CN106601872B - A kind of device of EFI print solar-energy photo-voltaic cell electrode - Google Patents

A kind of device of EFI print solar-energy photo-voltaic cell electrode Download PDF

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Publication number
CN106601872B
CN106601872B CN201611151576.3A CN201611151576A CN106601872B CN 106601872 B CN106601872 B CN 106601872B CN 201611151576 A CN201611151576 A CN 201611151576A CN 106601872 B CN106601872 B CN 106601872B
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motion platform
cell electrode
energy photo
voltaic cell
photovoltaic cell
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CN106601872A (en
Inventor
王大志
王强
孟庆博
李凯
梁军生
任同群
冯立
韦运龙
衣珊珊
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Dalian University of Technology
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Dalian University of Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention belongs to advanced manufacturing technology field, there is provided a kind of device of EFI print solar-energy photo-voltaic cell electrode, including fluid spray printing module, motion module, micro-vision module and the part of control module four.Described fluid spray printing module realizes that conductive ink flows out spray nozzle with certain flow velocity;Motion platform in described motion module realizes that two dimensional surface moves, its movement locus of PC control and movement velocity, motion platform substrate is connected with vacuum absorption device, the fixed photovoltaic cell semiconductor chip of vacuum absorption device absorption, makes it follow motion platform to move;The described real-time monitoring of software of micro-vision module monitors print procedure in real time.Beneficial effects of the present invention are that device is simple, can optimize photovoltaic cell electrode structure, improve the utilization rate of electrode material.

Description

A kind of device of EFI print solar-energy photo-voltaic cell electrode
Technical field
The invention belongs to advanced manufacturing technology field, there is provided a kind of device of EFI print solar-energy photo-voltaic cell electrode.
Background technology
Solar energy can be converted directly into electric energy by solar-energy photo-voltaic cell (hereinafter referred to as photovoltaic cell), and its principle is light Raw volta effect.At present, silicon solar cell development is most ripe, and is occupied an leading position in battery applications.
Silicon solar cell is mainly made up of Top electrode, bottom electrode, n-type semiconductor, p-type semiconductor and p-n junction etc., its Middle upper/lower electrode is to influence photovoltaic cell series connection resistance and electricity conversion directly with load connection and to load output voltage Key.Photovoltaic cell is generally used as electrode material using silver, and silver electrode is also to influence the pith of photovoltaic cell cost.Light Width, height, depth-width ratio and the electrode of volt battery electrode have in the area of cell panel to photovoltaic cell photoelectric transformation efficiency Material impact.Photovoltaic cell has two main grids and a plurality of thin grid, is arranged in parallel within the N-type semiconductor for being coated with antireflective coating.For Reduce light-shading effect and obtain smaller line resistance, it is desirable to which line width is small, line is tall and big, and adhesive force and conductivity are excellent.
Photovoltaic cell electrode is generally prepared using screen printing technique at present, the silver prepared after the technology single printing-sintering Electrode width is more than 50 μm, and highly at 12-20 μm, grid line depth-width ratio prepared by silk-screen printing is only 0.4.By mesh-plate structure With the limitation of slurry properties, it is difficult to further reduce the width of electrode structure, therefore, it is difficult to reduce face of the electrode on cell panel Product, cause to be difficult to reduce shadow loss.Although can improve electrode structure height by secondary printing, secondary printing is present The problems such as the control of electrode Line-width precision hardly possible, complex technical process, which has limited photovoltaic cell open-circuit voltage, short circuit current, plane The further raising of the performances such as utilization rate, photoelectric transformation efficiency.Further, since silk-screen printing belongs to contact production method therefor, it is straight Connect and pressure is applied on frangible semiconductor wafer, easily cause chip crackle, fracture equivalent damage.And the electricity of silk-screen printing Pole slurry utilization rate is limited, it is necessary to often change silk screen, and these increased the manufacturing cost of photovoltaic cell.
