CN106587696B - A kind of building decoration engineering environment-friendly type composite blend and preparation method thereof - Google Patents

A kind of building decoration engineering environment-friendly type composite blend and preparation method thereof Download PDF

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Publication number
CN106587696B
CN106587696B CN201611187408.XA CN201611187408A CN106587696B CN 106587696 B CN106587696 B CN 106587696B CN 201611187408 A CN201611187408 A CN 201611187408A CN 106587696 B CN106587696 B CN 106587696B
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building decoration
friendly type
decoration engineering
environment
type composite
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CN201611187408.XA
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CN106587696A (en
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董美达
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Shenzhen Hongtao Group Co ltd
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SHENZHEN HONGTAO DECORATION CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to building decoration engineering technology fields, more particularly to a kind of building decoration engineering environment-friendly type composite blend and preparation method thereof, by the material composition of following weight percent: steel slag 20wt%-30wt%, hydrotalcite 1wt%-5wt%, bed of material stable material 0.05wt%-0.3wt%, magnesium fluosilicate 0.1wt%-0.2wt%, enhancing material 0.1wt%-1wt%, fiber 0.1wt%-0.5wt%, nano aluminium oxide 1wt%-5wt%, surplus are slag.Building decoration engineering of the present invention is good with environment-friendly type composite blend using effect, can improve concrete properties comprehensively, also helps iron and steel enterprise's Recycling Economy Construction, protects environment.

