CN106596332A - Spray tower seriflux density measuring device by limestone method - Google Patents
Spray tower seriflux density measuring device by limestone method Download PDFInfo
- Publication number
- CN106596332A CN106596332A CN201710080124.9A CN201710080124A CN106596332A CN 106596332 A CN106596332 A CN 106596332A CN 201710080124 A CN201710080124 A CN 201710080124A CN 106596332 A CN106596332 A CN 106596332A
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- Prior art keywords
- pressure
- tube
- valve
- spray column
- measuring pipe
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007921 spray Substances 0.000 title claims abstract description 33
- 235000019738 Limestone Nutrition 0.000 title claims abstract description 19
- 239000006028 limestone Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002002 slurry Substances 0.000 claims description 24
- 238000001739 density measurement Methods 0.000 claims description 12
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 238000003672 processing method Methods 0.000 claims 1
- 229910052925 anhydrite Inorganic materials 0.000 abstract description 10
- 230000003009 desulfurizing effect Effects 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract description 2
- 238000011001 backwashing Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000005259 measurement Methods 0.000 description 13
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 238000009530 blood pressure measurement Methods 0.000 description 5
- 210000002445 nipple Anatomy 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 239000012066 reaction slurry Substances 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N9/00—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity
- G01N9/26—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity by measuring pressure differences
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N9/00—Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity
- G01N9/36—Analysing materials by measuring the density or specific gravity, e.g. determining quantity of moisture
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention relates to a spray tower seriflux density measuring device by a limestone method, and belongs to the field of environmental protection. According to the device, the bottom of a piezometer tube is connected to an outlet tube, an underflow valve is arranged between the piezometer tube and the outlet tube, one end of a backflow tube is connected to the outlet tube, the other end of the backflow tube is arranged on the side wall of the top of the piezometer tube, the backflow tube is provided with a flow-limiting valve, the side wall of the bottom of the piezometer tube is provided with an inlet tube, the other end of the inlet tube is connected to the side wall of the bottom of the spray tower, an inlet tube pipeline is provided with an inlet valve, and the side wall of the piezometer tube is provided with two pressure gauge connectors, a back washing water connector and a ph-meter connector. The spray tower seriflux density measuring device by the limestone method can effectively prevent the occurrence of situations that the measuring is not accurate and scale formation is easily generated in an original device, can run stably for a long time, and can achieve accurate measuring. Engineering practices show that by adopting the device, the density of a seriflux area CaSO4 can be accurately measured, thus the time of thick liquid discharging can be accurately controlled according to a numberical valve of online PH, and operational stability and reliability of a desulfurizing tower system are improved.
Description
Technical field
The present invention relates to a kind of limestone-based process spray column slurry density measurement device, belongs to field of environment protection.
Background technology
Wet process of FGD spray column is a kind of spray equipment that sprayed slurry is recycled, and loop slurry adopted mostly
Lime stone slurry, by the Ca in serosity2+With the SO in flue gas2Reaction generates CaSO4, by the SO in flue gas2Remove so as to reach
The purpose of purifying smoke.When the continuous circulated sprinkling of lime stone slurry until circulation fluid in CaSO4Reach certain proportion, and circulation fluid
PH value reduce desulfuration efficiency decline after, will circulation fluid discharge a part, continue cycling through after being supplemented with fresh lime stone slurry
Spray.So when a part of serosity of the outer row is supplemented with new serosity, is a very important ginseng in desulfurizing tower running
Number.The parameter is controlled, the stable of desulfuration efficiency has not only been can guarantee that but also lime stone slurry can be saved, reduced operating cost, it is more important
Be to control CaSO4Concentration can prevent in crystallization inside tower, so as to block shower nozzle and other tower internals, cause desulfurizing tower to stop transport
Phenomenon generation.
The desulfurizing tower of early stage is the mode that online PH meter is set up in bottom of towe slurry layer, by the monitoring of online pH value so as to sentencing
It is disconnected when to discharge serosity.But as loop slurry is the buffer solution of strong acid weak base, the pH value of monitoring can not reaction slurry well
Actual numerical value in liquid, along with CaSO4Can count in PH and crystallize on probe so as to many reasons such as cause PH measurements amount inaccurate
Occur, cause in actual motion can not control plasma discharge time well, reduce desulfuration efficiency, crystallization inside tower can more seriously occur
Phenomenon.
By improvement, using measurement CaSO4The mode of density can prevent above-mentioned phenomenon from occurring, by measuring CaSO in tower4's
Density can directly know CaSO4Volumetric concentration so as to being accurately controlled the plasma discharge time.Earliest by the way of density skill, but adopt
Similarly there is instrument check with the direct method of measurement to be forbidden, pop one's head in CaSO4The generation of the phenomenon of crystallization is forbidden so as to cause measurement.