The content of the invention
The invention solves technical barrier be to overcome the shortcomings of above-mentioned technology, invent a kind of EFI print solar photovoltaic Pond electrode assembly.The fine jet of micron order formed using conductive ink under electric field force effect, and handled simultaneously using thermal field The conductive jet and EFI of EFI India and China are printed as the conductive ink of type, exempt form technology process, in photovoltaic cell semiconductor chip Upper direct printing shaping photovoltaic cell electrode.
In order to achieve the above object, the technical solution adopted by the present invention is:
A kind of device of EFI print solar-energy photo-voltaic cell electrode, including fluid spray printing module, motion module, micro-vision Module and the part of control module four.
Described fluid spray printing module includes syringe pump 3, syringe 4, conductive ink 5, shower nozzle 6, spray nozzle fixture 7, voltage Controller 8 and heater;Described syringe pump 3 is powered by 220V AC powers, by the inhalation syringe 4 of conductive ink 5, is used Syringe pump 3 is fixedly clamped syringe 4.Syringe needle one end of syringe 4 is connected with the upper end of shower nozzle 6 by plastic catheter;Spray nozzle fixture 7 Positioning clamps shower nozzle 6, and the described front end of spray nozzle fixture 7 is conductive and clamps shower nozzle 6, and rear end, which is insulated and is fixed on, to be vertically moved Z offset axises on, realize the regulation of spray printing height.Described shower nozzle 6 is manufactured by conductive material, and it is micro- that head is machined with internal diameter 200 Spray orifice 13 below rice;The power line connection 220V AC powers of described voltage controller 8, voltage output range 0-5kV, Its output end is connected with the right-hand member of the current-carrying part of spray nozzle fixture 7.Described heater can use multiple heating mode, heating Device is heat lamp 9 or the inside of motion platform substrate 12 installation heating arrangement.It is red when being heated using heat lamp 9 Additional thermolamp 9 connects 0-30V dc sources, is powered by 0-30V dc sources, its heating power scope is 0-300W, and lamp body is put Put above photovoltaic cell semiconductor chip 15, make the whole surface region of photovoltaic cell semiconductor chip 15 of light-illuminating and heat photovoltaic Cell semiconductor piece 15.When being heated using the motion platform substrate 12 with heating function, it is cast with inside motion platform substrate 12 Electrothermal tube, its temperature is monitored by external digital temperature controller in real time, the temperature regulating range of motion platform substrate 12 is 20- 400℃。
Described motion module includes vacuum absorption device 10, motion platform 11, motion platform substrate 12, photovoltaic cell half Conductor piece 15;Described motion platform substrate 12 is the metal thick plate below 1 micron of flatness, and inside is machined with air flue, is used for Connect the pipeline of vacuum absorption device 10, its lower end is fixed on motion platform 11 with insulated screw and insulating washer, make its with Same movement is done with motion platform 11.Described motion platform 11 is powered by 220V AC powers, and with USB data line and upper Machine 1 connects, and realizes communication.Described motion platform 11 can do two dimensional surface motion under the programme-control of host computer 1, pass through Host computer 1 can also control its movement locus and movement velocity.Described vacuum absorption device 10 and motion platform substrate 12 Air flue is connected, and photovoltaic cell semiconductor chip 15 is placed above air flue, you can adsorbed fixation, it is followed motion platform 11 Do same movement.
Described micro-vision module includes camera 2 and its real-time monitoring of software.Described camera 2 is connected to data wire On host computer 1, region that alignment lenses are printing, you can printing is monitored by the real-time monitoring of software on host computer 1 in real time Process.
Described control module is host computer 1.Described host computer 1 can control the movement locus of motion platform 11, fortune The printing height of dynamic speed and spray orifice 13, and amplify display 2 print procedure within the vision of camera.
Beneficial effects of the present invention are:The present invention proposes a kind of device of EFI print solar-energy photo-voltaic cell electrode, obtains Micron order photovoltaic cell electrode, electrode line width can be tens microns and arrive microns up to a hundred, and highly up to tens microns, depth-width ratio is reachable More than 1;Photovoltaic cell electrode structure can be optimized, improve the utilization rate of electrode material, the plane for improving photovoltaic battery panel utilizes Rate, and it is beneficial to be lifted the electric property of photovoltaic cell electrode, be advantageous to improve photovoltaic cell photoelectric transformation efficiency, reduce light Lie prostrate battery manufacture cost.
