CN106589501A - Marine environment aviation tire tread rubber and preparation method thereof - Google Patents
Marine environment aviation tire tread rubber and preparation method thereof Download PDFInfo
- Publication number
- CN106589501A CN106589501A CN201611134304.2A CN201611134304A CN106589501A CN 106589501 A CN106589501 A CN 106589501A CN 201611134304 A CN201611134304 A CN 201611134304A CN 106589501 A CN106589501 A CN 106589501A
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- Prior art keywords
- parts
- agent
- marine environment
- tire tread
- carbon black
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses marine environment aviation tire tread rubber and a preparation method thereof. The marine environment aviation tire tread rubber is prepared from, by mass, 16-18 parts of smoke sheet rubber, 1-2 parts of a silane coupling agent, 6-10 parts of stearic acid, 1-3 parts of a heat stabilizer, 4-6 parts of zinc oxide, 11-13 parts of palm oil, 1-3 parts of an accelerant,40-60 parts of butadiene styrene rubber, 1-2 parts of a fracturing preventive, 6-10 parts of insoluble sulfur, 1-3 parts of an anti-ageing agent, 4-6 parts of carbon black, 6-8 parts of white carbon black and 1-3 parts of an anti-reversion agent. According to the tire tread rubber, the rubber material has the advantages of resisting ultraviolet rays, resisting ozone, resisting atmospheric ageing, resisting salt spray and resisting mold erosion, and the aviation tire has the good overall performance, and is particularly suitable for an appropriate marine environment.
Description
Technical field
The present invention relates to tire manufacturing art, in particular to a kind of marine environment aviation tire tread glue and its preparation
Method.
Background technology
When oceanic environment is used, the refraction, reflection due to seawater, tire is subject to ultraviolet irradiation to aircraft tyre
Especially strong, particularly summer, strong sunlight irradiation, metal deck temperature is higher, and it is big to add salt fog and air humidity on sea,
The easy mould growth of surface of tyre.The aircraft tyre for using in such an environment at present, to uvioresistant, high temperature resistant, wet-heat resisting, salt
The performance of mist and mould is all inadequate, needs to develop the higher aircraft tyre of performance to adapt to oceanic use environment.
The content of the invention
The invention provides a kind of marine environment aviation tire tread glue and preparation method thereof, the tire that inventive formulation is provided
Face glue, sizing material not only has the advantages that uvioresistant, ozone-resistant, anti-atmospheric aging and salt spray resistance, resistance to mould corrode, and has
There is the good combination property that aircraft tyre should have, the particularly suitable aircraft tyre used in marine environment is used.
For achieving the above object, the present invention provides following technical scheme：
A kind of marine environment aviation tire tread glue and preparation method thereof, is made up of following mass fraction formula components：Cigarette
Piece glue 16-18 parts, silane coupler 1-2 parts, stearic acid 6-10 parts, heat stabilizer 1-3 parts, zinc oxide 4-6 parts, palm oil 11-
13 parts, accelerator 1-3 parts, butadiene-styrene rubber 40-60 parts, cracking preventing agent 1-2 part, insoluble sulfur 6-10 parts, age resistor 1-3
Part, carbon black 4-6 parts, white carbon 6-8 parts, anti-recovery agent 1-3 parts.
Further：It is made up of following mass fraction formula components：16 parts of smoke sheet rubber, 1 part of silane coupler, 6 parts of stearic acid,
1 part of heat stabilizer, 4 parts of zinc oxide, 11 parts of palm oil, 1 part of accelerator, 40 parts of butadiene-styrene rubber, cracking 1 part of preventing agent, insoluble
6 parts of sulphur, 1 part of age resistor, 4 parts of carbon black, 6 parts of white carbon, 1 part of anti-recovery agent.