Later, by way of installing pressure transducer additional in serosity area diverse location, directly measured by two pressure transducers tested
The pressure differential in amount area, then according to density formula:ρ=P/gh (P:Interval pressure differential h of serosity area differing heights:Two pressure measurement
Vertical dimension between point) calculate indirectly CaSO4Density, pressure transducer do not affected by crystallizing, measurement accurately so as to
Solve the problems referred to above.The mounting means of pressure transducer is shown in accompanying drawing 1.
By the operation of a period of time, the shortcoming of this kind of mounting means also gradually manifests, is mainly shown as:
1st, the serosity in pipe nipple 1 and pipe nipple 2 is " dead band ", it is impossible to flowed well, and the serosity in serosity area has density
Difference.
2nd, need frequently backwash to be carried out using tap water, increase the ratio of water in serosity, be unfavorable for desulfuration efficiency
Lifting.
3rd, the easy fouling of " dead band " serosity in pipe nipple, blocks measurement pipe, causes measurement inaccurate.
The content of the invention
The present invention is to solve the problems, such as to cause measurement inaccurate due to " dead band " and fouling, there is provided a kind of limestone-based process spray
Tower slurry density measurement device.The device can realize tower external pelivimetry.
The purpose of the present invention is achieved through the following technical solutions.
A kind of limestone-based process spray column slurry density measurement device, including pressure-measuring pipe, return duct, inlet tube, outlet, limit
Stream valve, underflow valve, inlet valve, pressure tap, backwash water interface and Ph meter interfaces;
Pressure measurement bottom of the tube connection outlet pipe, is provided with therebetween underflow valve;Return duct one end is connected with outlet, another
End is in pressure-measuring pipe top sidewall;Flow-limiting valve is provided with return duct;Inlet tube is installed in pressure-measuring pipe bottom sidewall;Enter
The mouth pipe other end is connected with spray column bottom sidewall;Inlet valve is provided with inlet tube pipeline;It is provided with the side wall of pressure-measuring pipe
Two pressure tap, backwash water interface and Ph meter interfaces;
The distance between described two pressure taps are 500mm;The pressure tap forms folder with pressure measurement tube side wall
Angle;The angle is 60 °;
The common course of work:After device is fixedly connected with spray column, the serosity in spray column enters pressure measurement by inlet tube 3
Then pipe is flowed back in spray column through return duct and outlet;
Backwash --- when having fouling in device:
1st, Shao Liangshi:Underflow valve is opened, flow-limiting valve is closed, is realized from backwash by pressure reduction of the spray column with this device;
When the 2nd, measuring many:Underflow valve and flow-limiting valve are opened, by the external water under high pressure pipeline of backwash water interface, backwash is carried out;
The pressure-measuring pipe of the device is the rustless steel straight tube of a diameter DN250, length 2m.
Beneficial effect
The present invention provides a kind of Desulfurization tower slurry density measuring equipment, can effectively prevent original measurement device inaccurate, easy
The generation of fouling condition, operation that can be steady in a long-term, and measure accurate.Being shown by engineering practice can be accurate using the device
Measure serosity area CaSO4Density, and according to the numerical value of online PH, so as to accurately control the plasma discharge time, improve de-
The stability and reliability of sulfur Tower System operation.As the device belongs to independent measurement apparatus, installation site can be according to scene
Situation needs free variation;The serum density under fluidised form can be measured, there is no serosity dead band, certainty of measurement is high;Have simultaneously
There is on-line rinsing and rinse two kinds of pre-washing functions offline, the fouling scene that can be prevented effectively from meter probe surface occurs;Can adopt
Rustless steel, carbon steel line with rubber or other various materials make, and selection is extensive.
Description of the drawings
Fig. 1 spray column conventional densities meter instrumentation plans;
Fig. 2 is the schematic device of the present invention.
