CN106589646A - Novel polystyrene modified fluorescent material - Google Patents
Novel polystyrene modified fluorescent material Download PDFInfo
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- CN106589646A CN106589646A CN201611183993.6A CN201611183993A CN106589646A CN 106589646 A CN106589646 A CN 106589646A CN 201611183993 A CN201611183993 A CN 201611183993A CN 106589646 A CN106589646 A CN 106589646A
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- fluorescent material
- modified fluorescent
- polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a novel polystyrene modified fluorescent material and relates to the technical field of high polymer materials. The novel polystyrene modified fluorescent material is prepared from raw materials as follows: 120-140 parts of polystyrene, 13-19 parts of aluminum hydroxide, 7-14 parts of hexabromocyclododecane, 5-11 parts of phthalic acid diundecyl ester, 28-35 parts of epoxy oleic acid n-butyl ester, 23-29 parts of methyl acrylate, 12-17 parts of polyvinyl alcohol, 11-16 parts of polyvinyl acetate, 21-28 parts of glycerol trioleate, 3-7 parts of methyl palmitate, 15-20 parts of methyl triethoxysilane, 7-13 parts of diethyl n-butylmalonate, 25-32 parts of tributyl acetocitrate, 16-23 parts of nanometer magnesia, 32-39 parts of photo-induced energy-storage noctilucent powder, 7-16 parts of a plasticizer and 14-22 parts of a wear-resistant agent. The novel polystyrene modified fluorescent material has beneficial effects as follows: the polystyrene modified fluorescent material has the luminous function, and the location distinguishing degree in the dark place is increased.
Description
Technical field
The present invention relates to technical field of polymer materials, the especially a kind of ethylene modified fluorescent material of novel polyphenyl.
Background technology
Polystyrene (Polystyrene, abridge PS) was referred to by gathering that styrene monomer Jing free radical polymerizations synthesize
Compound, the product of traditional polystyrene has high transparency, and light transmittance can reach more than 90%, with electrical insulating property
The advantages of good, easy coloring of energy, good processing fluidity, good rigidity and resistance to chemical attack.But it is also fewer at present to be related to polyphenyl
Ethene has the data introduction in terms of fluorescence, which has limited polystyrene material application in this regard.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of ethylene modified fluorescent material of novel polyphenyl, gather this
Phenylethene modified fluorescent material has lighting function, improves location identification degree in the dark.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of ethylene modified fluorescent material of novel polyphenyl, constitutive material includes：Polystyrene 120-140 parts, aluminium hydroxide
13-19 parts, HBCD 7-14 parts, phthalic acid double 11 ester 5-11 parts, epoxyoleic acid butyl ester 28-35 part, propylene
Sour methyl esters 23-29 parts, polyvinyl alcohol 12-17 parts, polyvinyl acetate 11-16 parts, glycerol trioleate 21-28 parts, palmitic acid
Methyl esters 3-7 parts, MTES 15-20 parts, diethyl butylmalonate 7-13 parts, citroflex A-4
25-32 parts, excessively nano magnesia 16-23 parts, photo-induced energy storage luminescent powder 32-39 parts, plasticizer 7-16 parts, anti-wear agent 14-22 parts.
Further, a kind of described ethylene modified fluorescent material of novel polyphenyl, constitutive material includes：Polystyrene 130
Part, 15 parts of aluminium hydroxide, 11 parts of HBCD, phthalic acid double 8 parts of 11 ester, 32 parts of epoxyoleic acid butyl ester, propylene
28 parts of sour methyl esters, 15 parts of polyvinyl alcohol, 15 parts of polyvinyl acetate, 24 parts of glycerol trioleate, 5 parts of methyl hexadecanoate, methyl
18 parts of triethoxysilane, 11 parts of diethyl butylmalonate, excessively 28 parts of citroflex A-4, nano magnesia 19
Part, 35 parts of photo-induced energy storage luminescent powder, 11 parts of plasticizer, 19 parts of anti-wear agent.
Further, a kind of preparation method of the described ethylene modified fluorescent material of novel polyphenyl, comprises the following steps：
(1) by polystyrene, aluminium hydroxide, HBCD, double 11 esters of phthalic acid, epoxyoleic acid butyl ester,
Methyl acrylate, polyvinyl alcohol, polyvinyl acetate, glycerol trioleate, methyl hexadecanoate, MTES, just
Diethyl butylmalonate, citroflex A-4 and mistake nano magnesia are put in blender and are blended, the temperature of blending
Degree is 63-68 DEG C, and the blending time is 40-45min；
(2) step (1) material, photo-induced energy storage luminescent powder, plasticizer and anti-wear agent are together put in mixer, with
The speed of 88-95r/min, stirs 50-60min；
(3) the material double screw extruder in step (2) is extruded, pelletizing obtains pellet, as described novel polyphenyl
Ethylene modified fluorescent material.
