CN106622019A - Organic silicone compound modified surfactant with high cloud point - Google Patents
Organic silicone compound modified surfactant with high cloud point Download PDFInfo
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- CN106622019A CN106622019A CN201611257721.6A CN201611257721A CN106622019A CN 106622019 A CN106622019 A CN 106622019A CN 201611257721 A CN201611257721 A CN 201611257721A CN 106622019 A CN106622019 A CN 106622019A
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Abstract
The invention discloses an organic silicone compound modified surfactant with the high cloud point. The surfactant is prepared from raw materials including a modified organic silicone surfactant, nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, iso-tridecanol fatty alcohol polyoxyethylene ether, aminoethyl aminopropyl silicone oil, sodium undecenyl monoethanolamide sulfosuccinate, dodecyl betaine, hexadecyl betaine, triethanolamine, disodium EDTA (ethylene diamine tetraacetic acid), sodium dodecyl benzene sulfonate, sodium oxalate, sodium dodecyl sulfate, hexadecyl trimethyl ammonium bromide, docusate sodium, Tween 40, polysorbate 40, sodium 2-olefinsulfonate, dodecyloxy hydroxypropyl betaine, triethanolamine dodecylbenzene sulfonate, tetra-alkyl ammonium chloride and ethanol. The organic silicone compound modified surfactant with the high cloud point has good surface activity, good chemical stability, low surface tension and high cloud point.
Description
Technical field
The present invention relates to a kind of surfactant, more particularly to the composite modified surface-active of organosilicon that a kind of cloud point is high
Agent.
Background technology
Organic silicon surfactant is then meta or end wherein with PolydimethylsiloxaneChain Chain as its hydrophobic backbone
The class surfactant that position reconnects one or more polar organic groups and constitutes.Organic silicon surfactant has only
Special performance, can be reduced to 20mN/m by the surface tension of water, there is surface-active in the aqueous solution and non-aqueous media, and divide
Minor structure diversity, is still fluid during high relative molecular mass.At present in weaving, cosmetics, plastics, paint, coating, agricultural
The aspects such as chemicals, oil, chemical industry, medicine, automobile, electronics, machining are widely used.
Demand when organic silicon surfactant of the prior art cannot meet actually used, therefore need a kind of cloud point badly
The composite modified surfactant of high organosilicon is solving the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of high composite modified table of organosilicon of cloud point
Face activating agent, with good surface-active, chemical stability is good, and surface tension is low, and cloud point is high.
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
Modified silicone surfactants 20-40 parts, NPE 3-6 parts, OPEO 2-5 parts, isomery
Tridecanol AEO 3-5 parts, aminoethyl and aminopropyl silicone oil 1-4 parts, undecenoic acid single ethanol amide succinate
Sodium sulfonate 2-4 parts, empgen BB 3-6 parts, cetyl betaine 4-8 parts, triethanolamine 1-3 parts, ethylenediamine tetrem
Acid disodium 2-4 parts, neopelex 3-5 parts, sodium oxalate 1-3 parts, lauryl sodium sulfate 2-4 part, cetyl
Trimethylammonium bromide 3-5 parts, dioctyl succinate disulfonate acid 4-8 part, polysorbate40 2-5 parts, polysorbate 40 3-5 parts, α-alkene
Hydrocarbon sulfonate sodium 4-6 parts, dodecyloxy hydroxypropyl glycine betaine 1-3 part, DBSA triethanolamine salt 2-5 parts, four alkane
Ammonium chloride 1-3 parts, ethanol 4-8 parts.
Preferably, the raw material of modified silicone surfactants includes by weight：End group hydrogen containing siloxane 20-50
Part, acrylic polyethers 5-15 parts, chloroplatinic acid 2-6 parts, maleic anhydride 3-8 parts.
Preferably, modified silicone surfactants are prepared by following technique：By end group hydrogen containing siloxane and third
Alkenyl polyether is well mixed, and then passes to nitrogen gas stirring 5-15min, is then warming up to 60-120 DEG C, is incubated 20-40min, then
Chloroplatinic acid is added, 0.5-1.5h is stirred, then low-boiling-point substance is removed under reduced pressure in 0.05-0.15MPa pumping 20-40min, be subsequently adding
Maleic anhydride is well mixed, and is warming up to 80-90 DEG C, is incubated 2-4h, is cooled to room temperature and obtains modified silicone surfactants.
