CN106623819A - Prepration method for semisolid alloy slurry - Google Patents

Prepration method for semisolid alloy slurry Download PDF

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Publication number
CN106623819A
CN106623819A CN201611051773.8A CN201611051773A CN106623819A CN 106623819 A CN106623819 A CN 106623819A CN 201611051773 A CN201611051773 A CN 201611051773A CN 106623819 A CN106623819 A CN 106623819A
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China
Prior art keywords
hang plate
alloy
thin seam
semi
preparation
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CN201611051773.8A
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Chinese (zh)
Inventor
周荣锋
李友红
李永坤
王秋平
蒋业华
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN201611051773.8A priority Critical patent/CN106623819A/en
Publication of CN106623819A publication Critical patent/CN106623819A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • B22D17/007Semi-solid pressure die casting

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

The invention relates to a preparation method for semisolid alloy slurry and belongs to the technical field of material processing. The prepration method comprises the steps that an alloy is placed into a smelting device to be smelted to obtain metal melt, the metal melt is subjected to heat preservation at 10-50 DEG C above the liquidus for 30 min, then the metal melt is poured onto an oblique board and flows into a blank containing device along the oblique board, and accordingly semisolid slurry is obtained. A thin-gap channel is formed in the oblique board provided with a cooling device. A feed inlet is formed in the upper end of the oblique board. A discharge outlet is formed in the lower end of the oblique board. A feed funnel, the feed inlet, the thin-gap channel and the discharge outlet communicate in sequence. The discharge outlet directly faces the blank containing device. The metal melt flows into the blank containing device along the thin-gap channel in the oblique board. The preparation method can be used for preparing semisolid slurry of various alloys such as a cast iron alloy, an aluminum alloy, a magnesium alloy, a copper alloy, a tin alloy and the like and is particularly suitable for primary-hard-phase-containing hypereutectic alloys such as a hypereutectic high chromium cast iron alloy and a hypereutectic aluminum-silicon alloy, the process is simple, operation is convenient, the cost is low, and the efficiency is high.

