CN106587610A - Glass used for anti-fogging optical lens - Google Patents

Glass used for anti-fogging optical lens Download PDF

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Publication number
CN106587610A
CN106587610A CN201611166848.7A CN201611166848A CN106587610A CN 106587610 A CN106587610 A CN 106587610A CN 201611166848 A CN201611166848 A CN 201611166848A CN 106587610 A CN106587610 A CN 106587610A
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CN
China
Prior art keywords
parts
glass
preventing atomization
optical lens
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611166848.7A
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Chinese (zh)
Inventor
张小华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Original Assignee
ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd filed Critical ANHUI CHANGGENG OPTICAL TECHNOLOGY Co Ltd
Priority to CN201611166848.7A priority Critical patent/CN106587610A/en
Publication of CN106587610A publication Critical patent/CN106587610A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/112Deposition methods from solutions or suspensions by spraying

Abstract

The invention provides a glass used for anti-fogging optical lens, and relates to the technical field of production of optical glass. The glass is prepared from the following components in parts by mass: silica sand, sodium carbonate, quartz stone, alumina powder, sodium nitrate, amphibole, cerium oxide, antimonous oxide, tetrabutyl titanate, N,N-dimethylformamide, polyethylene glycol, a decolorizing adsorbent, a leveling agent and an anti-fogging liquid. The glass used for the anti-fogging optical lens provided by the invention has the advantages of anti-fogging function, uneasy adhesion of dust to the surface of the glass, high strength, high compactness and good optical performance.

