CN106592189B - The wear-resisting anti-sticking soleplate of one kind and preparation method - Google Patents
The wear-resisting anti-sticking soleplate of one kind and preparation method Download PDFInfo
- Publication number
- CN106592189B CN106592189B CN201611146723.8A CN201611146723A CN106592189B CN 106592189 B CN106592189 B CN 106592189B CN 201611146723 A CN201611146723 A CN 201611146723A CN 106592189 B CN106592189 B CN 106592189B
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- China
- Prior art keywords
- parts
- wear
- sticking
- silicon carbide
- resisting anti
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 64
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 30
- 229920001225 polyester resin Polymers 0.000 claims abstract description 28
- 239000004645 polyester resin Substances 0.000 claims abstract description 28
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 27
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010439 graphite Substances 0.000 claims abstract description 13
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 13
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 40
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- 238000010792 warming Methods 0.000 claims description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000012065 filter cake Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 13
- RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004411 aluminium Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 10
- 239000010445 mica Substances 0.000 claims description 10
- 229910052618 mica group Inorganic materials 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 8
- FFWSICBKRCICMR-UHFFFAOYSA-N 5-methyl-2-hexanone Chemical compound CC(C)CCC(C)=O FFWSICBKRCICMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 235000019260 propionic acid Nutrition 0.000 claims description 5
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 5
- 238000002604 ultrasonography Methods 0.000 claims description 5
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 239000012974 tin catalyst Substances 0.000 claims description 4
- 238000003763 carbonization Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000011863 silicon-based powder Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052791 calcium Inorganic materials 0.000 abstract description 10
- 239000011575 calcium Substances 0.000 abstract description 10
- 239000005543 nano-size silicon particle Substances 0.000 abstract description 10
- 239000003599 detergent Substances 0.000 abstract description 2
- 238000005119 centrifugation Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000001132 ultrasonic dispersion Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OHBRHBQMHLEELN-UHFFFAOYSA-N acetic acid;1-butoxybutane Chemical compound CC(O)=O.CCCCOCCCC OHBRHBQMHLEELN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- ZSDJVGXBJDDOCD-UHFFFAOYSA-N benzene dioctyl benzene-1,2-dicarboxylate Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=CC=C1 ZSDJVGXBJDDOCD-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- -1 methyl isoamyl Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002345 surface coating layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F75/00—Hand irons
- D06F75/38—Sole plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2202/00—Metallic substrate
- B05D2202/20—Metallic substrate based on light metals
- B05D2202/25—Metallic substrate based on light metals based on Al
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2508/00—Polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2518/00—Other type of polymers
- B05D2518/10—Silicon-containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/20—Inorganic fillers used for non-pigmentation effect
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of wear-resisting anti-sticking soleplates, including base material and it is covered on the coat on base material surface, the base material is made using aluminum alloy materials, and the coat raw material includes: 15-20 parts of nano silicon carbide calcium, 20-40 parts of silicone modified polyester resin, modified silicon carbide 20-30 parts, 1-5 parts of graphite, 3-6 parts of silane coupling agent, 5-15 parts of auxiliary material, 10-20 parts of solvent by weight；The invention also discloses a kind of preparation methods of wear-resisting anti-sticking soleplate.The present invention has under the high temperature conditions to have good wearability and anti-adhesion performance, extends using the time, conserves clothing, also has detergent resistance, meet the actual use performance of flatiron, preparation is simple.
Description
Technical field
The present invention relates to wear-resisting anti-sticking soleplate technical fields, more particularly to a kind of wear-resisting anti-sticking soleplate and preparation
Method.
Background technique
The wear-resisting anti-sticking soleplate material of presently commercially available aluminum mainly has aluminium, stainless steel, iron etc., and aluminum is wear-resisting anti-sticking to be pressed
The characteristic of bottom sheet is that heat distribution is excellent, and heat-transfer effect is 16 times of stainless steel flatiron, and relatively light.But aluminum pot anti-adhesion performance is poor,
Not easy cleaning.The characteristic of stainless steel is that heat distribution is bad, is also easy to produce heat build-up point and scorch clothes.Stainless steel weight, not easy cleaning.Iron
It is bad to make wear-resisting anti-sticking soleplate heat distribution, is also easy to produce heat build-up point and scorch clothes, easily gets rusty, not easy cleaning.Non-viscous paint
Since it has low-down surface tension, so that other materials are difficult to adhere on surface, the non-stick pan being produced from it has from appearance
Since to people life bring great convenience.Current coating flatiron using aluminium or aluminium alloy as metal base,
This is because the good heat conductivity of this metalloid, but the wear-resisting property of aluminum base is poor, be easy in use process by button or
Metal fittings scratching generates scratch and is embroidered, and the anti-adhesion performance of aluminium alloy is bad, can generate damage to clothing in use process, make
At economic loss.
