CN106590579B - For high salinity reservoir displacement composition and preparation method thereof - Google Patents
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Abstract
The present invention relates to the displacement composition and preparation method thereof for high salinity reservoir, mainly solve the problems, such as that oil displacement efficiency under the conditions of high salinity containing surfactant is low in the prior art.The present invention is by using a kind of displacement composition for high salinity reservoir, it in parts by weight include following components: (1) the 1 portion of 3- as shown in formula (I) (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt, wherein M1And M2It is independently selected from as any one in alkali metal, alkaline-earth metal, R C4~C20Alkyl, x=1~20, y=1~10；(2) 0.002-300 parts of Polymer Used For Oil Displacements；(3) technical solution of 10-10000 parts of water, preferably solves the problems, such as this, can be used in the intensified oil reduction production in oil field.
Description
Technical field
The displacement composition and preparation method thereof that the present invention relates to a kind of for high salinity reservoir.
Background technique
By the exploitation of decades, many oil fields in China all enter high water cut stage, and yield is faced with decline, and development is strong
Changing oil recovery is the important channel for improving oil recovery.Tertiary oil recovery is to continue exploitation ground using means such as physics, chemistry and biologies
Under remaining petroleum, so as to improve the method for oil recovery factor.The research that application surface activating agent recovers the oil in oil exploitation rises
Start from earlier 1930s, be developed so far, be an important means for improving recovery ratio in oil field, theoretical and
There is very big progress in practice.Currently, having basically formed following several injection systems: active water drive, foam flooding, lower bound
Face tension system displacement of reservoir oil etc..After oil field enters high water-cut stage, remaining oil is with discontinuous oil film by trap in reservoir rocks
In hole, the main power of two acted on oil droplet is viscap, if selecting suitable surfactant body
System reduces the interfacial tension between grease, the interfacial tension between oil reservoirs grease is made to be down to lower or ultralow value from 20~30mN/m
(10-3~10-4MN/m), it just can be reduced oil droplet when keeping remaining oil mobile and deform brought resistance, to greatly improve displacement of reservoir oil effect
Rate.
Most still petroleum sulfonates of oil recovery surfactant application, the oil refining by-product such as heavy alkylbenzene sulfonate change
Property surfactant, the characteristics of this kind of surfactant is that materials are extensive, cheap, still, this kind of surfactant
A series of problems, such as there is performances to be not sufficiently stable, and the especially resistance to bivalent cation performance of salt tolerant is poor, is not applied for high mineralization
The oil field block of degree.The novel surfactant that multiple active function groups are introduced in the same molecule, is greatly improved surface
Activity, and synergistic effect may be generated, increase salt-resistance.Patent U.S.Pat.No.4436672A alkylol and shrink
Glycerine reaction obtains alkylol polyglycidyl ether, then carries out sulfonation, obtains a kind of anion-nonionic surfactant；Patent
U.S.Pat.No.4466891A provides a kind of alkyl phenol polyoxyethylene ether propane sulfonic acid salt；Patent
For U.S.Pat.No.2011015111A1 with alhpa olefin and 1, the reaction of the chloro- 2- propyl alcohol of 3- bis- generates the ether containing chloro base, then into
Row sulfonating reaction obtains a kind of novel anionic surfactant of sulfo group containing there are two.
Complex oil displacing technology is also a kind of method of important raising oil recovery, polymer, surfactant and alkali
The ASP Oil-Displacing Technology of formation has carried out some field tests at home and abroad, achieves good oil displacement efficiency.But it is existing
In some ternary composite oil-displacing systems, the alkali containing high concentration, such as sodium hydroxide, sodium carbonate, in use, to stratum
Huge injury is brought with oil well etc., leads to that the fouling of oil recovery well shaft is serious, Produced Liquid processing is difficult, and is used
Surfactant be not easy to be biodegradable, and also have certain harmfulness to human body, such as: 1991, Zhao Guoxi was " surface is living
Property agent physical chemistry " P495；1994, the content disclosed in Liu Cheng " surfactant is complete works of " P35.
Various drawbacks make the application of ASP Oil-Displacing Technology be very limited.In contrast, polymer and surface
The binary combination flooding formula that activating agent is formed, due to being not added with alkali, thus can be to avoid the above drawback.But it is added in no alkali
In the case where, the activity of conventional surfactant can be greatly reduced, and the requirement of the displacement of reservoir oil is not achieved.It is introduced in the same molecule more
The novel surfactant of a active function groups is greatly improved surface-active, and may generate synergistic effect, increases anti-
Salt.Patent U.S.Pat.No.4436672A is reacted to obtain alkylol polyglycidyl ether with glycidol with alkylol, then
Sulfonation is carried out, a kind of anion-nonionic surfactant is obtained；Patent U.S.Pat.No.2011015111A1 is with alhpa olefin and 1,3-
Two chloro- 2- propyl alcohol reactions generate the ether containing chloro base, then carry out sulfonating reaction, obtain a kind of novel sulfo group containing there are two
Anionic surfactant.Patent U.S.Pat.No.4466891A provides a kind of alkyl phenol polyoxyethylene ether propane sulfonic acid salt,
Water-soluble and salt-resistance increases.
But the oil displacement efficiency using the displacement composition of existing surfactant on high salinity stratum is to be improved.
Summary of the invention
The first technical problem to be solved by the present invention is that there are under the conditions of high salinity for displacement composition in the prior art
The low problem of oil displacement efficiency, provides a kind of new displacement composition for high salinity reservoir, and the composition has in high salinity
Under the conditions of the high feature of oil displacement efficiency.
