CN106592280A - Anti-heat-yellowing agent for chinlon dyeing - Google Patents

Anti-heat-yellowing agent for chinlon dyeing Download PDF

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Publication number
CN106592280A
CN106592280A CN201610935292.7A CN201610935292A CN106592280A CN 106592280 A CN106592280 A CN 106592280A CN 201610935292 A CN201610935292 A CN 201610935292A CN 106592280 A CN106592280 A CN 106592280A
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CN
China
Prior art keywords
parts
acid
dyeing
heat
chinlon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610935292.7A
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Chinese (zh)
Inventor
吴军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongxiang Puyuan Woolen Knitting Technology Service Center
Original Assignee
Tongxiang Puyuan Woolen Knitting Technology Service Center
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongxiang Puyuan Woolen Knitting Technology Service Center filed Critical Tongxiang Puyuan Woolen Knitting Technology Service Center
Priority to CN201610935292.7A priority Critical patent/CN106592280A/en
Publication of CN106592280A publication Critical patent/CN106592280A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6424—Compounds containing isocyanate or isothiocyanate groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6425—Compounds containing hydrazine or azo groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65168—Sulfur-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to the technical field of dyeing auxiliaries, in particular to an anti-heat-yellowing agent for chinlon dyeing. The anti-heat-yellowing agent for chinlon dyeing is prepared from, by mass, 30-40 parts of monoacetyl guanidine, 15-20 parts of adopyl diacidhydrazine, 10-15 parts of pimelic acid dicarbonyl dihydrazide, 3-5 parts of silane coupling agent,1-2 parts of calcium carbonate, 0.5-1 part of 1,3,5-tri(4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzyl)isocyanurate and 1-2 parts of distearyl thiodipropionate. The obtained anti-heat-yellowing agent for chinlon dyeing is specially suitable for the dyeing process of chinlon fabric, yellowing and other situations generated in the dyeing process of the chinlon fabric can be effectively avoided, and the anti-heat-yellowing effect is good.

Description

A kind of heat resistanceheat resistant xanthochromia agent of nylon dyeing
Technical field
The present invention relates to the heat resistanceheat resistant xanthochromia agent of dyeing assistant technical field, especially a kind of nylon dyeing.
Background technology
Chinlon is called Fypro or nylon, has many amide groups in molecular structure.Spandex is called polyurethane fiber, There are many carbamate groups in molecular structure.Chinlon and spandex have many excellent physical and mechanical propertiess, weaving and Other industrial circles are widely used.But chinlon is there is also as heat resistance is poor, in light and heat, lower easy yellowing, the shortcomings of become fragile. Particularly in high temperature working processes, easy yellowing and there is complexion changed in such as heat setting and during pressing mold, affect the outward appearance matter of product Amount, while also can produce serious influence to the physical and mechanical propertiess of chinlon and spandex so as to which wearability is substantially reduced, therefore It is a very important link in its dyeing and finishing course of processing that heat resistanceheat resistant xanthochromia is arranged.Chinlon, spandex and its blend fabric are in high temperature In the hot procedure such as heat setting and pressing mold, add the agent of heat resistanceheat resistant xanthochromia can prevent oxidation under its high temperature with it is tendering, improve due to Yellowing and color change that light and heat, moisture, the effect of nitrogen oxides cause.
In the prior art, a kind of yellowing-resistant oil preparation is constituted using smooth agent, emulsifying agent, detergent, additive and take Obtained preferable yellowing-resistant effect, but the method was applied to dacron, to chinlon spandex and do not applied to.
The content of the invention
The invention aims to solve the not enough of above-mentioned technology and provide one kind and be applied to nylon fabric and yellowing-resistant The heat resistanceheat resistant xanthochromia agent of effect good nylon dyeing.
In order to achieve the above object, a kind of nylon dyeing heat resistanceheat resistant xanthochromia agent designed by the present invention, it is by following components Composition：Acetyl guanidine, adipic acid dihydrazide, two hydrazides of 1,5-pentanedicarboxylic acid., silane coupler, Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- Hydroxyl -2,6- dimethyl benzyls) isocyanuric acid ester, thio-2 acid 2 stearyl ester, the mass fraction of wherein each component is：Second Acyl guanidine 30-40 parts, adipic acid dihydrazide 15-20 parts, two hydrazides 10-15 parts of 1,5-pentanedicarboxylic acid., silane coupler 3-5 parts, Calcium Carbonate 1-2 Part, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) isocyanuric acid ester 0.5-1 parts, thio-2 acid distearyl Alcohol ester 1-2 parts.
A kind of heat resistanceheat resistant xanthochromia agent of nylon dyeing obtained by the present invention, which is specially adapted for the dyeing of nylon fabric Journey, situations such as can effectively avoid nylon fabric that yellowing occurs in dyeing course, heat resistanceheat resistant xanthochromia effect is good.
Specific embodiment
The present invention is further described by the following embodiment.
Embodiment 1：
A kind of nylon dyeing heat resistanceheat resistant xanthochromia agent of the present embodiment description, it is composed of the following components：Acetyl guanidine, two acyl of adipic acid Hydrazine, two hydrazides of 1,5-pentanedicarboxylic acid., silane coupler, Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) are different The mass fraction of cyanurate, thio-2 acid 2 stearyl ester, wherein each component is：30 parts of acetyl guanidine, adipic acid dihydrazide 15 parts, 10 parts of two hydrazides of 1,5-pentanedicarboxylic acid., 3 parts of silane coupler, 1 part of Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- bis- Methyl-benzyl) 0.5 part of isocyanuric acid ester, 2 parts of thio-2 acid 2 stearyl ester.
Embodiment 2：
A kind of nylon dyeing heat resistanceheat resistant xanthochromia agent of the present embodiment description, it is composed of the following components：Acetyl guanidine, two acyl of adipic acid Hydrazine, two hydrazides of 1,5-pentanedicarboxylic acid., silane coupler, Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) are different The mass fraction of cyanurate, thio-2 acid 2 stearyl ester, wherein each component is：40 parts of acetyl guanidine, adipic acid dihydrazide 20 parts, 15 parts of two hydrazides of 1,5-pentanedicarboxylic acid., 5 parts of silane coupler, 2 parts of Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- bis- Methyl-benzyl) 1 part of isocyanuric acid ester, 1 part of thio-2 acid 2 stearyl ester.
Embodiment 3：
A kind of nylon dyeing heat resistanceheat resistant xanthochromia agent of the present embodiment description, it is composed of the following components：Acetyl guanidine, two acyl of adipic acid Hydrazine, two hydrazides of 1,5-pentanedicarboxylic acid., silane coupler, Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) are different The mass fraction of cyanurate, thio-2 acid 2 stearyl ester, wherein each component is：35 parts of acetyl guanidine, adipic acid dihydrazide 18 parts, 12 parts of two hydrazides of 1,5-pentanedicarboxylic acid., 4 parts of silane coupler, 1.6 parts of Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- Dimethyl benzyl) 0.8 part of isocyanuric acid ester, 1.3 parts of thio-2 acid 2 stearyl ester.