Compared with prior art, the invention has the beneficial effects as follows：
The Polystyrene fluorescent material that the present invention makes can absorb luminous energy, store, and can stop
After light irradiation, then lentamente discharged in the way of fluorescence, the material can be applied and used under environment dimmed suddenly, be improved
The location recognition degree of the material product.
Specific embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
The preparation method of the ethylene modified fluorescent material of novel polyphenyl of the present invention, comprises the following steps：
(1) by polystyrene, aluminium hydroxide, HBCD, double 11 esters of phthalic acid, epoxyoleic acid butyl ester,
Methyl acrylate, polyvinyl alcohol, polyvinyl acetate, glycerol trioleate, methyl hexadecanoate, MTES, just
Diethyl butylmalonate, citroflex A-4 and mistake nano magnesia are put in blender and are blended, the temperature of blending
Degree is 65 DEG C, and the blending time is 43min；
(2) step (1) material, photo-induced energy storage luminescent powder, plasticizer and anti-wear agent are together put in mixer, with
The speed of 92r/min, stirs 55min；
(3) the material double screw extruder in step (2) is extruded, pelletizing obtains pellet, as described novel polyphenyl
Ethylene modified fluorescent material.
Embodiment 1
A kind of ethylene modified fluorescent material of novel polyphenyl, constitutive material includes：130 parts of polystyrene, 15 parts of aluminium hydroxide,
11 parts of HBCD, phthalic acid double 8 parts of 11 ester, 32 parts of epoxyoleic acid butyl ester, 28 parts of methyl acrylate, polyethylene
15 parts of alcohol, 15 parts of polyvinyl acetate, 24 parts of glycerol trioleate, 5 parts of methyl hexadecanoate, 18 parts of MTES,
11 parts of diethyl butylmalonate, excessively 28 parts of citroflex A-4,19 parts of nano magnesia, photo-induced energy storage luminescent powder
35 parts, 11 parts of plasticizer, 19 parts of anti-wear agent.
Embodiment 2
A kind of ethylene modified fluorescent material of novel polyphenyl, constitutive material includes：120 parts of polystyrene, 13 parts of aluminium hydroxide,
7 parts of HBCD, phthalic acid double 5 parts of 11 ester, 28 parts of epoxyoleic acid butyl ester, 23 parts of methyl acrylate, polyethylene
12 parts of alcohol, 11 parts of polyvinyl acetate, 21 parts of glycerol trioleate, 3 parts of methyl hexadecanoate, 15 parts of MTES,
7 parts of diethyl butylmalonate, excessively 25 parts of citroflex A-4,16 parts of nano magnesia, photo-induced energy storage luminescent powder
32 parts, 7 parts of plasticizer, 14 parts of anti-wear agent.
Embodiment 3
A kind of ethylene modified fluorescent material of novel polyphenyl, constitutive material includes：140 parts of polystyrene, 19 parts of aluminium hydroxide,
14 parts of HBCD, phthalic acid double 11 parts of 11 ester, 35 parts of epoxyoleic acid butyl ester, 29 parts of methyl acrylate, poly- second
17 parts of enol, 16 parts of polyvinyl acetate, 28 parts of glycerol trioleate, 7 parts of methyl hexadecanoate, MTES 20
Part, excessively 13 parts of diethyl butylmalonate, 32 parts of citroflex A-4,23 parts of nano magnesia, photo-induced energy storage night
39 parts of light powder, 16 parts of plasticizer, 22 parts of anti-wear agent.
With wattage be the incandescent lamp of 40W to embodiment 1, embodiment 2 and the sample irradiation 30min of embodiment 3, then by embodiment
1st, embodiment 2 and the sample of embodiment 3 are placed into dark place, and observable sends light, and three's average duration is 10.8h.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, the present invention is not limited to, although
The present invention is described in detail with reference to embodiment, for a person skilled in the art, it still can be to aforementioned
Technical scheme described in each embodiment is modified, or equivalent is carried out to which part technical characteristic, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in the protection of the present invention
Within the scope of.
Claims (3)
1. the ethylene modified fluorescent material of a kind of novel polyphenyl, it is characterised in that constitutive material includes：Polystyrene 120-140 parts,
Aluminium hydroxide 13-19 parts, HBCD 7-14 parts, phthalic acid double 11 ester 5-11 parts, epoxyoleic acid butyl esters 28-35
Part, methyl acrylate 23-29 parts, polyvinyl alcohol 12-17 parts, polyvinyl acetate 11-16 parts, glycerol trioleate 21-28 parts,
Methyl hexadecanoate 3-7 parts, MTES 15-20 parts, diethyl butylmalonate 7-13 parts, acetyl citrate
Tributyl 25-32 parts, excessively nano magnesia 16-23 parts, photo-induced energy storage luminescent powder 32-39 parts, plasticizer 7-16 parts, anti-wear agent
14-22 parts.
