CN106567521A - Preparation method of environment-friendly facing film high in metallic glossiness - Google Patents
Preparation method of environment-friendly facing film high in metallic glossiness Download PDFInfo
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- CN106567521A CN106567521A CN201610999495.2A CN201610999495A CN106567521A CN 106567521 A CN106567521 A CN 106567521A CN 201610999495 A CN201610999495 A CN 201610999495A CN 106567521 A CN106567521 A CN 106567521A
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- high metal
- metal luster
- facing film
- environmentally friendly
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a preparation method of an environment-friendly facing film high in metallic glossiness. The preparation method of the environment-friendly facing film high in metallic glossiness comprises the following technological steps of (1) preparation of a base material layer, (2) corona treatment, (3) evaporation, (4) coating treatment and (5) facing painting and varnishing. By the adoption of the preparation method, the preparation technology of the environment-friendly facing film high in metallic glossiness is optimized and precisely controlled, after vacuum evaporation of a high-metallic-glossiness decorative layer is conducted on the surface of the environment-friendly base material layer, postprocessing steps comprising coating, painting and vanishing are conducted, and therefore the prepared environment-friendly facing film high in metallic glossiness has the advantages of being free of toxicity and smell, bright in color and strong in metallic texture. Besides, according to the prepared environment-friendly facing film high in metallic glossiness, the light reflection rate reaches 97% or above, the surface tension is 38-40 m N/m, the surface hardness is 3-4 H, and the comprehensive performance is good.
Description
Technical field
The present invention relates to facing film field, the preparation method of the environmentally friendly facing film of more particularly to a kind of high metal luster.
Background technology
Fitted imitative metal decoration facial mask composite board be widely used in the households such as hotel, cabinet decoration.Imitative metal decoration
The metallic luster of facial mask high light reflectivity has vivid gorgeous brilliant aesthetic effect, while its folding resistance, toughness, moisture resistance are good
It is good, it is excellent to the barrier of gas, water vapour or smell etc., and possess certain electric conductivity, accumulation of static electricity will not be produced,
The features such as reducing dust suction, makes imitative metal decoration facial mask become a kind of function admirable, economical and beautiful new finishing material, increasingly for
Consumers in general are received, and in household field critical role is occupied.
Chinese patent《Artificial decorative materials》（Authorization Notice No. 201249620Y）A kind of artificial decorative materials are disclosed, its
The decorative layer with metal-like is formed to substrate layer using the water-soluble glue water layer and aluminum transfer on polyester film.So
And there is poor adhesion, defect rate etc., and complicated process of preparation in the decorative layer for so being formed by transfer, preparation cost
Height, is unfavorable for large-scale production.
Another kind of traditional imitative metal finish membrane preparation method is that printing is coated with bronze, silver powder to realize in PVC film, is printed
The continuity and compactness that the metal powder of brush is distributed on base material is inadequate, texture distortion, it is impossible to reach client to imitating metal finish
The cosmetic requirement of film.
The content of the invention
It is an object of the present invention to be directed to above-mentioned the deficiencies in the prior art, there is provided a kind of environmentally friendly facing of high metal luster
The preparation method of film.
The technical solution used in the present invention is：A kind of preparation method of the environmentally friendly facing film of high metal luster, it includes
Following processing step：
（1）It is prepared by substrate layer：According to the weight percentage of raw materials by 50 ~ 60% calcium carbonate powder, 20 ~ 25% polyethylene, 10 ~
Substrate layer is formed using calendering blowing blown film after 15% polypropylene, 10 ~ 15% magnesia, the mixing of 1 ~ 5% auxiliary agent；
（2）Sided corona treatment：Sided corona treatment, control sided corona treatment roller and electrode gap are carried out on a wherein surface of substrate layer
2mm, voltage is controlled in the range of 6500 ~ 8000V；
（3）Evaporation：By step（2）Base material after gained sided corona treatment is placed in vacuum chamber, closes vacuum chamber, surely
Reciprocal of duty cycle control reaches 4 × 10- 4During more than mba, evaporation boat is warming up to into 1300～1400 DEG C, purity is again then 99.9%
Aluminium wire is continuously delivered on evaporation boat, aluminium wire is continuously melted on evaporation boat, is evaporated to the base material layer surface of Jing sided corona treatments
On, cooling obtains high metal luster decorative layer；
（4）Coating process：High metal luster decor surface coat one layer of water-soluble polyester resin solution, after through baking oven dry
Dry-cure, obtains resin treatment layer；
（5）Facing printing, glazing：Clear aqueous ink is printed on resin treatment layer, one layer of aqueous poly- ammonia is coated with after solidification
Ester resin solution, Jing oven for drying winding, rewinding trimming obtains finished product.