The second technical problem to be solved by the present invention is to provide a kind of corresponding with one of solution technical problem be used for
The preparation method of the displacement composition of high salinity reservoir.
The third technical problem to be solved by the present invention is that displacement composition described in one of technical problem is former in oil field raising
Application in oil recovery.
One of to solve above-mentioned technical problem, The technical solution adopted by the invention is as follows: displacement composition, in parts by weight
Including following components:
(1) the 1 portion of 3- as shown in formula (I) (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt,
Wherein M1And M2It is independently selected from as any one in alkali metal, alkaline-earth metal, works as M1N when for alkali metal1It is 1, works as M1
N when for alkaline-earth metal1It is 0.5, works as M2N when for alkali metal2It is 1, works as M2N when for alkaline-earth metal2For 0.5, R C4~C20Hydrocarbon
Base, x=1~20, y=1~10；
(2) 0.002-300 parts of Polymer Used For Oil Displacements；
(3) 10-10000 parts of water.
In above-mentioned technical proposal, preferably x=2~8, y=2~8.
In above-mentioned technical proposal, the preferably described alkyl is C7~C10Alkyl.
In above-mentioned technical proposal, the Polymer Used For Oil Displacement can be the polymer of all kinds of displacement of reservoir oils commonly used in the art,
Those skilled in the art can carry out conventional selection according to the prior art, such as but not limit that preferably to be selected from acrylic acid acrylamide total
At least one of polymers, the polyacrylamide of hydrophobic modification, carboxymethyl cellulose, polyacrylamide, xanthan gum.
In above-mentioned technical proposal, the viscosity average molecular weigh of the preferably described polyacrylamide is 15,000,000-2,500 ten thousand.
In above-mentioned technical proposal, as the most preferred technical solution: the alkyl is C8~C9Alkyl, x=4~6, y
=2-3.
To solve above-mentioned technical problem two, The technical solution adopted by the invention is as follows: described in one of above-mentioned technical problem
The preparation method of displacement composition, comprising the following steps:
A) under basic catalyst effect, alkyl phenol and aequum reacting ethylene oxide obtain alkyl phenol polyethenoxy ether；
B) alkyl phenol polyethenoxy ether obtained by step a) is dissolved into C6~C8In aromatic hydrocarbons, be added alkali metal hydroxide or
At least one of alkaline earth metal hydroxide alkali alkalizes 0.5~3 hour at 30~60 DEG C, and the third sulphur of 3- chlorine-2-hydroxyl is added
The alkali metal salt of acid stirs lower reaction and obtains 3- (alkyl phenol polyethenoxy ether) -2- hydroxy-propanesulfonic acid salt；The alkyl phenol polyoxy
The molar ratio of vinethene and the alkali is preferably 1:(1~3)；The alkyl phenol polyethenoxy ether and 3- chlorine-2-hydroxyl propane sulfonic acid
The molar ratio of alkali metal salt is preferably 1:(1~4), reaction temperature is preferably 30~80 DEG C, and the reaction time is preferably 6~18 small
When；
C) by 3- (alkyl phenol polyethenoxy ether) -2- hydroxy-propanesulfonic acid salt obtained by step b), under basic catalyst effect,
The 3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) propane sulfonic acid salt is obtained with aequum reacting ethylene oxide；
D) by 3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) propane sulfonic acid salt obtained by step c), it is dissolved into C6~C8
In aromatic hydrocarbons, at least one of alkali metal hydroxide or alkaline earth metal hydroxide alkali is added, alkalizes 0.5 at 30~60 DEG C
~3 hours, chloroacetic alkali metal salt is added, stirs lower reaction and obtains 3- (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxy
Vinethene) propane sulfonic acid salt；Mole of 3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) the propane sulfonic acid salt and the alkali
Than being preferably 1:(1~3)；3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) the propane sulfonic acid salt and chloroacetic alkali
The molar ratio of metal salt is preferably 1:(1~4), reaction temperature is preferably 30~80 DEG C, and the reaction time is preferably 6~18 hours；
E) above-mentioned 3- (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt, the displacement of reservoir oil are polymerize
Object and water are mixed to get the displacement composition.
In above-mentioned technical proposal, step a) and/or the step c) basic catalyst are preferably sodium hydroxide or hydroxide
At least one of potassium.
In above-mentioned technical proposal, step a) and/or the step c) reaction temperature are preferably 85~160 DEG C, the reaction time
It is 1~10 hour；Step a) and/or the step c) pressure are preferably 0~0.40MPa (gauge pressure)；Reaction temperature is more preferably
120~140 DEG C, the reaction time is more preferably 6~8 hours.
It is the three of solution present invention problem, The technical solution adopted by the invention is as follows: one of above-mentioned technical problem institute
It states displacement composition and is improving the application in oil recovery factor.
In above-mentioned technical proposal, the specific method of the application can be to ask based on parts by weight including the technology of the present invention
1 part of 3- (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt and water 100 shown in one of topic formula (I)
~2000 parts of the displacement composition injects oil bearing bed.The water wherein used can be deionized water, river water, underground water,
Seawater, preferably total salinity range are 80000-300000mg/L, Ca2++Mg2+For the water of 1000-6000mg/L, for applying
The considerations of work convenience, saving water resource etc., more preferably oilfield injection water, such as Crude Oil used in the embodiment of the present invention
Water is injected in the Chengxi District Tian Pu.It can also include commonly used in the art add in displacement composition of the present invention to increase oil displacement efficiency
Add agent, such as small molecule alcohol, DMSO, diethanol amine, CTAC etc..
