, 11- helical flow paths, 12- distribution runners, 13- passages, 14- Melt distributes entrance.
Specific embodiment
As shown in figure 1, a kind of ultra-wide polyvinyl chloride film blow molding apparatus, are mainly squeezed by n platforms precision polyvinyl chloride Go out machine 1, blown-film die 2, membrane tube 3, collapser 4, carry-over pinch rolls 5, guide roller 6, vane 7 and wrap-up 8 to constitute, blown-film die 2 Inside have core 9 and a core sleeve 10, the gap between core 9 and core sleeve 10 for melt passage, the cylindricality appearance of core 9 Distribution runner 12 and helical flow path 11 are evenly equipped with face, there are passage 13, n platforms precision polyvinyl chloride extruder 1 in the center of core 9 It is connected with the core sleeve 10 of blown-film die 2 by flange (not shown), there is n melt inlet on core sleeve 10, is gathered Vinyl chloride becomes melt and enters between core 9 and core sleeve 10 Jing after the fusion plastification of n platforms precision polyvinyl chloride extruder 1;Core 9 Bottom arranges n and distributes entrance 14 with the corresponding melt of core sleeve 10, and the cylindrical outer surface of core 9 is provided with and enters with melt The corresponding n components of mouth match somebody with somebody runner 12, and each the allocated runner 12 of melt distribution entrance 14 evenly distributes into m heads helical flow path 11, N × m heads helical flow path 11 merges into upwards annular die gap on core 9;Melt is leading Jing after the extrusion of annular die gap Move upwards in the presence of pick-up roll 5, passage 13 and the lower inflation of the effect of vane 7 form membrane tube 3, the Jing herringbones of membrane tube 3 in Jing cores 9 Plate 4 draws in, and in the case where guide roller 6 is acted on wrap-up 8 and final molding are entered.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, as shown in Fig. 2 each melt distribution Quantity m of the allocated rear screw runner 11 of runner 12 of entrance 14 is taken as 4, and lead angle is generally 30-60 °, and the anglec of rotation is general Within 180 °, in a circumferential direction phase mutual is overlapped helical flow path 11, is specifically determined by handpiece size, it is ensured that material is not warm to be gone through The long decomposition of journey is limited, and when lead angle is 45 °, the length of helical flow path 11 can be the 50% of normal spiral runner.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, melt inlet, the distribution and of runner 12 Helical flow path 11 is all located on core 9, it is to avoid runner junction is rough and cause buildup to be decomposed when being arranged on different parts.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, are arranged on the bottom of core sleeve 10 The accurate adjustable polyvinyl chloride dedicated extruder 1 of the external flow of melt inlet, each melt inlet connects an accurate polychlorostyrene second Alkene extruder 1, the motor of accurate polyvinyl chloride extruder 1 adopts servomotor, it is possible to achieve by the accurate polyvinyl chloride of adjustment Adjusting the thickness of corresponding film, all porch flow into the melt flow of distribution runners 12 to the rotating speed of the motor of extruder 1 Amount is adjusted to identical, and quantity n of accurate polyvinyl chloride extruder 1 is 9 shown in Fig. 3.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, distribute the sectional area of runner 12 everywhere Identical or edge is extruded upwards direction and is slightly compressed, and runner is matched somebody with somebody in the melt distribution entrance 14 sectional area score for being arranged on the bottom of core 9 12 sectional area sum is bigger or identical, and each melt distributes the section of the sectional area than corresponding helical flow path 11 of entrance 14 Product sum is bigger, and depth of the helical flow path 11 along melt outlet direction shoals gradually, is zero in its end depth.
A kind of ultra-wide polyvinyl chloride film blow molding apparatus according to the present invention, are arranged on core sleeve 10 plus hot charging Putting can be electrical heating, or electromagnetic induction heating.
During work, core 9 and core sleeve 10 are heated to temperature required, and ensure the uniformity of temperature.Open accurate Polyvinyl chloride extruder 1, per platform, accurate polyvinyl chloride extruder 1 all distributes entrance 14 and distribution runner 12 and will plastify by melt Good material is fed forward and evenly distributes into m parts and enter to helical flow path 11.Logistics Jing helical flow path 11 is fed forward simultaneously Polyvinyl chloride blowing material base is topmost formed in core 9.It is in uneven thickness if there is material base ring, can be poly- by adjustment precision The flow of vinyl chloride extruder 1 is resolved.

