CN106589483A - Rubber material with compression-resisting effect and preparation method thereof - Google Patents

Rubber material with compression-resisting effect and preparation method thereof Download PDF

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Publication number
CN106589483A
CN106589483A CN201611234360.3A CN201611234360A CN106589483A CN 106589483 A CN106589483 A CN 106589483A CN 201611234360 A CN201611234360 A CN 201611234360A CN 106589483 A CN106589483 A CN 106589483A
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China
Prior art keywords
parts
rubber material
compression
preparation
powder
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CN201611234360.3A
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Chinese (zh)
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不公告发明人
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Henan Eight Ling Electronic Technology Co Ltd
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Henan Eight Ling Electronic Technology Co Ltd
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Priority to CN201611234360.3A priority Critical patent/CN106589483A/en
Publication of CN106589483A publication Critical patent/CN106589483A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a rubber material with a compression-resisting effect. The rubber material with the compression-resisting effect comprises, by weight, 4-9 parts of artemisia apiacea, 8-13 parts of carbon black, 25-36 parts of natural rubber, 15-24 parts of fluororubber, 2-5 parts of quartz powder, 3-7 parts of zinc oxide crystal whiskers, 5-13 parts of resin, 0.5-4 parts of sodium stearate, 3-8 parts of land plaster, 2-6 parts of paraffin, 1-4 parts of fire retardants, 5-10 parts of modified kaolin, 4-12 parts of nano-silica and 3-11 parts of diamond micro-powder. The invention further discloses a preparation method for the rubber material. According to the rubber material with the compression-resisting effect and the preparation method thereof, raw materials are wide in source, the preparation technique is simple, and production cost is low; the rubber material with the compression-resisting effect and the preparation method thereof are suitable for large-scale industrial production, all components of the rubber material play a synergic effect, and compared with an existing material, the wear-resisting property, the aging-resisting property and the vibration-reducing property of the obtained rubber material are obviously improved; and market prospects are wide.