Preferably, in the raw material of modified silicone surfactants, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond
For 0.7-0.9mmol/g.
Preferably, modified silicone surfactants, NPE, OPEO, isomery ten
Triol AEO, aminoethyl and aminopropyl silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate, dodecane
The weight ratio of base glycine betaine and cetyl betaine is 25-35：4-5：3-4：3.5-4.5：2-3：2.5-3.5：3.5-5.5：
5-7。
Preferably, its raw material includes by weight：Modified silicone surfactants 25-35 parts, Nonyl pheno
Ether 4-5 parts, OPEO 3-4 parts, isomerous tridecanol AEO 3.5-4.5 parts, aminoethyl ammonia third
Base silicone oil 2-3 parts, undecenoic acid single ethanol amide Disodium sulfosuccinate 2.5-3.5 parts, empgen BB 4-5 parts, ten
Six alkyl betaine 5-7 parts, triethanolamine 1.5-2.5 parts, disodium ethylene diamine tetraacetate 2.5-3.5 parts, DBSA
Sodium 3.5-4.5 parts, sodium oxalate 1.5-2.5 parts, lauryl sodium sulfate 2.5-3.5 part, cetyl trimethylammonium bromide
3.5-4.5 parts, dioctyl succinate disulfonate acid 5-7 part, polysorbate40 3-4 parts, polysorbate 40 3.5-4.5 parts, alpha-olefin sulphur
Sour sodium 4.5-5.5 parts, dodecyloxy hydroxypropyl glycine betaine 1.5-2.5 part, DBSA triethanolamine salt 3-4 parts,
Tetra-alkyl ammonium chloride 1.5-2.5 part, ethanol 5-7 parts.
Preferably, its raw material includes by weight：30 parts of modified silicone surfactants, NPE
4.5 parts, 3.5 parts of OPEO, 4 parts of isomerous tridecanol AEO, aminoethyl and aminopropyl silicone oil 2.5
Part, 3 parts of undecenoic acid single ethanol amide Disodium sulfosuccinate, 4.5 parts of empgen BB, 6 parts of cetyl betaine,
2 parts of triethanolamine, 3 parts of disodium ethylene diamine tetraacetate, 4 parts of neopelex, 2 parts of sodium oxalate, dodecyl sulphate
3 parts of sodium, 4 parts of cetyl trimethylammonium bromide, 6 parts of dioctyl succinate disulfonate acid, 3.5 parts of polysorbate40, polysorbate 40 4
Part, 5 parts of alpha-olefin sodium sulfonate, 2 parts of dodecyloxy hydroxypropyl glycine betaine, 3.5 parts of DBSA triethanolamine salt, four
2 parts of alkyl ammomium chloride, 6 parts of ethanol.
A kind of high composite modified surfactant of organosilicon of cloud point of the invention, its raw material includes modified organic silicon surface
Activating agent, NPE, OPEO, isomerous tridecanol AEO, aminoethyl ammonia
Propyl group silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate, empgen BB, cetyl betaine, three second
Hydramine, disodium ethylene diamine tetraacetate, neopelex, sodium oxalate, lauryl sodium sulfate, cetyl trimethyl
Ammonium bromide, dioctyl succinate disulfonate acid, polysorbate40, polysorbate 40, alpha-olefin sodium sulfonate, dodecyloxy hydroxypropyl beet
Alkali, DBSA triethanolamine salt, tetra-alkyl ammonium chloride and ethanol.Wherein based on modified silicone surfactants
Material, with NPE, OPEO, isomerous tridecanol AEO, aminoethyl ammonia third
Base silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate, empgen BB, cetyl betaine, three ethanol
Amine, disodium ethylene diamine tetraacetate, neopelex, sodium oxalate, lauryl sodium sulfate, cetyl trimethyl bromine
Change ammonium, dioctyl succinate disulfonate acid, polysorbate40, polysorbate 40, alpha-olefin sodium sulfonate, dodecyloxy hydroxypropyl beet
Alkali, DBSA triethanolamine salt, tetra-alkyl ammonium chloride and ethanol are reinforcing agent and auxiliary agent, wherein that what is added modified has
Organic silicon surface active agent is contained with end group hydrogen containing siloxane, acrylic polyethers, chloroplatinic acid and maleic anhydride as raw material by end group
Hydrogen polysiloxanes and acrylic polyethers carry out hydrosilylation, and recycling the terminal hydroxy group of polyethers, to carry out open loop with maleic anhydride anti-
Should, the modified silicone surfactants for preparing can effectively improve the composite modified surface of the high organosilicon of cloud point of the present invention
The system cloud point of activating agent, reduces surface tension, improves surface-active.The high composite modified surface of organosilicon of cloud point of the invention
Activating agent has good surface-active, and chemical stability is good, and surface tension is low, and cloud point is high.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are at this
In bright protection domain.