Key problem in technology of the invention is that surfactant uses novel anion-nonionic surfactant, containing more
A hydrophilic radical, wherein carboxymethyl is located at molecular chain-end, and propane sulfonic acid salt groups are located in polyoxyethylene and polyoxyethylene segment
Between, the hydrophily of surfactant can be controlled by the degree of polymerization of polyoxyethylene and polyoxyethylene segment.Simultaneously because multiple
The synergistic effect of group considerably increases the salt resistance of surfactant and the performance of anti-bivalent cation, in the prior art only with
The anion-nonionic surfactant that one ethylene oxide segment connects is compared, and the surfactant that the present invention uses can be used for Gao Kuang
The oil reservoir displacement of reservoir oil of change degree has very high theory significance, and is with a wide range of applications and practical significance.
Displacement composition of the present invention is in 85 DEG C of the Zhongyuan Oil Field Chengxi District Pu formation temperature, salinity 80000-300000mg/
L, Ca2+、Mg2+Concentration still can form 10 with the block dewatered oil under conditions of being 1000-6000mg/L-3The mN/m order of magnitude
Ultralow interfacial tension improve 10% or more recovery ratio, achieve preferable technical effect to drive crude oil.
Below by embodiment, the present invention is further elaborated.
Specific embodiment
[embodiment 1]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 1.5mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (3) ether.
B) nonylphenol polyoxyethylene ether (3) obtained by step a) is added to equipped with agitating device, condensation reflux unit and is divided
In the reactor of water installations, 250 milliliters of benzene and 40 grams of sodium hydroxides are added, alkalize 2 hours at 60 DEG C, 0.61mol 3- is added
Chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, hydrochloric acid that concentration is 6M is added dropwise by system
PH be transferred to 2, be extracted with ethyl acetate, oil solvent mutually is evaporated off after, neutralized with sodium hydroxide solution, then in volume ratio acetone:
Ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (3)) -2- hydroxy-propanesulfonic acid salt
(0.39mol)。
C) 3- (nonylphenol polyoxyethylene ether (3)) -2- hydroxy-propanesulfonic acid salt for synthesizing step b) is added to equipped with condensation
In the reactor of device, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, are heated in logical nitrogen
At 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is purged 4 times with nitrogen,
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 0.39mol ethylene oxide, control pressure≤0.40MPa is reacted；
After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (3)) -2- (polyoxy
Vinethene (1)) propane sulfonic acid salt (0.39mol).
D) 3- (nonylphenol polyoxyethylene ether (3)) -2- (polyoxyethylene ether (1)) propane sulfonic acid salt for synthesizing step c)
(0.39mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.78mol) alkalizes 2 hours at 60 DEG C, and 0.47mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (3)) -2- (carboxymethyl polyoxyethylene ether (1)) propane sulfonic acid salt (0.36mol).E) will
Water 500 is injected in above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the Chengxi District Pu
The transparent displacement composition that parts by weight are mixed to get is evaluated for interfacial tension and oil displacement experiment.Wherein all embodiments of the invention
1 is shown in Table with the composition of the Chengxi District Pu used in comparative example injection water.To be listed in table 2 convenient for the composition that compares displacement composition.
2. displacement composition performance evaluation
A) interfacial tension is evaluated
TX-500C rotating interfacial tensimeter, at 85 DEG C, revolving speed 4500 are produced using Texas ,Usa university
Under the conditions of rev/min, the interfacial tension measured between above-mentioned displacement composition and the dewatered oil of the Chengxi District Pu extraction be the results are shown in Table
3。
B) oil displacement experiment is evaluated
According to the composite oil-displacing system physical simulation flooding test in SY/T6424-2000 composite oil-displacing system performance test methods
Measure of merit, at 85 DEG C, length 30cm, diameter 2.5cm, permeability 1.5m2Rock core on to carry out imitation oil displacement experiment real
It tests.First water drive is carried out to aqueous 98%, after water drive, on metaideophone 0.3pv (rock pore volume) with the Chengxi District Pu injection water
Displacement composition is stated, then water drive to aqueous 98%, improving oil recovery factor the results are shown in Table 4.
[embodiment 2]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 0.5mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 130 grams of Nonyl pheno (1) ethers.
B) 0.5mol nonylphenol polyoxyethylene ether (1) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.6mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, the salt that concentration is 6M is added dropwise
The pH of system is transferred to 2 by acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in volume
Than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (1)) third sulphur of -2- hydroxyl
Hydrochlorate 0.38mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (1)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 1.5 grams of water are added, side leads to nitrogen
While being stirred to react 1 hour when being heated to 85 DEG C.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 1.52mol ethylene oxide, controls pressure≤0.40MPa by purging 4 times
Reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (1)) -2-
(polyoxyethylene ether (4)) propane sulfonic acid salt 0.37mol.
D) 3- (nonylphenol polyoxyethylene ether (1)) -2- (polyoxyethylene ether (4)) propane sulfonic acid salt for synthesizing step c)
(0.37mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.74mol) alkalizes 2 hours at 60 DEG C, and 0.45mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (1)) -2- (carboxymethyl polyoxyethylene ether (4)) propane sulfonic acid salt (0.35mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 3]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 1.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (2) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (2) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.59mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (2)) -2- hydroxyl third
Sulfonate 0.38mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (2)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 1.5 grams of water are added, side leads to nitrogen
While being stirred to react 1 hour when being heated to 85 DEG C.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 0.76mol ethylene oxide, controls pressure≤0.40MPa by purging 4 times
It is reacted；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether
(2)) -2- (polyoxyethylene ether (2)) propane sulfonic acid salt 0.36mol.
