CN106577740A - Disinfectant and preparation method thereof - Google Patents
Disinfectant and preparation method thereof Download PDFInfo
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- CN106577740A CN106577740A CN201611089182.XA CN201611089182A CN106577740A CN 106577740 A CN106577740 A CN 106577740A CN 201611089182 A CN201611089182 A CN 201611089182A CN 106577740 A CN106577740 A CN 106577740A
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- disinfectant solution
- perchlorate
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- mixed liquor
- disinfectant
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
- C25B1/265—Chlorates
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention relates to a disinfectant and a preparation method thereof. The disinfectant per liter contains 410 mg-430 mg of hypochlorite, 35 mg-45 mg of hypochlorous acid, 12 mg-15 mg of chlorate, 3,700 mg-3,900 mg of chloride, 0-10 mg of perchlorate, 0.034-0.036 mg of hydroxide and the balance of water. The disinfectant is good in disinfection and sterilization effect, and particularly can be used for disinfecting containers.
Description
Technical field
The present invention relates to disinfectant solution preparing technical field, and in particular to a kind of disinfectant solution and preparation method thereof.
Background technology
Existing disinfectant solution mixes being allocated generally by solution, this kind of preparation method cause the configuration of solution compared with
For loaded down with trivial details, and it is unfavorable for ensured sustained development industrial application.
The content of the invention
The technical problem to be solved is for the deficiencies in the prior art, there is provided a kind of disinfectant solution and its preparation side
Method.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of disinfectant solution, contains in per liter of disinfectant solution
The hypochlorite of 410mg-430mg, the hypochlorous acid of 35mg-45mg, the chlorate of 12mg-15mg, the chlorination of 3700mg-3900mg
The hydroxide of thing, the perchlorate of 0mg-10mg and 0.034-0.036mg, balance of water.
The invention has the beneficial effects as follows：The disinfectant solution of the present invention, good sterilization effect can especially be used for disappearing for container
Poison.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the hypochlorite containing 420mg in per liter of disinfectant solution, the hypochlorous acid of 40mg, the chlorate of 13mg,
The hydroxide of the chloride of 3800mg, the perchlorate of 0mg-10mg and 0.035mg, balance of water.
A kind of preparation method of disinfectant solution as described above, comprises the following steps：
S1, is put into semipermeable membrane, in electrolyzer using Ti/TiO2For negative electrode, C is anode, using the semipermeable membrane by sun
Pole is coated with the electrolysis bath to form closing；
S2, adopts the aqueous solution of perchlorate for electrolyte, and the concentration of aqueous solution of the perchlorate is 350-710g/L,
Once electrolytic is carried out to electrolyte and after semipermeable membrane, obtain the first mixed liquor in electrolysis bath and be located at semi-transparent
The second mixed liquor outside film；
S3, carries out re-electrolysiss to first mixed liquor and second mixed liquor；
S4, after re-electrolysiss, the solution outside electrolysis bath is the disinfectant solution.
The invention has the beneficial effects as follows：The preparation method of the present invention, using re-electrolysiss method, can make perchlorate molten
Liquid is sufficiently electrolysed.
Further, the once electrolytic and during re-electrolysiss, the electric current density of the anode is 10A/cm2-13A/cm2, institute
It is 6V-6.5V to state the tank voltage in electrolysis bath.
Further, the electrolysis temperature of the negative electrode is 45 ± 5 DEG C.
Further, the aperture of the semipermeable membrane is 0.22 μm.
Further, the concentration of the perchlorate aqueous solution is 540mg/L.
Description of the drawings
Fig. 1 is the electrolysis flow chart of the present invention.
In accompanying drawing, the list of parts representated by each label is as follows：
1st, electrolyzer；2nd, electrolysis bath；3rd, semipermeable membrane；4th, negative electrode；5th, anode.
Specific embodiment
The principle and feature of the present invention are described below in conjunction with accompanying drawing, example is served only for explaining the present invention, and
It is non-for limiting the scope of the present invention.
Embodiment 1
As shown in figure 1, a kind of disinfectant solution of the present embodiment, the hypochlorite containing 410mg in per liter of disinfectant solution,
The hydroxide of the hypochlorous acid of 35mg, the chlorate of 12mg, the chloride of 3700mg and 0.034mg, balance of water.The present embodiment
Disinfectant solution, good sterilization effect can especially be used for the sterilization of container.
A kind of preparation method of disinfectant solution as described above, comprises the following steps：
S1, is put into semipermeable membrane 3, in electrolyzer 1 using Ti/TiO2For negative electrode, C is anode, will using the semipermeable membrane 3
Anode 5 is coated with the electrolysis bath 2 to form closing；
S2, adopts the aqueous solution of perchlorate for electrolyte, and the concentration of aqueous solution of the perchlorate is 350-710g/L,
Once electrolytic is carried out to electrolyte and after semipermeable membrane 2 permeates, obtain the first mixed liquor in electrolysis bath 2 and be located at half
The second mixed liquor outside permeable membrane 3；
S3, carries out re-electrolysiss to first mixed liquor and second mixed liquor；
S4, after re-electrolysiss, the solution outside electrolysis bath 2 is the disinfectant solution.
