CN106587742A - Method for improving interface adhesion between glass aggregate and asphalt by using nanometer iron oxide - Google Patents
Method for improving interface adhesion between glass aggregate and asphalt by using nanometer iron oxide Download PDFInfo
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- CN106587742A CN106587742A CN201611169490.3A CN201611169490A CN106587742A CN 106587742 A CN106587742 A CN 106587742A CN 201611169490 A CN201611169490 A CN 201611169490A CN 106587742 A CN106587742 A CN 106587742A
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- glass
- iron oxide
- nano
- colophonium
- materials
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1066—Oxides, Hydroxides
Abstract
The invention discloses a method for improving the interface adhesion between glass aggregate and asphalt by using nanometer iron oxide. The nanometer iron oxide is used to improve the interface adhesion between glass aggregate and asphalt in order to improve the glass aggregate utilization rate and realize good adhesion, good durability, small energy consumption and no pollution to environment. The method comprises the following steps: 1, cleaning and drying the glass aggregate for later use; 2, preparing a nanometer iron oxide solution, immersing the glass aggregate in step 1 in the nanometer iron oxide solution, and taking out and drying the glass aggregate after the surface of the glass aggregate is completed infiltrated with the nanometer iron oxide solution; and 3, immersing the glass aggregate obtained in step 2 in hot matrix asphalt to make the surface of the glass aggregate completely wrapped with the matrix asphalt.
Description
Technical field
The present invention relates to the preparation method of construction material, and in particular to it is a kind of using nano-sized iron oxide improve glass gather materials with
The method of interfacial adhesion power between Colophonium.
Background technology
Glass is at normal temperatures a kind of transparent solid, and in melting contiguous network structure, viscosity in cooling procedure are formed
Gradually increase and harden and non crystallized silicates nonmetallic materials.With the development of building industry and sending out for other industry
The various glass such as exhibition, building, door/window glass of automobile, glass container, electrical type glass and vial are wide in national economy in a large number
It is general to use so that scrap glass rolls up, ten thousand tons of the scrap glass about 450-750 in the annual city in ground, main source in China
In industry and life, the 3%-5% of domestic waste total amount is accounted for.600,000 tons annual of scrap glass of Taiwan, Hong Kong is annual
Nearly 120,000 tons of cullet are produced, nearly 90% is transported to stacking fills out buried regions and discard.On the one hand, as a kind of industrial waste and
House refuse, a large amount of scrap glasses are flooded with the soot in city, and directly landfill takes valuable soil to become " dodging color pollution ",
Increase environmental pressure.On the other hand, it is unprecedented in Chinese large-sized infrastructure scale, natural aggregate worsening shortages, therefore waste and old
The situation that glass discharge capacity increasingly increases again under, scrap glass recycling is carried out into secondary utilization, scrap glass is due to its thing
Physicochemical is stable in properties, as building material, but greatly destruction can be caused to environment using not good to it in reality.
And be combined using waste ceramic and glass be prepared into construction material be not only able to mitigate environment burden, while also turn waste into wealth,
Save natural resourcess.It is not only that a large amount of urban solid garbages that reduce have found an effective way, but also can be to development green
Environment-friendly type building plays important impetus, with very big environmental conservation meaning.But glass gathers materials because surface is compared
Smooth, relatively poor with the interfacial adhesion power between Colophonium compared with common gravel gathers materials, the technology for not reaching coarse aggregate will
Ask.And nanometer ferro oxide is basic matterial, the property that glass gathers materials will not be changed, and easily be attached on glass surface, be increased
The degree of roughness of large surface, the interfacial adhesion power gathered materials so as to reinforcing glass between Colophonium.
The content of the invention
In order to solve the problems of the prior art, the present invention proposes that one kind improves glass and gathers materials and drip using nano-sized iron oxide
The method of interfacial adhesion power between green grass or young crops, utilization rate of gathering materials glass is high, and adhesion, durability are good, little to energy resource consumption, to ring
Border is pollution-free.
In order to realize object above, the technical solution adopted in the present invention is：Comprise the following steps：
1) glass gathers materials standby after clean drying；
2) preparation of nano iron oxide solution, and by step 1) in glass gather materials and be immersed in nano oxidized ferrous solution, treat
Drying is taken out after the nano oxidized ferrous solution of glass surface of aggregate complete wetting；
3) by step 2) glass that obtains gather materials immersion heat matrix pitch in, make glass surface of aggregate wrap substrate completely
Colophonium.
