CN106567256A - Modified polysiloxane antistatic agent - Google Patents
Modified polysiloxane antistatic agent Download PDFInfo
- Publication number
- CN106567256A CN106567256A CN201610953130.6A CN201610953130A CN106567256A CN 106567256 A CN106567256 A CN 106567256A CN 201610953130 A CN201610953130 A CN 201610953130A CN 106567256 A CN106567256 A CN 106567256A
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- CN
- China
- Prior art keywords
- parts
- antistatic additive
- modified
- siloxane
- modified polyorganosiloxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polysiloxane Polymers 0.000 title claims abstract description 25
- 239000002216 antistatic agent Substances 0.000 title abstract description 4
- 229920001296 polysiloxane Polymers 0.000 title abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 18
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004166 Lanolin Substances 0.000 claims abstract description 9
- 229940039717 lanolin Drugs 0.000 claims abstract description 9
- 235000019388 lanolin Nutrition 0.000 claims abstract description 9
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 9
- 239000011592 zinc chloride Substances 0.000 claims abstract description 9
- 239000000654 additive Substances 0.000 claims description 27
- 230000000996 additive effect Effects 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
- 238000005984 hydrogenation reaction Methods 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 150000001336 alkenes Chemical group 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 13
- 239000004744 fabric Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 239000012209 synthetic fiber Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicon Polymers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a modified polysiloxane antistatic agent, which comprises the following components in parts by weight: 100 parts of modified polymethyl siloxane, 15 to 20 parts of terminal hydroxyl dimethyl siloxane, 2 to 5 parts of water soluble lanolin, 7 to 12 parts of critic acid, 30 to 40 parts of zinc chloride, and 50 to 80 parts of water. The antistatic agent has a good antistatic performance and a high adhesion force, and can maintain a good antistatic performance after several times of water washing.
Description
Technical field：
The present invention relates to textile auxiliary field, more particularly to polysiloxane-based antistatic additive.
Background technology：
In daily life, the generation of electrostatic phenomenon is carried out and sees not fresh, in the process of textile fabric, can because fiber with
Friction between fiber or fiber and machine and produce electrostatic.Especially the insulating properties of synthetic fibers itself is very strong, generation
Electrostatic charge is difficult to spread, and this electrostatic there are problems that on fiber can bring a lot.Such as, tow can be caused in spinning process
Diverging, it is difficult to wind, produces lousiness, the phenomenon of fracture of wire；The problem of sleave then occurs in drying course, surpasses in cutting-off process
Long over-length fibre can increase.Say for another example and occur that lap layering is unclear in cotton mill, web is unstable, occurs when knitting disconnected
First order issue.Also, easily absorption dust also occurs during textile use, easily the problem of winding, affects aesthetics.
So as to the presence of electrostatic can cause the production efficiency of synthetic fibers factory and spinnery to reduce, the limited simultaneously shadow of product quality
Ring using effect.Therefore, the antistatic property for increasing synthetic fibers is particularly significant.
In order to avoid electrostatic is assembled in fiber, electrostatic produced in fiber is evacuated as early as possible, typically there are two kinds of solutions
Method：A kind of is conductive component to be introduced in the production process of synthetic fibers or carries out glycerol polymerization to carry from hydrophilic monomer
The hygroscopicity of high microsteping, so as to eliminate electrostatic；Another kind of method is exactly that fiber is arranged using antistatic additive, improves fiber
Polarity or hygroscopicity, this method is simple to operate, restricted little, is a kind of current widely used antistatic method.
It is coated with the fiber surface after one layer of antistatic additive, therefore fabric face there can be the feel of flexible smooth, together
When can reduce coefficient of friction, so as to reduce the electrostatic of generation.The water-wash resistance of antistatic additive is not good, easily takes off after repeatedly washing
Fall, but if using the compound of reactivity, with fiber Covalent bonding together is formed at high temperature, can effectively improve antistatic
The washing fastness of agent.