Description

A kind of preventing atomization optical lens glass
Technical field:
The present invention relates to optical glass production technical field, and in particular to a kind of preventing atomization optical lens glass.
Background technology:
Optical lens are requisite parts in Vision Builder for Automated Inspection, directly affect the quality of image quality, affect to calculate The realization of method and effect.Optical lens can be divided into short-focus lens, middle zoom lens, telephoto lens from focal length;From visual field size point There are Radix Rumiciss, standard, long shot;Dividing in structure has fixed aperture tight shot, and manual iris tight shot, auto iris is focused Camera lens, manual zoom camera lens, automatic zoom camera lens, auto iris motorized zoom lenses, electronic three variable (aperture, focal length, focusing It is variable) camera lens etc..The general resin material of eyeglass material or the material of glass of optical lens, two kinds of materials respectively have excellent lacking Point, easily crushes as the optical lens of glass material, but good in optical property, yet with the difference of production technology, for The compactness of the optical glass of some castings is not enough, so not only affects its intensity, and can affect after grinding and polishing To its optical property.And the surface of the glass of optical lens has compared with high-adhesiveness, is easily adhered dust or felt, inconvenience In cleaning.
The content of the invention:
The technical problem to be solved is to overcome existing technological deficiency, there is provided a kind of intensity is high, compactness Height, good in optical property, the preventing atomization optical lens glass with extremely strong atomization-preventing function.
The technical problem to be solved is realized using following technical scheme:
A kind of preventing atomization optical lens glass, is prepared from by the component of following mass fraction:
100~120 parts of silica sand, 50~55 parts of sodium carbonate, 20~40 parts of quartz, 1~5 part of alumina powder, sodium nitrate 0.5 ~0.8 part, 2~5 parts of amphibole, 0.2~0.3 part of cerium oxide, 1~5 part of antimony oxide, 0.8~2 part of butyl titanate, N, N- 3~5 parts of dimethylformamide, 1~3 part of Polyethylene Glycol, 3~5 parts of decolorising agent, 2~4 parts of levelling agent, 3~8 parts of preventing atomization liquid;
Above-mentioned decolorising agent by:3~4 parts of dicyandiamide, 8~10 parts of aluminium polychlorid, 5~8 parts of ferrous sulfate and Melanteritum 3~5 Part is prepared from;
Above-mentioned levelling agent is powder levelling agent;
The preventing atomization liquid by:10~15 parts of alkyl sodium phosphate, 8~10 parts of methylene glycol, 3~5 parts of diethanolamine, second 5~8 parts of glycol methyl ether, 1~3 part of glycerol triacetate, 10~15 parts of pure water, 4~6 parts of octadecylsilane chemically bonded silica 3~4 parts are prepared from Resina persicae;
A kind of preventing atomization optical lens glass is prepared from by following methods:
(1) dispensing:Following raw material is weighed by mass fraction:Silica sand, sodium carbonate, quartz, alumina powder, sodium nitrate, sudden strain of a muscle It is stone, cerium oxide, antimony oxide, butyl titanate, N,N-dimethylformamide, Polyethylene Glycol, decolorising agent, levelling agent, antifog Change liquid;
(2) found:The mixed raw material of dispensing is carried out into 1550~1600 degree of heating of high temperature in melting furnace, is allowed to be formed Even liquid glass;
(3) molding:The calendering formation under conditions of 800~1000 DEG C;
(4) heat treatment:By annealing, quenching technical, stress, split-phase or the crystallization of inside glass are eliminated or produce, and Change the configuration state of glass
(5) grind and polish:Formerly 0.2~1mm of corase grind, is passing through to refine 0.2~0.5mm;
(6) making of preventing atomization liquid, raw material is prepared by component, by raw material alkyl sodium phosphate, methylene glycol, diethyl Hydramine, Ethylene glycol methyl ether, glycerol triacetate, the pure water high-temperature fusion at 800~1000 DEG C;Being subsequently cooled to temperature is Octadecylsilane chemically bonded silica and Resina persicae are added when 200~250 DEG C and 10~15 minutes are incubated;It is cooled to room temperature;
(7) spray:Preventing atomization liquid is sprayed on into the surface of glass, so far the glass preparation of preventing atomization optical lens is complete Into;
Described spraying and calendering is carried out under conditions of vacuum.
Thickness of glass after described calendering formation is 3~15mm.
Described calendering formation is rolled using double roller therapy, and wakes up with a start frosted process to the glass one side after molding.
The raw material of uniqueness is present invention employs, the glass of production itself has atomization-preventing function, and in external spray One layer of liquid with atomization-preventing function, preventing atomization optical lens glass of the present invention has elimination well to vapor and fog Effect, even if carrying out using under the larger environment of the temperature difference by the use of preventing atomization liquid also mirror will not be made because of the huge temperature difference There is atomizating phenomenon on head, therefore the photovoltaic glass of present invention production has the function of preventing atomization.
The invention has the beneficial effects as follows:The glass of the present invention has atomization-preventing function, and dust is not easy to stick to its surface, Intensity is high, and compactness is high, good in optical property.
Specific embodiment:
In order that technological means, creation new feature, reached purpose and effect that the present invention is realized are easy to understand, below With reference to instantiation, the present invention is expanded on further.
Embodiment 1
A kind of preventing atomization optical lens glass, is prepared from by the component of following mass fraction:
100 parts of silica sand, 50 parts of sodium carbonate, 20 parts of quartz, 1 part of alumina powder, 0.5 part of sodium nitrate, 2 parts of amphibole, oxidation 0.2 part of cerium, 1 part of antimony oxide, 0.8 part of butyl titanate, 3 parts of N,N-dimethylformamide, 1 part of Polyethylene Glycol, decolorising agent 3 Part, 2 parts of levelling agent, 3 parts of preventing atomization liquid;
Above-mentioned decolorising agent by:3 parts of 3 parts of dicyandiamide, 8 parts of aluminium polychlorid, 5 parts of ferrous sulfate and Melanteritum are prepared from;
Above-mentioned levelling agent is powder levelling agent;
The preventing atomization liquid by:10 parts of alkyl sodium phosphate, 8 parts of methylene glycol, 3 parts of diethanolamine, Ethylene glycol methyl ether 5 Part, 1 part of glycerol triacetate, 10 parts of pure water, 4 parts of octadecylsilane chemically bonded silica and 3 parts of Resina persicae are prepared from;
A kind of preventing atomization optical lens glass is prepared from by following methods:
(1) dispensing:Following raw material is weighed by mass fraction:Silica sand, sodium carbonate, quartz, alumina powder, sodium nitrate, sudden strain of a muscle It is stone, cerium oxide, antimony oxide, butyl titanate, N,N-dimethylformamide, Polyethylene Glycol, decolorising agent, levelling agent, antifog Change liquid;
(2) found:The mixed raw material of dispensing is carried out into 1550 degree of heating of high temperature in melting furnace, is allowed to form uniform liquid State glass;
(3) molding:The calendering formation under conditions of 800 DEG C;
(4) heat treatment:By annealing, quenching technical, stress, split-phase or the crystallization of inside glass are eliminated or produce, and Change the configuration state of glass
(5) grind and polish:Formerly corase grind 0.2mm, is passing through to refine 0.2mm;
(6) making of preventing atomization liquid, raw material is prepared by component, by raw material alkyl sodium phosphate, methylene glycol, diethyl Hydramine, Ethylene glycol methyl ether, glycerol triacetate, the pure water high-temperature fusion at 800 DEG C;Temperature is subsequently cooled to for 200 DEG C When add octadecylsilane chemically bonded silica and Resina persicae and be incubated 10 minutes;It is cooled to room temperature;
(7) spray:Preventing atomization liquid is sprayed on into the surface of glass, so far the glass preparation of preventing atomization optical lens is complete Into;
Embodiment 2
A kind of preventing atomization optical lens glass, is prepared from by the component of following mass fraction:
120 parts of silica sand, 55 parts of sodium carbonate, 40 parts of quartz, 5 parts of alumina powder, 0.8 part of sodium nitrate, 5 parts of amphibole, oxidation 0.3 part of cerium, 5 parts of antimony oxide, 2 parts of butyl titanate, 5 parts of N,N-dimethylformamide, 3 parts of Polyethylene Glycol, decolorising agent 5 Part, 4 parts of levelling agent, 8 parts of preventing atomization liquid;
Above-mentioned decolorising agent by:5 parts of 4 parts of dicyandiamide, 10 parts of aluminium polychlorid, 8 parts of ferrous sulfate and Melanteritum are prepared from;
Above-mentioned levelling agent is powder levelling agent;
The preventing atomization liquid by:15 parts of alkyl sodium phosphate, 10 parts of methylene glycol, 5 parts of diethanolamine, Ethylene glycol methyl ether 4 parts of 8 parts, 3 parts of glycerol triacetate, 15 parts of pure water, 6 parts of octadecylsilane chemically bonded silica and Resina persicae are prepared from;
A kind of preventing atomization optical lens glass is prepared from by following methods:
(1) dispensing:Following raw material is weighed by mass fraction:Silica sand, sodium carbonate, quartz, alumina powder, sodium nitrate, sudden strain of a muscle It is stone, cerium oxide, antimony oxide, butyl titanate, N,N-dimethylformamide, Polyethylene Glycol, decolorising agent, levelling agent, antifog Change liquid;
(2) found:The mixed raw material of dispensing is carried out into 1600 degree of heating of high temperature in melting furnace, is allowed to form uniform liquid State glass;
(3) molding:The calendering formation under conditions of 1000 DEG C;
(4) heat treatment:By annealing, quenching technical, stress, split-phase or the crystallization of inside glass are eliminated or produce, and Change the configuration state of glass
(5) grind and polish:Formerly corase grind 1mm, is passing through to refine 0.5mm;
(6) making of preventing atomization liquid, raw material is prepared by component, by raw material alkyl sodium phosphate, methylene glycol, diethyl Hydramine, Ethylene glycol methyl ether, glycerol triacetate, the pure water high-temperature fusion at 1000 DEG C;Temperature is subsequently cooled to for 250 DEG C When add octadecylsilane chemically bonded silica and Resina persicae and be incubated 15 minutes;It is cooled to room temperature;
(7) spray:Preventing atomization liquid is sprayed on into the surface of glass, so far the glass preparation of preventing atomization optical lens is complete Into;
The ultimate principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description this The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (4)