Summary of the invention
The invention proposes a kind of wear-resisting anti-sticking soleplate and preparation methods, including base portion material is made by aluminum alloy materials
Expecting and be covered on the coat on base material surface, the present invention has under the high temperature conditions to have good wearability and anti-adhesion performance,
Clothing is conserved, meets the actual use performance of flatiron, preparation process is simple, reduces production cost.
The wear-resisting anti-sticking soleplate of one kind proposed by the present invention, including metal base and is covered on metal base surface
Coat, the base material are made using aluminum alloy materials, and the coat raw material includes: nano silicon carbide calcium by weight
15-20 parts, 20-40 parts of silicone modified polyester resin, modified silicon carbide 20-30 parts, 1-5 parts of graphite, silane coupling agent 3-6
Part, 5-15 parts of auxiliary material, 10-20 parts of solvent；
The modified silicon carbide is made using following steps: silicon carbide powder, dispersing agent and organic solvent is uniformly mixed,
It is passed through protection gas, is warming up to 85-95 DEG C of reaction, filters obtain filter cake material while hot, filter cake material is placed in sonification medium and is surpassed
Sound dispersion, centrifuge washing is dry, cooling to obtain modified silicon carbide.
Preferably, solvent is ethylene glycol ether acetate, butyl acetate, isobutyl isobutyrate, propionic acid -3-
One or more mixtures of ether ethyl ester and methyl isoamyl ketone.
Preferably, auxiliary material includes one or more mixtures of calcium carbonate, mica, aluminium powder, quartz.
Preferably, auxiliary material includes mica and aluminium powder.
Preferably, in silicon carbide modifying process, the amount volume ratio g:ml of silicon carbide powder and organic solvent is 1:7.
Preferably, in silicon carbide modifying process, dispersing agent is silane coupling agent.
Preferably, in silicon carbide modifying process, organic solvent is acetone and/or toluene.
Preferably, in silicon carbide modifying process, organic solvent is toluene.
Preferably, in silicon carbide modifying process, protection gas is N2。
Preferably, in silicon carbide modifying process, 5-7h is reacted after heating.
Preferably, in silicon carbide modifying process, sonification medium is deionized water and/or acetone, supersonic frequency 1500-
2000Hz, ultrasonic time 25-35min.
Preferably, in silicon carbide modifying process, filter cake material is placed in progress repeated ultrasonic dispersion in sonification medium.
Preferably, in silicon carbide modifying process, centrifuge washing medium is water and/or acetone, centrifugation rate 4000-
5000r/min is washed 5-10 times.
Preferably, in silicon carbide modifying process, drying temperature is 100-120 DEG C, drying time 10-15h.
Preferably, silicone modified polyester resin is made by following steps: neopentyl glycol, organotin catalysts being added anti-
Device is answered, nitrogen is passed through into reactor, is warming up to 130~150 DEG C, organosilicon is added, is warming up to 160~180 DEG C, is added to benzene
Dioctyl phthalate and organotin catalysts are warming up to 170~190 DEG C, keep the temperature 0.5h, are continuously heating to 250 DEG C, and phosphorous triphenyl phosphate is added
Ester, vacuum reaction are cooled to 180~190 DEG C, and cooling obtains silicone modified polyester resin.
Preferably, silicone content is 1-3wt% in silicone modified polyester resin.
Preferably, vacuum reaction 20-40min.
Preferably, the coat raw material includes: 17.5 parts of nano silicon carbide calcium, silicone modified polyester resin by weight
30 parts, modified 25 parts of silicon carbide, 3 parts of graphite, 4.5 parts of silane coupling agent, 10 parts of auxiliary material, 15 parts of solvent.
A kind of preparation method of wear-resisting anti-sticking soleplate includes the following steps: to carry out base material at the decontamination of surface
Reason, is dried to obtain substrate；By nano silicon carbide calcium, silicone modified polyester resin, modified silicon carbide, graphite, silane coupling agent, auxiliary
After material and solvent mixing mix, melting extrusion, smashing obtains coating material；Coating material is sprayed into substrate surface with electrostatic gun,
Solidification obtains wear-resisting anti-sticking soleplate under the conditions of 195-205 DEG C of temperature.