D) 3- (nonylphenol polyoxyethylene ether (2)) -2- (polyoxyethylene ether (2)) propane sulfonic acid salt for synthesizing step c)
(0.36mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.72mol) alkalizes 2 hours at 60 DEG C, and 0.42mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (2)) -2- (carboxymethyl polyoxyethylene ether (2)) propane sulfonic acid salt (0.33mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 4]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 2.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (4) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (4) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (4)) -2- hydroxyl third
Sulfonate 0.38mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (4)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, in logical nitrogen
When being heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is blown with nitrogen
Sweep 4 times, system reaction temperature be then adjusted to 150 DEG C and is slowly passed through 0.76mol ethylene oxide, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (4))-
2- (polyoxyethylene ether (2)) propane sulfonic acid salt 0.37mol.
D) 3- (nonylphenol polyoxyethylene ether (2)) -2- (polyoxyethylene ether (2)) propane sulfonic acid salt for synthesizing step c)
(0.36mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.72mol) alkalizes 2 hours at 60 DEG C, and 0.42mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (2)) -2- (carboxymethyl polyoxyethylene ether (2)) propane sulfonic acid salt (0.33mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 5]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 3.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (6) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (6) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 500 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (6)) -2- hydroxyl third
Sulfonate 0.39mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (6)) -2- hydroxy-propanesulfonic acid salt 0.39mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, in logical nitrogen
When being heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is blown with nitrogen
Sweep 4 times, system reaction temperature be then adjusted to 150 DEG C and is slowly passed through 1.18mol ethylene oxide, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (6))-
2- (polyoxyethylene ether (3)) propane sulfonic acid salt 0.38mol.
D) 3- (nonylphenol polyoxyethylene ether (6)) -2- (polyoxyethylene ether (3)) propane sulfonic acid salt for synthesizing step c)
(0.38mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.76mol) alkalizes 2 hours at 60 DEG C, and 0.44mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (6)) -2- (carboxymethyl polyoxyethylene ether (3)) propane sulfonic acid salt (0.35mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 6]
1. prepared by surfactant
The surfactant synthesized using embodiment 5, except that compound concentration.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 7]
1. prepared by surfactant
The surfactant synthesized using embodiment 5, except that compound concentration.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 8]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 4.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (8) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (8) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (8)) -2- hydroxyl third
Sulfonate 0.39mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (8)) -2- hydroxy-propanesulfonic acid salt 0.39mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 15 grams of water are added, side leads to nitrogen
While being stirred to react 1 hour when being heated to 85 DEG C.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 1.17mol ethylene oxide, controls pressure≤0.40MPa by purging 4 times
It is reacted；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether
(8)) -2- (polyoxyethylene ether (3)) propane sulfonic acid salt 0.38mol.
D) 3- (nonylphenol polyoxyethylene ether (8)) -2- (polyoxyethylene ether (3)) propane sulfonic acid salt for synthesizing step c)
(0.38mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.76mol) alkalizes 2 hours at 60 DEG C, and 0.44mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (8)) -2- (carboxymethyl polyoxyethylene ether (3)) propane sulfonic acid salt (0.35mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 9]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 2.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (4) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (4) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (4)) -2- hydroxyl third
Sulfonate 0.39mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (4)) -2- hydroxy-propanesulfonic acid salt 0.39mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, in logical nitrogen
When being heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is blown with nitrogen
Sweep 4 times, system reaction temperature be then adjusted to 150 DEG C and is slowly passed through 0.39mol ethylene oxide, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (4))-
2- (polyoxyethylene ether (1)) propane sulfonic acid salt 0.39mol.
D) 3- (nonylphenol polyoxyethylene ether (4)) -2- (polyoxyethylene ether (1)) propane sulfonic acid salt for synthesizing step c)
(0.39mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.78mol) alkalizes 2 hours at 60 DEG C, and 0.48mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (4)) -2- (carboxymethyl polyoxyethylene ether (1)) propane sulfonic acid salt (0.36mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 10]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 6.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.5mol Nonyl pheno (12) ether.
B) 0.5mol nonylphenol polyoxyethylene ether (12) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 400 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.6mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, the salt that concentration is 6M is added dropwise
The pH of system is transferred to 2 by acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in volume
Than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (12)) -2- hydroxyl third
Sulfonate 0.38mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (12)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, in logical nitrogen
When being heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is blown with nitrogen
It sweeps 4 times, system reaction temperature is then adjusted to 150 DEG C and is slowly passed through 3.8mol ethylene oxide, control pressure≤0.40MPa is carried out
Reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (12))-
2- (polyoxyethylene ether (10)) propane sulfonic acid salt 0.38mol.
D) 3- (nonylphenol polyoxyethylene ether (12)) -2- (polyoxyethylene ether (10)) propane sulfonic acid salt for synthesizing step c)
(0.38mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.76mol) alkalizes 2 hours at 60 DEG C, and 0.45mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (nonylphenol polyoxyethylene ether (12)) -2- (carboxymethyl polyoxyethylene ether (10)) propane sulfonic acid salt (0.35mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 11]
1. prepared by surfactant
A) 0.5mol octyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 1.5mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol octylphenol polyethylene ethylene oxide (3) ether.
B) 0.49mol octyl phenol polyoxyethylene ether (3) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 300 milliliters of benzene and 38 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (octyl phenol polyoxyethylene ether (3)) -2- hydroxyl third
Sulfonate 0.38mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (3)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 15 grams of water are added, side leads to nitrogen
While being stirred to react 1 hour when being heated to 85 DEG C.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 1.2mol ethylene oxide by purging 4 times, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (octyl phenol polyoxyethylene ether (3))-
2- (polyoxyethylene ether (3)) propane sulfonic acid salt 0.38mol.
