CN106584953A - Automatic packaging composite film for betel nuts and preparation method of automatic packaging composite film - Google Patents
Automatic packaging composite film for betel nuts and preparation method of automatic packaging composite film Download PDFInfo
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- CN106584953A CN106584953A CN201610999608.9A CN201610999608A CN106584953A CN 106584953 A CN106584953 A CN 106584953A CN 201610999608 A CN201610999608 A CN 201610999608A CN 106584953 A CN106584953 A CN 106584953A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/14—Printing or colouring
- B32B38/145—Printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B11/00—Wrapping, e.g. partially or wholly enclosing, articles or quantities of material, in strips, sheets or blanks, of flexible material
- B65B11/50—Enclosing articles, or quantities of material, by disposing contents between two sheets, e.g. pocketed sheets, and securing their opposed free margins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B47/00—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved
- B65B47/04—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved by application of mechanical pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses an automatic packaging composite film for betel nuts and a preparation method of the automatic packaging composite film. The composite film comprises a printed layer, a barrier layer and a heat sealing layer, wherein the printed layer is a biaxially stretched nylon film, the barrier layer is alloy aluminum foil, and the heat sealing layer is a metallocene polyethylene film; the layers are adhered by a two-component solvent-free polyurethane adhesive. When the composite film is used for packaging, the film is cut into an upper film and a base film, and the betel nuts are automatically packaged in an automatic packaging machine. The composite film effectively prevents the betel nuts from deforming and breaking bags in an automatic packaging process due to high pressure vacuum pumping and filling, has excellent oxygen barrier property and mechanical strength and prevents active ingredients in the betel nuts from oxidative deterioration, and the packaging is neat and beautiful and is easily torn open.
Description
Technical field
The present invention relates to packaging field, automatic packaging composite film of particularly a kind of Semen Arecae and preparation method thereof.
Background technology
Semen Arecae is one of China's famous and precious " four great Nan medicines ", with certain medical value.At present, through modern processing work
Skill develops, it has also become leisure food, deep to be favored by people, and Semen Arecae is chewed the excitation after eating and is mainly derived from its Bin for containing
Bulky alkali basic active composition, in addition also containing fat such as cinnamic acid, Palmic acid, stearic acid, Oleic acid, linoleic acids.Therefore, Semen Arecae activity into
Point preservation seem most important, especially dioxygen oxidation effect be easily caused it is rotten, the barrier property of packaging material be it is crucial because
Element.Semen Arecae is sharp due to its profile, even more hard after smoke-dried beancurd, is easily caused and punctures packaging, in the market mostly polyester aluminizer
Packaging, one is that barrier property is inadequate, but easily openable is not opened, and the shelf-life mostly is 6 months, therefore, the machinery of aluminum foil package material
Strength problem is a technical bottleneck of the pendulum in face of us all the time.
In addition, Semen Arecae Packaging Modernizations are Semen Arecaes promoting for the crucial of Modern Leisure food from traditional pure folk custom food development
One of power.So far, kind of packing is a lot, and total is roughly divided into the packed and big class of mmic package two, is used for manually
Packaging, but as the safe and sanitary problem of the development of society, cost of human resources problem and packaging progressively becomes Semen Arecae enterprise
Development obstacles.
The content of the invention
A kind of stretching foil laminated film that the present invention is provided and preparation method thereof, can effectively overcome existing packaging film-strength
Not enough broken bag, the problem of bale breaking because barrier is not strong enough, are particularly suitable for requirement high-barrier and high intensity, for evacuation bag
The packing instructions of dress.
To solve above-mentioned technical problem, the technical solution adopted in the present invention is:A kind of automatic packaging composite film of Semen Arecae, it is multiple
Close film to be made up of the printing layer, barrier layer, hot sealing layer that set gradually, wherein printing layer is biaxial tension nylon film, barrier layer is
Alloy aluminium foil, is fitted between layers by double component solvent-free polyurethane adhesive.
Further, the thickness of the printing layer is 15 microns.
Further, the alloy aluminium foil be 8011-0 types, thickness be 10-20 microns, tensile strength in 80-100 MPa,
Elongation percentage is 2.5-8%.Pinhole number≤100 PCS/m2。
Further, the hot sealing layer is metallocene PE film;Made using blow moulding process, thickness is 50 micro-
Rice.The metallocene PE film is density≤0.915g/cm3Metallocene catalysed polyethylene, the three-layer co-extruded blow molding works of Jing
Skill is produced, and blow-up ratio is 1:2.2.