1. a kind of preventing atomization optical lens glass, it is characterised in that:It is prepared from by the component of following mass fraction:
100~120 parts of silica sand, 50~55 parts of sodium carbonate, 20~40 parts of quartz, 1~5 part of alumina powder, sodium nitrate 0.5~ 0.8 part, 2~5 parts of amphibole, 0.2~0.3 part of cerium oxide, 1~5 part of antimony oxide, 0.8~2 part of butyl titanate, N, N- bis- 3~5 parts of methylformamide, 1~3 part of Polyethylene Glycol, 3~5 parts of decolorising agent, 2~4 parts of levelling agent, 3~8 parts of preventing atomization liquid;
Above-mentioned decolorising agent by:3~4 parts of dicyandiamide, 8~10 parts of aluminium polychlorid, 3~5 parts of systems of 5~8 parts of ferrous sulfate and Melanteritum It is standby to form;
Above-mentioned levelling agent is powder levelling agent;
The preventing atomization liquid by:10~15 parts of alkyl sodium phosphate, 8~10 parts of methylene glycol, 3~5 parts of diethanolamine, ethylene glycol 5~8 parts of methyl ether, 1~3 part of glycerol triacetate, 10~15 parts of pure water, 4~6 parts of octadecylsilane chemically bonded silica and Fructus Persicae 3~4 parts of glue is prepared from.
2. a kind of preventing atomization optical lens glass, it is characterised in that:It is prepared from by following methods:
(1) dispensing:Following raw material is weighed by mass fraction:Silica sand, sodium carbonate, quartz, alumina powder, sodium nitrate, amphibole, oxygen Change cerium, antimony oxide, butyl titanate, N,N-dimethylformamide, Polyethylene Glycol, decolorising agent, levelling agent, preventing atomization liquid;
(2) found:The mixed raw material of dispensing is carried out into 1550~1600 degree of heating of high temperature in melting furnace, is allowed to form uniform Liquid glass;
(3) molding:The calendering formation under conditions of 800~1000 DEG C;
(4) heat treatment:By annealing, quenching technical, stress, split-phase or the crystallization of inside glass are eliminated or produced, and change The configuration state of glass
(5) grind and polish:Formerly 0.2~1mm of corase grind, is passing through to refine 0.2~0.5mm;
(6) making of preventing atomization liquid, raw material is prepared by component, by raw material alkyl sodium phosphate, methylene glycol, diethanol Amine, Ethylene glycol methyl ether, glycerol triacetate, the pure water high-temperature fusion at 800~1000 DEG C;Being subsequently cooled to temperature is Octadecylsilane chemically bonded silica and Resina persicae are added when 200~250 DEG C and 10~15 minutes are incubated;It is cooled to room temperature;
(7) spray:Preventing atomization liquid is sprayed on into the surface of glass, so far preventing atomization optical lens glass preparation is completed.
3. a kind of preventing atomization optical lens glass according to claim 1, it is characterised in that:The preventing atomization optical lens The preferred ingredient scheme of glass is:120 parts of silica sand, 55 parts of sodium carbonate, 40 parts of quartz, 5 parts of alumina powder, 0.8 part of sodium nitrate, 5 parts of amphibole, 0.3 part of cerium oxide, 5 parts of antimony oxide, 2 parts of butyl titanate, 5 parts of N,N-dimethylformamide, Polyethylene Glycol 3 Part, 5 parts of decolorising agent, 4 parts of levelling agent, 8 parts of preventing atomization liquid.
4. a kind of preventing atomization optical lens glass according to claim 1, it is characterised in that:The preventing atomization liquid is by following Component is prepared from:10 parts of alkyl sodium phosphate, 8 parts of methylene glycol, 3 parts of diethanolamine, 5 parts of Ethylene glycol methyl ether, glycerol three 3 parts of 1 part of acetass, 10 parts of pure water, 4 parts of octadecylsilane chemically bonded silica and Resina persicae.
CN201611166848.7A 2016-12-16 2016-12-16 Glass used for anti-fogging optical lens Pending CN106587610A (en)

