CN106596332A - Spray tower seriflux density measuring device by limestone method - Google Patents

Spray tower seriflux density measuring device by limestone method Download PDF

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Publication number
CN106596332A
CN106596332A CN201710080124.9A CN201710080124A CN106596332A CN 106596332 A CN106596332 A CN 106596332A CN 201710080124 A CN201710080124 A CN 201710080124A CN 106596332 A CN106596332 A CN 106596332A
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China
Prior art keywords
pressure
tube
valve
spray column
measuring pipe
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Pending
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CN201710080124.9A
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Chinese (zh)
Inventor
马迁
王�华
卫祥民
王杰
赵青涛
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CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd
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CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd
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Priority to CN201710080124.9A priority Critical patent/CN106596332A/en
Publication of CN106596332A publication Critical patent/CN106596332A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N9/00Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity
    • G01N9/26Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity by measuring pressure differences
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N9/00Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity
    • G01N9/36Analysing materials by measuring the density or specific gravity, e.g. determining quantity of moisture

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a spray tower seriflux density measuring device by a limestone method, and belongs to the field of environmental protection. According to the device, the bottom of a piezometer tube is connected to an outlet tube, an underflow valve is arranged between the piezometer tube and the outlet tube, one end of a backflow tube is connected to the outlet tube, the other end of the backflow tube is arranged on the side wall of the top of the piezometer tube, the backflow tube is provided with a flow-limiting valve, the side wall of the bottom of the piezometer tube is provided with an inlet tube, the other end of the inlet tube is connected to the side wall of the bottom of the spray tower, an inlet tube pipeline is provided with an inlet valve, and the side wall of the piezometer tube is provided with two pressure gauge connectors, a back washing water connector and a ph-meter connector. The spray tower seriflux density measuring device by the limestone method can effectively prevent the occurrence of situations that the measuring is not accurate and scale formation is easily generated in an original device, can run stably for a long time, and can achieve accurate measuring. Engineering practices show that by adopting the device, the density of a seriflux area CaSO4 can be accurately measured, thus the time of thick liquid discharging can be accurately controlled according to a numberical valve of online PH, and operational stability and reliability of a desulfurizing tower system are improved.