Description

A kind of preparation method of semi-solid alloy slurry
Technical field
The present invention relates to a kind of preparation method of semi-solid alloy slurry, belongs to materials processing technology field.
Background technology
Semi-solid forming technology, abbreviation SSM is 70 years 20th century by the M.C.Flemings of Massachusetts Institute Technology What in generation, proposed.The technology is in process of setting, it is stirred vigorously, changes its forming core growth process, obtains a kind of gold Solid-liquid mixed slurry with certain solid phase in category melt.It is low due to forming temperature, and resistance of deformation is little, the spy such as steady that fills type Point, has a extensive future in fields such as automobile, aviations.
The preparation of semi solid slurry is the key of semi-solid-state shaping, and its preparation method mainly has two kinds:One kind is in external force Or formed dendrite is crushed in the presence of outfield, mainly including mechanical mixing method, electromagnetic stirring method, Isothermal treatment method, Hang plate cooling method, ultrasonic vibration method etc.;Second is that control process of setting carrys out dendrite inhibition shaping, mainly there is additive method. Both of which has its pluses and minuses, and some has been applied in actual production.Up to the present, semi-solid-state metal Forming technique is generally used in aluminium alloy and magnesium alloy.
Hang plate is to be used within 1996 manufacture aluminium alloy and magnesium alloy semisolid slurry by Japanese UBE companies utility model New technology.Forming process is:The alloy melt that will be above a certain temperature of aluminium alloy phase line is cast in graphite or steel alloy is made Hang plate on, through the chilling action of hang plate, the quick forming core of alloy melt is grown up, and on hang plate trickle process In, melt internal grain constantly rubs, collide and finally give uniform, tiny spheroidal structure.
The oxidative phenomena of metal bath is extremely serious when conventional bevel plate prepares semi solid slurry, obtained semi solid slurry The oxidizing slag of middle generation is more, and the mechanical property of the defective effect materials such as oxide slag inclusion is produced in actual casting forming process, In order to improve this phenomenon, the present invention adopts thin seam hang plate, by channel interior air when metal bath flows through thin seam passage Emptying, make metal bath flow through hang plate it is thin seam passage during hardly with air contact, can preferably prevent metal bath Oxidation.And upper and lower two of hang plate is connected with cooling water, it is ensured that thin seam passage and metal bath contact surface keep needed for it is relatively low Temperature, it is to avoid channel interior surface temperature is persistently raised.There is shearing on the thin each surface in passage upper and lower, left and right of stitching to metal bath And chilling action, enhance treatment effect of the hang plate to metal bath.
The content of the invention
It is an object of the invention to provide a kind of preparation method of semi-solid alloy slurry, alloy is placed in smelting apparatus Melting is obtained metal bath, metal bath temperature 10 DEG C of -50 DEG C of insulation 30min more than liquidus curve is made, then by metal bath It is cast on hang plate, melt is flowed into along hang plate and holds blank device, obtains semi solid slurry;Set inside the hang plate There is thin seam passage, hang plate is provided with cooling device;The upper end of hang plate is provided with charging aperture, and lower end is provided with discharging opening, charging leakage Bucket, charging aperture, thin seam passage, discharging opening are sequentially communicated, and discharging opening is with to hold blank device just right;Metal bath is along hang plate Thin seam passage road flow into hold blank device.
Thin seam passage length of the present invention is 50-600mm(Hang plate lower plate is maintained static, can by adjusting nut come Adjust the position of hang plate upper plate to determine the length that upper plate and lower plate overlap, the part of coincidence is thin seam passage length), lead to The width in road is 100-200mm, is highly 5-10mm, and angle is at 10 ° -70 °(There are two can adjust up and down below hang plate Support, the size of angle is adjusted by the height of adjusting bracket), metal bath flow through it is thin seam passage when metal bath hardly With air contact.
Thin seam channel interior of the present invention has been provided with thermocouple, can be real-time to flowing through the metal bath of thin seam channel interior Temperature control.
The hang plate is made up of 45 steel, and each surface of skewing channel internal scribbles graphite, and hang plate is solid by support Calmly on the ground, support is Height Adjustable.
Hang plate of the present invention can arrange multiple thin seam passages(Multisection type hang plate can arrange multiple thin seam passages).
The present invention principle be:It is thin seam passage and inclining with temperature-controlled cooling device that metal bath is flowed through into an inside Swash plate, metal bath through hang plate chilling action, the quick forming core of crystal grain in metal bath, and due to during trickling Constantly mutually shearing, collision, friction, finally gives tiny, uniform spheroidal structure between metal bath internal grain.Thin seam passage Inner space is narrow and small, and metal bath all empties air in passage when flowing through thin seam passage, metal bath hardly with air Contact, preferably prevents molten metal oxidization, the oxidizing slag that obtained semi solid slurry the inside is contained compared with conventional bevel plate Significantly reduce, the formation of the defects such as oxide slag inclusion is avoided in actual casting forming process, the mechanical property of foundry goods can be improved Energy.Upper and lower two of hang plate is connected with cooling water, and the temperature on thin seam passage surface can be controlled, and prevents in casting process In, thin seam passage surface is persistently overheating, it is ensured that thin seam channel table is made in the face of the lasting Quench of metal bath in casting process With, and there are shearing, chilling action in each surface in thin seam passage upper and lower, left and right to the metal bath for flowing through thin seam passage, strengthens Treatment effect of the hang plate to metal bath, constantly obtains even tissue, tiny half solid in continuous casting process State slurry.
Patent of the present invention compared with prior art, this have the advantage that:
(1)This method is simple to operate, low cost, flow process are short, can be connected with follow-up former, directly processes foundry goods.