Description

A kind of building decoration engineering environment-friendly type composite blend and preparation method thereof
Technical field
The invention belongs to building decoration engineering technology fields, and in particular to a kind of building decoration engineering environment-friendly type is compound to mix Close material and preparation method thereof.
Technical background
The rapid development of China's steel and iron industry produces in production process while significantly improving people's living standard Raw a lot of steel slag and slag also brings very big puzzlement to people's lives, and 300,000,000 tons of China's slag year yield or more at present, steel 100,000,000 tons of slag or more, their stockpiling is not only occupied valuable soil, is polluted to ambient enviroment, while being also a kind of huge The wasting of resources.Contain in steel slag and slag largely with gelling mineral or glass state material as clinker constituent class, grinds There is preferable gelation activity under suitable condition after fining-off.It is all that industrial residue provides in cement-based material all the time The main object of source research on utilization.In recent years, the production scale of Chinese high performance mineral ground-slag and equipment have been in international Forefront, the production of slag powders become completely new green building material industry also independently of traditional cement industry.And steel slag due to It is difficult to grinding, the low reason of activity, utilization rate is very low, and a lot of steel slag is caused to accumulate, and pollutes environment, influences iron and steel enterprise's economy effect Benefit.As country increasingly payes attention to ecological protection and circular economy, to the processing of steel slag using extremely urgent, using steel slag and Slag synergistic effect, by the modification of additive, develops high value-added product, is a good approach.
Summary of the invention
The present invention is in view of the above-mentioned problems, provide a kind of using steel slag, slag as the building decoration engineering ring of main component Guarantor's type composite blend and preparation method thereof, the admixture industrial solid castoff utilization rate is high and hydration reaction activity is high, both Industrial solid castoff, which can be efficiently used, again can save the consumption of natural resources, environmentally protective.In order to achieve the above objectives, of the invention Using following technical scheme.
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent:
Steel slag: 20wt%-30wt%
Hydrotalcite: 1wt%-5wt%
Bed of material stable material: 0.05wt%-0.3wt%
Magnesium fluosilicate: 0.1wt%-0.2wt%
Enhancing material: 0.1wt%-1wt%
Fiber: 0.1wt%-0.5wt%
Nano aluminium oxide: 1wt%-5wt%
Slag: surplus
The bed of material stable material refers to one of calcium saccharate, polyacrylamide, polyvinyl alcohol and polyglycereol or one Kind or more.
Preferably, the bed of material stable material is made of polyvinyl alcohol and polyglycereol.
It is furthermore preferred that the polyglycereol is one or both of five polyglycereol and ten polyglycereol.
The enhancing material is one of sodium nitrate, iminodiacetic acid, aluminum sulfate or more.
Preferably, the enhancing material is iminodiacetic acid.
The fiber is one of coconut fibre, sisal fiber, ramee, basalt fibre or more.
Preferably, the fiber is made of coconut fibre and basalt fibre according to the weight ratio of 1-2:1.
Preferably, the fibre length is 1mm-3mm.
Building decoration engineering of the present invention is suitable for Vertical Mill production technology with environment-friendly type composite blend, comprising the following steps: 1) raw material is weighed by above-mentioned weight percent, grain diameter < 5mm is crushed to by crusher;2) raw material in step 1) is mixed Vertical mill grinding is sent into after even to specific surface area in 420m2/kg-450m2/ kg, both the building decoration engineering environment-friendly type is compound Admixture.
Building decoration engineering of the present invention is suitble to prepare using Vertical Mill technique grinding with environment-friendly type composite blend, material therein Layer stabilizer plays adhesive action in the environment of grinding disc of vertical mill superheated vapor, stablizes the bed of material, makes rolling more sufficiently for grinding roller, Raising rolls efficiency, with the reduction of temperature and subtracting for moisture of the good building decoration engineering environment-friendly type composite blend of grinding It is few, peptizaiton is gradually played, the mobility of building decoration engineering environment-friendly type composite blend is increased, is conducive to powder concentrator work Make, therefore improve the whole efficiency of vertical mill grinding building decoration engineering environment-friendly type composite blend, in building decoration engineering When being applied in concrete with environment-friendly type composite blend, the bed of material therein, which stablizes component, can increase the cohesiveness of concrete, Increase the ability of slurry cladding aggregate;Under Vertical Mill plus water soaking condition, magnesium fluosilicate has corruption to the vitreum in steel slag, slag Dissolution is lost, more defects can be formed on steel slag, slag particle surface, increase reactivity;Hydrotalcite is a kind of with just The metal oxide of charge, interlayer by the hydrogen bond of hydroxyl and electrostatic force association can with the trace metal ion in steel slag, such as Calcium, magnesium, iron etc. generate complex reaction, make steel slag surface active and form network chelation structure, it is anti-to significantly improve steel slag aquation Active is answered, in addition, hydrotalcite has certain alkalinity, to the building decoration engineering hydration reaction of environment-friendly type composite blend There is certain facilitation;The main hydration products calcium silicates of cementitious material is nano-scale in concrete, nano aluminium oxide It is added, on the one hand can play nucleus effect and be bonded more hydrated calcium silicates, on the one hand can fill small slit improves Behavior of Hardened Cement Paste Pore structure, improve the mechanical property and durability of concrete;Enhancing material can promote building decoration engineering environment-friendly type multiple The hydration reaction of admixture and cement is closed, early strength is improved.
Beneficial effects of the present invention:
(1) be conducive to iron and steel enterprise's Recycling Economy Construction.Helping iron and steel enterprise's building, " resource-product-waste-is again The reaction type cyclic process in production-goods source " can more effectively be utilized resource, protection environment, be consumed with the smallest resource and environment Cost obtains economic benefit and social benefit as big as possible, promotes iron and steel enterprise's solid waste comprehensive utilization of resources level and industry The competitiveness of chain extension product.
(2) using effect is good, can improve concrete properties comprehensively.
(3) effects of energy conservation and environmental protection is good, can reduce cement consumption, and then reduce because of manufacture of cement bring resource, the energy Consumption and pollutant discharge.
(4) significant economic benefit, iron and steel enterprise reduce waste residue land occupation expense, charges for disposing pollutants and become " useless " as " treasured " generation Income;Cement is substituted in commerical ready-mixed concrete uses reduced production cost.
Specific embodiment
Son illustrates the present invention with reference to embodiments.
Embodiment 1
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 20wt%, hydrotalcite 1wt%, bed of material stable material 0.05wt%, magnesium fluosilicate 0.1wt%, enhancing material 0.1wt%, fiber 0.1wt%, nano aluminium oxide 1wt%, surplus are slag.
The bed of material stable material refers to calcium saccharate.
The enhancing material refers to sodium nitrate.
The fiber is coconut fibre.
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 420m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Embodiment 2
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 30wt%, hydrotalcite 5wt%, bed of material stable material 0.3wt%, magnesium fluosilicate 0.2wt%, enhancing material 1wt%, fiber 0.5wt%, nano aluminium oxide 5wt%, surplus are slag.
The bed of material stable material is pressed the weight of 1:1:1:1 by calcium saccharate, polyacrylamide, polyvinyl alcohol and ten polyglycereol Amount is than composition.
The enhancing material in sodium nitrate, iminodiacetic acid and aluminum sulfate by the weight ratio of 2:1:2 by being formed.
The fiber is made of sisal fiber, ramee, basalt fibre by the weight ratio of 1:1:3.
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 430m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Embodiment 3
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 24wt%, hydrotalcite 3wt%, bed of material stable material 0.2wt%, magnesium fluosilicate 0.12wt%, enhancing material 0.6wt%, fiber 0.4wt%, nano aluminium oxide 2wt%, surplus are slag.
The bed of material stable material is made of polyvinyl alcohol and five polyglycereol according to the weight ratio of 1:1.
The enhancing material is iminodiacetic acid.
The fiber is made of coconut fibre and basalt fibre according to the weight ratio of 2:1, and the fibre length is 1mm- 3mm。
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 450m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Production of the present embodiment building decoration engineering with environment-friendly type composite blend on 2650 type Vertical Mill grinding machine of certain factory MLK Amount is 44t/h.
Embodiment 4
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 28wt%, hydrotalcite 3wt%, bed of material stable material 0.2wt%, magnesium fluosilicate 0.15wt%, enhancing material 0.4wt%, fiber 0.3wt%, nano aluminium oxide 3wt%, surplus are slag.
The bed of material stable material in five polyglycereol and ten polyglycereol by the weight ratio of 1:1 by being formed.
The enhancing material is aluminum sulfate.
The fiber is made of coconut fibre and basalt fibre according to the weight ratio of 1:1, and the fibre length is 1mm- 3mm。
Embodiment 5
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 21wt%, hydrotalcite 2wt%, bed of material stable material 0.1wt%, magnesium fluosilicate 0.12wt%, enhancing material 0.7wt%, fiber 0.2wt%, nano aluminium oxide 3wt%, surplus are slag.
Embodiment 6
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 27wt%, hydrotalcite 5wt%, polyacrylamide 0.05wt%, polyvinyl alcohol 0.05wt%, ten polyglycereol 0.1wt%, fluosilicic acid Magnesium 0.1wt%, iminodiacetic acid 0.2wt%, aluminum sulfate 0.6wt%, sisal fiber 0.1wt%, ramee 0.1wt%, Basalt fibre 0.2wt%, nano aluminium oxide 3wt%, surplus are slag.
Comparative example 1
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 24wt%, hydrotalcite 3wt%, bed of material stable material 0.2wt%, enhancing material 0.6wt%, fiber 0.4wt%, nano aluminium oxide 2wt%, surplus are slag.
The bed of material stable material is made of polyvinyl alcohol and five polyglycereol according to the weight ratio of 1:1.
The enhancing material is iminodiacetic acid.
The fiber is made of coconut fibre and basalt fibre according to the weight ratio of 2:1, and the fibre length is 1mm- 3mm。
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 450m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Comparative example 2
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 24wt%, hydrotalcite 3wt%, magnesium fluosilicate 0.12wt%, enhancing material 0.6wt%, fiber 0.4wt%, nano aluminium oxide 2wt%, surplus are slag.
The enhancing material is iminodiacetic acid.
The fiber is made of coconut fibre and basalt fibre according to the weight ratio of 2:1, and the fibre length is 1mm- 3mm。
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 450m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Production of the present embodiment building decoration engineering with environment-friendly type composite blend on 2650 type Vertical Mill grinding machine of certain factory MLK Amount is 36t/h.
Comparative example 3
A kind of building decoration engineering environment-friendly type composite blend, by the material composition of following weight percent: steel slag 24wt%, hydrotalcite 3wt%, bed of material stable material 0.2wt%, magnesium fluosilicate 0.12wt%, enhancing material 0.6wt%, nanometer Aluminium oxide 2wt%, surplus are slag.
The bed of material stable material is made of polyvinyl alcohol and five polyglycereol according to the weight ratio of 1:1.
The enhancing material is iminodiacetic acid.
Preparation method: weighing raw material by above-mentioned weight percent, is crushed to grain diameter < 5mm by crusher;It will be former Material is sent into vertical mill grinding to specific surface area in 450m after mixing2/ kg, both building decoration engineering environment-friendly type complex mixture Material.
Performance test
The building decoration engineering that embodiment 1-6 and comparative example 1-2 are obtained uses GB/ with environment-friendly type composite blend T18046-2008, according to cement 360kg, building decoration engineering environment-friendly type composite blend in every cube of concrete The match ratio progress testing concrete performance of 100kg, sand 740kg, stone 1050kg, water 175kg, polycarboxylate water-reducer 4.6kg.Knot Fruit see the table below 1.
1 the performance test results of table