Brief description of the drawings
Fig. 1 is photovoltaic cell electrode electricity jet printing appts sketch;
Fig. 2 is that photovoltaic cell electrode EFI prints technical process sketch;
In figure:1 host computer, 2 cameras, 3 syringe pumps, 4 syringes, 5 conductive inks, 6 shower nozzles, 7 spray nozzle fixtures, 8 voltage controls Device processed, 9 heat lamps, 10 vacuum absorption devices, 11 motion platforms, 12 motion platform substrates, 13 spray orifices, 14 jets, 15 light Lie prostrate cell semiconductor piece, 16 photovoltaic cell electrodes.
Embodiment
Describe the embodiment of the present invention in detail below in conjunction with technical scheme and accompanying drawing.The spray printing device master of embodiment To be made up of fluid spray printing module, motion module, micro-vision module and the part of control module four.Described fluid spray printing module It is made up of syringe pump 3, syringe 4, conductive ink 5, shower nozzle 6, spray nozzle fixture 7, voltage controller 8 and heater.It is described Syringe 4 be fixed on the top of syringe pump 3, syringe 4 passes through conduit and the upper end of shower nozzle 6 built with conductive ink 5, syringe 4 Import connects.Shower nozzle 6 is manufactured by conductive material, and head is machined with the spray orifice 13 of 100 microns of internal diameter, and is positioned by spray nozzle fixture 7 Clamp.The rear end of spray nozzle fixture 7 is insulated and is fixed on the Z offset axises that can be vertically moved, to realize the regulation of spray printing height;Before End is conductive and clamps shower nozzle 6.The output end of voltage controller 8 is connected to the right-hand member of spray nozzle fixture 7.Described heater can be with Using multiple heating mode, heated wherein including using heat lamp 9 and using the motion platform substrate with heating function The mode of heatings such as 12 heating.When being heated using heat lamp 9, heat lamp 9 connects 0-30V dc sources, straight by 0-30V Power supply power supply is flowed, its heating power scope is 0-300W, and lamp body is placed on the upper right side of photovoltaic cell semiconductor chip 15, shines light Penetrate the whole surface region of photovoltaic cell semiconductor chip 15 and heat photovoltaic cell semiconductor chip 15.Use the fortune with heating function When moving platform substrate 12 heats, electrothermal tube is cast with inside motion platform substrate 12, is monitored in real time by external digital temperature controller Its temperature, the temperature regulating range of motion platform substrate 12 is 20-400 DEG C.
Motion module is by vacuum absorption device 10, motion platform 11, motion platform substrate 12, photovoltaic cell semiconductor chip 15 Composition.Described motion platform 11 can realize that two dimensional surface moves, and connect host computer 1 using USB data line, pass through host computer 1 controls its movement locus and movement velocity.Described motion platform substrate 12 is the metal thick plate of 0.5 micron of flatness, is passed through Insulated screw is fixed on the top of motion platform 11 with insulating washer, follows motion platform 11 to move together.In motion platform substrate Processing air flue in 12, air flue lower section are connected with vacuum absorption device 10, photovoltaic cell semiconductor chip 15 are placed above air flue, thus The fixed photovoltaic cell semiconductor chip 15 of the absorption of vacuum absorption device 10 can be used, makes it follow motion platform 11 to move together.
By camera 2 and its in real time, monitoring of software forms micro-vision module.Described camera 2 is directed at the area printed Domain, data are observed by USB data line and are transferred to host computer 1, it is possible thereby to real by the real-time monitoring of software on host computer 1 When monitor print procedure.
Control module is made up of host computer 1.Described host computer 1 controls the movement locus and motion speed of motion platform 11 Degree, controls the printing height of spray orifice 13, and monitors 2 print procedure within the vision of camera.