Description

A kind of limestone-based process spray column slurry density measurement device
Technical field
The present invention relates to a kind of limestone-based process spray column slurry density measurement device, belongs to field of environment protection.
Background technology
Wet process of FGD spray column is a kind of spray equipment that sprayed slurry is recycled, and loop slurry adopted mostly Lime stone slurry, by the Ca in serosity2+With the SO in flue gas2Reaction generates CaSO4, by the SO in flue gas2Remove so as to reach The purpose of purifying smoke.When the continuous circulated sprinkling of lime stone slurry until circulation fluid in CaSO4Reach certain proportion, and circulation fluid PH value reduce desulfuration efficiency decline after, will circulation fluid discharge a part, continue cycling through after being supplemented with fresh lime stone slurry Spray.So when a part of serosity of the outer row is supplemented with new serosity, is a very important ginseng in desulfurizing tower running Number.The parameter is controlled, the stable of desulfuration efficiency has not only been can guarantee that but also lime stone slurry can be saved, reduced operating cost, it is more important Be to control CaSO4Concentration can prevent in crystallization inside tower, so as to block shower nozzle and other tower internals, cause desulfurizing tower to stop transport Phenomenon generation.
The desulfurizing tower of early stage is the mode that online PH meter is set up in bottom of towe slurry layer, by the monitoring of online pH value so as to sentencing It is disconnected when to discharge serosity.But as loop slurry is the buffer solution of strong acid weak base, the pH value of monitoring can not reaction slurry well Actual numerical value in liquid, along with CaSO4Can count in PH and crystallize on probe so as to many reasons such as cause PH measurements amount inaccurate Occur, cause in actual motion can not control plasma discharge time well, reduce desulfuration efficiency, crystallization inside tower can more seriously occur Phenomenon.
By improvement, using measurement CaSO4The mode of density can prevent above-mentioned phenomenon from occurring, by measuring CaSO in tower4's Density can directly know CaSO4Volumetric concentration so as to being accurately controlled the plasma discharge time.Earliest by the way of density skill, but adopt Similarly there is instrument check with the direct method of measurement to be forbidden, pop one's head in CaSO4The generation of the phenomenon of crystallization is forbidden so as to cause measurement. Later, by way of installing pressure transducer additional in serosity area diverse location, directly measured by two pressure transducers tested The pressure differential in amount area, then according to density formula:ρ=P/gh (P:Interval pressure differential h of serosity area differing heights:Two pressure measurement Vertical dimension between point) calculate indirectly CaSO4Density, pressure transducer do not affected by crystallizing, measurement accurately so as to Solve the problems referred to above.The mounting means of pressure transducer is shown in accompanying drawing 1.
By the operation of a period of time, the shortcoming of this kind of mounting means also gradually manifests, is mainly shown as:
1st, the serosity in pipe nipple 1 and pipe nipple 2 is " dead band ", it is impossible to flowed well, and the serosity in serosity area has density Difference.
2nd, need frequently backwash to be carried out using tap water, increase the ratio of water in serosity, be unfavorable for desulfuration efficiency Lifting.
3rd, the easy fouling of " dead band " serosity in pipe nipple, blocks measurement pipe, causes measurement inaccurate.
The content of the invention
The present invention is to solve the problems, such as to cause measurement inaccurate due to " dead band " and fouling, there is provided a kind of limestone-based process spray Tower slurry density measurement device.The device can realize tower external pelivimetry.
The purpose of the present invention is achieved through the following technical solutions.
A kind of limestone-based process spray column slurry density measurement device, including pressure-measuring pipe, return duct, inlet tube, outlet, limit Stream valve, underflow valve, inlet valve, pressure tap, backwash water interface and Ph meter interfaces;
Pressure measurement bottom of the tube connection outlet pipe, is provided with therebetween underflow valve;Return duct one end is connected with outlet, another End is in pressure-measuring pipe top sidewall;Flow-limiting valve is provided with return duct;Inlet tube is installed in pressure-measuring pipe bottom sidewall;Enter The mouth pipe other end is connected with spray column bottom sidewall;Inlet valve is provided with inlet tube pipeline;It is provided with the side wall of pressure-measuring pipe Two pressure tap, backwash water interface and Ph meter interfaces;
The distance between described two pressure taps are 500mm;The pressure tap forms folder with pressure measurement tube side wall Angle;The angle is 60 °;
The common course of work:After device is fixedly connected with spray column, the serosity in spray column enters pressure measurement by inlet tube 3 Then pipe is flowed back in spray column through return duct and outlet;
Backwash --- when having fouling in device:
1st, Shao Liangshi:Underflow valve is opened, flow-limiting valve is closed, is realized from backwash by pressure reduction of the spray column with this device;
When the 2nd, measuring many:Underflow valve and flow-limiting valve are opened, by the external water under high pressure pipeline of backwash water interface, backwash is carried out;