The preparation method of the present embodiment, using re-electrolysiss method, can be such that perchlorate solution is sufficiently electrolysed.
When the once electrolytic and re-electrolysiss, the electric current density of the anode 5 is 10A/cm2, in the electrolysis bath 2
Tank voltage is 6V.The electrolysis temperature of the negative electrode 4 is 45 DEG C.Polymer membrane of the semipermeable membrane 3 using porous, aperture
For 0.22 μm.The concentration of the perchlorate aqueous solution is preferably 540mg/L.
Embodiment 2
As shown in figure 1, a kind of disinfectant solution of the present embodiment, the hypochlorite containing 420mg in per liter of disinfectant solution,
The hydroxide of the hypochlorous acid of 40mg, the chlorate of 13mg, the chloride of 3800mg, the perchlorate of 5mg and 0.035mg, it is remaining
Measure as water.The disinfectant solution of the present embodiment, good sterilization effect can especially be used for the sterilization of container.
A kind of preparation method of disinfectant solution as described above, comprises the following steps：
S1, is put into semipermeable membrane 3, in electrolyzer 1 using Ti/TiO2For negative electrode 4, C is anode 5, using the semipermeable membrane 3
Anode 5 is coated with the electrolysis bath 2 to form closing；
S2, adopts the aqueous solution of perchlorate for electrolyte, and the concentration of aqueous solution of the perchlorate is 350-710g/L,
Once electrolytic is carried out to electrolyte and after semipermeable membrane 3 permeates, obtain the first mixed liquor in electrolysis bath 2 and be located at half
The second mixed liquor outside permeable membrane 3；
S3, carries out re-electrolysiss to first mixed liquor and second mixed liquor；
S4, after re-electrolysiss, the solution outside electrolysis bath 2 is the disinfectant solution.
The preparation method of the present embodiment, using re-electrolysiss method, can be such that perchlorate solution is sufficiently electrolysed.
When the once electrolytic and re-electrolysiss, the electric current density of the anode 5 is 12A/cm2, in the electrolysis bath 2
Tank voltage is 6.2V.The electrolysis temperature of the negative electrode 4 is 40 DEG C.Polymer membrane of the semipermeable membrane 3 using porous, hole
Footpath is 0.22 μm.The concentration of the perchlorate aqueous solution is preferably 540mg/L.
Embodiment 3
As shown in figure 1, a kind of disinfectant solution of the present embodiment, the hypochlorite containing 430mg in per liter of disinfectant solution,
The hydroxide of the hypochlorous acid of 45mg, the chlorate of 15mg, the chloride of 3900mg, the perchlorate of 10mg and 0.036mg, it is remaining
Measure as water.The disinfectant solution of the present embodiment, good sterilization effect can especially be used for the sterilization of container.
A kind of preparation method of disinfectant solution as described above, comprises the following steps：
S1, is put into semipermeable membrane 3, in electrolyzer 1 using Ti/TiO2For negative electrode 4, C is anode 5, using the semipermeable membrane 3
Anode 5 is coated with the electrolysis bath 2 to form closing；
S2, adopts the aqueous solution of perchlorate for electrolyte, and the concentration of aqueous solution of the perchlorate is 350-710g/L,
Once electrolytic is carried out to electrolyte and after semipermeable membrane 3 permeates, obtain the first mixed liquor in electrolysis bath 2 and be located at half
The second mixed liquor outside permeable membrane 3；
S3, carries out re-electrolysiss to first mixed liquor and second mixed liquor；
S4, after re-electrolysiss, the solution outside electrolysis bath 2 is the disinfectant solution.
The preparation method of the present embodiment, using re-electrolysiss method, can be such that perchlorate solution is sufficiently electrolysed.
When the once electrolytic and re-electrolysiss, the electric current density of the anode 5 is 13A/cm2, in the electrolysis bath 2
Tank voltage is 6.5V.The electrolysis temperature of the negative electrode 4 is 50 DEG C.Polymer membrane of the semipermeable membrane 3 using porous, hole
Footpath is 0.22 μm.The concentration of the perchlorate aqueous solution is preferably 540mg/L.
The foregoing is only presently preferred embodiments of the present invention, not to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (7)
1. a kind of disinfectant solution, it is characterised in that the hypochlorite containing 410mg-430mg, 35mg- in per liter of disinfectant solution
The hypochlorous acid of 45mg, the chlorate of 12mg-15mg, the chloride of 3700mg-3900mg, the perchlorate of 0mg-10mg and
The hydroxide of 0.034-0.036mg, balance of water.