Claims (1)

1. a kind of nylon dyeing heat resistanceheat resistant xanthochromia agent, is characterized in that：It is composed of the following components：Acetyl guanidine, adipic acid dihydrazide, Two hydrazides of 1,5-pentanedicarboxylic acid., silane coupler, Calcium Carbonate, 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) isocyanide urea The mass fraction of acid esters, thio-2 acid 2 stearyl ester, wherein each component is：Acetyl guanidine 30-40 parts, adipic acid dihydrazide 15-20 parts, two hydrazides 10-15 parts of 1,5-pentanedicarboxylic acid., silane coupler 3-5 parts, Calcium Carbonate 1-2 part, 1,3,5- tri- (the 4- tert-butyl group -3- Hydroxyl -2,6- dimethyl benzyls) isocyanuric acid ester 0.5-1 parts, thio-2 acid 2 stearyl ester 1-2 parts.
CN201610935292.7A 2016-11-01 2016-11-01 Anti-heat-yellowing agent for chinlon dyeing Pending CN106592280A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114635298A (en) * 2022-03-17 2022-06-17 伟格仕纺织助剂（江门）有限公司 Pollution-free high-safety chinlon anti-thermal yellowing agent and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04174781A (en) * 1990-11-02 1992-06-22 Kagoshima Univ Cloth made from silk yarn treated with zeolite
CN103044776A (en) * 2012-12-31 2013-04-17 广东银禧科技股份有限公司 Low-odor and yellowing resistant polypropylene composition and preparation method thereof
CN103556459A (en) * 2013-10-28 2014-02-05 四川大学 Composite heat-yellow discolouration resistant finishing agent of chinlon, spandex and blended fabric of two

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04174781A (en) * 1990-11-02 1992-06-22 Kagoshima Univ Cloth made from silk yarn treated with zeolite
CN103044776A (en) * 2012-12-31 2013-04-17 广东银禧科技股份有限公司 Low-odor and yellowing resistant polypropylene composition and preparation method thereof
CN103556459A (en) * 2013-10-28 2014-02-05 四川大学 Composite heat-yellow discolouration resistant finishing agent of chinlon, spandex and blended fabric of two

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
甘绍宁等: "《专利信息利用的实践》", 31 January 2016 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114635298A (en) * 2022-03-17 2022-06-17 伟格仕纺织助剂（江门）有限公司 Pollution-free high-safety chinlon anti-thermal yellowing agent and preparation method thereof
CN114635298B (en) * 2022-03-17 2023-02-28 伟格仕纺织助剂（江门）有限公司 Pollution-free high-safety chinlon anti-thermal yellowing agent and preparation method thereof

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Application publication date: 20170426