The step 1) in the preparation gathered materials of glass comprise the following steps：
1.1) by glass immersion in hydrochloric acid solution, post-drying is then cleaned；
1.2) it is put into after is heated at a temperature of 130 DEG C～150 DEG C glass in pure water and rapidly cools down, produces glass surface
Random crack(ing)；
1.3) glass to there is crackle carries out being put in marshall compaction instrument after crushing and carries out hitting reality, hits after reality to glass dregs
Sieved, that is, obtain glass and gather materials.
The particle diameter that the glass gathers materials is 13.2～19mm.
The step 2) in nano oxidized ferrous solution adopt mass fraction for the nano oxidized ferrous solutions of the 50nm of 5-20%.
The nano oxidized ferrous solution preferred mass fraction is the 10% nano oxidized ferrous solutions of 50nm.
The step 2) in surface be impregnated with the glass of nano oxidized ferrous solution and gather materials and first dry in natural environment, then
Dry at a temperature of 100 DEG C～110 DEG C.
The step 3) in heat matrix pitch temperature be 130 DEG C～150 DEG C.
Compared with prior art, the present invention is added to the base of heat after glass surface of aggregate infiltrates nano oxidized ferrous solution
In matter Colophonium, nanometer ferro oxide is basic matterial, will not change the property that glass gathers materials, and is easily attached on glass surface, is increased
The degree of roughness of large surface, so as to reinforcing glass gathers materials the interfacial adhesion power between Colophonium, so as to solve glass gather materials by
It is smooth in surface, with the problem of the relatively poor technical requirements for not reaching coarse aggregate of interfacial adhesion power between Colophonium, so as to carry
High glass gathers materials utilization rate, and makes gather materials adhesion, durability between Colophonium of glass good using nano-sized iron oxide, to the energy
Little, environmentally safe is consumed, so that glass gathers materials is prepared into the burden that construction material is not only able to mitigation environment, while
Turn waste into wealth, save natural resourcess, be not only that a large amount of urban solid garbages that reduce have found an effective way, and to development
Environmental type building plays important impetus, with very high environmental conservation meaning.
Further, the principle expanded with heat and contract with cold using glass, glass is heated to insert cold water after uniform temperature rapidly cools down,
Glass is made because internal stress produces a large amount of random crack(ing)s, broken hitting after reality is then carried out and is sieved, convenient and simple can be made
Experimental glass gathers materials, be conveniently easy to get with material, technological process it is simple to operate, easily grasp, time-consuming, high working efficiency, while
The risk of splashing glass is evaded, work circumstances safe is high.
Further, adopt mass fraction for 10% 50nm nano-sized iron oxide solution soaking glass surface, through sticking
Property test experiments obtain, asphalt membrane small part is moved by water, in uneven thickness, peels off area percentage rate be less than 10%, stick
Property grade be 4 grades, asphalt stripping low degree, adhesion is good.
Specific embodiment
The present invention is further explained with reference to specific embodiment.
The present invention specifically includes following steps：
1) glass gathers materials standby after clean drying, and the preparation that glass gathers materials is comprised the following steps：
1.1) by glass immersion in hydrochloric acid solution, post-drying is then cleaned；
1.2) it is put into after is heated at a temperature of 130 DEG C～150 DEG C glass in pure water and rapidly cools down, produces glass surface
Random crack(ing)；
1.3) glass to there is crackle carries out being put in marshall compaction instrument after crushing and carries out hitting reality, hits after reality to glass dregs
Sieved, that is, obtain glass and gather materials, the particle diameter that glass gathers materials is 13.2～19mm；
2) preparation of nano iron oxide solution, and by step 1) in glass gather materials and be immersed in nano oxidized ferrous solution, receive
Rice iron oxide solution adopts mass fraction for the nano oxidized ferrous solutions of the 50nm of 5-20%, and preferred mass fraction is 10% 50nm
Nano oxidized ferrous solution, after the nano oxidized ferrous solution of glass surface of aggregate complete wetting, first dries, then in natural environment
Dry at a temperature of 100 DEG C～110 DEG C；
3) by step 2) glass that obtains gather materials 130 DEG C～150 DEG C heat of immersion matrix pitch in, make glass surface of aggregate
Matrix pitch is wrapped completely.