In specific embodiment, the weight portion of modified silicone surfactants can for 20 parts, 21 parts, 22 parts, 23 parts,
24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39
Part, 40 parts；The weight portion of NPE can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Octyl group
The weight portion of phenol polyethenoxy ether can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Isomerous tridecanol fatty alcohol
The weight portion of APEO can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of aminoethyl and aminopropyl silicone oil can be with
For 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of undecenoic acid single ethanol amide Disodium sulfosuccinate
It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of empgen BB can for 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts；The weight portion of cetyl betaine can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7
Part, 7.5 parts, 8 parts；The weight portion of triethanolamine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Disodium ethylene diamine tetraacetate
Weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of neopelex can for 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The weight portion of sodium oxalate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight of lauryl sodium sulfate
Amount part can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of cetyl trimethylammonium bromide can for 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts；The weight portion of dioctyl succinate disulfonate acid can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5
Part, 7 parts, 7.5 parts, 8 parts；The weight portion of polysorbate40 can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Poly- sorb
The weight portion of ester 40 can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of alpha-olefin sodium sulfonate can for 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts；The weight portion of dodecyloxy hydroxypropyl glycine betaine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；
The weight portion of DBSA triethanolamine salt can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Four alkane
The weight portion of ammonium chloride can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight portion of ethanol can for 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts.
Embodiment 1
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
30 parts of modified silicone surfactants, 4.5 parts of NPE, 3.5 parts of OPEO, isomery 13
4 parts of alcohol AEO, 2.5 parts of aminoethyl and aminopropyl silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate 3
Part, 4.5 parts of empgen BB, 6 parts of cetyl betaine, 2 parts of triethanolamine, 3 parts of disodium ethylene diamine tetraacetate, 12
4 parts of sodium alkyl benzene sulfonate, 2 parts of sodium oxalate, 3 parts of lauryl sodium sulfate, 4 parts of cetyl trimethylammonium bromide, dioctyl
6 parts of sodium sulfosuccinate, 3.5 parts of polysorbate40,4 parts of polysorbate 40,5 parts of alpha-olefin sodium sulfonate, dodecyloxy hydroxypropyl
2 parts of glycine betaine, 3.5 parts of DBSA triethanolamine salt, 2 parts of tetra-alkyl ammonium chloride, 6 parts of ethanol.
Modified silicone surfactants are prepared by following technique：By weight by 35 parts of end group hydrogen containing siloxanes
It is well mixed with 10 parts of acrylic polyethers, then passes to nitrogen gas stirring 10min, be then warming up to 90 DEG C, is incubated 30min, then
4 parts of chloroplatinic acids are added, 1.0h is stirred, then low-boiling-point substance is removed under reduced pressure in 0.1MPa pumping 30min, be subsequently adding 5.5 parts of Malaysias
Acid anhydrides is well mixed, and is warming up to 85 DEG C, is incubated 3h, is cooled to room temperature and obtains modified silicone surfactants.
Wherein, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.8mmol/g.
