CN106587495A - Treating method for industrial sewage - Google Patents

Treating method for industrial sewage Download PDF

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Publication number
CN106587495A
CN106587495A CN201611112920.8A CN201611112920A CN106587495A CN 106587495 A CN106587495 A CN 106587495A CN 201611112920 A CN201611112920 A CN 201611112920A CN 106587495 A CN106587495 A CN 106587495A
Authority
CN
China
Prior art keywords
sewage
water
electric flocculation
activated sludge
medicament
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611112920.8A
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Chinese (zh)
Inventor
吴福勤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201611112920.8A priority Critical patent/CN106587495A/en
Publication of CN106587495A publication Critical patent/CN106587495A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/465Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electroflotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention relates to a treating method for industrial sewage. The method mainly comprises the following steps that 1, sewage to be treated is subjected to electrolytic treatment through an electric flocculation device, and impurities and water are removed through flotation pollution discharge and sedimentation pollution discharge; 2, a treating agent is put into the sewage obtained after being treated through the electric flocculation device through a dosing device, and sufficient mixing is performed in a mixing device; 3, a medicament is put and the mixed sewage enters an efficient activated sludge purifier for performing a reaction to form activated sludge, and filtering treatment is performed. The electrooxidation-flocculation and efficient activated sludge water purification technology is adopted for treating oil field wastewater, the dosage of a water treatment chemical medicament is decreased, and formation water quality eutrophication is avoided.