Further：It is made up of following mass fraction formula components：17 parts of smoke sheet rubber, 1.5 parts of silane coupler, stearic acid 8
Part, 2 parts of heat stabilizer, 5 parts of zinc oxide, 14 parts of palm oil, 2 parts of accelerator, 50 parts of butadiene-styrene rubber, cracking 1.5 parts of preventing agent, no
8 parts of dissolubility sulphur, 2 parts of age resistor, 5 parts of carbon black, 7 parts of white carbon, 2 parts of anti-recovery agent.
Further：It is made up of following mass fraction formula components：18 parts of smoke sheet rubber, 2 parts of silane coupler, stearic acid 10
Part, 3 parts of heat stabilizer, 6 parts of zinc oxide, 13 parts of palm oil, 3 parts of accelerator, 60 parts of butadiene-styrene rubber, cracking 2 parts of preventing agent, insoluble
10 parts of sulphur of property, 3 parts of age resistor, 6 parts of carbon black, 8 parts of white carbon, 3 parts of anti-recovery agent.
Further：Preparation method of the present invention has following steps：
Step one, butadiene-styrene rubber is added in banbury, banbury rotating speed 40-80 rev/min, pressurize 15-20MPa, 30-
60s rises floating weight, and now, each component macromolecular material has been in viscous state, then, input smoke sheet rubber, carbon black, palm oil, white
Carbon black, pressurize 15-18MPa, and floating weight is risen when temperature reaches 120-130 DEG C, and pressurize 15-18MPa, arranges to when 150-170 DEG C
Glue, obtains one section of elastomeric compound；
Step 2, in banbury add one section of elastomeric compound, banbury rotating speed 30-50 rev/min pressure the floating weight 30-40 seconds,
Floating weight, plus stearic acid, zinc oxide, insoluble sulfur are risen, pressurize 15-18MPa, 30-40s rises floating weight, pressurizes 135-155 DEG C
Dumping, obtains two-stage mixing glue；
Step 3, in banbury two-stage mixing glue is put into, add silane coupler, heat stabilizer, accelerator, cracking anti-
Only agent, age resistor, anti-recovery agent, 20-40 rev/min of rotating speed, pressurize 15-17MPa, and the 20-40 seconds rise floating weight, dumping, i.e.,
.
The invention has the beneficial effects as follows：
1st, the tread rubber that inventive formulation is provided, sizing material not only has uvioresistant, ozone-resistant, anti-atmospheric aging and resistance to
The advantage that salt fog, resistance to mould corrode；
2nd, the good combination property that the present invention should have with aircraft tyre, particularly suitable used in marine environment
Aircraft tyre is used.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of marine environment aviation tire tread glue is made up of following mass fraction formula components：Smoke sheet rubber 16-18 parts, silicon
Alkane coupling agent 1-2 parts, stearic acid 6-10 parts, heat stabilizer 1-3 parts, zinc oxide 4-6 parts, palm oil 11-13 parts, accelerator 1-3
It is part, butadiene-styrene rubber 40-60 parts, cracking preventing agent 1-2 part, insoluble sulfur 6-10 parts, age resistor 1-3 parts, carbon black 4-6 parts, white
Carbon black 6-8 parts, anti-recovery agent 1-3 parts.
Embodiment two：
A kind of marine environment aviation tire tread glue is made up of following mass fraction formula components：16 parts of smoke sheet rubber, silane
1 part of coupling agent, 6 parts of stearic acid, 1 part of heat stabilizer, 4 parts of zinc oxide, 11 parts of palm oil, 1 part of accelerator, 40 parts of butadiene-styrene rubber,
1 part of preventing agent of cracking, 6 parts of insoluble sulfur, 1 part of age resistor, 4 parts of carbon black, 6 parts of white carbon, 1 part of anti-recovery agent.
Embodiment three：
A kind of marine environment aviation tire tread glue is made up of following mass fraction formula components：17 parts of smoke sheet rubber, silane
1.5 parts of coupling agent, 8 parts of stearic acid, 2 parts of heat stabilizer, 5 parts of zinc oxide, 14 parts of palm oil, 2 parts of accelerator, butadiene-styrene rubber 50
Part, 1.5 parts of preventing agent of cracking, 8 parts of insoluble sulfur, 2 parts of age resistor, 5 parts of carbon black, 7 parts of white carbon, 2 parts of anti-recovery agent.