The method that EFI print solar-energy photo-voltaic cell electrode is carried out using said apparatus, is comprised the following steps:
1) fluidic vectoring thrust under the conditions of electric field-thermal field
Photovoltaic cell semiconductor chip 15 is placed on motion platform substrate 12, opens vacuum absorption device 10 by photovoltaic cell Semiconductor chip 15 is fixed.By syringe pump 3 by the injection nozzle 6 of conductive ink 5, and the flow of conductive ink 5 is adjusted, adjust model Enclose for 0.01-5 μ L/min.Adjust the spacing of spray orifice 13 and photovoltaic cell semiconductor chip 15, adjustable range 1-3mm.Open electricity Pressure controller, apply electric field between spray orifice 13 and motion platform substrate 12, adjust voltage controller output voltage, adjustable range is 1000-3000V.Above-mentioned three parameters are coordinated mutually, are finally formed the conductive ink 5 at spray orifice 13 and are much smaller than the size of spray orifice 13 Stable jet 14.
2) the spray printing manufacture of photovoltaic cell electrode structure
According to the shape of photovoltaic cell electrode 16, motion control program is write, the fortune of motion platform 11 is controlled by host computer 1 Dynamic rail mark and speed, the flow of the conductive ink 5 of spray orifice 13 is adjusted by syringe pump 3, print the pattern of photovoltaic cell electrode 16. The line width and thickness of described pattern are by the speed of motion platform 11 and the flow effect of conductive ink 5, velocity interval 0.1- In the case of 30mm/s, range of flow 0.01-5 μ L/min, described pattern width is 10-150 μm, and thickness is 5-70 μm.Institute The print procedure for the pattern stated should be monitored by camera 2 and real-time monitoring of software, to ensure the stability of jet 14.
3) curing molding of photovoltaic cell electrode structure
When being heated using heat lamp 9, for the pattern of photovoltaic cell electrode 16 while printing, the lower section of jet 14 is The region of printing is in the irradiation heated perimeter of heat lamp 9, adjusts the power of heat lamp 9, adjustable range 100- 300W, ensure the rapid curing molding of structure that jet is formed on photovoltaic cell semiconductor chip 15, obtain solar-energy photo-voltaic cell Electrode 16.Described photovoltaic cell electrode line width is 30-60 μm, is highly 30-60 μm, depth-width ratio is about 1.
When being heated using the motion platform substrate 12 with heating function, the pattern of photovoltaic cell electrode 16 is in the same of printing When, photovoltaic cell semiconductor chip 15 is roughly the same with the temperature of motion platform substrate 12, the temperature of regulation digital temperature controller setting, Adjustable range is 20-400 DEG C, ensures the rapid curing molding of structure that jet is formed on photovoltaic cell semiconductor chip 15, obtains Solar-energy photo-voltaic cell electrode 16.
The present invention proposes a kind of EFI printing manufacturing apparatus of solar-energy photo-voltaic cell electrode.Using conductive ink 5 in electric current The stable jet 14 of micron order is formed under the effect of body dynamic effect at spray orifice 13, the spray printing of conductive ink 5 is partly led in photovoltaic cell On body piece 15, and the electrode structure on photovoltaic cell semiconductor chip 15 is heated by heat lamp 9, make electrode structure rapid Solidification, form micron order solar-energy photo-voltaic cell electrode structure.Present invention optimizes solar-energy photo-voltaic cell electrode structure, improves The utilization rate of electrode material, improves the plane utilization rate of solar photovoltaic cell panel, and is beneficial to lift solar energy The electric property of battery electrode is lied prostrate, and solar-energy photo-voltaic cell manufacturing cost can be reduced.