(2)Temperature control is carried out to hang plate by the cooling water of hang plate top and the bottom, prevents hang plate from holding in casting process Temperature of continuing rising, it is ensured that lasting chilling action of the hang plate to metal bath.
(3)In casting process, the thin each surface in passage upper and lower, left and right of stitching has to the metal bath for flowing through thin seam passage Shearing, chilling action, enhance treatment effect of the hang plate to metal bath.
(4)In casting process, thin seam channel space is narrow and small, and metal bath flows through during thin seam passage that air in passage is complete Portion empty so that metal bath not with contacting external air, be effectively prevented the oxidation of the metal bath in casting process, greatly The big generation for reducing oxidizing slag in semi solid slurry, avoids the defects such as oxide slag inclusion in actual casting forming process Formed, the mechanical property of foundry goods can be improved.
Description of the drawings
Fig. 1 is apparatus of the present invention schematic diagram;
Fig. 2 is hang plate cross-sectional schematic;
Fig. 3 is the micro-organization chart of the semi solid slurry that example 1 prepares Al-25%Si-2Fe alloys;
Fig. 4 routine hang plate systems prepare the micro-organization chart of the semi solid slurry of Al-25%Si-2Fe alloys;
Fig. 5 is the micro-organization chart of the semi solid slurry that example 2 prepares Al-25%Si aluminium alloy alloys;
Fig. 6 routine hang plate systems prepare the micro-organization chart of the semi solid slurry of Al-25%Si aluminium alloy alloys;
Fig. 7 is the micro-organization chart of the semi solid slurry that example 3 prepares Cu-10%Sn alloys.
In figure:1- tapered rods;2- smelting apparatus;3- delivery ports;4- charging apertures;5- loading hoppers;7- thermocouples;8- is positioned Bolt;9- hang plates top;10- water inlets;11- discharging openings;12- hang plates bottom;14- holds blank device.
Specific embodiment
The present invention is further described below in conjunction with the drawings and specific embodiments, but protection scope of the present invention is not It is limited to the content.
The present invention implements 1 ~ 3 equipment therefor to be included tapered rod 1, smelting apparatus 2, loading hopper 5, hang plate, holds blank Device 14, is provided with thin seam passage inside hang plate, hang plate is provided with cooling system;The upper end of hang plate is provided with charging aperture 4, under End is provided with discharging opening 11, and loading hopper 5, charging aperture 4, thin seam passage, discharging opening 11 are sequentially communicated, discharging opening 11 with hold blank Device 14 is just right, and the lower end of smelting apparatus 2 is just right with loading hopper 5;The hang plate is included under hang plate top 9 and hang plate Portion 12, thin seam passage is located between hang plate top 9 and hang plate bottom 12, and hang plate top 9 and hang plate bottom are by fixed Position bolt 8 connects;Thermocouple 7 is provided with thin seam passage, as shown in Figure 1 and 2.
Embodiment 1
Raw material:Al-25%Si-2%Fe aluminium alloys(573 DEG C of solidus temperature, 770 DEG C of liquidus temperature)
The metal bath of Al-25%Si-2%Fe aluminium alloys is prepared using the smelting apparatus above hang plate, melted metal is made Temperature is maintained at 790 DEG C of insulation 30min;The thin seam hang plate with cooling device is used, thin seam passage length is 300mm, channel width are 200mm, are highly 5mm, and hang plate is 20 ° with the angle of horizontal plane.Open hang plate top melting Tapered rod in device;Make metal bath and be cast in thin seam passage along funnel with appropriate speed, the thin seam passages of Jing are last Slurry collection device is flowed into, semi solid slurry is finally given, slurry tissues are as shown in Figure 3.
Semi solid slurry tissue is obtained for conventional hang plate as shown in figure 4, contrast Fig. 3 and Fig. 4 can see that thin seam passage inclines The shape great majority of semi solid slurry tissue primary silicon obtained in swash plate and Fe-riched phase are polygon and subsphaeroidal, conventional hang plate The primary silicon of obtained semi solid slurry and Fe-riched phase are shaped as elongated rod shape or needle-like and the serious crystal grain distribution of segregation phenomena not Uniformly;Concentrate because the crystal grain of needle-like has neighbouring generation profit that can be in acicular grains in actual application, finally cut Split matrix.
Embodiment 2
Raw material:Al-25%Si aluminium alloys(564 DEG C of solidus temperature, 775 DEG C of liquidus temperature)
The metal bath of Al-25%Si aluminium alloys is prepared using the smelting apparatus above hang plate, melted metal temperature is protected Hold and be incubated 30min at 785 DEG C;The thin seam hang plate with cooling device is used, thin seam passage length is 400mm, leads to Road width is 150mm, is highly 7mm, and hang plate is 60 ° with the angle of horizontal plane.In opening hang plate top smelting apparatus Tapered rod;Make metal bath and be cast in thin seam passage along funnel with appropriate speed, the thin seam passages of Jing are finally flowed into slurry Material collection device, finally gives semi solid slurry, and slurry tissues are as shown in Figure 5.
Semi solid slurry tissue is obtained for conventional hang plate as shown in fig. 6, contrast Fig. 5 and Fig. 6 can see that thin seam passage inclines The shape great majority of semi solid slurry tissue primary silicon obtained in swash plate are polygon and subsphaeroidal, conventional hang plate obtained half The primary silicon of solid size be shaped as elongated rod shape or needle-like and the serious crystal grain distribution of segregation phenomena is uneven.Due to the crystalline substance of needle-like There is neighbouring generation profit that can be in acicular grains in actual application and concentrate in grain, finally isolate matrix.
Embodiment 3
Raw material:Cu-10%Sn alloys(830 DEG C of solid-state temperature line, 1024 DEG C of liquidus temperature)
The metal bath of Cu-10%Sn alloys is prepared using the smelting apparatus above hang plate, melted metal temperature is kept 30min is incubated at 1060 DEG C;Using the thin seam hang plate with cooling device, thin seam passage length is 400mm, channel width For 100mm, be highly 10mm, the angle of hang plate and horizontal plane is 30 °;Open the taper in the smelting apparatus of hang plate top Rod, is made metal bath and is cast in thin seam passage along funnel with appropriate speed, and the thin seam passages of Jing are finally flowed into slurry receipts Acquisition means, finally give semi solid slurry, and slurry tissues are as shown in Figure 7.