The preparation that glass gathers materials specifically includes following steps：
(1) scrap glass is immersed in into the hydrochloric acid solution 30min that mass fraction is 10%, then takes out glass and be put into clear water
In clean up, take out glass；
(2) scrap glass is placed in into 10min in 50 DEG C of ± 5 DEG C of baking ovens, glass is taken out after drying；
(3) scrap glass is placed in into 2h in 130 DEG C of -150 DEG C of baking ovens, takes out cullet, the scrap glass after heating is fast
Speed is put in cold water and rapidly cools down, and now glass surface stands 10min because of a large amount of random crack(ing)s of internal stress appearance；
(4) glass is taken out, with hammer glass is rapped, make glass breaking, because inside glass there are many crackles, hammer is gently
The splashing of glass fragment is had no when tapping glass, it is safe；
(5) glass after will be broken inserts marshall compaction instrument to carry out hitting after reality, is sieved with screening machine, obtains particle diameter
Glass for 13.2～19mm gathers materials.
The effect of the present invention is illustrated below by specific adhesion test experiments embodiment：
Embodiment one：
(1) by glass gather materials successively cross 13.2mm and 19mm sieves sieved, take 13.2～19mm of particle diameter shapes be close to
Cubical rule is gathered materials 5, uses pure water wash clean, is placed in the baking oven that temperature is 105 DEG C ± 5 DEG C and is dried, and is then placed on dry
It is standby in dry device；
(2) glass is gathered materials and is fastened at middle part with fine rule one by one, with the 50nm nano oxygens that pure water configuration quality fraction is 5%
Change ferrous solution, after stirring, glass is gathered materials and is lifted, in being completely immersed in solution, stand 5 minutes；
(3) after the completion of step (2), lift glass and gather materials, dry in natural environment 30 minutes, then be placed in 105 DEG C ± 5 DEG C
1 hour in baking oven, same sample arranges the glass aggregate particle of 5 parallel tests；
(4) with line lift the glass particle of heating one by one, immerse 45s in pre-warmed matrix pitch (130 DEG C -150 DEG C)
Afterwards, gently take out, make aggregate particle be entirely that asphalt membrane is wrapped, the glass aggregate particle for wrapping Colophonium is fastened with fine rule,
And hang on test stand, a scrap of paper is padded below, make unnecessary Colophonium pour off, and cool down 15 minutes at room temperature；
(5) after aggregate particle cooling, lifted with line one by one, soak the large beaker central authorities that people fills boil water, adjustment heating
Stove, makes the water in beaker keep slight boiling condition, but is not allow for the foam for boiling out；
(6) after digestion 3min, will gather materials and taken out from water, observe the peeling degree of asphalt membrane on mineral aggregate granule, evaluate it
Adhesion grade.
Test result indicate that：Asphalt membrane local is significantly moved by water, is remained substantially in surface of aggregate, peels off area
Percentage rate is less than 30%, so adhesion grade is 3 grades.
Embodiment two：
(1) glass 13.2mm, 19mm sieve that gathered materials is sieved, is taken the close cube of particle diameter 13.2～19mm shapes
Rule gather materials 5, use pure water wash clean, it is to dry in 105 DEG C ± 5 DEG C of baking oven to be placed in temperature, is then placed in exsiccator
It is standby；
(2) glass is gathered materials and is fastened at middle part with fine rule one by one, with the 50nm nanometers that pure water configuration quality fraction is 10%
Iron oxide solution, after stirring, glass is gathered materials and is lifted, and in being completely immersed in solution, stands 5 minutes；
(3) after the completion of step (2), lift glass and gather materials, dry in natural environment 30 minutes, then be placed in 105 DEG C ± 5 DEG C
1 hour in baking oven, same sample arranges the glass aggregate particle of 5 parallel tests；
(4) with line lift the glass particle of heating one by one, immerse 45s in pre-warmed matrix pitch (130 DEG C -150 DEG C)
Afterwards, gently take out, make aggregate particle be entirely that asphalt membrane is wrapped, the glass aggregate particle for wrapping Colophonium is fastened with fine rule,
And hang on test stand, a scrap of paper is padded below, make unnecessary Colophonium pour off, and cool down 15 minutes at room temperature；
(5) after aggregate particle cooling, lifted with line one by one, soak the large beaker central authorities that people fills boil water, adjustment heating
Stove, makes the water in beaker keep slight boiling condition, but is not allow for the foam for boiling out；
(6) after digestion 3min, will gather materials and taken out from water, observe the peeling degree of asphalt membrane on mineral aggregate granule, evaluate it
Adhesion grade.