Chinese patent CN201510120620.3 discloses a kind of preparation method of fabric lining composite antistatic agent, and this is answered
Close antistatic additive include butanol phosphate antistatic additive, superbrnaching end-hydroxy antistatic additive, end carboxyl super branched antistatic additive with
And the hyperbranched antistatic additive of end quaternary ammonium salt.It is simple that the antistatic additive prepares method of putting, prepare antistatic additive have it is good
Anti- electric effect, but its washability is not good, and the persistence on fabric is not good, so improving the water-wash resistance of antistatic additive
Extremely it is necessary.
The content of the invention：
It is an object of the invention to provide a kind of modified polyorganosiloxane class antistatic additive, the antistatic additive has good anti-quiet
Electrical property, attachment degree is high, and through repeatedly washing preferable antistatic property still can be kept.
For achieving the above object, the present invention is employed the following technical solutions：
A kind of modified polyorganosiloxane class antistatic additive, in parts by weight, including following components：
100 parts of modified polymethyl siloxane, hydroxyl-terminated injecting two methyl siloxane 15-20 parts, water-soluble lanolin 2-5, lemon
Lemon acid 7-12 parts, zinc chloride 30-40 parts, water 50-80 parts.
The polymethyl siloxane that is wherein modified is part hydrogenation type polymethoxy hydrogen siloxane and pi-allyl containing aminoethyl
It is obtained after polyether reactant.
As the preferred of above-mentioned technical proposal, quilt in the part hydrogenation type polymethoxy hydrogen siloxane containing aminoethyl
The modified proportion of aminopropyl is 20%-30%.
As the preferred of above-mentioned technical proposal, hydrogen in the part hydrogenation type polymethoxy hydrogen siloxane containing aminoethyl
It is 30% to change chlorine.
As the preferred of above-mentioned technical proposal, the part hydrogenation type polymethoxy hydrogen siloxane containing aminoethyl and alkene
The mass ratio of propyl group polyethers is 1:4.
Used as the preferred of above-mentioned technical proposal, the allyl polyether is allyl polyethenoxy ether or pi-allyl polyoxy third
One or two mixtures in alkene ether.
Used as the preferred of above-mentioned technical proposal, the allyl polyether is allyl polyethenoxy ether and pi-allyl polyoxy third
Alkene ether mass ratio is 3:1 mixture.
Used as the preferred of above-mentioned technical proposal, the modified polyorganosiloxane class antistatic additive can be used alone also can be with dye
Material is used with bath.
The invention has the advantages that, the modified polymethyl siloxane that the present invention is used, using aminoethyl and polyethers
It is simultaneously modified, can effectively improve the antistatic effect of fabric after fabric use, and keep the pliability of fabric, maintain compared with
Comfortable feel.Simultaneously modified polymethyl siloxane can react with hydroxyl-terminated injecting two methyl siloxane, be formed in fabric face
Network structure, so as to improve the attachment degree of antistatic additive.The Jing antistatic additive arrange after fabric through long-time repeatedly
After washing, preferable antistatic property still can be kept.
Specific embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
100 parts of modified polymethyl siloxane, 15 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble 2 parts of lanolin, citric acid
7 parts, 30 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Embodiment 2
100 parts of modified polymethyl siloxane, 16 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble 4 parts of lanolin, citric acid
10 parts, 35 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Embodiment 3
100 parts of modified polymethyl siloxane, 17 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble lanolin 5, citric acid 9
Part, 40 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Embodiment 4
100 parts of modified polymethyl siloxane, 18 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble 3 parts of lanolin, citric acid
8 parts, 30 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Embodiment 5
100 parts of modified polymethyl siloxane, 19 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble 5 parts of lanolin, citric acid
12 parts, 35 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Embodiment 6
100 parts of modified polymethyl siloxane, 20 parts of hydroxyl-terminated injecting two methyl siloxane, water-soluble 4 parts of lanolin, citric acid
11 parts, 40 parts of zinc chloride, 60 parts of water.
After mentioned component is mixed, 5 times of dilute with water stirs that polyster fibre is put in mixed liquor and pads, afterwards
80-90 DEG C is warming up to after 50-60 DEG C of low temperature drying of taking-up persistently process 2h.