Embodiment 2
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
20 parts of modified silicone surfactants, 6 parts of NPE, 2 parts of OPEO, isomerous tridecanol fat
5 parts of fat alcohol APEO, 1 part of aminoethyl and aminopropyl silicone oil, 4 parts of undecenoic acid single ethanol amide Disodium sulfosuccinate, ten
3 parts of dialkyl group glycine betaine, 8 parts of cetyl betaine, 1 part of triethanolamine, 4 parts of disodium ethylene diamine tetraacetate, detergent alkylate
3 parts of sodium sulfonate, 3 parts of sodium oxalate, 2 parts of lauryl sodium sulfate, 5 parts of cetyl trimethylammonium bromide, dioctyl succinate acid
4 parts of sodium sulfonate, 5 parts of polysorbate40,3 parts of polysorbate 40,6 parts of alpha-olefin sodium sulfonate, dodecyloxy hydroxypropyl glycine betaine 1
Part, 5 parts of DBSA triethanolamine salt, 1 part of tetra-alkyl ammonium chloride, 8 parts of ethanol.
Modified silicone surfactants are prepared by following technique：By weight by 20 parts of end group hydrogen containing siloxanes
It is well mixed with 15 parts of acrylic polyethers, then passes to nitrogen gas stirring 5min, be then warming up to 120 DEG C, is incubated 20min, then
6 parts of chloroplatinic acids are added, 0.5h is stirred, then low-boiling-point substance is removed under reduced pressure in 0.15MPa pumping 20min, be subsequently adding 8 parts of maleic acids
Acid anhydride is well mixed, and is warming up to 80 DEG C, is incubated 4h, is cooled to room temperature and obtains modified silicone surfactants.
Wherein, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.7mmol/g.
Embodiment 3
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
40 parts of modified silicone surfactants, 3 parts of NPE, 5 parts of OPEO, isomerous tridecanol fat
3 parts of fat alcohol APEO, 4 parts of aminoethyl and aminopropyl silicone oil, 2 parts of undecenoic acid single ethanol amide Disodium sulfosuccinate, ten
6 parts of dialkyl group glycine betaine, 4 parts of cetyl betaine, 3 parts of triethanolamine, 2 parts of disodium ethylene diamine tetraacetate, detergent alkylate
5 parts of sodium sulfonate, 1 part of sodium oxalate, 4 parts of lauryl sodium sulfate, 3 parts of cetyl trimethylammonium bromide, dioctyl succinate acid
8 parts of sodium sulfonate, 2 parts of polysorbate40,5 parts of polysorbate 40,4 parts of alpha-olefin sodium sulfonate, dodecyloxy hydroxypropyl glycine betaine 3
Part, 2 parts of DBSA triethanolamine salt, 3 parts of tetra-alkyl ammonium chloride, 4 parts of ethanol.
Modified silicone surfactants are prepared by following technique：By weight by 50 parts of end group hydrogen containing siloxanes
It is well mixed with 5 parts of acrylic polyethers, then passes to nitrogen gas stirring 15min, be then warming up to 60 DEG C, be incubated 40min, then adds
Enter 2 parts of chloroplatinic acids, stir 1.5h, then low-boiling-point substance is removed under reduced pressure in 0.05MPa pumping 40min, be subsequently adding 3 parts of maleic anhydrides
It is well mixed, is warming up to 90 DEG C, be incubated 2h, is cooled to room temperature and obtains modified silicone surfactants.
Wherein, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.9mmol/g.
Embodiment 4
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
25 parts of modified silicone surfactants, 5 parts of NPE, 3 parts of OPEO, isomerous tridecanol fat
4.5 parts of fat alcohol APEO, 2 parts of aminoethyl and aminopropyl silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate 3.5
Part, 4 parts of empgen BB, 7 parts of cetyl betaine, 1.5 parts of triethanolamine, 3.5 parts of disodium ethylene diamine tetraacetate, ten
3.5 parts of dialkyl benzene sulfonic acids sodium, 2.5 parts of sodium oxalate, 2.5 parts of lauryl sodium sulfate, cetyl trimethylammonium bromide 4.5
Part, 5 parts of dioctyl succinate disulfonate acid, 4 parts of polysorbate40,3.5 parts of polysorbate 40,5.5 parts of alpha-olefin sodium sulfonate, dodecane
1.5 parts of epoxide hydroxypropyl glycine betaine, 4 parts of DBSA triethanolamine salt, 1.5 parts of tetra-alkyl ammonium chloride, 7 parts of ethanol.