In the present invention, in the silicone modified polyester resin of coat, the addition of a small amount of organosilicon forms bigger molecule
Silicone segments, be grafted on organic resin, so that the molecular chain movement of modified resin becomes difficult, improve polyester resin
Plasticity and impact flexibility, improve the adhesive force of coat and metallic matrix, coating surface forms one layer of siliceous protective layer, makes
The hydrophobicity and weather resistance of coating surface improve；The introducing for controlling a small amount of organic siliconresin will cause on film coated surface gloss
It rises, and other basic performances for maintaining coat are good；Modified silicon carbide has good corrosion resistance and good thermally conductive
Property, bottom plate can be effectively improved to the chemical stability of clothing residual detergent by adding it in superficial layer, while ensure that painting
Layer uniform heat distribution, reduces coefficient of friction, reduces, bottom plate corrosion resistance Nian Jie with clothes generation when using under hot conditions
Good, nanometer calcium carbonate particle forms the crack propagation that stress concentration point generates floor base material as the filler in coating liquid
It is obstructed and is passivated, pressure check development will not occur destructive cracking；Meanwhile nanometer calcium carbonate and modified silicon carbide have association
Same-action enhances the hardness and heat resistance of coat, extends the service life of flatiron, and the filling of nanometer calcium carbonate can make table
The face compact imporosity of coat microcosmic surface, preferably protects aluminum matrix, and enhance coating does not glue effect；Preparation process
The dosage of middle control deionized water, so that surface coating layer is through forming the biggish sol body of the netted or degree of cross linking after hydrolytic condensation
System, improves the wear-resisting property of bottom plate；The further very high thermally conductive and wear-resisting property of wear-resisting anti-sticking soleplate of graphite, mica
As filler, wearability, the chemical corrosion resistance of coating are enhanced, has aluminium powder synergistic effect, further improves mechanical property
Energy.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: that 20 parts of nano silicon carbide calcium, organosilicon change by weight
Property 40 parts of polyester resin, modified 20 parts of silicon carbide, 3 parts of graphite, 4.5 parts of silane coupling agent, 10 parts of auxiliary material, 15 parts of solvent；
The modified silicon carbide is made using following steps: silicon carbide powder, dispersing agent and organic solvent is uniformly mixed,
It is passed through protection gas, is warming up to 85 DEG C of reactions, filters obtain filter cake material while hot, filter cake material is placed in ultrasound point in sonification medium
It dissipates, centrifuge washing, it is dry, it is cooling to obtain modified silicon carbide.
Embodiment 2
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: that 15 parts of nano silicon carbide calcium, organosilicon change by weight
Property 20 parts of polyester resin, modified 25 parts of silicon carbide, 1 part of graphite, 3 parts of silane coupling agent, 5 parts of mica, ethylene glycol ether acetate
10 parts；
The modified silicon carbide is made using following steps: silicon carbide powder, silane coupling agent and toluene is uniformly mixed,
It is passed through N2, 95 DEG C of reactions are warming up to, filters obtain filter cake material while hot, filter cake material is placed in ultrasonic disperse in sonification medium,
Centrifuge washing, it is dry, it is cooling to obtain modified silicon carbide.
Embodiment 3
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: 17.5 parts of nano silicon carbide calcium, organosilicon by weight
30 parts of modified polyester resin, modified 30 parts of silicon carbide, 4 parts of graphite, 6 parts of silane coupling agent, 5 parts of mica, 5 parts of aluminium powder, diethyl two
10 parts of alcohol monobutyl ether acetate, 10 parts of isobutyl isobutyrate；
The modified silicon carbide is made using following steps: silicon carbide powder, silane coupling agent and acetone is uniformly mixed,
It is passed through N2, 90 DEG C of reaction 5h are warming up to, filters obtain filter cake material while hot, filter cake material is placed in ultrasound point in deionized water
It dissipates, supersonic frequency 1500Hz, ultrasonic time 25min, with deionized water centrifuge washing 5 times, centrifugation rate 4000r/
Min, dry 10h under the conditions of temperature is 100 DEG C, it is cooling to obtain modified silicon carbide.