Claims (7)

1. a kind of building decoration engineering environment-friendly type composite blend, which is characterized in that by the substance group of following weight percent At: steel slag 20wt%-30wt%, hydrotalcite 1wt%-5wt%, bed of material stable material 0.05wt%-0.3wt%, magnesium fluosilicate 0.1wt%-0.2wt%, enhancing material 0.1wt%-1wt%, fiber 0.1wt%-0.5wt%, nano aluminium oxide 1wt%- 5wt%, surplus are slag;The bed of material stable material refers in calcium saccharate, polyacrylamide, polyvinyl alcohol and polyglycereol It is one or more kinds of;The fiber is one of coconut fibre, sisal fiber, ramee, basalt fibre or more.
2. building decoration engineering according to claim 1 environment-friendly type composite blend, which is characterized in that the bed of material is steady Earnest matter is made of polyvinyl alcohol and polyglycereol.
3. building decoration engineering according to claim 2 environment-friendly type composite blend, which is characterized in that the polyglycereol For one or both of five polyglycereol and ten polyglycereol.
4. building decoration engineering according to claim 1 environment-friendly type composite blend, which is characterized in that the enhancing Substance is one of sodium nitrate, iminodiacetic acid, aluminum sulfate or more.
5. building decoration engineering according to claim 4 environment-friendly type composite blend, which is characterized in that the reinforcer Matter is iminodiacetic acid.
6. building decoration engineering according to claim 1 environment-friendly type composite blend, which is characterized in that the fiber by Coconut fibre and basalt fibre are formed according to the weight ratio of 1-2:1.
7. the preparation method of any building decoration engineering environment-friendly type composite blend described in -6 according to claim 1, special Sign is, comprising the following steps:
1) raw material is weighed by above-mentioned weight percent, grain diameter < 5mm is crushed to by crusher;
2) vertical mill grinding is sent into after mixing the raw material in step 1) to specific surface area in 420m2/kg-450m2/ kg had both been obtained described Concrete building decoration engineering environment-friendly type composite blend.
CN201611187408.XA 2016-12-20 2016-12-20 A kind of building decoration engineering environment-friendly type composite blend and preparation method thereof Expired - Fee Related CN106587696B (en)

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CN107226660A (en) * 2017-08-02 2017-10-03 合肥仙之峰农业科技有限公司 A kind of toughening type light cellular partition board and preparation method thereof
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CN1280110A (en) * 2000-07-11 2001-01-17 北京中土奥特赛特科技发展有限公司 Porcelain slag firming agent and its use
CN1207235C (en) * 2002-10-14 2005-06-22 上海市建筑科学研究院 Admixture specially for high-performance marine concrete
CN101851080B (en) * 2010-03-19 2013-08-28 华东交通大学 Acid rain corrosion resisting concrete additive and preparation method thereof
CN104891842A (en) * 2015-05-20 2015-09-09 上海市建筑科学研究院 S115-grade steel and mineral powder composite admixture and preparation method thereof

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