Modified silicone surfactants are prepared by following technique：By weight by 25 parts of end group hydrogen containing siloxanes
It is well mixed with 12 parts of acrylic polyethers, then passes to nitrogen gas stirring 8min, be then warming up to 115 DEG C, is incubated 25min, then
5 parts of chloroplatinic acids are added, 0.8h is stirred, then low-boiling-point substance is removed under reduced pressure in 0.12MPa pumping 25min, be subsequently adding 7 parts of maleic acids
Acid anhydride is well mixed, and is warming up to 82 DEG C, is incubated 3.5h, is cooled to room temperature and obtains modified silicone surfactants.
Wherein, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.75mmol/g.
Embodiment 5
A kind of high composite modified surfactant of organosilicon of cloud point proposed by the present invention, its raw material includes by weight：
35 parts of modified silicone surfactants, 4 parts of NPE, 4 parts of OPEO, isomerous tridecanol fat
3.5 parts of fat alcohol APEO, 3 parts of aminoethyl and aminopropyl silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate 2.5
Part, 5 parts of empgen BB, 5 parts of cetyl betaine, 2.5 parts of triethanolamine, 2.5 parts of disodium ethylene diamine tetraacetate, ten
4.5 parts of dialkyl benzene sulfonic acids sodium, 1.5 parts of sodium oxalate, 3.5 parts of lauryl sodium sulfate, cetyl trimethylammonium bromide 3.5
Part, 7 parts of dioctyl succinate disulfonate acid, 3 parts of polysorbate40,4.5 parts of polysorbate 40,4.5 parts of alpha-olefin sodium sulfonate, dodecane
2.5 parts of epoxide hydroxypropyl glycine betaine, 3 parts of DBSA triethanolamine salt, 2.5 parts of tetra-alkyl ammonium chloride, 5 parts of ethanol.
Modified silicone surfactants are prepared by following technique：By weight by 45 parts of end group hydrogen containing siloxanes
It is well mixed with 8 parts of acrylic polyethers, then passes to nitrogen gas stirring 12min, be then warming up to 65 DEG C, be incubated 35min, then adds
Enter 3 parts of chloroplatinic acids, stir 1.2h, then low-boiling-point substance is removed under reduced pressure in 0.08MPa pumping 35min, be subsequently adding 4 parts of maleic anhydrides
It is well mixed, is warming up to 88 DEG C, be incubated 2.5h, is cooled to room temperature and obtains modified silicone surfactants.
Wherein, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.85mmol/g.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. the composite modified surfactant of the high organosilicon of a kind of cloud point, it is characterised in that its raw material includes by weight：It is modified
Organic silicon surfactant 20-40 parts, NPE 3-6 parts, OPEO 2-5 parts, isomery 13
Alcohol AEO 3-5 parts, aminoethyl and aminopropyl silicone oil 1-4 parts, undecenoic acid single ethanol amide succinate sulfonic acid
Sodium 2-4 parts, empgen BB 3-6 parts, cetyl betaine 4-8 parts, triethanolamine 1-3 parts, ethylenediamine tetra-acetic acid two
Sodium 2-4 parts, neopelex 3-5 parts, sodium oxalate 1-3 parts, lauryl sodium sulfate 2-4 part, cetyl front three
Base ammonium bromide 3-5 parts, dioctyl succinate disulfonate acid 4-8 part, polysorbate40 2-5 parts, polysorbate 40 3-5 parts, alpha-olefin sulphur
Sour sodium 4-6 parts, dodecyloxy hydroxypropyl glycine betaine 1-3 part, DBSA triethanolamine salt 2-5 parts, tetraalkyl chlorine
Change ammonium 1-3 parts, ethanol 4-8 parts.
2. the composite modified surfactant of the high organosilicon of cloud point according to claim 1, it is characterised in that modified organic
The raw material of silicon surface active agent includes by weight：End group hydrogen containing siloxane 20-50 parts, acrylic polyethers 5-15 parts, chlorine platinum
Sour 2-6 parts, maleic anhydride 3-8 parts.