Specifically, substrate layer of the invention is prepared from by environment-friendly materials, and it contains substantial amounts of non-polar material and weak pole
Property material, it is relatively low to be coextruded the film surface energy come, and such as directly carries out vacuum evaporation on its surface, its high metal luster decorative layer
Firmness is not strong enough, and high metal luster decorative layer is easily peeled off, and is easily caused defect rate in production process is high, and life of product is short etc.
Quality problems.Therefore, sided corona treatment is significant.When voltage control is in the range of 6500 ~ 8000V, the table of substrate layer
Face tension force and mechanical performance are greatly improved.
As the further improvement of such scheme, step（1）Described auxiliary agent includes titanium dioxide, silica and fat
Sour powder.
As the further improvement of such scheme, step（2）Described sided corona treatment adopts 6 tip electrodes, and corona frequency is
30kHz, the sided corona treatment roller speed of service is 25m/min.Specifically, by corona frequency and the sided corona treatment rod speed of service
Regulation and control, the surface tension that can make substrate layer reaches 38 ~ 40 m N/m.
As the further improvement of such scheme, step（3）During the evaporation, control substrate layer coiling speed exists
In the range of 250 ~ 300m/min, the speed of conveying aluminium wire is controlled in the range of 0.6 ~ 0.8m/min, can make the Gao Jin of vacuum evaporation
Category plate finish layer evenly with it is smooth, so as to improve its light reflectivity.
As the further improvement of such scheme, step（3）During the evaporation, high metal luster decorative layer is controlled
Thickness is 500～600.Specifically, its surface smoothness of blocked up decorative layer is poor, and its uniformity of excessively thin decorative layer compared with
Difference, thus can not all reach excellent light reflection effect.It is 500～600 that the present invention controls the thickness of high metal luster decorative layer
, so that its light reflectivity reaches more than 97%.
As the further improvement of such scheme, step（4）In the coating procedure control coating fluid viscosity 9.5～
11s（Apply 4# cups）In the range of, coating speed is 80m/min, and coated weight is 3～3.5g/m2。
As the further improvement of such scheme, step（5）Described in clear aqueous ink press raw material weight percentage
Meter is made up of following component：Transparent yellow pigment 13～15%, waterborne polyurethane resin solution 55～58%, water 18～20%, industrial wine
Essence 4～5%, propylene glycol monomethyl ether 2.5%, dispersant 1%, modified silicon class defoamer 0.3%, alkynol class moistening flatting agent 0.2% and PH are adjusted
Section agent 0.2%.Further, wherein the pigment particle size≤300nm of transparent yellow pigment.Specifically, clear aqueous ink is to high metal
Plate finish layer plays a protective role, while good surface tension can be kept.The clear aqueous ink that the present invention is adopted, while
Solve the adhesion problem that ink is printed on high metal luster decorative layer.
As the further improvement of such scheme, step（5）Printing plate cylinder used in middle printing process is 200 mesh, is printed
Brush speed is 90 ~ 100m/min.
As the further improvement of such scheme, step（5）Control coating fluid viscosity is in 10～12s in the coating procedure
（Apply 4# cups）In the range of, coating speed is 80m/min, and coated weight is 3.5～4g/m2。
A kind of environmentally friendly facing film of high metal luster as above, the light reflectivity of the environmentally friendly facing film is more than 97%,
Surface tension is 38 ~ 40 m N/m, and case hardness is 3 ~ 4H.
The invention has the beneficial effects as follows：The present invention by the environmentally friendly facing film preparation technique to high metal luster improve and
Precision control, is coated, prints, glazing after carrying out vacuum evaporation high metal luster decorative layer in the base material layer surface of environmental protection
Deng post processing, the environmentally friendly facing film for making the high metal luster for preparing of the invention has nonpoisonous and tasteless, bright in luster, metallic
The strong advantage of sense, while its light reflectivity reaches more than 97%, surface tension is 38 ~ 40 m N/m, and case hardness is 3 ~ 4H, is had
There is good combination property.