Further, the hot sealing layer is by polyamide, ethylene and ethenol copolymer, polyvinylidene chloride, the poly- second of metallocene
Alkene is by weight 1:2:1:2 are co-extruded.
Fitted using double component solvent-free polyurethane adhesive between each layer, gravure coating process forms plastic-aluminum combined
Film, coating weight is 1.5-2.5 g/m2。
The invention further relates to the preparation method of above-mentioned composite membrane, comprises the concrete steps that first to biaxial tension nylon film Jing Jing electronics
Technique is printed in axle intaglio plate, color original text printing is completed, print film is formed;Then double component solvent-free polyurethane gluing is adopted with barrier layer
Agent is combined, and in 40 DEG C of ripening 12h, then itself and hot sealing layer are carried out using double component solvent-free polyurethane adhesive multiple
Close, finally in 40 DEG C of ripening 12h, naturally cool to room temperature and the automatic packaging composite film of Semen Arecae is obtained.
Aluminum-plastic composite membrane of the present invention in automatic packaging process, by the compound film slitting for obtaining into upper film and counterdie wound membrane,
Counterdie forms little groove through 2 KG active forces, is filled through film in Semen Arecae seed post heat-seal, and upper film acts on shape with counterdie through heat seal
Into a complete composite membrane independent packaging.
Chinese patent application, application number:201310184488.3 disclose a kind of new Semen Arecae packaging composite film and its system
Preparation Method, the main employing of the patent Semen Arecae packaging includes answering for polyethylene film, polyvinyl alcohol printing coated film and composite layer
Membrane structure is closed, it is main to form modeling/modeling composite membrane by the way of polyvinyl alcohol emulsions coating.Composite membrane has the heat-sealing of one side strong
Degree is high, and another side is excellent to the barrier property of oxygen, vapor and fragrance, while with good impact strength, rigidity, by force
Toughness and printing adaptability.
Chinese patent application, application number:201310484568.0 disclose a kind of solvent-free cold stamping shaped composite membrane life
Product method, is processed, core mainly for polyamide film, normal aluminium foil and polyvinyl chloride film using special combination process
Technology is to unreel position and carry out aluminium foil second to unreel, and aluminium foil is positioned over the polyamide film lower section, and aluminium foil is by compound pressure
Roller and composite roll are wound, polyamide film and aluminium foil are pressed together when the composite press roller is pressed down after, winding;Gu
Change;Gluing again;Position is unreeled second to unreel to polyvinyl chloride film, composite press roller is pushed the polyamide film after pressing
Three layers of laminated film of formation of fitting are pressed onto with aluminium foil and polyvinyl chloride film, are then wound;Solidify again.The patent is thought multiple
The firmness for closing layers of material during processing is greatly reinforced, therefore composite membrane than prior art there is excellent depth to draw
Stretch performance.
Of the invention to contrast with above-mentioned patent application, maximum difference is:
1)The present invention adopts bi-directional synchronization tensile nylon film, 10-20 micron thickness alloy aluminium foils, and metallocene PE is main material
Material, meets food safety.Barrier property is almost unchanged after material-structure design promotes composite membrane before packing, better than current plating
Aluminum composite membrane is packed.
2)Material characteristic is different, and aluminium foil is respectively provided with certain ductility with each layer plastic polymer material, and the present invention is compound
Film reaches in vertical direction the core index such as 8 mm stretching depths, 20% extensibility, from for 8011-0 type alloy aluminium foils
The ductility of material, is especially suitable for the independent packaging of Semen Arecae.And the elongation percentage of common 7 micron thick aluminium foil is typically≤2%.
3)Combination process is the solvent-free compound of the glutinous agent of two-component polyurethane adhesive, and no solvent residue meets food safety, protects
Quality guarantee is fresh.
4)Due to aluminum foil material characteristic in the middle of composite membrane, this flexible packaging very easily openable rises.
The present invention is modified by material technology, aluminum-plastic composite membrane tensile properties is enhanced, by upper film and counterdie automatic
The automatic packaging to Semen Arecae is completed on packer.Jing is tested, after the composite film packaging using present invention offer, oxygen transit dose
≤0.8cm3/m2.24h.0.1MPa, steam penetrating capacity≤0.5 g/m2.24h, the mg/m of dissolvent residual total amount < 32;Tear at right angle
Resistance to spalling < 50N/m;Impact strength is more than 1.4 J;Can effectively prevent Semen Arecae in automatic packaging process because of high pressure evacuation
Filling deformation, broken bag, with excellent oxygen barrier property and mechanical strength, prevent Semen Arecae active component oxidation deterioration, and wrap
Fill smooth attractive in appearance, easily openable to open.