Test result indicate that：Asphalt membrane small part is moved by water, in uneven thickness, and peels off area percentage rate is less than
10%, so adhesion grade is 4 grades.
Embodiment three：
(1) glass 13.2mm, 19mm sieve that gathered materials is sieved, is taken the close cube of particle diameter 13.2～19mm shapes
Rule gather materials 5, use pure water wash clean, it is to dry in 105 DEG C ± 5 DEG C of baking oven to be placed in temperature, is then placed in exsiccator
It is standby；
(2) glass is gathered materials and is fastened at middle part with fine rule one by one, with the 50nm nanometers that pure water configuration quality fraction is 15%
Iron oxide solution, after stirring, glass is gathered materials and is lifted, and in being completely immersed in solution, stands 5 minutes；
(3) after the completion of step (2), lift glass and gather materials, dry in natural environment 30 minutes, then be placed in 105 DEG C ± 5 DEG C
1 hour in baking oven, same sample arranges the glass aggregate particle of 5 parallel tests；
(4) with line lift the glass particle of heating one by one, immerse 45s in pre-warmed matrix pitch (130 DEG C -150 DEG C)
Afterwards, gently take out, make aggregate particle be entirely that asphalt membrane is wrapped, the glass aggregate particle for wrapping Colophonium is fastened with fine rule,
And hang on test stand, a scrap of paper is padded below, make unnecessary Colophonium pour off, and cool down 15 minutes at room temperature；
(5) after aggregate particle cooling, lifted with line one by one, soak the large beaker central authorities that people fills boil water, adjustment heating
Stove, makes the water in beaker keep slight boiling condition, but is not allow for the foam for boiling out；
(6) after digestion 3min, will gather materials and taken out from water, observe the peeling degree of asphalt membrane on mineral aggregate granule, evaluate it
Adhesion grade.
Test result indicate that：Asphalt membrane local is significantly moved by water, is remained substantially in surface of aggregate, peels off area
Percentage rate is less than 30%, so adhesion grade is 3 grades.
Example IV：
(1) glass 13.2mm, 19mm sieve that gathered materials is sieved, is taken the close cube of particle diameter 13.2～19mm shapes
Rule gather materials 5, use pure water wash clean, it is to dry in 105 DEG C ± 5 DEG C of baking oven to be placed in temperature, is then placed in exsiccator
It is standby；
(2) glass is gathered materials and is fastened at middle part with fine rule one by one, with the 50nm nanometers that pure water configuration quality fraction is 20%
Iron oxide solution, after stirring, glass is gathered materials and is lifted, and in being completely immersed in solution, stands 5 minutes；
(3) after the completion of step (2), lift glass and gather materials, dry in natural environment 30 minutes, then be placed in 105 DEG C ± 5 DEG C
1 hour in baking oven, same sample arranges 5 glass aggregate particles of parallel test；
(4) with line lift the glass particle of heating one by one, immerse 45s in pre-warmed matrix pitch (130 DEG C -150 DEG C)
Afterwards, gently take out, make aggregate particle be entirely that asphalt membrane is wrapped, the glass aggregate particle for wrapping Colophonium is fastened with fine rule,
And hang on test stand, a scrap of paper is padded below, make unnecessary Colophonium pour off, and cool down 15 minutes at room temperature；
(5) after aggregate particle cooling, lifted with line one by one, soak the large beaker central authorities that people fills boil water, adjustment heating
Stove, makes the water in beaker keep slight boiling condition, but is not allow for the foam for boiling out；
(6) after digestion 3min, will gather materials and taken out from water, observe the peeling degree of asphalt membrane on mineral aggregate granule, evaluate it
Adhesion grade.
Test result indicate that：Asphalt membrane major part is moved by water, is locally retained in surface of aggregate, peels off area percentage
Number is more than 30%, so adhesion grade is 2 grades.