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CN201611166848.7A CN106587610A (en) 2016-12-16 2016-12-16 Glass used for anti-fogging optical lens

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Application Number Priority Date Filing Date Title
CN201611166848.7A CN106587610A (en) 2016-12-16 2016-12-16 Glass used for anti-fogging optical lens

Publications (1)

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CN106587610A true CN106587610A (en) 2017-04-26

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101306918A (en) * 2007-08-03 2008-11-19 李彪 Production process of ultra-white patterned glass
CN101475311A (en) * 2009-02-13 2009-07-08 徐传龙 Glass tube for cold cathode fluorescent lamp and manufacturing method thereof
KR100990875B1 (en) * 2010-07-02 2010-11-01 군산대학교산학협력단 Photovoltaic low iron flat glass batches containing alkali-free alumino-borosilicate display glass cullet
CN104419535A (en) * 2013-08-19 2015-03-18 南通市通州区悦硕农业开发有限公司 Anti-fogging glass washing agent
CN105000619A (en) * 2015-07-20 2015-10-28 湖州吉昌丝绸有限公司 Novel composite decolorant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101306918A (en) * 2007-08-03 2008-11-19 李彪 Production process of ultra-white patterned glass
CN101475311A (en) * 2009-02-13 2009-07-08 徐传龙 Glass tube for cold cathode fluorescent lamp and manufacturing method thereof
KR100990875B1 (en) * 2010-07-02 2010-11-01 군산대학교산학협력단 Photovoltaic low iron flat glass batches containing alkali-free alumino-borosilicate display glass cullet
CN104419535A (en) * 2013-08-19 2015-03-18 南通市通州区悦硕农业开发有限公司 Anti-fogging glass washing agent
CN105000619A (en) * 2015-07-20 2015-10-28 湖州吉昌丝绸有限公司 Novel composite decolorant

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Application publication date: 20170426