Example IV：
A kind of marine environment aviation tire tread glue is made up of following mass fraction formula components：18 parts of smoke sheet rubber, silane
2 parts of coupling agent, 10 parts of stearic acid, 3 parts of heat stabilizer, 6 parts of zinc oxide, 13 parts of palm oil, 3 parts of accelerator, 60 parts of butadiene-styrene rubber,
2 parts of preventing agent of cracking, 10 parts of insoluble sulfur, 3 parts of age resistor, 6 parts of carbon black, 8 parts of white carbon, 3 parts of anti-recovery agent.
Embodiment five：
A kind of preparation method preparation method of marine environment aviation tire tread glue comprises the steps：
Step one, butadiene-styrene rubber is added in banbury, banbury rotating speed 40-80 rev/min, pressurize 15-20MPa, 30-
60s rises floating weight, and now, each component macromolecular material has been in viscous state, then, input smoke sheet rubber, carbon black, palm oil, white
Carbon black, pressurize 15-18MPa, and floating weight is risen when temperature reaches 120-130 DEG C, and pressurize 15-18MPa, arranges to when 150-170 DEG C
Glue, obtains one section of elastomeric compound；
Step 2, in banbury add one section of elastomeric compound, banbury rotating speed 30-50 rev/min pressure the floating weight 30-40 seconds,
Floating weight, plus stearic acid, zinc oxide, insoluble sulfur are risen, pressurize 15-18MPa, 30-40s rises floating weight, pressurizes 135-155 DEG C
Dumping, obtains two-stage mixing glue；
Step 3, in banbury two-stage mixing glue is put into, add silane coupler, heat stabilizer, accelerator, cracking anti-
Only agent, age resistor, anti-recovery agent, 20-40 rev/min of rotating speed, pressurize 15-17MPa, and the 20-40 seconds rise floating weight, dumping, i.e.,
.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of marine environment aviation tire tread glue, it is characterised in that：It is made up of following mass fraction formula components：
Smoke sheet rubber 16-18 parts, silane coupler 1-2 parts, stearic acid 6-10 parts, heat stabilizer 1-3 parts, zinc oxide 4-6 parts, palm
Oily 11-13 parts, accelerator 1-3 parts, butadiene-styrene rubber 40-60 parts, cracking preventing agent 1-2 part, insoluble sulfur 6-10 parts, age resistor
1-3 parts, carbon black 4-6 parts, white carbon 6-8 parts, anti-recovery agent 1-3 parts.
2. a kind of marine environment aviation tire tread glue according to claim 1, it is characterised in that：By following mass fraction
Formula components are constituted：
16 parts of smoke sheet rubber, 1 part of silane coupler, 6 parts of stearic acid, 1 part of heat stabilizer, 4 parts of zinc oxide, 11 parts of palm oil, promotion
It is 1 part of agent, 40 parts of butadiene-styrene rubber, 1 part of preventing agent of cracking, 6 parts of insoluble sulfur, 1 part of age resistor, 4 parts of carbon black, 6 parts of white carbon, anti-
1 part of recovery agent.
3. a kind of marine environment aviation tire tread glue according to claim 1, it is characterised in that：By following mass fraction
Formula components are constituted：
17 parts of smoke sheet rubber, 1.5 parts of silane coupler, 8 parts of stearic acid, 2 parts of heat stabilizer, 5 parts of zinc oxide, 14 parts of palm oil, rush
Enter 2 parts of agent, 50 parts of butadiene-styrene rubber, 1.5 parts of preventing agent of cracking, 8 parts of insoluble sulfur, 2 parts of age resistor, 5 parts of carbon black, white carbon 7
Part, 2 parts of anti-recovery agent.