The pressure-measuring pipe of the device is the rustless steel straight tube of a diameter DN250, length 2m.
Beneficial effect
The present invention provides a kind of Desulfurization tower slurry density measuring equipment, can effectively prevent original measurement device inaccurate, easy The generation of fouling condition, operation that can be steady in a long-term, and measure accurate.Being shown by engineering practice can be accurate using the device Measure serosity area CaSO4Density, and according to the numerical value of online PH, so as to accurately control the plasma discharge time, improve de- The stability and reliability of sulfur Tower System operation.As the device belongs to independent measurement apparatus, installation site can be according to scene Situation needs free variation;The serum density under fluidised form can be measured, there is no serosity dead band, certainty of measurement is high;Have simultaneously There is on-line rinsing and rinse two kinds of pre-washing functions offline, the fouling scene that can be prevented effectively from meter probe surface occurs;Can adopt Rustless steel, carbon steel line with rubber or other various materials make, and selection is extensive.
Description of the drawings
Fig. 1 spray column conventional densities meter instrumentation plans;
Fig. 2 is the schematic device of the present invention.
Wherein:1- pressure-measuring pipes, 2- return ducts, 3- inlet tubes, 4- outlets, 5- flow-limiting valves, 6- underflow valves, 7- inlet valves, 8- pressure taps, 9- backwash water interfaces, 10-Ph meter interfaces
Specific embodiment
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of limestone-based process spray column slurry density measurement device, including pressure-measuring pipe 1, return duct 2, inlet tube 3, outlet 4th, flow-limiting valve 5, underflow valve 6, inlet valve 7, pressure tap 8, backwash water interface 9 and Ph meter interface 10;
1 bottom connection outlet pipe 4 of pressure-measuring pipe, is provided with therebetween underflow valve 6;2 one end of return duct is connected with outlet 4 Connect, the other end is arranged in 1 top sidewall of pressure-measuring pipe;Flow-limiting valve 5 is provided with return duct 2;Install in 1 bottom sidewall of pressure-measuring pipe There is inlet tube 3;3 other end of inlet tube is connected with spray column bottom sidewall;Inlet valve 7 is provided with 3 pipeline of inlet tube;Pressure-measuring pipe Two pressure taps 8, backwash water interface 9 and Ph meter interface 10 is provided with 1 side wall;
The distance between described two pressure taps 8 are 500mm;The pressure tap 8 is formed with 1 side wall of pressure-measuring pipe Angle;The angle is 60 °;
The common course of work:After device is fixedly connected with spray column, the serosity in spray column enters pressure measurement by inlet tube 3 Then pipe 1 is flowed back in spray column through return duct 2 and outlet 4;
Backwash --- when having fouling in device
When a small amount of:Underflow valve 6 is opened, flow-limiting valve 5 is closed, is realized from backwash by pressure reduction of the spray column with this device;
When measuring many:Underflow valve 6 and flow-limiting valve 5 are opened, by 9 external water under high pressure pipeline of backwash water interface, backwash is carried out;
Rustless steel straight tube of the pressure-measuring pipe 1 of the device for a diameter DN250, length 2m.
The course of work:A kind of limestone-based process spray column slurry density measurement device, including the device such as pressure-measuring pipe 1, return duct 2 Composition.This device has abandoned the conventional mounting mode that densimeter is directly installed on spray column bottom, belongs to, can module Metaplasia is produced.Will the mouth of pipe reserved of inlet tube 3 and bottom of towe bottom be connected, outlet 4 can be directly discharged into absorption tower melt pit, then by ground Hole pump returns desulfurizing tower.The inlet valve 7 of pressure-measuring pipe 1 need to be only opened during measurement, and by adjusting flow-limiting valve 5 to control pressure-measuring pipe 1 Interior slurry flow rate.By pressure-measuring pipe 1 and the liquid level difference in Desulfurization tower slurry area, serosity constantly flows into pressure-measuring pipe 1, by pressure-measuring pipe Two differential manometers on 1, measure pressure differential, but according to density formula and the height value of two pressure taps, by inside on DCS Computing, you can draw the density value for flowing through pressure-measuring pipe serosity.Simultaneously by adjusting serosity in the controllable pressure-measuring pipe of 5 aperture of flow-limiting valve Flow velocity, it is ensured that the serosity in pressure-measuring pipe is in flow regime all the time, it is to avoid the dead band at differential manometer pipe nipple.Increase flow-limiting valve 5 Aperture can instantaneously increase slurry flow rate in pressure-measuring pipe, play souring, can avoid CaSO in pressure-measuring pipe4Fouling, it is ensured that measurement Precision.The backwash water interface 9 that can also pass through on pressure-measuring pipe 1 simultaneously squeezes into high-pressure washing water, thoroughly can remove in pressure-measuring pipe Scale forming matter, and while play a part of rinse differential manometer probe and PH meter probe.
Actual operating data is as follows:
Sequence number Data one Data two Data three Data four Data five
Pressure reduction (Pa) 2.14032 2.2246 2.42256 2.26968 2.3226
Measurement height (m) 0.2 0.2 0.2 0.2 0.2
Density (kg/m3) 1.092 1.135 1.236 1.158 1.185