2. a kind of ethylene modified fluorescent material of novel polyphenyl according to claim 1, it is characterised in that constitutive material bag
Include：130 parts of polystyrene, 15 parts of aluminium hydroxide, 11 parts of HBCD, phthalic acid double 8 parts of 11 ester, epoxyoleic acids
32 parts of butyl ester, 28 parts of methyl acrylate, 15 parts of polyvinyl alcohol, 15 parts of polyvinyl acetate, 24 parts of glycerol trioleate, palmitic acid
5 parts of methyl esters, 18 parts of MTES, 11 parts of diethyl butylmalonate, 28 parts of citroflex A-4, mistake
19 parts of nano magnesia, 35 parts of photo-induced energy storage luminescent powder, 11 parts of plasticizer, 19 parts of anti-wear agent.
3. a kind of preparation method of the ethylene modified fluorescent material of novel polyphenyl according to claim 1 and 2, its feature exists
In comprising the following steps：
(1) by polystyrene, aluminium hydroxide, HBCD, phthalic acid double 11 esters, epoxyoleic acid butyl ester, propylene
Sour methyl esters, polyvinyl alcohol, polyvinyl acetate, glycerol trioleate, methyl hexadecanoate, MTES, normal-butyl
Diethyl malonate, citroflex A-4 and mistake nano magnesia are put in blender and are blended, and the temperature of blending is
63-68 DEG C, the blending time is 40-45min；
(2) step (1) material, photo-induced energy storage luminescent powder, plasticizer and anti-wear agent are together put in mixer, with 88-
The speed of 95r/min, stirs 50-60min；
(3) the material double screw extruder in step (2) is extruded, pelletizing obtains pellet, as described novel polyphenyl ethene
Modified fluorescent material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201611183993.6A CN106589646A (en) | 2016-12-20 | 2016-12-20 | Novel polystyrene modified fluorescent material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611183993.6A CN106589646A (en) | 2016-12-20 | 2016-12-20 | Novel polystyrene modified fluorescent material |
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| CN106589646A true CN106589646A (en) | 2017-04-26 |
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| CN201611183993.6A Pending CN106589646A (en) | 2016-12-20 | 2016-12-20 | Novel polystyrene modified fluorescent material |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070392A (en) * | 2007-06-18 | 2007-11-14 | 济南朗星科技有限公司 | Method for preparing luminous thermoplastic plastic parent particles |
| CN102443185A (en) * | 2011-08-09 | 2012-05-09 | 四川威尔达化工有限公司 | Organic fire-proof warm-keeping particles, and preparation process and application thereof |
| CN102898736A (en) * | 2012-11-05 | 2013-01-30 | 科创聚合物(苏州)有限公司 | Process for manufacturing noctilucent polystyrene transparent material |
| CN102952346A (en) * | 2011-08-23 | 2013-03-06 | 上海甲秀工业设计有限公司 | Rare-earth noctilucent plastic injection molded part and its making method |
| CN104004287A (en) * | 2014-06-12 | 2014-08-27 | 吴永刚 | Regenerated polystyrene flame-retardant toughening modification material and preparation method thereof |
| CN104356525A (en) * | 2014-10-27 | 2015-02-18 | 昆山古加拉高分子科技有限公司 | High-hardness plastic material |
-
2016
- 2016-12-20 CN CN201611183993.6A patent/CN106589646A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070392A (en) * | 2007-06-18 | 2007-11-14 | 济南朗星科技有限公司 | Method for preparing luminous thermoplastic plastic parent particles |
| CN102443185A (en) * | 2011-08-09 | 2012-05-09 | 四川威尔达化工有限公司 | Organic fire-proof warm-keeping particles, and preparation process and application thereof |
| CN102952346A (en) * | 2011-08-23 | 2013-03-06 | 上海甲秀工业设计有限公司 | Rare-earth noctilucent plastic injection molded part and its making method |
| CN102898736A (en) * | 2012-11-05 | 2013-01-30 | 科创聚合物(苏州)有限公司 | Process for manufacturing noctilucent polystyrene transparent material |
| CN104004287A (en) * | 2014-06-12 | 2014-08-27 | 吴永刚 | Regenerated polystyrene flame-retardant toughening modification material and preparation method thereof |
| CN104356525A (en) * | 2014-10-27 | 2015-02-18 | 昆山古加拉高分子科技有限公司 | High-hardness plastic material |
Non-Patent Citations (1)
| Title |
|---|
| 《聚氯乙烯加工手册》编写组: "《聚氯乙烯加工手册》", 28 February 1990, 中国轻工业出版社 * |
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