Description

A kind of processing method of trade effluent
Technical field
The present invention relates to a kind of sewage treatment process, specifically refers to a kind of processing method of trade effluent.
Background technology
What current disposing polluted water in oil was commonly used has two methods:A kind of is to take traditional gravity floatation+coagulant precipitation+pressure The handling process of power filtration+corrosion-mitigation scale-inhibition adding of agent, the technique is preliminary to remove ratio by gravity natural subsidence and aeration flotation The larger suspension of weight and free oil, then add coagulated agent, make suspension combine to form larger floccule body increase suspension With the difference in specific gravity of water, acceleration suspended particulate purpose detached with sewage is reached, finally by multistage filtering technology, further reduced Suspension and oil content in water outlet.And for the corrosion and scaling and problem of bacteria of injection water, then by adding a certain amount of inhibition Agent, scale preventative and bactericide are solving.
The content of the invention
The technical problem to be solved is to provide a kind of processing method of trade effluent, and it adopts electroxidation-wadding The technique of solidifying+high-efficiency activated sludge water purification is processed oil field waste, not only reduces the dosage of chemistry in water treatment medicament, And avoid stratum water Water Eutrophication.
The present invention solves the technical scheme that adopted of above-mentioned technical problem:A kind of processing method of trade effluent, it is special Levy and be, mainly include the following steps that:
A pending sewage is carried out electrolysis process by () by electric flocculation device, and will be miscellaneous by flotation blowdown and precipitation blowdown Matter is separated from water, removes;
B the sewage after the process of () electric flocculation device adds treatment agent and is fully mixed in mixing arrangement by chemicals dosing plant Close;
C () adds medicament and mixed sewage carries out reaction and forms activated sludge into high-efficiency activated sludge water purifier, enters one Step filtration treatment.
Sewage is carried out into electrolysis process in electric flocculation device in described step (a) to further include:
(a.1) described electric flocculation device is provided with electrolytic cell, equidistant parallel arrangement iron and graphite electricity in the electrolytic cell Pole plate, by the electrolytic cell of sewage transport to electric flocculation device from storage tank, Jing electrolytic cells carry out electrolysis oxygen to the boosted pump of sewage Change, electroreduction, electrofloatation and electrolytic flocculation are processed;
(a.2) floating thing and sediment of gained after electrolysis process are emitted into respectively by flotation blowdown, precipitation drainage Waste oil collecting groove and sludge concentration tank.
Sewage dosing mixed processing after the process of electric flocculation device is further included in described step (b):
(b.1) sewage after step (a.1) process is delivered in chemical-dosing mixer from intermediate water tank using middle water pump;
(b.2) medicament for preparing is added in sewage using dosing pump, and medicament and sewage is sufficiently mixed in a mixer, Treatment agent is added to include dosing pump is respectively adopted from medicament preparing tank by PH conditioning agents, water purification agent and its flocculant in sewage In adding blender;Described PH conditioning agents are formulated by calcium hydroxide and NaOH by 9: 1 mass ratio, and sewage PH value is adjusted To 7.0-7.5;Described water purification agent adopts bentonite composite water purifying agent, dosage 30-50mg/L;Described flocculant is using cloudy The high polymer polyacrylamide of ionic and molecular weight more than 10,000,000, dosage is 5mg/L.
Filtration treatment is carried out in the step (c) by high-efficiency activated sludge water purifier to further include:
(c.1) sewage transport Jing after processing in step (b.2) is filtered to efficient activated sludge water purifier;
(c.2) by the mud discharging of sedimentation and filtration section retention to sludge concentration tank;
(c.3) water qualified after process is noted by reinjected water blowback.
In order to discharge sludge can circular treatment, sludge is emitted into the Jing steps (a.2) and step (c.2) dense Sludge in contracting pond is returned to supernatant in sewage storage tank with clarified water pump after sedimentation, and is repeated in step (a), step Suddenly (b) and step (c).
To the sludge that is emitted in sludge concentration tank after sedimentation, using sludge pump base sludge is extracted out and done Change is processed.
To sum up, the invention has the beneficial effects as follows:Oil field is processed using electroxidation-flocculation+high-efficiency activated sludge water purification technology Sewage, realize purifying water by the method for physics, control corrosion rate, the effect that suppresses fouling, kill bacterium, reduce water process Learn the dosage of medicament, it is to avoid the problems such as stratum water Water Eutrophication, the resistance to the action of a drug of bacterium, improve injection water with stratum water Compatibility, reduces water process operating cost;Simultaneously remove the harmful ions such as removing ferro in water, sulphur, it is to avoid water quality in the injecting process Change, realizes stablizing for water quality.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
The present invention is processed oil field waste using the technique of electroxidation-flocculation+high-efficiency activated sludge water purification.The present invention Technological process it is as follows:Wastewater storage tank water pump boosted first is promoted in the built-in electrolytic cell of electric flocculation equipment, in electrolytic cell Equidistant parallel arranges iron and graphite electrode plate, and unlike material battery lead plate ratio is true according to parameters such as water quality sulphur and bacterial contents It is fixed, sewage Jing electrolytic cell Inner electrolysis, while electrolytic oxidation, electroreduction effect, electrofloatation effect, electrolysis wadding can be produced Solidifying effect.Thus, the such as H+ of the cation in sewage obtains electronics and is reduced into hydrogen in electrolytic cell inner cathode annex.In remaining water Rise other metal ions K+, Na+ due in water have its activity, still with ionic state presence.And there is electrolysis in sewage The anion of betatopic activity such as Cl-, OH- lose electronics near electrolytic cell inner anode and are oxidized to Cl2, O2, the Cl2 of generation Pole be dissolved in water formed ClO-, substantial amounts of ClO- sewage is had strength sterilizing effect, with this to reduce eliminating water in Bacterium.The a large amount of H2 generated in anode and cathode and O2, its bubble is little, and decentralization is high, adheres to the light oil in water as carrier and hangs Float and float, outside Jing overflow launders arrange, reach the effect of oil removing.Simultaneously because soluble metal electrolysis is produced in electrolytic process OH- effects in a large amount of cations of life, with water, form metal hydroxides colloid flocculant and adsorb the polluter in waste water Precipitation or formation larger particles provide advantage for subsequent treatment.
Waste water Jing after electroxidation-flocculation treatment is adjusted PH to 7.0-7.5, the PH through adding PH conditioning agents Conditioning agent presses 9: 1 proportions using calcium hydroxide and NaOH, and dosage is according to sewage PH dynamic regulations, the Fe2+ ions in water Generation FeS being combined with the S2- in water to precipitate, then being added a small amount of water purification agent and flocculation aid, the water purification agent is adopted swelling Native composite water purifying agent, dosage 30-50mg/L, measuring pump is quantitatively added, and the flocculation aid adopts high polymer polyacrylamide, cloudy Ionic, molecular weight more than 10,000,000, dosage 5mg/L, measuring pump is quantitatively added, and makes waste water enter high-efficiency activated sludge water purification Flco rapid subsidence forms high-efficiency activated sludge filtering layer after device, and this filtering layer is special by surface physicses absorption, the net effect of catching and electrochemistry Property and Van der Waals force effect, suspension colloid particle, flco, part microorganism etc. impurity is all intercepted here and is efficiently lived On property sludge filtering layer, effluent quality is set to reach processing requirement.
The above, is only presently preferred embodiments of the present invention, not does any pro forma restriction to the present invention, it is every according to Any simple modification, the equivalent variations made to above example in technical spirit according to the present invention, each fall within the guarantor of the present invention Within the scope of shield.