D) 3- (octyl phenol polyoxyethylene ether (3)) -2- (polyoxyethylene ether (3)) propane sulfonic acid salt for synthesizing step c)
(0.38mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.76mol) alkalizes 2 hours at 60 DEG C, and 0.44mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (octyl phenol polyoxyethylene ether (3)) -2- (carboxymethyl polyoxyethylene ether (3)) propane sulfonic acid salt (0.34mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 12]
1. prepared by surfactant
A) to equipped with condensing unit, agitating device and gas distributor reactor in be added 0.5mol grams of octyl phenol and
1.5 grams of sodium hydroxides and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, 90
At a temperature of DEG C, dehydration 1 hour is vacuumized, then 4 times is purged with nitrogen with the air in removing system, system is then reacted into temperature
Degree is adjusted to 150 DEG C and is slowly passed through 4.2mol ethylene oxide, and control pressure≤0.40MPa carries out ethoxylation；Reaction terminates
Afterwards, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 0.5mol octylphenol polyethylene ethylene oxide (8) ether.
B) 0.5mol octyl phenol polyoxyethylene ether (8) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 250 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.6mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, the salt that concentration is 6M is added dropwise
The pH of system is transferred to 2 by acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in volume
Than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (octyl phenol polyoxyethylene ether (8)) third sulphur of -2- hydroxyl
Hydrochlorate 0.38mol.
C) step b) is synthesized into 3- (octyl phenol polyoxyethylene ether (8)) -2- hydroxy-propanesulfonic acid salt 0.38mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 15 grams of water are added, side leads to nitrogen
While being stirred to react 1 hour when being heated to 85 DEG C.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Then system reaction temperature is adjusted to 150 DEG C and is slowly passed through 2.0mol ethylene oxide by purging 4 times, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (octyl phenol polyoxyethylene ether (8))-
2- (polyoxyethylene ether (5)) propane sulfonic acid salt 0.38mol.
D) 3- (octyl phenol polyoxyethylene ether (8)) -2- (polyoxyethylene ether (5)) propane sulfonic acid salt for synthesizing step c)
(0.38mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.76mol) alkalizes 2 hours at 60 DEG C, and 0.45mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (octyl phenol polyoxyethylene ether (8)) -2- (carboxymethyl polyoxyethylene ether (5)) propane sulfonic acid salt (0.35mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 13]
1. prepared by surfactant
A) 0.5mol amylic phenol and 1 gram are added into the reactor equipped with condensing unit, agitating device and gas distributor
Sodium hydroxide and 10 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under, dehydration 1 hour is vacuumized, then 4 times is purged with nitrogen with the air in removing system, is then adjusted to system reaction temperature
150 DEG C are slowly passed through 2.6mol ethylene oxide, and control pressure≤0.40MPa carries out ethoxylation；After reaction, nitrogen is used
System is swept in air-blowing, is neutralized, dehydration after cooling, is obtained 0.5mol amyl phenol polyethenoxy (5) ether.
B) 0.5mol amyl phenol polyethenoxy (5) ether obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 500 milliliters of benzene solvents and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.6mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, excessive dilute hydrochloric acid is added dropwise
The pH of system is transferred to 2, is extracted with ethyl acetate, after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in volume ratio
Acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 0.36mol 3- (amyl phenol polyethenoxy (5) ether) -2- hydroxyl
Base propane sulfonic acid salt.
C) 3- (amyl phenol polyethenoxy (5) ether) -2- hydroxy-propanesulfonic acid salt 0.35mol for synthesizing step b), is added to
In reactor equipped with condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 15 grams of water are added, side leads to nitrogen
When gas side is heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Air-blowing sweeps 4 times, and system reaction temperature is then adjusted to 150 DEG C and is slowly passed through 0.72mol ethylene oxide, and control pressure≤
0.40MPa is reacted；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (amylic phenol polyoxy second
Alkene (5) ether) -2- (polyoxyethylene (2) ether) propane sulfonic acid salt 0.35mol.
D) 3- (amyl phenol polyethenoxy (5) ether) -2- (polyoxyethylene (2) ether) propane sulfonic acid salt for synthesizing step c)
(0.35mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.70mol) alkalizes 2 hours at 60 DEG C, and 0.40mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (amyl phenol polyethenoxy (5) ether) -2- (carboxymethyl polyoxyethylene (2) ether) propane sulfonic acid salt (0.31mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 14]
1. prepared by surfactant
A) to equipped with condensing unit, agitating device and gas distributor reactor in be added 0.5mol dodecylphenol and
1.5 grams of sodium hydroxides and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, 90
At a temperature of DEG C, dehydration 1 hour is vacuumized, then 4 times is purged with nitrogen with the air in removing system, system is then reacted into temperature
Degree is adjusted to 150 DEG C and is slowly passed through 1.1mol ethylene oxide, and control pressure≤0.40MPa carries out ethoxylation；Reaction terminates
Afterwards, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 0.5mol dodecyl phenol polyethenoxy (2) ether.