Specific embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.The present invention will be further described it is emphasized that embodiment is only intended to be necessary here, it is impossible to is interpreted as to this
The restriction of invention protection domain, art person skilled in the art, according to the non-intrinsically safe that foregoing invention content is made to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of preparation method of the environmentally friendly facing film of high metal luster, it is comprised the technical steps that：
（1）It is prepared by substrate layer：According to the weight percentage of raw materials by 50% calcium carbonate powder, 25% polyethylene, poly- the third of 10%
Alkene, 12% magnesia, the mixing of 2% auxiliary agent, wherein auxiliary agent includes titanium dioxide, silica and aliphatic acid powder, afterwards using pressure
Prolong blowing blown film and form substrate layer；
（2）Sided corona treatment：Sided corona treatment is carried out on a wherein surface of substrate layer, using 6 tip electrodes, sided corona treatment roller is controlled
With electrode gap 2mm, control voltage is 6500V, and corona frequency is 30kHz, and the sided corona treatment roller speed of service is 25m/min, electric
It is dizzy process after substrate layer surface tension be 38mN/m, greatly improve the firm of high metal luster decorative layer after vacuum evaporation
Degree；
（3）Evaporation：By step（2）Base material after gained sided corona treatment is placed in vacuum chamber, closes vacuum chamber, surely
Reciprocal of duty cycle control reaches 4 × 10- 4During more than mba, evaporation boat is warming up to into 1300 DEG C, then again the aluminium wire company that purity is 99.9%
Continuous to deliver on evaporation boat, it is 0.65m/min to control substrate layer coiling speed for 260m/min, the speed for controlling to convey aluminium wire, is made
Aluminium wire continuously melts on evaporation boat, is evaporated in the base material layer surface of Jing sided corona treatments, cooling, obtains high metal luster decoration
Layer, its thickness is 500；
（4）Coating process：One layer of water-soluble polyester resin solution is coated in high metal luster decor surface, control coating liquid glues
Degree is in 9.8s（Apply 4# cups）In the range of, coating speed is 80m/min, and coated weight is 3.1g/m2, after through oven for drying process,
Obtain resin treatment layer；
（5）Facing printing, glazing：Clear aqueous ink is printed on resin treatment layer, wherein the clear aqueous ink is by original
Material percentage by weight meter is by the transparent yellow pigment 13% that particle diameter is 300nm, waterborne polyurethane resin solution 55%, water 18%, industrial wine
Essence 5%, propylene glycol monomethyl ether 2.5%, dispersant 1%, modified silicon class defoamer 0.3%, alkynol class moistening flatting agent 0.2% and PH are adjusted
Agent 0.2% is constituted, and the printing plate cylinder used in printing process is 200 mesh, and print speed printing speed is 90m/min；Clear aqueous ink solidification
After be coated with one layer of waterborne polyurethane resin solution, in coating procedure control coating fluid viscosity in 10s（Apply 4# cups）In the range of, apply
It is 80m/min to cover speed, and coated weight is 4g/m2, the winding of Jing oven for drying, rewinding trimming obtains finished product.
The environmentally friendly facing film of the high metal luster that above-described embodiment 1 is prepared into is detected that it is 97% to obtain light reflectivity,
High metal luster decorative layer peels off area is 0%, and case hardness is 4H.
Embodiment 2
A kind of preparation method of the environmentally friendly facing film of high metal luster, it is comprised the technical steps that：
（1）It is prepared by substrate layer：According to the weight percentage of raw materials by 60% calcium carbonate powder, 20% polyethylene, poly- the third of 15%
Alkene, 15% magnesia, the mixing of 5% auxiliary agent, wherein auxiliary agent includes titanium dioxide, silica and aliphatic acid powder, afterwards using pressure
Prolong blowing blown film and form substrate layer；
（2）Sided corona treatment：Sided corona treatment is carried out on a wherein surface of substrate layer, using 6 tip electrodes, sided corona treatment roller is controlled
With electrode gap 2mm, control voltage is 7000V, and corona frequency is 30kHz, and the sided corona treatment roller speed of service is 25m/min, electric
It is dizzy process after substrate layer surface tension be 39mN/m, greatly improve the firm of high metal luster decorative layer after vacuum evaporation
Degree；
（3）Evaporation：By step（2）Base material after gained sided corona treatment is placed in vacuum chamber, closes vacuum chamber, surely
Reciprocal of duty cycle control reaches 4 × 10- 4During more than mba, evaporation boat is warming up to into 1350 DEG C, then again the aluminium wire company that purity is 99.9%