Claims (3)

1. a kind of processing method of trade effluent, it is characterised in that mainly include the following steps that:A () leads in pending sewage Crossing electric flocculation device carries out electrolysis process, and is separated from water impurity, is removed by flotation blowdown and precipitation blowdown;(b) electricity wadding Sewage after solidifying device is processed adds treatment agent and is sufficiently mixed in mixing arrangement by chemicals dosing plant;C () adds Medicament and mixed sewage carries out reaction and forms activated sludge, further filtration treatment into high-efficiency activated sludge water purifier.
2. the processing method of a kind of trade effluent according to claim 1, it is characterised in that will in described step (a) Sewage carries out electrolysis process in electric flocculation device and further includes:(a.1) described electric flocculation device is provided with electrolytic cell, By in the electrolytic cell of sewage transport to electric flocculation device from storage tank, Jing electrolytic cells carry out electrolytic oxidation, electricity to the boosted pump of sewage Solution reduction, electrofloatation and electrolytic flocculation are processed;(a.2) floating thing and sediment of gained after electrolysis process are arranged by flotation Dirty, precipitation drainage is emitted into respectively waste oil collecting groove and sludge concentration tank.
3. the processing method of a kind of trade effluent according to claim 2, it is characterised in that right in described step (b) Sewage dosing mixed processing is further included after the process of electric flocculation device:(b.1) using middle water pump by after step (a.1) process Sewage be delivered in chemical-dosing mixer from intermediate water tank;(b.2) medicament for preparing is added in sewage using dosing pump, and Medicament and sewage is set to be sufficiently mixed in a mixer.
CN201611112920.8A 2016-12-07 2016-12-07 Treating method for industrial sewage Pending CN106587495A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611112920.8A CN106587495A (en) 2016-12-07 2016-12-07 Treating method for industrial sewage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611112920.8A CN106587495A (en) 2016-12-07 2016-12-07 Treating method for industrial sewage

Publications (1)

Publication Number Publication Date
CN106587495A true CN106587495A (en) 2017-04-26

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Application Number Title Priority Date Filing Date
CN201611112920.8A Pending CN106587495A (en) 2016-12-07 2016-12-07 Treating method for industrial sewage

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109188998A (en) * 2018-10-25 2019-01-11 成都市自来水有限责任公司 Water treatment plant PAC Intelligent adding control system based on data fitting method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109188998A (en) * 2018-10-25 2019-01-11 成都市自来水有限责任公司 Water treatment plant PAC Intelligent adding control system based on data fitting method

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Application publication date: 20170426

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