Specific embodiment
The present invention is further illustrated with reference to embodiment, but the scope of protection of present invention is not limited to implement
The scope of example statement.
Embodiment 1:
The preparation technology of composite membrane is as follows:
(1)Color printing
Initially with 15 micron thickness bi-directional synchronization tensile nylon film BOPA, technique is printed in Jing electronical line shaft intaglio plates, complete color original text print
Brush, forms print film;
(2)It is compound
Print film and the solvent-free combination process of 20 micron thickness 8011-0 type alloy aluminium foil Jing, double component solvent-free adhesive is formed
BOPA/AL composite membranes;
(3)Ripening
BOPA/AL composite membranes are placed into 40 DEG C of environment, the h of ripening 12;
(4)It is secondary compound
The three-layer co-extruded blow molding PE films of BOPA/AL composite membranes and metallocene PE are combined again, the solvent-free compound works of Jing
Skill, forms BOPA/AL/PE composite membranes;
(5)Post cure
BOPA/AL/PE composite membranes are placed into 40 DEG C of environment, after the h of ripening 24, room temperature is naturally cooled to
(6)Cutting
Compound film slitting after cooling carries out Semen Arecae packaging into upper film and counterdie wound membrane for automatic packaging machine.
Composite membrane has good Automatic-drawing packing character, is applied to bulky grain Semen Arecae W60*L120*H7mm and independently wraps
Dress, the shelf-life can be promoted to 12 months by original 6 months, and package formation is attractive in appearance, it is easy to tear.Composite film material performance such as following table
1:
Table 1
Embodiment 2:
The preparation technology of composite membrane is as follows:
(1)Color printing
Initially with 15 micron thickness bi-directional synchronization tensile nylon film BOPA, technique is printed in Jing electronical line shaft intaglio plates, complete color original text print
Brush, forms print film;
(2)It is compound
Print film and the solvent-free combination process of 15 micron thickness 8011-0 type alloy aluminium foil Jing, double component solvent-free adhesive is formed
BOPA/AL composite membranes;
(3)Ripening
BOPA/AL composite membranes are placed into 40 DEG C of environment, the h of ripening 12;
(4)It is secondary compound
The three-layer co-extruded blow molding PE films of BOPA/AL composite membranes and metallocene PE are combined again, the solvent-free compound works of Jing
Skill, forms BOPA/AL/PE composite membranes;
(5)Post cure
BOPA/AL/PE composite membranes are placed into 40 DEG C of environment, after the h of ripening 24, room temperature is naturally cooled to.
(6)Cutting
Compound film slitting after cooling carries out Semen Arecae packaging into upper film and counterdie wound membrane for automatic packaging machine.
Composite membrane has good Automatic-drawing packing character, is applied to Semen Arecae size W55*L110*H5mm independent packaging,
Shelf-life can be promoted to 12 months by original 6 months, and package formation is attractive in appearance, it is easy to tear.Concrete material property such as table 2 below:
Table 2
Embodiment 3:
It is as follows as the preparation technology of the composite membrane of barrier layer using 10 micron thickness 8011-0 type alloy aluminium foils:
(1)Color printing
The present invention prints technique initially with 15 micron thickness bi-directional synchronization tensile nylon film BOPA in Jing electronical line shaft intaglio plates, completes
Color original text printing, forms print film;
(2)It is compound
Print film and the solvent-free combination process of 10 micron thickness 8011-0 type alloy aluminium foil Jing, double component solvent-free adhesive is formed
BOPA/AL composite membranes;
(3)Ripening
BOPA/AL composite membranes are placed into 40 DEG C of environment, the h of ripening 12;
(4)It is secondary compound
The three-layer co-extruded blow molding PE films of BOPA/AL composite membranes and metallocene PE are combined again, the solvent-free compound works of Jing
Skill, forms BOPA/AL/PE composite membranes;
(5)Post cure
BOPA/AL/PE composite membranes are placed into 40 DEG C of environment, after the h of ripening 24, room temperature is naturally cooled to.
(6)Cutting
Compound film slitting after cooling carries out Semen Arecae packaging into upper film and counterdie wound membrane for automatic packaging machine.