B) 0.5mol dodecyl phenol polyethenoxy (2) ether obtained by step a) is added to equipped with agitating device, is condensed back to
In the reactors for flowing device and division box, 400 milliliters of benzene solvents and 30 grams of sodium hydroxides are added, alkalize 2 hours at 60 DEG C,
0.6mol 3- chlorine-2-hydroxyl propanesulfonate is added, at reflux, reacts 8 hours.After reaction, it is 6M that concentration, which is added dropwise,
Hydrochloric acid the pH of system is transferred to 2, be extracted with ethyl acetate, oil solvent mutually is evaporated off after, neutralized with sodium hydroxide solution, then existed
Volume ratio acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (dodecyl phenol polyethenoxy (2) ether) -2-
Hydroxy-propanesulfonic acid salt 0.36mol.
C) step b) is synthesized into 3- (dodecyl phenol polyethenoxy (2) ether) -2- hydroxypropionate sodium 0.36mol, be added
Into the reactor equipped with condensing unit, agitating device and gas distributor, 1.5 grams of sodium hydroxides and 15 grams of water, Bian Tong is added
When nitrogen side is heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses
Nitrogen purges 4 times, and system reaction temperature is then adjusted to 150 DEG C and is slowly passed through 1.5mol ethylene oxide, and control pressure≤
0.40MPa is reacted；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtaining 3-, (dodecylphenol is poly-
Ethylene oxide (2) ether) -2- (polyoxyethylene (4) ether) sulfonate 0.36mol.
D) 3- (dodecyl phenol polyethenoxy (2) ether) -2- (polyoxyethylene (4) ether) sulfonate for synthesizing step c)
(0.36mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.72mol) alkalizes 2 hours at 60 DEG C, and 0.42mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (dodecyl phenol polyethenoxy (2) ether) -2- (carboxymethyl polyoxyethylene (4) ether) sulfonate (0.33mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Method of evaluating performance is the same as embodiment 1.To be listed in table 2 convenient for the composition that compares displacement composition, by evaluation result
It is listed in table 3 and table 4.
[embodiment 15]
1. prepared by surfactant
A) to equipped with condensing unit, agitating device and gas distributor reactor in be added 0.5mol cetyl phenol and
2 grams of sodium hydroxides and 20 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, at 90 DEG C
At a temperature of, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature with nitrogen
It is adjusted to 150 DEG C and is slowly passed through 2.5mol ethylene oxide, control pressure≤0.40MPa carries out ethoxylation；After reaction,
System is purged with nitrogen, is neutralized after cooling, dehydration, obtains 0.49mol cetyl phenol polyethenoxy (5) ether.
B) 0.49mol cetyl phenol polyethenoxy (5) ether obtained by step a) is added to equipped with agitating device, is condensed back to
In the reactors for flowing device and division box, 400 milliliters of benzene solvents and 26 grams of sodium hydroxides are added, alkalize 2 hours at 60 DEG C,
0.58mol 3- chlorine-2-hydroxyl propanesulfonate is added, at reflux, reacts 8 hours.After reaction, concentration is added dropwise is
The pH of system is transferred to 2 by the hydrochloric acid of 6M, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then
In volume ratio acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (cetyl phenol polyethenoxy (5) ether)-
2- hydroxy-propanesulfonic acid salt 0.36mol.
C) step b) is synthesized into 3- (cetyl phenol polyethenoxy (5) ether) -2- hydroxy-propanesulfonic acid salt 0.36mol, be added
Into the reactor equipped with condensing unit, agitating device and gas distributor, 1 gram of sodium hydroxide and 10 grams of water is added, side leads to nitrogen
When gas side is heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Air-blowing is swept 4 times, and system reaction temperature is then adjusted to 150 DEG C and is slowly passed through 1.8mol ethylene oxide, controls pressure≤0.40MPa
It is reacted；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (cetyl phenol polyethenoxy
(5) ether) -2- (polyoxyethylene (5) ether) propane sulfonic acid salt 0.35mol.
D) 3- (cetyl phenol polyethenoxy (5) ether) -2- (polyoxyethylene (5) ether) propane sulfonic acid salt for synthesizing step c)
(0.35mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, be added 200 milliliters of benzene and
Sodium hydroxide (0.70mol) alkalizes 2 hours at 60 DEG C, and 0.40mol sodium chloroacetate is added, and at reflux, reaction 5 is small
When, obtain 3- (cetyl phenol polyethenoxy (5) ether) -2- (carboxymethyl polyoxyethylene (5) ether) propane sulfonic acid salt (0.31mol).
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight, the west of a city Pu
Area's injection 500 parts by weight of water and the transparent displacement composition that is mixed to get of 1 parts by weight of diethanol amine, for interfacial tension evaluation and
Oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[embodiment 16]
1. prepared by surfactant
A) to equipped with condensing unit, agitating device and gas distributor reactor in be added 0.2mol eicosyl phenol and
2 grams of sodium hydroxides and 20 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, at 90 DEG C
At a temperature of, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature with nitrogen
It is adjusted to 150 DEG C and is slowly passed through 4.0 ethylene oxide, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.2mol eicosyl phenol polyethenoxy (20) ether.
B) 0.2mol eicosyl phenol polyethenoxy (20) ether obtained by step a) is added to equipped with agitating device, is condensed back to
In the reactors for flowing device and division box, 250 milliliters of benzene solvents and 16 grams of sodium hydroxides are added, alkalize 2 hours at 60 DEG C,
0.25mol 3- chlorine-2-hydroxyl propanesulfonate is added, at reflux, reacts 8 hours.After reaction, it is added dropwise excessive
The pH of system is transferred to 2 by dilute hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, is then existed
Volume ratio acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (eicosyl phenol polyethenoxy (20) ether)-
2- hydroxy-propanesulfonic acid salt 0.15mol.