Claims (6)

1. a kind of limestone-based process spray column slurry density measurement device, it is characterised in that:Including pressure-measuring pipe (1), return duct (2), Inlet tube (3), outlet (4), flow-limiting valve (5), underflow valve (6), inlet valve (7), pressure tap (8), backwash water interface (9) With Ph meters interface (10);
Pressure-measuring pipe (1) bottom connection outlet pipe (4), is provided with therebetween underflow valve (6);Return duct (2) one end and outlet (4) connect, the other end is arranged in pressure-measuring pipe (1) top sidewall;Flow-limiting valve (5) is provided with return duct (2);Pressure-measuring pipe (1) Inlet tube (3) is installed in bottom sidewall;Inlet tube (3) other end is connected with spray column bottom sidewall;On inlet tube (3) pipeline It is provided with inlet valve (7);Two pressure taps (8), backwash water interface (9) and Ph meter is provided with the side wall of pressure-measuring pipe (1) Interface (10).
2. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 1, it is characterised in that:It is described two The distance between pressure tap (8) is 500mm.
3. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 1, it is characterised in that:The pressure Meter interface (8) forms angle with pressure-measuring pipe (1) side wall.
4. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 3, it is characterised in that:The angle For 60 °.
5. a kind of limestone-based process spray column slurry density measurement device as described above described in arbitrary claim, its feature exist In:When having fouling in described device, processing method is as follows:
Method one, when having a small amount of incrustation scale:Underflow valve (6) is opened, flow-limiting valve (5) is closed, by spray column and the pressure of this device Difference is realized from backwash;
Method two, when having more incrustation scale:Underflow valve (6) and flow-limiting valve (5) are opened, by the external high pressure of backwash water interface (9) Water lines, carry out backwash.
6. a kind of limestone-based process spray column slurry density measurement device as described in Claims 1-4 is arbitrary, its feature exist In:The pressure-measuring pipe (1) is the rustless steel straight tube of a diameter of DN250, and its length is 2m.
CN201710080124.9A 2017-02-15 2017-02-15 Spray tower seriflux density measuring device by limestone method Pending CN106596332A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5410909A (en) * 1994-06-01 1995-05-02 The Babcock & Wilcox Company Plug proof simple device to measure liquid flow in flue gas desulfurization systems using nozzle pressure as an input
CN2863903Y (en) * 2006-01-20 2007-01-31 北京中大华瑞科技有限公司 Three-parameter major cycle grouting instrumentation system with density sampling branck
CN201754140U (en) * 2010-03-04 2011-03-02 杨玉娟 Slurry density measuring system of flue gas desulfurization apparatus
CN102489144A (en) * 2011-12-23 2012-06-13 武汉光谷环保科技股份有限公司 Measure apparatus of flue gas desulphurization absorbing tower, slurry pH meter and densitometer by using wet method and its method
CN202421014U (en) * 2011-12-15 2012-09-05 浙江天蓝环保技术股份有限公司 Slurry density-measuring unit
CN202683067U (en) * 2012-08-03 2013-01-23 中国大唐集团环境技术有限公司 Continuous on-line measurement device for Potential of Hydrogen (pH) value and density of exhaust gas wet desulphurization parget slurry fluid
CN204731123U (en) * 2015-07-14 2015-10-28 曾永健 A kind of wet desulfuration tower inner differential pressure type density measure means for anti-jamming
CN205435458U (en) * 2015-12-28 2016-08-10 北京北方节能环保有限公司 Spray column import flue connecting device
CN206787968U (en) * 2017-02-15 2017-12-22 北京北方节能环保有限公司 A kind of limestone-based process spray column slurry density measurement device

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5410909A (en) * 1994-06-01 1995-05-02 The Babcock & Wilcox Company Plug proof simple device to measure liquid flow in flue gas desulfurization systems using nozzle pressure as an input
CN2863903Y (en) * 2006-01-20 2007-01-31 北京中大华瑞科技有限公司 Three-parameter major cycle grouting instrumentation system with density sampling branck
CN201754140U (en) * 2010-03-04 2011-03-02 杨玉娟 Slurry density measuring system of flue gas desulfurization apparatus
CN202421014U (en) * 2011-12-15 2012-09-05 浙江天蓝环保技术股份有限公司 Slurry density-measuring unit
CN102489144A (en) * 2011-12-23 2012-06-13 武汉光谷环保科技股份有限公司 Measure apparatus of flue gas desulphurization absorbing tower, slurry pH meter and densitometer by using wet method and its method
CN202683067U (en) * 2012-08-03 2013-01-23 中国大唐集团环境技术有限公司 Continuous on-line measurement device for Potential of Hydrogen (pH) value and density of exhaust gas wet desulphurization parget slurry fluid
CN204731123U (en) * 2015-07-14 2015-10-28 曾永健 A kind of wet desulfuration tower inner differential pressure type density measure means for anti-jamming
CN205435458U (en) * 2015-12-28 2016-08-10 北京北方节能环保有限公司 Spray column import flue connecting device
CN206787968U (en) * 2017-02-15 2017-12-22 北京北方节能环保有限公司 A kind of limestone-based process spray column slurry density measurement device

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