Embodiment 4
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: 17.5 parts of nano silicon carbide calcium, organosilicon by weight
30 parts of modified polyester resin, modified 25 parts of silicon carbide, 3 parts of graphite, 4.5 parts of silane coupling agent, 3 parts of calcium carbonate, 4 parts of mica, aluminium
5 parts of powder, 5 parts of isobutyl isobutyrate, 5 parts, 5 parts of methyl isoamyl ketone of propionic acid -3- ether ethyl ester；
The modified silicon carbide is made using following steps: silicon carbide powder, silane coupling agent, acetone and toluene are mixed
Uniformly, it is passed through N2, 92 DEG C of reaction 7h are warming up to, filters obtain filter cake material while hot, filter cake material is placed in ultrasound point in acetone
It dissipates, supersonic frequency 2000Hz, ultrasonic time 35min, with deionized water centrifuge washing 10 times, centrifugation rate 5000r/
Min, dry 15h under the conditions of temperature is 120 DEG C, it is cooling to obtain modified silicon carbide；
The silicone modified polyester resin is made by following steps: reaction is added in neopentyl glycol, organotin catalysts
Device is passed through nitrogen into reactor, is warming up to 140 DEG C, and organosilicon is added, and is warming up to 170 DEG C, and terephthalic acid (TPA) and organic is added
Tin catalyst, is warming up to 180 DEG C, keeps the temperature 0.5h, is continuously heating to 250 DEG C, is added triphenyl phosphite, vacuum reaction 30min,
185 DEG C are cooled to, cooling obtains silicone modified polyester resin, and silicone content is 2wt% in silicone modified polyester resin.
Embodiment 5
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: that 18 parts of nano silicon carbide calcium, organosilicon change by weight
Property 40 parts of polyester resin, modified 30 parts of silicon carbide, 5 parts of graphite, 3 parts of silane coupling agent, 3 parts of calcium carbonate, 3 parts of mica, aluminium powder 4
Part, quartzy 3 parts, 3 parts of ethylene glycol ether acetate, 5 parts of butyl acetate, 3 parts of isobutyl isobutyrate, propionic acid -3-
5 parts of ether ethyl ester；
The modified silicon carbide is made using following steps: by silicon carbide powder, silane coupling agent and acetone, control carbonization
The w/v g:ml of Si powder and acetone is 1:7, is passed through N2, 92 DEG C of reaction 7h are warming up to, filters obtain filter cake object while hot
Filter cake material is placed in progress repeated ultrasonic dispersion in acetone, supersonic frequency 2000Hz by material, and each ultrasonic time is 35min,
With deionized water centrifuge washing 8 times, centrifugation rate 5000r/min, dry 15h, cooling are obtained under the conditions of temperature is 120 DEG C
Modified silicon carbide；
The silicone modified polyester resin is made by following steps: reaction is added in neopentyl glycol, organotin catalysts
Device is passed through nitrogen into reactor, is warming up to 130 DEG C, and organosilicon is added, and is warming up to 160 DEG C, and terephthalic acid (TPA) and organic is added
Tin catalyst, is warming up to 170 DEG C, keeps the temperature 0.5h, is continuously heating to 250 DEG C, is added triphenyl phosphite, vacuum reaction 20min,
180 DEG C are cooled to, cooling obtains silicone modified polyester resin, and silicone content is 1wt% in silicone modified polyester resin.
Embodiment 6
A kind of wear-resisting anti-sticking soleplate including base material and is covered on the coat on base material surface, described
Base material is made using aluminum alloy materials, and the coat raw material includes: that 16 parts of nano silicon carbide calcium, organosilicon change by weight
Property 25 parts of polyester resin, modified 28 parts of silicon carbide, 4 parts of graphite, 4 parts of silane coupling agent, 3 parts of mica and 7 parts of aluminium powder, ethylene glycol ethyl ethers
2 parts of ether acetate, 3 parts of butyl acetate, 5 parts of isobutyl isobutyrate, 3 parts of propionic acid -3- ether ethyl ester, methyl isoamyl
4 parts of base ketone；
The modified silicon carbide is made using following steps: by silicon carbide powder, silane coupling agent and toluene, control carbonization
The w/v g:ml of Si powder and toluene is 1:7, is passed through N2, 92 DEG C of reaction 7h are warming up to, filters obtain filter cake object while hot
Filter cake material is placed in progress repeated ultrasonic dispersion in acetone, supersonic frequency 2000Hz by material, and each ultrasonic time is 35min,
With deionized water centrifuge washing 8 times, centrifugation rate 4500r/min, dry 15h, cooling are obtained under the conditions of temperature is 110 DEG C
Modified silicon carbide；
The silicone modified polyester resin is made by following steps: reaction is added in neopentyl glycol, organotin catalysts
Device is passed through nitrogen into reactor, is warming up to 150 DEG C, and organosilicon is added, and is warming up to 160 DEG C, and terephthalic acid (TPA) and organic is added