C) step b) is synthesized into 3- (eicosyl phenol polyethenoxy (20) ether) -2- hydroxy-propanesulfonic acid salt 0.15mol, be added
Into the reactor equipped with condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, side leads to nitrogen
When gas side is heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, uses nitrogen
Air-blowing sweeps 4 times, and system reaction temperature is then adjusted to 150 DEG C and is slowly passed through 0.61 ethylene oxide, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (eicosyl phenol polyethenoxy
(20) ether) -2- (polyoxyethylene (4) ether) propane sulfonic acid salt 0.15mol.
D) 3- (eicosyl phenol polyethenoxy (20) ether) -2- (polyoxyethylene (4) ether) propane sulfonic acid for synthesizing step c)
Salt (0.15mol) is added in the reactor equipped with agitating device, condensation reflux unit and division box, and 200 milliliters of benzene are added
It with sodium hydroxide (0.30mol), alkalizes 2 hours at 60 DEG C, 0.20mol sodium chloroacetate is added, at reflux, reaction 5
Hour, obtain 3- (eicosyl phenol polyethenoxy (20) ether) -2- (carboxymethyl polyoxyethylene (4) ether) propane sulfonic acid salt
(0.33mol).E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the city Pu
The transparent displacement composition that the CTAC of West injection 1000 parts by weight of water and 1 parts by weight is mixed to get, is evaluated for interfacial tension
And oil displacement experiment.
2. displacement composition performance evaluation
Other than displacement composition composition is different, method of evaluating performance is the same as embodiment 1.To combine the displacement of reservoir oil convenient for comparing
The composition of object is listed in table 2, and evaluation result is listed in table 3 and table 4.
[comparative example 1]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 4.5mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa is carried out ethoxylation 4 hours；Reaction terminates
Afterwards, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 0.49mol Nonyl pheno (6) polyoxyethylene (3) ether.
B) 0.49mol Nonyl pheno (9) ether obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 500 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (Nonyl pheno (9) ether) -2- hydroxyl third
Sulfonate 0.38mol, structure are as follows:
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
A) interfacial tension is evaluated
TX-500C rotating interfacial tensimeter, at 85 DEG C, revolving speed 4500 are produced using Texas ,Usa university
Under the conditions of rev/min, the interfacial tension between above-mentioned displacement composition and the Chengxi District Pu injection water and the dewatered oil of extraction is measured
It the results are shown in Table 5.
B) oil displacement experiment is evaluated
According to the composite oil-displacing system physical simulation flooding test in SY/T6424-2000 composite oil-displacing system performance test methods
Measure of merit, at 85 DEG C, length 30cm, diameter 2.5cm, permeability 1.5m2Rock core on to carry out imitation oil displacement experiment real
It tests.First water drive is carried out to aqueous 98%, after water drive, on metaideophone 0.3pv (rock pore volume) with the Chengxi District Pu injection water
Displacement composition is stated, then water drive to aqueous 98%, improving oil recovery factor the results are shown in Table 5.
[comparative example 2]
1. prepared by surfactant
A) 0.5mol nonyl phenol and 1.5 is added into the reactor equipped with condensing unit, agitating device and gas distributor
Gram sodium hydroxide and 15 grams of water are stirred to react 1 hour when being heated to 85 DEG C in logical nitrogen.Vacuum system is opened, in 90 DEG C of temperature
Under degree, dehydration 1 hour is vacuumized, then purges 4 times with the air in removing system, then by system reaction temperature tune with nitrogen
It is slowly passed through 3.0mol ethylene oxide to 150 DEG C, control pressure≤0.40MPa carries out ethoxylation；After reaction, it uses
Nitrogen purges system, neutralizes, dehydration after cooling, obtains 0.49mol Nonyl pheno (6) ether.
B) 0.49mol nonylphenol polyoxyethylene ether (6) obtained by step a) is added to equipped with agitating device, is condensed back dress
It sets in the reactor with division box, 500 milliliters of benzene and 40 grams of sodium hydroxides is added, alkalize 2 hours at 60 DEG C, be added
0.58mol 3- chlorine-2-hydroxyl propanesulfonate reacts 8 hours at reflux.After reaction, it is 6M's that concentration, which is added dropwise,
The pH of system is transferred to 2 by hydrochloric acid, is extracted with ethyl acetate, and after mutually solvent is evaporated off in oil, is neutralized with sodium hydroxide solution, then in body
Product is than acetone: ethyl alcohol: water is that the in the mixed solvent of 2:1:1 is recrystallized to give 3- (nonylphenol polyoxyethylene ether (6)) -2- hydroxyl third
Sulfonate 0.39mol.
C) step b) is synthesized into 3- (nonylphenol polyoxyethylene ether (6)) -2- hydroxy-propanesulfonic acid salt 0.39mol, is added to dress
In the reactor for having condensing unit, agitating device and gas distributor, 2 grams of sodium hydroxides and 20 grams of water are added, in logical nitrogen
When being heated to 85 DEG C, it is stirred to react 1 hour.Vacuum system is opened, at a temperature of 90 DEG C, dehydration 1 hour is vacuumized, is blown with nitrogen
Sweep 4 times, system reaction temperature be then adjusted to 150 DEG C and is slowly passed through 1.18mol ethylene oxide, control pressure≤0.40MPa into
Row reaction；After reaction, system is purged with nitrogen, is neutralized after cooling, dehydration, obtains 3- (nonylphenol polyoxyethylene ether (6))-
2- (polyoxyethylene ether (3)) propane sulfonic acid salt 0.38mol, structure are as follows:
E) by above-mentioned 1 parts by weight of surfactant, polyacrylamide (viscosity average molecular weigh 25,000,000) 1 parts by weight and the west of a city Pu
The transparent displacement composition that area's injection 500 parts by weight of water are mixed to get, for interfacial tension evaluation and oil displacement experiment.