Antistatic detection is carried out to the polyster fibre obtained by various embodiments above, data are as shown in table 1, through 20 times
As shown in table 2, wherein comparative example is the detection data of undressed polyster fibre to data after water washed：
Table one
Table two
Claims (7)
1. a kind of modified polyorganosiloxane class antistatic additive, it is characterised in that in parts by weight, including following components：
100 parts of modified polymethyl siloxane, hydroxyl-terminated injecting two methyl siloxane 15-20 parts, water-soluble lanolin 2-5, citric acid
7-12 parts, zinc chloride 30-40 parts, water 50-80 parts.
The polymethyl siloxane that is wherein modified is part hydrogenation type polymethoxy hydrogen siloxane and allyl polyether containing aminoethyl
It is obtained after reaction.
2. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The portion containing aminoethyl
The proportion being modified by aminopropyl in hydrogenation type polymethoxy hydrogen siloxane is divided to be 20%-30%.
3. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The portion containing aminoethyl
Divide in hydrogenation type polymethoxy hydrogen siloxane and hydrogenate chlorine for 30%.
4. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The portion containing aminoethyl
Hydrogenation type polymethoxy hydrogen siloxane is divided to be 1 with the mass ratio of allyl polyether:4.
5. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The allyl polyether is alkene
One or two mixtures in propyl group APEO or pi-allyl polyethenoxy ether.
6. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The allyl polyether is alkene
Propyl group APEO is 3 with pi-allyl polyethenoxy ether mass ratio:1 mixture.
7. modified polyorganosiloxane class antistatic additive according to claim 1, it is characterised in that：The modified polyorganosiloxane class
Antistatic additive can be used alone also can be used with one-bath dyeing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610953130.6A CN106567256A (en) | 2016-11-03 | 2016-11-03 | Modified polysiloxane antistatic agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610953130.6A CN106567256A (en) | 2016-11-03 | 2016-11-03 | Modified polysiloxane antistatic agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106567256A true CN106567256A (en) | 2017-04-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610953130.6A Pending CN106567256A (en) | 2016-11-03 | 2016-11-03 | Modified polysiloxane antistatic agent |
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| Country | Link |
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| CN (1) | CN106567256A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108560265A (en) * | 2018-04-25 | 2018-09-21 | 常州市蓝勖化工有限公司 | A kind of preparation method of antistatic agent |
| CN109056338A (en) * | 2018-06-06 | 2018-12-21 | 苏州印丝特纺织数码科技有限公司 | A kind of polysiloxane type antistatic finishing agent and preparation method thereof |
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| JP2007031625A (en) * | 2005-07-29 | 2007-02-08 | Jsr Corp | Conductive particle-containing curable composition, cured product thereof, and laminate |
| CN104233821A (en) * | 2013-06-17 | 2014-12-24 | 上海氟聚化学产品有限公司 | Modified polysiloxane softening agent and preparation method thereof |
| CN105648127A (en) * | 2016-02-16 | 2016-06-08 | 北京泛博清洁技术研究院有限公司 | Environment-friendly antibacterial fur after-finishing agent and preparation method thereof |
-
2016
- 2016-11-03 CN CN201610953130.6A patent/CN106567256A/en active Pending
Patent Citations (3)
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|---|---|---|---|---|
| JP2007031625A (en) * | 2005-07-29 | 2007-02-08 | Jsr Corp | Conductive particle-containing curable composition, cured product thereof, and laminate |
| CN104233821A (en) * | 2013-06-17 | 2014-12-24 | 上海氟聚化学产品有限公司 | Modified polysiloxane softening agent and preparation method thereof |
| CN105648127A (en) * | 2016-02-16 | 2016-06-08 | 北京泛博清洁技术研究院有限公司 | Environment-friendly antibacterial fur after-finishing agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108560265A (en) * | 2018-04-25 | 2018-09-21 | 常州市蓝勖化工有限公司 | A kind of preparation method of antistatic agent |
| CN109056338A (en) * | 2018-06-06 | 2018-12-21 | 苏州印丝特纺织数码科技有限公司 | A kind of polysiloxane type antistatic finishing agent and preparation method thereof |
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Application publication date: 20170419 |
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