Claims (5)

1. a kind of ultra-wide polyvinyl chloride film blow molding apparatus, mainly by n platforms precision polyvinyl chloride extruder, inflation film manufacturing machine Head, membrane tube, collapser, carry-over pinch rolls, guide roller, vane and wrap-up composition, there is core and core sleeve, core in blown-film die Gap between mould and core sleeve is the passage of melt, it is characterised in that:Distribution stream is evenly equipped with the cylindrical outer surface of core There is passage at road and helical flow path, the center of core, and n platforms precision polyvinyl chloride extruder is by flange and the core of blown-film die Sleeve connection, there is the n melt inlet corresponding with accurate polyvinyl chloride extruder, polyvinyl chloride Jing n platforms essence on core sleeve Become melt after close polyvinyl chloride extruder fusion plastification to enter between core and core sleeve;Core bottom arranges n and core The corresponding melt of sleeve distributes entrance, and the cylindrical outer surface of core is provided with n components corresponding with melt inlet with runner, each The allocated uniform flow passage of melt distribution entrance is distributed into m head helical flow paths, n × m heads helical flow path part phase mutual respect on core It is folded to merge into annular die gap upwards;Melt is moved upwards Jing after the extrusion of annular die gap in the presence of carry-over pinch rolls, Jing Passage and the lower inflation of vane effect form membrane tube in core, and membrane tube Jing collapser draws in, and under guide roller effect winding is entered Device and final molding.
2. a kind of ultra-wide polyvinyl chloride film blow molding apparatus according to claim 1, it is characterised in that:Spiral flow The lead angle in road is 30-60 °, and the corresponding central angle of chord length of helical flow path is within 180 °.
3. a kind of ultra-wide polyvinyl chloride film blow molding apparatus according to claim 1, it is characterised in that:It is arranged on The accurate adjustable accurate polyvinyl chloride extruder of the external flow of melt inlet of core bottom, the electricity of accurate polyvinyl chloride extruder Machine is servomotor, and all porch flow into the melt flow of distribution runners and adjust to identical.
4. a kind of ultra-wide polyvinyl chloride film blow molding apparatus according to claim 1, it is characterised in that:Distribution stream The sectional area in road is identical everywhere or slightly compresses along direction is extruded upwards, is arranged on the melt inlet sectional area score of core bottom Sectional area with runner is bigger or identical.
5. a kind of ultra-wide polyvinyl chloride film blow molding apparatus according to claim 1, it is characterised in that:Each melts The sectional area of body distribution entrance is more bigger than the sectional area sum of corresponding helical flow path, and helical flow path is along melt outlet direction Depth shoal gradually, be zero in its end depth.
CN201611077577.8A 2016-11-29 2016-11-29 Ultra-wide polyvinyl chloride thin film blow-molding device Pending CN106626343A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611077577.8A CN106626343A (en) 2016-11-29 2016-11-29 Ultra-wide polyvinyl chloride thin film blow-molding device

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Application Number Priority Date Filing Date Title
CN201611077577.8A CN106626343A (en) 2016-11-29 2016-11-29 Ultra-wide polyvinyl chloride thin film blow-molding device

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
WO2023015651A1 (en) * 2021-08-13 2023-02-16 重庆沃特智成新材料科技有限公司 Film blow-molding device

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Publication number Priority date Publication date Assignee Title
WO2023015651A1 (en) * 2021-08-13 2023-02-16 重庆沃特智成新材料科技有限公司 Film blow-molding device

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