Embodiment five：
(1) glass 13.2mm, 19mm sieve that gathered materials is sieved, is taken the close cube of particle diameter 13.2～19mm shapes
Rule gather materials 5, use pure water wash clean, it is to dry in 105 DEG C ± 5 DEG C of baking oven to be placed in temperature, is then placed in exsiccator
It is standby；
(2) glass is gathered materials and is fastened at middle part with fine rule one by one, with pure water as blank control group, after stirring, will
Glass gathers materials and lifts, and in being completely immersed in solution, stands 5 minutes；
(3) after the completion of step (2), lift glass and gather materials, dry in natural environment 30 minutes, then be placed in 105 DEG C ± 5 DEG C
1 hour in baking oven, same sample arranges 5 parallel test glass aggregate particles；
(4) with line lift the glass particle of heating one by one, immerse 45s in pre-warmed matrix pitch (130 DEG C -150 DEG C)
Afterwards, gently take out, make aggregate particle be entirely that asphalt membrane is wrapped, the glass aggregate particle for wrapping Colophonium is fastened with fine rule,
And hang on test stand, a scrap of paper is padded below, make unnecessary Colophonium pour off, and cool down 15 minutes at room temperature；
(5) after aggregate particle cooling, lifted with line one by one, soak the large beaker central authorities that people fills boil water, adjustment heating
Stove, makes the water in beaker keep slight boiling condition, but is not allow for the foam for boiling out；
(6) after digestion 3min, will gather materials and taken out from water, observe the peeling degree of asphalt membrane on mineral aggregate granule, evaluate it
Adhesion grade.
Test result indicate that：Asphalt membrane is entirely that water is moved, and gathers materials substantially exposed, on Colophonium is bubbled through the water column completely, institute
With adhesion grade as 1 grade.
To sum up embodiment, it could be assumed that：After glass surface of aggregate infiltrates nano oxidized ferrous solution, the base of heat is added to
In matter Colophonium, nanometer ferro oxide is basic matterial, will not change the property that glass gathers materials, and is easily attached on glass surface, is increased
The degree of roughness of large surface, so as to reinforcing glass gathers materials the interfacial adhesion power between Colophonium, so as to solve glass gather materials by
It is smooth in surface, with the problem of the relatively poor technical requirements for not reaching coarse aggregate of interfacial adhesion power between Colophonium, it is preferable that
Mass fraction is that the glass surface asphalt stripping degree of 10% 50nm nano-sized iron oxide solution soaking is minimum, and adhesion grade is most
Height, verifies the interfacial adhesion power that the nano oxidized ferrous solutions of 50nm can be gathered materials between Colophonium with reinforcing glass, its 50nm nano oxygen
It is 10% to change ferrous solution best in quality fraction.
Claims (7)
1. a kind of utilization nano-sized iron oxide improves glass and gathers materials the method for between Colophonium interfacial adhesion power, it is characterised in that bag
Include following steps：
1) glass gathers materials standby after clean drying；
2) preparation of nano iron oxide solution, and by step 1) in glass gather materials and be immersed in nano oxidized ferrous solution, treat glass
Drying is taken out after the nano oxidized ferrous solution of surface of aggregate complete wetting；
3) by step 2) glass that obtains gather materials immersion heat matrix pitch in, make glass surface of aggregate wrap substrate drip completely
It is blue or green.
2. a kind of utilization nano-sized iron oxide according to claim 1 improves glass and gathers materials the interfacial adhesion power between Colophonium
Method, it is characterised in that the step 1) in the preparation gathered materials of glass comprise the following steps：
1.1) by glass immersion in hydrochloric acid solution, post-drying is then cleaned；
1.2) it is put into after is heated at a temperature of 130 DEG C～150 DEG C glass in pure water and rapidly cools down, produces glass surface random
Then crackle；
1.3) glass to there is crackle carries out being put in marshall compaction instrument after crushing and carries out hitting reality, and hit after reality is carried out to glass dregs
Screening, that is, obtain glass and gather materials.
3. a kind of utilization nano-sized iron oxide according to claim 2 improves glass and gathers materials the interfacial adhesion power between Colophonium
Method, it is characterised in that the particle diameter that the glass gathers materials is 13.2～19mm.
4. a kind of utilization nano-sized iron oxide according to claim 1 improves glass and gathers materials the interfacial adhesion power between Colophonium
Method, it is characterised in that the step 2) in nano oxidized ferrous solution adopt mass fraction for the 50nm of 5-20% it is nano oxidized
Ferrous solution.