Wherein:1- pressure-measuring pipes, 2- return ducts, 3- inlet tubes, 4- outlets, 5- flow-limiting valves, 6- underflow valves, 7- inlet valves,
8- pressure taps, 9- backwash water interfaces, 10-Ph meter interfaces
Specific embodiment
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of limestone-based process spray column slurry density measurement device, including pressure-measuring pipe 1, return duct 2, inlet tube 3, outlet
4th, flow-limiting valve 5, underflow valve 6, inlet valve 7, pressure tap 8, backwash water interface 9 and Ph meter interface 10;
1 bottom connection outlet pipe 4 of pressure-measuring pipe, is provided with therebetween underflow valve 6;2 one end of return duct is connected with outlet 4
Connect, the other end is arranged in 1 top sidewall of pressure-measuring pipe;Flow-limiting valve 5 is provided with return duct 2;Install in 1 bottom sidewall of pressure-measuring pipe
There is inlet tube 3;3 other end of inlet tube is connected with spray column bottom sidewall;Inlet valve 7 is provided with 3 pipeline of inlet tube;Pressure-measuring pipe
Two pressure taps 8, backwash water interface 9 and Ph meter interface 10 is provided with 1 side wall;
The distance between described two pressure taps 8 are 500mm;The pressure tap 8 is formed with 1 side wall of pressure-measuring pipe
Angle;The angle is 60 °;
The common course of work:After device is fixedly connected with spray column, the serosity in spray column enters pressure measurement by inlet tube 3
Then pipe 1 is flowed back in spray column through return duct 2 and outlet 4;
Backwash --- when having fouling in device
When a small amount of:Underflow valve 6 is opened, flow-limiting valve 5 is closed, is realized from backwash by pressure reduction of the spray column with this device;
When measuring many:Underflow valve 6 and flow-limiting valve 5 are opened, by 9 external water under high pressure pipeline of backwash water interface, backwash is carried out;
Rustless steel straight tube of the pressure-measuring pipe 1 of the device for a diameter DN250, length 2m.
The course of work:A kind of limestone-based process spray column slurry density measurement device, including the device such as pressure-measuring pipe 1, return duct 2
Composition.This device has abandoned the conventional mounting mode that densimeter is directly installed on spray column bottom, belongs to, can module
Metaplasia is produced.Will the mouth of pipe reserved of inlet tube 3 and bottom of towe bottom be connected, outlet 4 can be directly discharged into absorption tower melt pit, then by ground
Hole pump returns desulfurizing tower.The inlet valve 7 of pressure-measuring pipe 1 need to be only opened during measurement, and by adjusting flow-limiting valve 5 to control pressure-measuring pipe 1
Interior slurry flow rate.By pressure-measuring pipe 1 and the liquid level difference in Desulfurization tower slurry area, serosity constantly flows into pressure-measuring pipe 1, by pressure-measuring pipe
Two differential manometers on 1, measure pressure differential, but according to density formula and the height value of two pressure taps, by inside on DCS
Computing, you can draw the density value for flowing through pressure-measuring pipe serosity.Simultaneously by adjusting serosity in the controllable pressure-measuring pipe of 5 aperture of flow-limiting valve
Flow velocity, it is ensured that the serosity in pressure-measuring pipe is in flow regime all the time, it is to avoid the dead band at differential manometer pipe nipple.Increase flow-limiting valve 5
Aperture can instantaneously increase slurry flow rate in pressure-measuring pipe, play souring, can avoid CaSO in pressure-measuring pipe4Fouling, it is ensured that measurement
Precision.The backwash water interface 9 that can also pass through on pressure-measuring pipe 1 simultaneously squeezes into high-pressure washing water, thoroughly can remove in pressure-measuring pipe
Scale forming matter, and while play a part of rinse differential manometer probe and PH meter probe.
Actual operating data is as follows:
Sequence number | Data one | Data two | Data three | Data four | Data five |
Pressure reduction (Pa) | 2.14032 | 2.2246 | 2.42256 | 2.26968 | 2.3226 |
Measurement height (m) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
Density (kg/m3) | 1.092 | 1.135 | 1.236 | 1.158 | 1.185 |
Claims (6)
1. a kind of limestone-based process spray column slurry density measurement device, it is characterised in that:Including pressure-measuring pipe (1), return duct (2),
Inlet tube (3), outlet (4), flow-limiting valve (5), underflow valve (6), inlet valve (7), pressure tap (8), backwash water interface (9)
With Ph meters interface (10);
Pressure-measuring pipe (1) bottom connection outlet pipe (4), is provided with therebetween underflow valve (6);Return duct (2) one end and outlet
(4) connect, the other end is arranged in pressure-measuring pipe (1) top sidewall;Flow-limiting valve (5) is provided with return duct (2);Pressure-measuring pipe (1)
Inlet tube (3) is installed in bottom sidewall;Inlet tube (3) other end is connected with spray column bottom sidewall;On inlet tube (3) pipeline
It is provided with inlet valve (7);Two pressure taps (8), backwash water interface (9) and Ph meter is provided with the side wall of pressure-measuring pipe (1)
Interface (10).
2. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 1, it is characterised in that:It is described two
The distance between pressure tap (8) is 500mm.
3. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 1, it is characterised in that:The pressure
Meter interface (8) forms angle with pressure-measuring pipe (1) side wall.
4. a kind of limestone-based process spray column slurry density measurement device as claimed in claim 3, it is characterised in that:The angle
For 60 °.