Continuous to deliver on evaporation boat, it is 0.8m/min to control substrate layer coiling speed for 300m/min, the speed for controlling to convey aluminium wire, makes aluminium
Silk continuously melts on evaporation boat, is evaporated in the base material layer surface of Jing sided corona treatments, cools down, and obtains high metal luster decoration
Layer, its thickness is 560；
（4）Coating process：One layer of water-soluble polyester resin solution is coated in high metal luster decor surface, control coating liquid glues
Degree is in 10s（Apply 4# cups）In the range of, coating speed is 80m/min, and coated weight is 3.5g/m2, after through oven for drying process, obtain
Resin treatment layer；
（5）Facing printing, glazing：Clear aqueous ink is printed on resin treatment layer, wherein the clear aqueous ink is by original
Material percentage by weight meter is by the transparent yellow pigment 15% that particle diameter is 200nm, waterborne polyurethane resin solution 58%, water 20%, industrial wine
Essence 4%, propylene glycol monomethyl ether 2.5%, dispersant 1%, modified silicon class defoamer 0.3%, alkynol class moistening flatting agent 0.2% and PH are adjusted
Agent 0.2% is constituted, and the printing plate cylinder used in printing process is 200 mesh, and print speed printing speed is 100m/min；Clear aqueous ink is consolidated
One layer of waterborne polyurethane resin solution is coated with after change, control coating fluid viscosity is in 12s in coating procedure（Apply 4# cups）In the range of,
Coating speed is 80m/min, and coated weight is 3.5g/m2, the winding of Jing oven for drying, rewinding trimming obtains finished product.
The environmentally friendly facing film of the high metal luster that above-described embodiment 1 is prepared into is detected that obtaining light reflectivity is
97.6%, high metal luster decorative layer peels off area is 0%, and case hardness is 3.8H.
Embodiment 3
A kind of preparation method of the environmentally friendly facing film of high metal luster, it is comprised the technical steps that：
（1）It is prepared by substrate layer：According to the weight percentage of raw materials by 56% calcium carbonate powder, 23% polyethylene, poly- the third of 12%
Alkene, 10% magnesia, the mixing of 1% auxiliary agent, wherein auxiliary agent includes titanium dioxide, silica and aliphatic acid powder, afterwards using pressure
Prolong blowing blown film and form substrate layer；
（2）Sided corona treatment：Sided corona treatment is carried out on a wherein surface of substrate layer, using 6 tip electrodes, sided corona treatment roller is controlled
With electrode gap 2mm, control voltage is 8000V, and corona frequency is 30kHz, and the sided corona treatment roller speed of service is 25m/min, electric
It is dizzy process after substrate layer surface tension be 40mN/m, greatly improve the firm of high metal luster decorative layer after vacuum evaporation
Degree；
（3）Evaporation：By step（2）Base material after gained sided corona treatment is placed in vacuum chamber, closes vacuum chamber, surely
Reciprocal of duty cycle control reaches 4 × 10- 4During more than mba, evaporation boat is warming up to into 1400 DEG C, then again the aluminium wire company that purity is 99.9%
Continuous to deliver on evaporation boat, it is 0.72m/min to control substrate layer coiling speed for 300m/min, the speed for controlling to convey aluminium wire, is made
Aluminium wire continuously melts on evaporation boat, is evaporated in the base material layer surface of Jing sided corona treatments, cooling, obtains high metal luster decoration
Layer, its thickness is 600；
（4）Coating process：One layer of water-soluble polyester resin solution is coated in high metal luster decor surface, control coating liquid glues
Degree is in 11s（Apply 4# cups）In the range of, coating speed is 80m/min, and coated weight is 3g/m2, after through oven for drying process, must set
Fat process layer；
（5）Facing printing, glazing：Clear aqueous ink is printed on resin treatment layer, wherein the clear aqueous ink is by original
Material percentage by weight meter is by the transparent yellow pigment 15% that particle diameter is 150nm, waterborne polyurethane resin solution 55%, water 20%, industrial wine
Essence 3%, propylene glycol monomethyl ether 2.5%, dispersant 1%, modified silicon class defoamer 0.3%, alkynol class moistening flatting agent 0.2% and PH are adjusted
Agent 0.2% is constituted, and the printing plate cylinder used in printing process is 200 mesh, and print speed printing speed is 100m/min；Clear aqueous ink is consolidated
One layer of waterborne polyurethane resin solution is coated with after change, control coating fluid viscosity is in 10s in coating procedure（Apply 4# cups）In the range of,
Coating speed is 80m/min, and coated weight is 4g/m2, the winding of Jing oven for drying, rewinding trimming obtains finished product.