5. improve glass according to a kind of utilization nano-sized iron oxide described in claim 4 to gather materials the side of between Colophonium interfacial adhesion power
Method, it is characterised in that the nano oxidized ferrous solution preferred mass fraction is the 10% nano oxidized ferrous solutions of 50nm.
6. a kind of utilization nano-sized iron oxide according to claim 1 improves glass and gathers materials the interfacial adhesion power between Colophonium
Method, it is characterised in that the step 2) in surface be impregnated with the glass of nano oxidized ferrous solution and gather materials first in natural environment
Dry, then dry at a temperature of 100 DEG C～110 DEG C.
7. a kind of utilization nano-sized iron oxide according to claim 1 improves glass and gathers materials the interfacial adhesion power between Colophonium
Method, it is characterised in that the step 3) in heat matrix pitch temperature be 130 DEG C～150 DEG C.
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| CN201611169490.3A CN106587742B (en) | 2016-12-16 | 2016-12-16 | A method of improving glass using nano-sized iron oxide and gathers materials the interfacial adhesion power between pitch |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111097230A (en) * | 2019-12-31 | 2020-05-05 | 浙江金龙自控设备有限公司 | Modified glass filter material for oilfield sewage treatment and preparation method thereof |
| CN112390569A (en) * | 2020-11-04 | 2021-02-23 | 广东诚泰投资集团有限公司 | Anti-migration asphalt mixture |
| CN114349332A (en) * | 2022-01-06 | 2022-04-15 | 泰安市泉峰玻璃纤维有限公司 | Glass fiber forming processing technology |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU773004A1 (en) * | 1978-05-30 | 1980-10-23 | Научно-Исследовательский Институт Главмосстроя "Ниимосстрой" | Asphalt-concrete mix |
| JPH1053443A (en) * | 1996-08-07 | 1998-02-24 | Seishin Kogyo Kk | Glass aggregate and its production |
| CN1618886A (en) * | 2004-09-30 | 2005-05-25 | 邢台路桥建设总公司 | Method of raising stone material and asphalt adhesion |
| CN101560072A (en) * | 2009-06-02 | 2009-10-21 | 天津市市政工程研究院 | Treatment method for strengthening surface adhesiveness of granite or limestone aggregates |
| CN104513460A (en) * | 2015-01-26 | 2015-04-15 | 华南理工大学 | Interface modifier material of aggregate-bitumen and application of interface modifier material |
-
2016
- 2016-12-16 CN CN201611169490.3A patent/CN106587742B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU773004A1 (en) * | 1978-05-30 | 1980-10-23 | Научно-Исследовательский Институт Главмосстроя "Ниимосстрой" | Asphalt-concrete mix |
| JPH1053443A (en) * | 1996-08-07 | 1998-02-24 | Seishin Kogyo Kk | Glass aggregate and its production |
| CN1618886A (en) * | 2004-09-30 | 2005-05-25 | 邢台路桥建设总公司 | Method of raising stone material and asphalt adhesion |
| CN101560072A (en) * | 2009-06-02 | 2009-10-21 | 天津市市政工程研究院 | Treatment method for strengthening surface adhesiveness of granite or limestone aggregates |
| CN104513460A (en) * | 2015-01-26 | 2015-04-15 | 华南理工大学 | Interface modifier material of aggregate-bitumen and application of interface modifier material |
Non-Patent Citations (2)
| Title |
|---|
| 张国强等: "废弃玻璃在沥青混凝土中的应用研究现状及展望", 《平顶山工学院学报》 * |
| 陈风晨等: "废玻璃沥青混合料性能的试验研究", 《建筑材料学报》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111097230A (en) * | 2019-12-31 | 2020-05-05 | 浙江金龙自控设备有限公司 | Modified glass filter material for oilfield sewage treatment and preparation method thereof |
| CN112390569A (en) * | 2020-11-04 | 2021-02-23 | 广东诚泰投资集团有限公司 | Anti-migration asphalt mixture |
| CN112390569B (en) * | 2020-11-04 | 2022-06-21 | 广东诚泰投资集团有限公司 | Anti-migration asphalt mixture |
| CN114349332A (en) * | 2022-01-06 | 2022-04-15 | 泰安市泉峰玻璃纤维有限公司 | Glass fiber forming processing technology |
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| CN106587742B (en) | 2018-10-30 |
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