Claims (10)

1. a kind of device of EFI print solar-energy photo-voltaic cell electrode, it is characterised in that described device includes fluid spray printing mould Block, motion module, micro-vision module and control module;
Described fluid spray printing module includes syringe pump (3), syringe (4), conductive ink (5), shower nozzle (6), spray nozzle fixture (7), voltage controller (8) and heater;Described syringe pump (3) connection 220V AC powers, syringe pump (3) are fixedly clamped Syringe (4), conductive ink (5) is by syringe pump (3) inhalation syringe (4);Syringe needle one end of syringe (4) passes through plastic catheter It is connected with shower nozzle (6) upper end;Described spray nozzle fixture (7) front end is conductive and positions clamping shower nozzle (6), and rear end is insulated and is fixed on On the Z offset axises that can be vertically moved, regulation spray printing height;Described shower nozzle (6) is manufactured by conductive material, head processing spray orifice (13);Described voltage controller (8) is connected with 220V AC powers, its output end and the right side of spray nozzle fixture (7) current-carrying part End is connected;Described heater is heat lamp 9 or the inside of motion platform substrate 12 installation heating arrangement;
Described motion module includes vacuum absorption device (10), motion platform (11), motion platform substrate (12) and photovoltaic electric Pond semiconductor chip (15);Described motion platform substrate (12) is the metallic plate below 1 micron of flatness, inside processing air flue, For connecting the pipeline of vacuum absorption device (10), the insulation of motion platform substrate (12) lower end is fixed on motion platform (11), It is set to do same movement with motion platform (11);Described motion platform (11) is powered by 220V AC powers, and and host computer (1) connect, realize communication, motion platform (11) does two dimensional surface motion, host computer (1) under the programme-control of host computer (1) Control its movement locus and movement velocity;Described vacuum absorption device (10) is connected with the air flue of motion platform substrate (12), Photovoltaic cell semiconductor chip (15) is absorbed and fixed above air flue, and same movement is done with motion platform (11);
Described micro-vision module includes camera (2) and real-time monitoring of software;Described camera (2) is connected with host computer (1), The region of alignment lenses printing, print procedure is monitored by the real-time monitoring of software of host computer (1) in real time;
Described control module is host computer (1), the movement locus of host computer (1) control motion platform (11), movement velocity with And the printing height of spray orifice (13), and amplify display camera (2) print procedure within the vision.
2. the device of a kind of EFI print solar-energy photo-voltaic cell electrode according to claim 1, it is characterised in that described Heat lamp (9) connects 0-30V dc sources, is powered by 0-30V dc sources, lamp body is placed on photovoltaic cell semiconductor chip (15) top, makes whole photovoltaic cell semiconductor chip (15) surface region of light-illuminating and heats photovoltaic cell semiconductor chip (15)。
A kind of 3. device of EFI print solar-energy photo-voltaic cell electrode according to claim 1 or 2, it is characterised in that institute Installation heating arrangement is to be cast with electrothermal tube inside motion platform substrate (12) inside the motion platform substrate (12) stated, by external Digital temperature controller monitor its temperature in real time, the temperature regulating range of motion platform substrate (12) is 20-400 DEG C.
A kind of 4. device of EFI print solar-energy photo-voltaic cell electrode according to claim 1 or 2, it is characterised in that institute Below 200 microns of the internal diameter for the spray orifice (13) stated.
5. the device of a kind of EFI print solar-energy photo-voltaic cell electrode according to claim 3, it is characterised in that described Below 200 microns of the internal diameter of spray orifice (13).
A kind of 6. device of EFI print solar-energy photo-voltaic cell electrode according to claim 1 or 2 or 5, it is characterised in that The voltage output range of described voltage controller (8) is 0-5kV.
7. the device of a kind of EFI print solar-energy photo-voltaic cell electrode according to claim 3, it is characterised in that described The voltage output range of voltage controller (8) is 0-5kV.
8. a kind of device of EFI print solar-energy photo-voltaic cell electrode according to claim 1 or 2 or 5 or 7, its feature exist In the heating power scope of described heat lamp (9) is 0-300W.
9. the device of a kind of EFI print solar-energy photo-voltaic cell electrode according to claim 3, it is characterised in that described The heating power scope of heat lamp (9) is 0-300W.
10. the device of a kind of EFI print solar-energy photo-voltaic cell electrode according to claim 6, it is characterised in that described The heating power scope of heat lamp (9) be 0-300W.
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