The environmentally friendly facing film of the high metal luster that above-described embodiment 1 is prepared into is detected that obtaining light reflectivity is
98.6%, high metal luster decorative layer peels off area is 0%, and case hardness is 3.6H.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (10)
1. the preparation method of the environmentally friendly facing film of a kind of high metal luster, it is characterised in that comprise the technical steps that：
（1）It is prepared by substrate layer：According to the weight percentage of raw materials by 50 ~ 60% calcium carbonate powder, 20 ~ 25% polyethylene, 10 ~
Substrate layer is formed using calendering blowing blown film after 15% polypropylene, 10 ~ 15% magnesia, the mixing of 1 ~ 5% auxiliary agent；
（2）Sided corona treatment：Sided corona treatment, control sided corona treatment roller and electrode gap are carried out on a wherein surface of substrate layer
2mm, voltage is controlled in the range of 6500 ~ 8000V；
（3）Evaporation：By step（2）Base material after gained sided corona treatment is placed in vacuum chamber, closes vacuum chamber, surely
Reciprocal of duty cycle control reaches 4 × 10- 4During more than mba, evaporation boat is warming up to into 1300～1400 DEG C, purity is again then 99.9%
Aluminium wire is continuously delivered on evaporation boat, aluminium wire is continuously melted on evaporation boat, is evaporated to the base material layer surface of Jing sided corona treatments
On, cooling obtains high metal luster decorative layer；
（4）Coating process：High metal luster decor surface coat one layer of water-soluble polyester resin solution, after through baking oven dry
Dry-cure, obtains resin treatment layer；
（5）Facing printing, glazing：Clear aqueous ink is printed on resin treatment layer, one layer of aqueous poly- ammonia is coated with after solidification
Ester resin solution, Jing oven for drying winding, rewinding trimming obtains finished product.
2. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（1）Described auxiliary agent includes titanium dioxide, silica and aliphatic acid powder.
3. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（2）Described sided corona treatment adopts 6 tip electrodes, and corona frequency is 30kHz, and the sided corona treatment roller speed of service is 25m/min.
4. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（3）During the evaporation, control substrate layer coiling speed is in the range of 250 ~ 300m/min, the speed of control conveying aluminium wire exists
In the range of 0.6 ~ 0.8m/min.
5. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1 or 4, it is characterised in that：
Step（3）During the evaporation, the thickness for controlling high metal luster decorative layer is 500～600.
6. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（4）Control coating fluid viscosity is in 9.5～11s in the coating procedure（Apply 4# cups）In the range of, coating speed is 80m/min, is applied
The amount of covering is 3～3.5g/m2。
7. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（5）Described in clear aqueous ink be made up of following component according to the weight percentage of raw materials：Transparent yellow pigment 13～15%, water
Property polyurethane resin solution 55～58%, water 18～20%, industrial alcohol 4～5%, propylene glycol monomethyl ether 2.5%, dispersant 1%, be modified
Silicon class defoamer 0.3%, alkynol class moistening flatting agent 0.2% and PH conditioning agents 0.2%.
8. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1 or 7, it is characterised in that：
Step（5）Printing plate cylinder used in middle printing process is 200 mesh, and print speed printing speed is 90 ~ 100m/min.
9. the preparation method of the environmentally friendly facing film of a kind of high metal luster according to claim 1, it is characterised in that：Step
（5）Control coating fluid viscosity is in 10～12s in the coating procedure（Apply 4# cups）In the range of, coating speed is 80m/min, coating
Measure as 3.5～4g/m2。
10. a kind of environmentally friendly facing film of the high metal luster as described in claim 1 ~ 9, it is characterised in that：The environmentally friendly facing film
Light reflectivity be more than 97%, surface tension be 38 ~ 40 m N/m, case hardness be 3 ~ 4H.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107892503A (en) * | 2017-10-16 | 2018-04-10 | 广东天元汇邦新材料股份有限公司 | A kind of environmentally-friendly decorative paper and preparation method thereof |
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| CN106567521B (en) | 2019-02-05 |
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Denomination of invention: Preparation method of environmental friendly decorative facial mask with high metallic luster Effective date of registration: 20220507 Granted publication date: 20190205 Pledgee: China Co. truction Bank Corp Foshan branch Pledgor: GUANGDONG TIANYUAN HUIBANG NEW MATERIAL CO.,LTD. Registration number: Y2022980005179 |