Description

A kind of elastomeric material with resistance to compression effect and preparation method thereof
Technical field
The present invention relates to a kind of elastomeric material, specifically a kind of elastomeric material with resistance to compression effect.
Background technology
As scientific and technological development and large-scale industrialization come into vogue, vibrations and noise have become the tight of every field Weight problem:Vibrations and noise can reduce the performance accuracy for producing, and affect the quality of product;Shorten the use longevity of high precision instrument Life so that high precision instrument cisco unity malfunction;To equipment and building composition early damage, reduce equipment and using for building is pacified Quan Xing;Vibrations and noise can also affect that people's is healthy.It has been industrial development to grasp shake control and noise control technology The key subjects for facing.It is to reduce the vibrations that fire eliminates vibroseis to eliminate vibrations and the most basic method of noise at present, Anti-vibration article is current most widely used method, and rubber damping product is favored by people because of cheap, extensive It is applied to the vibration isolation of the equipment such as various motor vehicles, aircraft, blower fan, water pump.But existing rubber damping product subtracts Shock stability does not reach people's production and the needs lived, and this just brings inconvenience for the use of people.
The content of the invention
It is an object of the invention to provide a kind of elastomeric material with resistance to compression effect, to solve to carry in above-mentioned background technology The problem for going out.
For achieving the above object, the present invention provides following technical scheme:
A kind of elastomeric material with resistance to compression effect, is made up of according to weight portion following raw material:Herba Artemisiae Annuae 4-9 parts, white carbon black 8- 13 parts, natural rubber 25-36 parts, fluorubber 15-24 parts, quartz powder 2-5 parts, ZnOw 3-7 parts, resin 5-13 parts, Sodium stearate 0.5-4 parts, Gypsum Fibrosum powder 3-8 parts, paraffin 2-6 parts, fire retardant 1-4 parts, modified kaolin 5-10 parts, nanometer titanium dioxide Silicon 4-12 parts and diadust 3-11 parts.
As further scheme of the invention:Modified kaolin is Kaolin 15-20 point under the ultrasound wave of 25-45KHz Clock, then by the product for obtaining be put in carbamide and under 60-120 degree Celsius react 20-40 minutes obtain.
As further scheme of the invention:Fire retardant adopts stibium oxide powder.
The preparation method of the elastomeric material with resistance to compression effect, comprises the following steps that:
Step one, smashs and adopts Herba Artemisiae Annuae to pieces centrifugal filtration, obtains Herba Artemisiae Annuae juice;
Step 2, white carbon black, quartz powder, diadust, sodium stearate and nano silicon are added in blender, Blender with the rotating speed stirring 30-50 minutes of 150-300rpm, obtains the first mixture under 35-48 degree Celsius;
Step 3, Herba Artemisiae Annuae juice, natural rubber, fluorubber and resin are put in banbury, then put into Zinc Oxide again Whisker, input ZnOw after 70-85 degree Celsius of banburying 10-15 minute, then add Gypsum Fibrosum powder, paraffin, fire retardant, Modified kaolin and the first mixture are in 115-125 degree Celsius of lower banburying;
Step 4, by the extrusion molding of banburying product and sulfuration, you can obtain finished product.
Compared with prior art, the invention has the beneficial effects as follows:The raw material sources of the present invention are extensive, preparation process is simple, Low production cost, it is adaptable to large-scale industrial production;Synergism is played between each component of the present invention, the rubber material for obtaining Material abrasion resistance properties, ageing-resistant performance and damping performance are significantly improved than current material, wide market.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of elastomeric material with resistance to compression effect, is made up of according to weight portion following raw material:4 parts of Herba Artemisiae Annuae, 8 parts of white carbon black, 25 parts of natural rubber, 15 parts of fluorubber, 2 parts of quartz powder, 3 parts of ZnOw, 5 parts of resin, 0.5 part of sodium stearate, Gypsum Fibrosum 3 parts of 3 parts of powder, 2 parts of paraffin, 1 part of fire retardant, 5 parts of modified kaolin, 4 parts of nano silicon and diadust.Modified kaolinite Soil is Kaolin 15 minutes under the ultrasound wave of 25KHz, then the product for obtaining is put in carbamide and anti-at 80 degrees celsius Answer 25 minutes and obtain.
The preparation method of the elastomeric material with resistance to compression effect, comprises the following steps that:
Step one, smashs and adopts Herba Artemisiae Annuae to pieces centrifugal filtration, obtains Herba Artemisiae Annuae juice;
Step 2, white carbon black, quartz powder, diadust, sodium stearate and nano silicon are added in blender, Blender is stirred 34 minutes with the rotating speed of 180rpm under 35 degrees Celsius, obtains the first mixture;
Step 3, Herba Artemisiae Annuae juice, natural rubber, fluorubber and resin are put in banbury, then put into Zinc Oxide again Whisker, in 75 degrees Celsius of banburyings 12 minutes after input ZnOw, then adds Gypsum Fibrosum powder, paraffin, fire retardant, modified height Ridge soil and the first mixture are in 115 degrees Celsius of lower banburyings;
Step 4, by the extrusion molding of banburying product and sulfuration, you can obtain finished product.
Embodiment 2
A kind of elastomeric material with resistance to compression effect, is made up of according to weight portion following raw material:6 parts of Herba Artemisiae Annuae, 10 parts of white carbon black, 29 parts of natural rubber, 21 parts of fluorubber, 3 parts of quartz powder, 5 parts of ZnOw, 8 parts of resin, 2 parts of sodium stearate, Gypsum Fibrosum powder 6 Part, 4 parts of paraffin, 2 parts of fire retardant, 7 parts of modified kaolin, 10 parts of nano silicon and 7 parts of diadust.Fire retardant is adopted Stibium oxide powder.
The preparation method of the elastomeric material with resistance to compression effect, comprises the following steps that:
Step one, smashs and adopts Herba Artemisiae Annuae to pieces centrifugal filtration, obtains Herba Artemisiae Annuae juice;
Step 2, white carbon black, quartz powder, diadust, sodium stearate and nano silicon are added in blender, Blender is stirred 37 minutes with the rotating speed of 240rpm under 42 degrees Celsius, obtains the first mixture;
Step 3, Herba Artemisiae Annuae juice, natural rubber, fluorubber and resin are put in banbury, then put into Zinc Oxide again Whisker, in 78 degrees Celsius of banburyings 12 minutes after input ZnOw, then adds Gypsum Fibrosum powder, paraffin, stibium oxide powder, changes Property Kaolin and the first mixture are in 119 degrees Celsius of lower banburyings;
Step 4, by the extrusion molding of banburying product and sulfuration, you can obtain finished product.
Embodiment 3
A kind of elastomeric material with resistance to compression effect, is made up of according to weight portion following raw material:9 parts of Herba Artemisiae Annuae, 12 parts of white carbon black, 34 parts of natural rubber, fluororubber 23 part, 5 parts of quartz powder, 7 parts of ZnOw, 13 parts of resin, 3.5 parts of sodium stearate, Gypsum Fibrosum 11 parts of 8 parts of powder, 6 parts of paraffin, 4 parts of fire retardant, 10 parts of modified kaolin, 12 parts of nano silicon and diadust.It is modified Kaolin is Kaolin 18 minutes under the ultrasound wave of 38Hz, then the product for obtaining is put in carbamide and at 108 degrees Celsius Lower reaction is obtained for 35 minutes.Fire retardant adopts stibium oxide powder.
The preparation method of the elastomeric material with resistance to compression effect, comprises the following steps that:
Step one, smashs and adopts Herba Artemisiae Annuae to pieces centrifugal filtration, obtains Herba Artemisiae Annuae juice;
Step 2, white carbon black, quartz powder, diadust, sodium stearate and nano silicon are added in blender, Blender is stirred 50 minutes with the rotating speed of 300rpm under 45 degrees Celsius, obtains the first mixture;
Step 3, Herba Artemisiae Annuae juice, natural rubber, fluorubber and resin are put in banbury, then put into Zinc Oxide again Whisker, in 82 degrees Celsius of banburyings 15 minutes after input ZnOw, then adds Gypsum Fibrosum powder, paraffin, stibium oxide powder, changes Property Kaolin and the first mixture are in 125 degrees Celsius of lower banburyings;
Step 4, by the extrusion molding of banburying product and sulfuration, you can obtain finished product.
Comparative example
Except Herba Artemisiae Annuae is not contained, remaining component of comparative example 1 and preparation method are same as Example 1.
The product of embodiment 1-3, the product of comparative example 1 and existing product are carried out into performance test, test result is shown in Table 1.
Table 1
Due to the damping performance of rubber it is relevant with the index of the hardness of elastomeric material, tensile strength and elongation at break, can To find out that the damping performance of embodiment 1-3 product is substantially better than the product and existing product of comparative example 1, the product of embodiment 1-3 In various performance changes under resistance to low temperature, low temperature and abrasion resistance properties also superior to comparative example 1 product and existing product, Ageing-resistant performance is good.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (4)