Claims (5)

1. a kind of preparation method of semi-solid alloy slurry, it is characterised in that:Alloy is placed in into melting in smelting apparatus gold is obtained Category melt, makes 10 DEG C of -50 DEG C of insulations more than liquidus curve of metal bath temperature, and then metal bath is cast on hang plate, Melt is flowed into along hang plate and holds blank device, obtains semi solid slurry;Thin seam passage is provided with inside the hang plate, is inclined Plate is provided with cooling device;The upper end of hang plate is provided with charging aperture, and lower end is provided with discharging opening, and loading hopper, charging aperture, thin seam lead to Road, discharging opening are sequentially communicated, and discharging opening is with to hold blank device just right;Metal bath is flowed into along the thin seam passage road of hang plate Hold blank device.
2. the preparation method of semi-solid alloy slurry according to claim 1, it is characterised in that:Thin seam passage length is 50- 600mm, the width of passage is 100-200mm, is highly 5-10mm, and angle is 10 ° -70 °.
3. the preparation method of semi-solid alloy slurry according to claim 1, it is characterised in that:Thin seam channel interior has been provided with Thermocouple.
4. the preparation method of semi-solid alloy slurry according to claim 1, it is characterised in that:The hang plate arranges multiple Thin seam passage.
5. the preparation method of semi-solid alloy slurry according to claim 1, it is characterised in that:The hang plate passes through support Fix on the ground, support it is Height Adjustable.
CN201611051773.8A 2016-11-25 2016-11-25 Prepration method for semisolid alloy slurry Pending CN106623819A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109848390A (en) * 2019-01-28 2019-06-07 浙江大学宁波理工学院 The preparation of low-melting alloy semi solid slurry and recovery valve island heat supply integrated system
CN110000344A (en) * 2019-03-14 2019-07-12 昆明理工大学 A kind of device and method for continuously preparing semi solid slurry inhibiting ZCuSn10P1 alloy tin element segregation
CN110273087A (en) * 2019-06-25 2019-09-24 昆明理工大学 Regulate and control the method for hypereutectic aluminum-silicon alloy casting overall performance
CN111375748A (en) * 2018-12-28 2020-07-07 井冈山大学 Vibration slope casting device
CN113134580A (en) * 2021-04-26 2021-07-20 兰州理工大学 Preparation method and preparation device of metal semi-solid non-dendritic crystal slurry
CN113182502A (en) * 2021-06-03 2021-07-30 东北大学 Semi-solid pressure casting forming equipment and forming method