4. a kind of marine environment aviation tire tread glue according to claim 1, it is characterised in that：By following mass fraction
Formula components are constituted：
18 parts of smoke sheet rubber, 2 parts of silane coupler, 10 parts of stearic acid, 3 parts of heat stabilizer, 6 parts of zinc oxide, 13 parts of palm oil, promotion
3 parts of agent, 60 parts of butadiene-styrene rubber, cracking 2 parts of preventing agent, 10 parts of insoluble sulfur, 3 parts of age resistor, 6 parts of carbon black, 8 parts of white carbon,
3 parts of anti-recovery agent.
5. a kind of a kind of preparation method of marine environment aviation tire tread glue according to claim 1, it is characterised in that：
Comprise the steps：
Step one, butadiene-styrene rubber is added in banbury, banbury rotating speed 40-80 rev/min, pressurize 15-20MPa, 30-60s liters
Floating weight, now, each component macromolecular material be in viscous state, then, input smoke sheet rubber, carbon black, palm oil, white carbon,
Pressurization 15-18MPa, floating weight is risen when temperature reaches 120-130 DEG C, and pressurize 15-18MPa, to dumping when 150-170 DEG C, obtains
To one section of elastomeric compound；
Step 2, in banbury add one section of elastomeric compound, banbury rotating speed 30-50 rev/min pressure the floating weight 30-40 seconds, go up
Top bolt, plus stearic acid, zinc oxide, insoluble sulfur, pressurize 15-18MPa, and 30-40s rises floating weight, and pressurize 135-155 DEG C of row
Glue, obtains two-stage mixing glue；
Step 3, in banbury two-stage mixing glue is put into, add silane coupler, heat stabilizer, accelerator, cracking to prevent
Agent, age resistor, anti-recovery agent, 20-40 rev/min of rotating speed, pressurize 15-17MPa, and the 20-40 seconds rise floating weight, and dumping is obtained final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134304.2A CN106589501A (en) | 2016-12-10 | 2016-12-10 | Marine environment aviation tire tread rubber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134304.2A CN106589501A (en) | 2016-12-10 | 2016-12-10 | Marine environment aviation tire tread rubber and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589501A true CN106589501A (en) | 2017-04-26 |
Family
ID=58598893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611134304.2A Pending CN106589501A (en) | 2016-12-10 | 2016-12-10 | Marine environment aviation tire tread rubber and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106589501A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467748A (en) * | 2019-08-26 | 2019-11-19 | 青岛黑猫新材料研究院有限公司 | Complex carbon material and preparation method thereof, rubber composite material and tire |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200560A (en) * | 2007-11-01 | 2008-06-18 | 中橡集团曙光橡胶工业研究设计院 | Formula of aviation tire tread glue adaptive to ocean environment |
| CN101747537A (en) * | 2009-12-30 | 2010-06-23 | 中国化工橡胶桂林有限公司 | Trend rubber for helicopter tires |
| CN103865120A (en) * | 2014-04-01 | 2014-06-18 | 山东万鑫轮胎有限公司 | Tire tread compound material and preparation method thereof |
-
2016
- 2016-12-10 CN CN201611134304.2A patent/CN106589501A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200560A (en) * | 2007-11-01 | 2008-06-18 | 中橡集团曙光橡胶工业研究设计院 | Formula of aviation tire tread glue adaptive to ocean environment |
| CN101747537A (en) * | 2009-12-30 | 2010-06-23 | 中国化工橡胶桂林有限公司 | Trend rubber for helicopter tires |
| CN103865120A (en) * | 2014-04-01 | 2014-06-18 | 山东万鑫轮胎有限公司 | Tire tread compound material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467748A (en) * | 2019-08-26 | 2019-11-19 | 青岛黑猫新材料研究院有限公司 | Complex carbon material and preparation method thereof, rubber composite material and tire |
| CN110467748B (en) * | 2019-08-26 | 2021-03-02 | 青岛黑猫新材料研究院有限公司 | Composite carbon material, preparation method thereof, rubber composite material and tire |
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Application publication date: 20170426 |
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