2. displacement composition performance evaluation
Evaluation method is with comparative example 1, for result is listed in table 5 convenient for comparing.
Water is injected in the 1 Zhongyuan Oil Field Chengxi District Pu of table
| Project | Na++K+ | Mg2+ | Ca2+ | Cl- | SO4 2- | HCO3 - | TDS |
| mg/L | 85066 | 367 | 3840 | 138006 | 1089 | 282 | 228650 |
2 embodiment 1-16 displacement composition of table composition
3 embodiment 1-16 displacement composition interfacial tension performance of table
| Embodiment | Interfacial tension (mN/m) |
| 1 | 0.0081 |
| 2 | 0.0103 |
| 3 | 0.0045 |
| 4 | 0.0036 |
| 5 | 0.0021 |
| 6 | 0.0004 |
| 7 | 0.0078 |
| 8 | 0.0035 |
| 9 | 0.0078 |
| 10 | 0.0085 |
| 11 | 0.0063 |
| 12 | 0.0052 |
| 13 | 0.0269 |
| 14 | 0.0103 |
| 15 | 0.0058 |
| 16 | 0.0079 |
4 embodiment 1-16 oil displacement experiment result of table
| Embodiment | Improve recovery ratio % |
| 1 | 8.9 |
| 2 | 8.5 |
| 3 | 10.2 |
| 4 | 12.4 |
| 5 | 12.6 |
| 6 | 14.8 |
| 7 | 6.8 |
| 8 | 10.5 |
| 9 | 8.9 |
| 10 | 6.7 |
| 11 | 8.5 |
| 12 | 8.8 |
| 13 | 6.3 |
| 14 | 6.3 |
| 15 | 7.9 |
| 16 | 7.5 |
5 comparative example 1-2 the performance test results of table
| Comparative example | Interfacial tension (mN/m) | Improve recovery ratio % |
| 1 | 0.087 | 6.7 |
| 2 | 0.059 | 6.5 |
Claims (9)
1. displacement composition includes following components in parts by weight:
(1) the 1 portion of 3- as shown in formula (I) (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt,
Wherein M1And M2It is independently selected from as any one in alkali metal, alkaline-earth metal, works as M1N when for alkali metal1It is 1, works as M1For alkali
N when earth metal1It is 0.5, works as M2N when for alkali metal2It is 1, works as M2N when for alkaline-earth metal2For 0.5, R C4~C20Alkyl, x=
1~20, y=1~10；
(2) 0.002-300 parts of Polymer Used For Oil Displacements；
(3) 100-2000 parts of water.
2. displacement composition according to claim 1, it is characterised in that x=2~8, y=2~8.
3. displacement composition according to claim 2, it is characterised in that the alkyl is C7~C10Alkyl.
4. displacement composition according to claim 1, it is characterised in that the Polymer Used For Oil Displacement is selected from propylene acid propylene
At least one of amide copolymer, the polyacrylamide of hydrophobic modification, carboxymethyl cellulose, polyacrylamide, xanthan gum.
5. displacement composition according to claim 4, it is characterised in that the viscosity average molecular weigh of the polyacrylamide is
15000000-2,500 ten thousand.
6. the preparation method of displacement composition described in claim 1, comprising the following steps:
A) under basic catalyst effect, alkyl phenol and aequum reacting ethylene oxide obtain alkyl phenol polyethenoxy ether；
B) alkyl phenol polyethenoxy ether obtained by step a) is dissolved into C6~C8In aromatic hydrocarbons, alkali metal hydroxide or alkaline earth is added
At least one of metal hydroxides alkali alkalizes 0.5~3 hour at 30~60 DEG C, and 3- chlorine-2-hydroxyl propane sulfonic acid is added
Alkali metal salt stirs lower reaction and obtains 3- (alkyl phenol polyethenoxy ether) -2- hydroxy-propanesulfonic acid salt；
C) by 3- (alkyl phenol polyethenoxy ether) -2- hydroxy-propanesulfonic acid salt obtained by step b), under basic catalyst effect, with institute
Requirement reacting ethylene oxide obtains the 3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) propane sulfonic acid salt；
D) by 3- (alkyl phenol polyethenoxy ether) -2- (polyoxyethylene ether) propane sulfonic acid salt obtained by step c), it is dissolved into C6~C8Aromatic hydrocarbons
In, at least one of alkali metal hydroxide or alkaline earth metal hydroxide alkali is added, the alkalization 0.5~3 at 30~60 DEG C
Hour, chloroacetic alkali metal salt is added, stirs lower reaction and obtains 3- (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxy second
Alkene ether) propane sulfonic acid salt；
E) by above-mentioned 3- (alkyl phenol polyethenoxy ether) -2- (carboxymethyl polyoxyethylene ether) propane sulfonic acid salt, Polymer Used For Oil Displacement and
Water is mixed to get the displacement composition.
7. the preparation method of displacement composition according to claim 6, it is characterized in that step a) and/or the step c) alkali
Property catalyst be at least one of sodium hydroxide or potassium hydroxide.
8. the preparation method of displacement composition according to claim 6, it is characterized in that step a) and/or step c) is described anti-
Answering temperature is 85~160 DEG C, and the reaction time is 1~10 hour.
9. any displacement composition of Claims 1 to 5 is improving the application in oil recovery factor.
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