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CN1424420A (en) * 2002-12-30 2003-06-18 西安交通大学 Preparation for ferroalloys semisolid slurry material
CN101367123A (en) * 2008-10-08 2009-02-18 南昌大学 Method for manufacturing and shaping semi-solid alloy slurry
CN201512567U (en) * 2009-09-25 2010-06-23 河北科技大学 Device for preparing semi-solid alloy melt
CN101817064A (en) * 2009-04-24 2010-09-01 兰州理工大学 Device and method for preparing metal semi-solid slurry
EP2347840A2 (en) * 2010-01-22 2011-07-27 Honda Motor Co., Ltd. Casting method and casting apparatus
CN102240796A (en) * 2011-06-27 2011-11-16 大连理工大学 Semisolid alloy forming process and forming device used by same
CN203737962U (en) * 2013-10-29 2014-07-30 昆明理工大学 Refining device for metal solidification structure

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Publication number Priority date Publication date Assignee Title
CN1424420A (en) * 2002-12-30 2003-06-18 西安交通大学 Preparation for ferroalloys semisolid slurry material
CN101367123A (en) * 2008-10-08 2009-02-18 南昌大学 Method for manufacturing and shaping semi-solid alloy slurry
CN101817064A (en) * 2009-04-24 2010-09-01 兰州理工大学 Device and method for preparing metal semi-solid slurry
CN201512567U (en) * 2009-09-25 2010-06-23 河北科技大学 Device for preparing semi-solid alloy melt
EP2347840A2 (en) * 2010-01-22 2011-07-27 Honda Motor Co., Ltd. Casting method and casting apparatus
CN102240796A (en) * 2011-06-27 2011-11-16 大连理工大学 Semisolid alloy forming process and forming device used by same
CN203737962U (en) * 2013-10-29 2014-07-30 昆明理工大学 Refining device for metal solidification structure

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111375748A (en) * 2018-12-28 2020-07-07 井冈山大学 Vibration slope casting device
CN111375748B (en) * 2018-12-28 2021-11-05 井冈山大学 Vibration slope casting device
CN109848390A (en) * 2019-01-28 2019-06-07 浙江大学宁波理工学院 The preparation of low-melting alloy semi solid slurry and recovery valve island heat supply integrated system
CN109848390B (en) * 2019-01-28 2021-01-01 浙江大学宁波理工学院 Low-melting-point alloy semi-solid slurry preparation and recovery valve island type heat supply integrated system
CN110000344A (en) * 2019-03-14 2019-07-12 昆明理工大学 A kind of device and method for continuously preparing semi solid slurry inhibiting ZCuSn10P1 alloy tin element segregation
CN110273087A (en) * 2019-06-25 2019-09-24 昆明理工大学 Regulate and control the method for hypereutectic aluminum-silicon alloy casting overall performance
CN113134580A (en) * 2021-04-26 2021-07-20 兰州理工大学 Preparation method and preparation device of metal semi-solid non-dendritic crystal slurry
CN113182502A (en) * 2021-06-03 2021-07-30 东北大学 Semi-solid pressure casting forming equipment and forming method

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