Tin catalyst, is warming up to 190 DEG C, keeps the temperature 0.5h, is continuously heating to 250 DEG C, is added triphenyl phosphite, vacuum reaction 40min,
190 DEG C are cooled to, cooling obtains silicone modified polyester resin, and silicone content is 3wt% in silicone modified polyester resin.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of wear-resisting anti-sticking soleplate, which is characterized in that including base material and be covered on the painting on base material surface
Coating, the base material are made using aluminum alloy materials, and the coat raw material includes: nanometer calcium carbonate 15- by weight
20 parts, it is 20-40 parts of silicone modified polyester resin, silicon carbide 20-30 parts modified, 1-5 parts of graphite, 3-6 parts of silane coupling agent, auxiliary
5-15 parts, 10-20 parts of solvent of material；
The modified silicon carbide is made using following steps: silicon carbide powder, dispersing agent and organic solvent being uniformly mixed, are passed through
Gas is protected, 85-95 DEG C of reaction is warming up to, filters obtain filter cake material while hot, filter cake material is placed in ultrasound point in sonification medium
It dissipates, centrifuge washing, it is dry, it is cooling to obtain modified silicon carbide；
Silicone modified polyester resin is made by following steps: reactor, Xiang Fanying is added in neopentyl glycol, organotin catalysts
It is passed through nitrogen in device, is warming up to 130~150 DEG C, organosilicon is added, is warming up to 160~180 DEG C, terephthalic acid (TPA) is added and has
Machine tin catalyst is warming up to 170~190 DEG C, and heat preservation is continuously heating to 250 DEG C, and triphenyl phosphite, vacuum reaction, drop is added
For temperature to 180~190 DEG C, cooling obtains silicone modified polyester resin；
Silicone content is 1-3wt% in silicone modified polyester resin.
2. wear-resisting anti-sticking soleplate according to claim 1, which is characterized in that solvent be ethylene glycol ether acetate,
One or both of butyl acetate, isobutyl isobutyrate, propionic acid -3- ether ethyl ester and methyl isoamyl ketone with
Upper mixture.
3. wear-resisting anti-sticking soleplate according to claim 1, which is characterized in that auxiliary material includes calcium carbonate, mica, aluminium
One or more mixtures of powder, quartz.
4. wear-resisting anti-sticking soleplate according to claim 3, which is characterized in that auxiliary material includes mica and aluminium powder.
5. wear-resisting anti-sticking soleplate according to claim 1, which is characterized in that in silicon carbide modifying process, carbonization
The w/v g:ml of Si powder and organic solvent is 1:7.
6. wear-resisting anti-sticking soleplate according to claim 5, which is characterized in that organic solvent is acetone and/or toluene.
7. wear-resisting anti-sticking soleplate according to claim 6, which is characterized in that organic solvent is toluene.
8. wear-resisting anti-sticking soleplate according to claim 1, which is characterized in that in silicon carbide modifying process, ultrasound
Medium is deionized water and/or acetone, supersonic frequency 1500-2000Hz, ultrasonic time 25-35min.
9. a kind of preparation method of wear-resisting anti-sticking soleplate according to claim 1-8, which is characterized in that packet
It includes following steps: base material being subjected to surface abatement processes, is dried to obtain substrate；By nanometer calcium carbonate, organic-silicon-modified poly-
After ester resin, modified silicon carbide, graphite, silane coupling agent, auxiliary material and solvent mixing mix, melting extrusion, smashing is coated
Material；Coating material is sprayed into substrate surface with electrostatic gun, solidification obtains wear-resisting anti-sticking flatiron under the conditions of 195-205 DEG C of temperature
Bottom plate.
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| CN105884997A (en) * | 2014-12-09 | 2016-08-24 | 任海涛 | Production technique of silicon carbide-polyurethane elastic composite material |
| CN105925176A (en) * | 2016-04-22 | 2016-09-07 | 宁波高新区夏远科技有限公司 | Nonstick pan coating layer, and production method and nonstick pan thereof |
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| EP0711863A1 (en) * | 1994-11-14 | 1996-05-15 | Koninklijke Philips Electronics N.V. | Iron having an anti-friction layer |
| CN1260013A (en) * | 1996-01-17 | 2000-07-12 | 穆里内克斯股份有限公司 | Soleplate for an iron |
| CN1205039A (en) * | 1996-09-24 | 1999-01-13 | 菲利浦电子有限公司 | Iron and soleplate for iron |
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Denomination of invention: A wear-resistant and anti stick iron bottom plate and its preparation method Effective date of registration: 20231211 Granted publication date: 20191025 Pledgee: Anhui Dingyuan Minfeng Rural Bank Co.,Ltd. Pledgor: ANHUI YUCAN NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2023980070550 |
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