1. it is a kind of with resistance to compression effect elastomeric material, it is characterised in that be made up of according to weight portion following raw material:Herba Artemisiae Annuae 4-9 Part, white carbon black 8-13 parts, natural rubber 25-36 parts, fluorubber 15-24 parts, quartz powder 2-5 parts, ZnOw 3-7 parts, tree Fat 5-13 parts, sodium stearate 0.5-4 parts, Gypsum Fibrosum powder 3-8 parts, paraffin 2-6 parts, fire retardant 1-4 parts, modified kaolin 5-10 parts, Nano silicon 4-12 parts and diadust 3-11 parts.
2. it is according to claim 1 with resistance to compression effect elastomeric material, it is characterised in that the modified kaolin for height Ridge soil 15-20 minutes under the ultrasound wave of 25-45Hz, then the product for obtaining is put in carbamide and under 60-120 degree Celsius Reaction 20-40 minutes obtain.
3. the elastomeric material with resistance to compression effect according to claim 1 and 2, it is characterised in that the fire retardant is adopted Stibium oxide powder.
4. it is a kind of as described in claim 1-3 is arbitrary with resistance to compression effect elastomeric material preparation method, it is characterised in that Comprise the following steps that:
Step one, smashs and adopts Herba Artemisiae Annuae to pieces centrifugal filtration, obtains Herba Artemisiae Annuae juice;
Step 2, white carbon black, quartz powder, diadust, sodium stearate and nano silicon is added in blender, stirring Machine with the rotating speed stirring 30-50 minutes of 150-300rpm, obtains the first mixture under 35-48 degree Celsius;
Step 3, Herba Artemisiae Annuae juice, natural rubber, fluorubber and resin are put in banbury, then put into ZnOw again, 70-85 degree Celsius of banburying 10-15 minute after input ZnOw, Gypsum Fibrosum powder, paraffin, fire retardant, modified is then added Kaolin and the first mixture are in 115-125 degree Celsius of lower banburying;
Step 4, by the extrusion molding of banburying product and sulfuration, you can obtain finished product.
CN201611234360.3A 2016-12-28 2016-12-28 Rubber material with compression-resisting effect and preparation method thereof Pending CN106589483A (en)

Priority Applications (1)

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CN201611234360.3A CN106589483A (en) 2016-12-28 2016-12-28 Rubber material with compression-resisting effect and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611234360.3A CN106589483A (en) 2016-12-28 2016-12-28 Rubber material with compression-resisting effect and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915875A (en) * 2017-12-27 2018-04-17 安徽微威环保科技有限公司 A kind of environment-protective rubber material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915875A (en) * 2017-12-27 2018-04-17 安徽微威环保科技有限公司 A kind of environment-protective rubber material

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Application publication date: 20170426

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