5. a kind of limestone-based process spray column slurry density measurement device as described above described in arbitrary claim, its feature exist
In:When having fouling in described device, processing method is as follows:
Method one, when having a small amount of incrustation scale:Underflow valve (6) is opened, flow-limiting valve (5) is closed, by spray column and the pressure of this device
Difference is realized from backwash;
Method two, when having more incrustation scale:Underflow valve (6) and flow-limiting valve (5) are opened, by the external high pressure of backwash water interface (9)
Water lines, carry out backwash.
6. a kind of limestone-based process spray column slurry density measurement device as described in Claims 1-4 is arbitrary, its feature exist
In:The pressure-measuring pipe (1) is the rustless steel straight tube of a diameter of DN250, and its length is 2m.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710080124.9A CN106596332A (en) | 2017-02-15 | 2017-02-15 | Spray tower seriflux density measuring device by limestone method |
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CN201710080124.9A CN106596332A (en) | 2017-02-15 | 2017-02-15 | Spray tower seriflux density measuring device by limestone method |
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Publication Number | Publication Date |
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CN106596332A true CN106596332A (en) | 2017-04-26 |
Family
ID=58587377
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CN201710080124.9A Pending CN106596332A (en) | 2017-02-15 | 2017-02-15 | Spray tower seriflux density measuring device by limestone method |
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US5410909A (en) * | 1994-06-01 | 1995-05-02 | The Babcock & Wilcox Company | Plug proof simple device to measure liquid flow in flue gas desulfurization systems using nozzle pressure as an input |
CN2863903Y (en) * | 2006-01-20 | 2007-01-31 | 北京中大华瑞科技有限公司 | Three-parameter major cycle grouting instrumentation system with density sampling branck |
CN201754140U (en) * | 2010-03-04 | 2011-03-02 | 杨玉娟 | Slurry density measuring system of flue gas desulfurization apparatus |
CN102489144A (en) * | 2011-12-23 | 2012-06-13 | 武汉光谷环保科技股份有限公司 | Measure apparatus of flue gas desulphurization absorbing tower, slurry pH meter and densitometer by using wet method and its method |
CN202421014U (en) * | 2011-12-15 | 2012-09-05 | 浙江天蓝环保技术股份有限公司 | Slurry density-measuring unit |
CN202683067U (en) * | 2012-08-03 | 2013-01-23 | 中国大唐集团环境技术有限公司 | Continuous on-line measurement device for Potential of Hydrogen (pH) value and density of exhaust gas wet desulphurization parget slurry fluid |
CN204731123U (en) * | 2015-07-14 | 2015-10-28 | 曾永健 | A kind of wet desulfuration tower inner differential pressure type density measure means for anti-jamming |
CN205435458U (en) * | 2015-12-28 | 2016-08-10 | 北京北方节能环保有限公司 | Spray column import flue connecting device |
CN206787968U (en) * | 2017-02-15 | 2017-12-22 | 北京北方节能环保有限公司 | A kind of limestone-based process spray column slurry density measurement device |
-
2017
- 2017-02-15 CN CN201710080124.9A patent/CN106596332A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5410909A (en) * | 1994-06-01 | 1995-05-02 | The Babcock & Wilcox Company | Plug proof simple device to measure liquid flow in flue gas desulfurization systems using nozzle pressure as an input |
CN2863903Y (en) * | 2006-01-20 | 2007-01-31 | 北京中大华瑞科技有限公司 | Three-parameter major cycle grouting instrumentation system with density sampling branck |
CN201754140U (en) * | 2010-03-04 | 2011-03-02 | 杨玉娟 | Slurry density measuring system of flue gas desulfurization apparatus |
CN202421014U (en) * | 2011-12-15 | 2012-09-05 | 浙江天蓝环保技术股份有限公司 | Slurry density-measuring unit |
CN102489144A (en) * | 2011-12-23 | 2012-06-13 | 武汉光谷环保科技股份有限公司 | Measure apparatus of flue gas desulphurization absorbing tower, slurry pH meter and densitometer by using wet method and its method |
CN202683067U (en) * | 2012-08-03 | 2013-01-23 | 中国大唐集团环境技术有限公司 | Continuous on-line measurement device for Potential of Hydrogen (pH) value and density of exhaust gas wet desulphurization parget slurry fluid |
CN204731123U (en) * | 2015-07-14 | 2015-10-28 | 曾永健 | A kind of wet desulfuration tower inner differential pressure type density measure means for anti-jamming |
CN205435458U (en) * | 2015-12-28 | 2016-08-10 | 北京北方节能环保有限公司 | Spray column import flue connecting device |
CN206787968U (en) * | 2017-02-15 | 2017-12-22 | 北京北方节能环保有限公司 | A kind of limestone-based process spray column slurry density measurement device |
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