3. the composite modified surfactant of the high organosilicon of cloud point according to claim 1 and 2, it is characterised in that modified
Organic silicon surfactant is prepared by following technique：End group hydrogen containing siloxane and acrylic polyethers are well mixed, so
After be passed through nitrogen gas stirring 5-15min, be then warming up to 60-120 DEG C, be incubated 20-40min, be subsequently added into chloroplatinic acid, stir 0.5-
1.5h, is then removed under reduced pressure low-boiling-point substance in 0.05-0.15MPa pumping 20-40min, is subsequently adding maleic anhydride and is well mixed, and rises
Temperature is incubated 2-4h to 80-90 DEG C, is cooled to room temperature and obtains modified silicone surfactants.
4. the high composite modified surfactant of organosilicon of cloud point according to any one of claim 1-3, it is characterised in that
In the raw material of modified silicone surfactants, in end group hydrogen containing siloxane, the molal quantity of Si -- H bond is 0.7-0.9mmol/
g。
5. the high composite modified surfactant of organosilicon of cloud point according to any one of claim 1-4, it is characterised in that
Modified silicone surfactants, NPE, OPEO, isomerous tridecanol fatty alcohol polyoxy second
Alkene ether, aminoethyl and aminopropyl silicone oil, undecenoic acid single ethanol amide Disodium sulfosuccinate, empgen BB and hexadecane
The weight ratio of base glycine betaine is 25-35：4-5：3-4：3.5-4.5：2-3：2.5-3.5：3.5-5.5：5-7.
6. the high composite modified surfactant of organosilicon of cloud point according to any one of claim 1-5, it is characterised in that
Its raw material includes by weight：Modified silicone surfactants 25-35 parts, NPE 4-5 parts, octylphenol polyethylene
Oxygen vinethene 3-4 parts, isomerous tridecanol AEO 3.5-4.5 parts, aminoethyl and aminopropyl silicone oil 2-3 parts, 11
Olefin(e) acid single ethanol amide Disodium sulfosuccinate 2.5-3.5 parts, empgen BB 4-5 parts, cetyl betaine 5-7
Part, triethanolamine 1.5-2.5 parts, disodium ethylene diamine tetraacetate 2.5-3.5 parts, neopelex 3.5-4.5 parts, second two
Sour sodium 1.5-2.5 parts, lauryl sodium sulfate 2.5-3.5 part, cetyl trimethylammonium bromide 3.5-4.5 parts, dioctyl amber
Amber disulfonate acid 5-7 parts, polysorbate40 3-4 parts, polysorbate 40 3.5-4.5 parts, alpha-olefin sodium sulfonate 4.5-5.5 parts, 12
Alkoxyl hydroxypropyl glycine betaine 1.5-2.5 part, DBSA triethanolamine salt 3-4 parts, tetra-alkyl ammonium chloride 1.5-2.5
Part, ethanol 5-7 parts.
7. the high composite modified surfactant of organosilicon of cloud point according to any one of claim 1-6, it is characterised in that
Its raw material includes by weight：30 parts of modified silicone surfactants, 4.5 parts of NPE, octyl phenol polyoxy
3.5 parts of vinethene, 4 parts of isomerous tridecanol AEO, 2.5 parts of aminoethyl and aminopropyl silicone oil, undecenoic acid list second
3 parts of alkylolamides Disodium sulfosuccinate, 4.5 parts of empgen BB, 6 parts of cetyl betaine, 2 parts of triethanolamine, second
3 parts of edetate disodium, 4 parts of neopelex, 2 parts of sodium oxalate, 3 parts of lauryl sodium sulfate, cetyl
4 parts of trimethylammonium bromide, 6 parts of dioctyl succinate disulfonate acid, 3.5 parts of polysorbate40,4 parts of polysorbate 40, alpha-olefin sulfonic acid
5 parts of sodium, 2 parts of dodecyloxy hydroxypropyl glycine betaine, 3.5 parts of DBSA triethanolamine salt, tetra-alkyl ammonium chloride 2
Part, 6 parts of ethanol.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135344A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint the surface treatment compound modifier of anti-aging calcium carbonate and its application |
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| CN109135344A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint the surface treatment compound modifier of anti-aging calcium carbonate and its application |
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