Composite membrane has good Automatic-drawing packing character, is applied to Semen Arecae size W48*L90*H5mm independent packaging,
Shelf-life can be promoted to 12 months by original 6 months, and package formation is attractive in appearance, it is easy to tear.Concrete composite film material performance is as follows
Table 3:
Table 3
Embodiment 4:
A kind of automatic packaging composite film of Semen Arecae, is made up of the printing layer, barrier layer, hot sealing layer that set gradually, and wherein printing layer is
Biaxial tension nylon film, thickness is 15 microns, and barrier layer is 15 microns of alloy aluminium foil, and tensile strength extends in 80-100 MPa
Rate is 2.5-8%;Hot sealing layer be metallocene PE film, metallocene catalysed polyethylene density≤0.915g/cm3, thickness is 50 micro-
Rice;Fitted by double component solvent-free polyurethane adhesive between layers.
Embodiment 5:
A kind of automatic packaging composite film of Semen Arecae, is made up of the printing layer, barrier layer, hot sealing layer that set gradually, and wherein printing layer is
Biaxial tension nylon film, thickness is 15 microns, and barrier layer is 10 microns of alloy aluminium foil, and tensile strength extends in 80-100 MPa
Rate is 2.5-8%;Hot sealing layer is by weight by polyamide, ethylene and ethenol copolymer, polyvinylidene chloride, metallocene PE
Amount compares 1:2:1:2 are co-extruded, and thickness is 50 microns;Fitted by double component solvent-free polyurethane adhesive between layers.
Embodiment 6:
A kind of automatic packaging composite film of Semen Arecae, is made up of the printing layer, barrier layer, hot sealing layer that set gradually, and wherein printing layer is
Biaxial tension nylon film, thickness is 15 microns, and barrier layer is 15 microns of alloy aluminium foil, and tensile strength extends in 80-100 MPa
Rate is 2.5-8%;Hot sealing layer be metallocene PE film, metallocene catalysed polyethylene density≤0.915g/cm3, thickness is 50 micro-
Rice;Fitted by double component solvent-free polyurethane adhesive between layers, coating weight is 1.5-2.5 g/m2。
Claims (9)
1. the automatic packaging composite film of a kind of Semen Arecae, it is characterised in that:Composite membrane is by printing layer, barrier layer, the heat-sealing for setting gradually
Layer is constituted, and wherein printing layer is biaxial tension nylon film, and barrier layer is alloy aluminium foil, between layers by double component solvent-free
Adhesive for polyurethane is fitted.
2. composite membrane according to claim 1, it is characterised in that:The thickness of the printing layer is 15 microns.
3. composite membrane according to claim 1, it is characterised in that:The alloy aluminium foil is 8011-0 types, and thickness is 10-20
Micron, in 80-100 MPa, elongation percentage is 2.5-8% to tensile strength.
4. composite membrane according to claim 1, it is characterised in that:The hot sealing layer is metallocene PE film, and thickness is
50 microns.
5. composite membrane according to claim 4, it is characterised in that:The metallocene PE film is density≤0.915g/
cm3Metallocene catalysed polyethylene, the three-layer co-extruded blow moulding process productions of Jing, blow-up ratio is 1:2.2.
6. composite membrane according to claim 1, it is characterised in that:The hot sealing layer is by polyamide, ethylene and vinyl alcohol
Copolymer, polyvinylidene chloride, metallocene PE are by weight 1:2:1:2 are co-extruded.
7. composite membrane according to claim 1, it is characterised in that:It is described poly- using double component solvent-free between layers
Urethane adhesive is fitted, and gravure coating process forms aluminum-plastic composite membrane, and coating weight is 1.5-2.5 g/m2。
8. the method for preparing composite membrane described in claim 1-7 any one, it is characterised in that concretely comprise the following steps:
First to printing technique in biaxial tension nylon film Jing Jing electronical line shaft intaglio plates, color original text printing is completed, form print film;Then with resistance
Interlayer is combined using double component solvent-free polyurethane adhesive, and in 40 DEG C of ripening 12h, then it is adopted with hot sealing layer
Double component solvent-free polyurethane adhesive is combined, and finally in 40 DEG C of ripening 12h, naturally cools to room temperature and Bin is obtained
Bulky automatic packaging composite film.
9. the method that Semen Arecae is packed automatically is carried out using composite membrane described in claims 1-7 any one, its step is:
By the compound film slitting for obtaining into upper film and counterdie wound membrane, when being packed, counterdie forms groove through 2 KG active forces,
Fill film in Semen Arecae seed post heat-seal in the groove, upper film and counterdie act on forming a complete composite membrane and independently wrapping through heat seal
Dress, you can complete packaging operation.
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