2. a kind of disinfectant solution according to claim 1, it is characterised in that the secondary chlorine containing 420mg in per liter of disinfectant solution
The hydrogen of hydrochlorate, the hypochlorous acid of 40mg, the chlorate of 13mg, the chloride of 3800mg, the perchlorate of 0mg-10mg and 0.035mg
Oxide, balance of water.
3. a kind of preparation method of disinfectant solution as claimed in claim 1 or 2, it is characterised in that comprise the following steps：
S1, is put into semipermeable membrane (3), in electrolyzer (2) using Ti/TiO2For negative electrode (4), C is anode (5), using described semi-transparent
Anode (5) is coated with film (3) electrolysis bath (2) to form closing；
S2, adopts the aqueous solution of perchlorate for electrolyte, and the concentration of aqueous solution of the perchlorate is 350-710g/L, to electricity
Solution liquid carries out once electrolytic and after semipermeable membrane (3) infiltration, obtains the first mixed liquor in electrolysis bath (2) and is located at half
Permeable membrane (3) the second mixed liquor outward；
S3, carries out re-electrolysiss to first mixed liquor and second mixed liquor；
S4, after re-electrolysiss, is the disinfectant solution positioned at electrolysis bath (2) solution outward.
4. a kind of preparation method of disinfectant solution according to claim 3, it is characterised in that the once electrolytic and re-electrolysiss
When, the electric current density of the anode (5) is 10A/cm2-13A/cm2, the tank voltage in the electrolysis bath (2) is 6V-6.5V.
5. a kind of preparation method of disinfectant solution according to claim 4, it is characterised in that the electrolysis temperature of the negative electrode (4)
For 45 ± 5 DEG C.
6. a kind of preparation method of disinfectant solution according to claim 5, it is characterised in that the aperture of the semipermeable membrane (3) is
0.22μm。
7. a kind of preparation method of disinfectant solution according to any one of claim 3 to 6, it is characterised in that the perchlorate
The concentration of aqueous solution is 540mg/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089182.XA CN106577740A (en) | 2016-11-30 | 2016-11-30 | Disinfectant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089182.XA CN106577740A (en) | 2016-11-30 | 2016-11-30 | Disinfectant and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106577740A true CN106577740A (en) | 2017-04-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611089182.XA Pending CN106577740A (en) | 2016-11-30 | 2016-11-30 | Disinfectant and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821436A (en) * | 2017-10-12 | 2018-03-23 | 合肥柏堰捷成保洁有限公司 | One kind is kept a public place clean with disinfectant and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2301205Y (en) * | 1996-12-19 | 1998-12-23 | 山东长天环保科技有限公司 | Hypochlorous disinfection liquid productor |
| CN1538808A (en) * | 2001-08-03 | 2004-10-20 | ���ø��������˻�ѧ���Ϲɷ�����˾ | Disinfectant solution based on sodium hydrochlorite and process for preparing it |
| CN102487961A (en) * | 2011-12-05 | 2012-06-13 | 刘志强 | Air smell removing disinfectant |
| CN104430509A (en) * | 2014-11-26 | 2015-03-25 | 安徽信灵检验医学科技有限公司 | Raw material and process for preparing disinfectant |
| CN104621181A (en) * | 2015-02-16 | 2015-05-20 | 毕力格巴特尔 | Disinfectant and preparation method and device thereof |
| CN105613573A (en) * | 2014-11-05 | 2016-06-01 | 刘聪 | Disinfectant |
| CN205275711U (en) * | 2015-11-24 | 2016-06-01 | 成都百鸥飞达生物科技有限公司 | Novel half diaphragm time inferior sour sodium generator |
-
2016
- 2016-11-30 CN CN201611089182.XA patent/CN106577740A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2301205Y (en) * | 1996-12-19 | 1998-12-23 | 山东长天环保科技有限公司 | Hypochlorous disinfection liquid productor |
| CN1538808A (en) * | 2001-08-03 | 2004-10-20 | ���ø��������˻�ѧ���Ϲɷ�����˾ | Disinfectant solution based on sodium hydrochlorite and process for preparing it |
| CN102487961A (en) * | 2011-12-05 | 2012-06-13 | 刘志强 | Air smell removing disinfectant |
| CN105613573A (en) * | 2014-11-05 | 2016-06-01 | 刘聪 | Disinfectant |
| CN104430509A (en) * | 2014-11-26 | 2015-03-25 | 安徽信灵检验医学科技有限公司 | Raw material and process for preparing disinfectant |
| CN104621181A (en) * | 2015-02-16 | 2015-05-20 | 毕力格巴特尔 | Disinfectant and preparation method and device thereof |
| CN205275711U (en) * | 2015-11-24 | 2016-06-01 | 成都百鸥飞达生物科技有限公司 | Novel half diaphragm time inferior sour sodium generator |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821436A (en) * | 2017-10-12 | 2018-03-23 | 合肥柏堰捷成保洁有限公司 | One kind is kept a public place clean with disinfectant and preparation method thereof |
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Application publication date: 20170426 |