CN106566583A - High octane number vehicle fuel capable of replacing gasoline, and preparation method thereof - Google Patents

High octane number vehicle fuel capable of replacing gasoline, and preparation method thereof Download PDF

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Publication number
CN106566583A
CN106566583A CN201510656960.8A CN201510656960A CN106566583A CN 106566583 A CN106566583 A CN 106566583A CN 201510656960 A CN201510656960 A CN 201510656960A CN 106566583 A CN106566583 A CN 106566583A
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China
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molecular formula
mtbe
chemical formula
acetone
dichloropropane
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李�荣
钟晓东
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Abstract

The invention relates to a high octane number vehicle fuel capable of replacing gasoline, and a preparation method thereof, wherein the high octane number vehicle fuel comprises, by mass, 1 part of mixed aromatic hydrocarbon, 1 part of MTBE, 1 part of propane, 1 part of dichloropropane, 1 part of acetone, and 1 part of a 501 preservative. The preparation method comprises: selecting and purchasing 12% of high-quality mixed aromatic hydrocarbon (molecular formula of C7H8) 12%, 10% of MTBE (chemical formula of C5H12O), 35% of propane (chemical formula of C3H8), 39% of dichloropropane (molecular formula of C3H6CI2), 4% of acetone (chemical formula of CH3COCH3), and 0.2% of a 501 preservative (molecular formula of C15H24O), and respectively loading in respective material storage tanks so as to be spare; compressing the propane into the liquid state by using a compressor, and storing in a pressure tank to obtain a material a; sequentially mixing the acetone, the MTBE, the mixed aromatics and the 501 preservative, and uniformly stirring for about half an hour to obtain a material b; carrying out mixing stirring on the dichloropropane and the material a for half an hour to obtain a material c; and uniformly mixing the material c and the material b, standing for 30 min to obtain a finished product fuel, loading into a finished product tank, and sealing so as to be spare.

Description

A kind of high-octane rating vehicle fuel of replacing gasoline and preparation method
First, technical field
The present invention relates to fuel technology field, and in particular to a kind of high-octane rating vehicle fuel of replacing gasoline, The high-octane rating vehicle fuel for particularly using for all types of automobiles and the field of preparation method.
2nd, background technology
Jing consults relevant information, and China is a rich coal, oil-poor and have one of country of gas, with national Jing The fast development of Ji, automobile pollution is also constantly rising, and shows according to relevant information, automobile number in 2012 Amount is more than 2.4 hundred million (wherein 1.2 hundred million are strong car), it is contemplated that will reach 3.3 to the year two thousand twenty total vehicle Hundred million, the year two thousand thirty will reach 4.3-5 hundred million, it can be seen that, following 20 years China will face sternness Energy problem, if or else changing the situation that the energy is overly dependent upon for a long time natural oil, will seriously undermine the energy The ability of sustainable development, if the fuel for motor vehicle of China excessively dependence on import oil, it will have influence on state The alternative of border political realms decision-making, therefore, the searching to oil replacement fuel, to rapid economic development China seem even more important and urgent.
At present, domestic petroleum imbalance between supply and demand day aobvious protrusion, increases year by year the interdependency of import, cut-off 2015 The first half of the year in year, China's country's oil consumption demand has broken through 5.3 hundred million tons, and to the end of the year 2015 5.8 will be reached Hundred million tons, it is contemplated that will break through 7.2 hundred million tons to the year two thousand twenty, and will even up to break through 7.8 hundred million tons, CNPC External dependence degree thus constantly expand, be possible to be up to 70% to the year two thousand twenty, but, China's natural gas Gross reserves is 38 tcms, coal gross reserves is 114,500,000,000 tons, therefore, popularization and application high-octane rating Vehicle fuel is used as the supplement of petroleum resources, has had very important strategic importance to China.
Show according to documents and materials, on existing market some synthetic fuels are occurred in that, made using a high proportion of methanol Based on fuel, component and mass parts are added than upper unreasonable, imperfection, non-science, so as to cause skill The deficiency of art content, by this component and mass parts than the product produced, in actual use, makes Not enough into engine power, summer is affected by vapour lock, can also cause excessive oil consumption, prevents electromotor from just Often work, based on the defect of prior art, is now badly in need of a kind of not only energy-conservation, not only clean environment firendly but also can solve The high-octane rating vehicle fuel of problem is stated, existing technical bottleneck is made up with this, for this purpose, we pass through Repeatedly tune side, test, preparation and practice, and the utilization on all types of automobiles, achieve one kind finally Not only energy-conservation but also the high-octane rating vehicle fuel of clean environment firendly.
3rd, the content of the invention
It is an object of the invention to provide the high-octane rating vehicle fuel and preparation method of a kind of replacing gasoline, to solve Certainly all types of automobiles reach both powerfuls and energy-conservation, clear during using high-octane rating vehicle fuel Clean, environmentally friendly problem.The purpose of the present invention is realized by technical scheme below:The high-octane rating vehicle fuel is With common industrial chemicals and fuel additive as raw material, with it is cheap, not stratified, without vapour lock, nothing Cigarette is tasteless, non-corrosiveness, energy-conserving and environment-protective, octane number are high, can with the GB gasoline for occurring on the market at present, The mixing of methanol gasoline, ethanol petrol and alcohol-based fuel arbitrary proportion, its burning is clean, powerful, It is stable, it is not required to clean electromotor, the harmful substance of discharge is reduced than the existing merchantable gasoline for occurring on the market More than 52%, meet the People's Republic of China (PRC)《Energy-conserving and environment-protective standard》Relevant requirement.
To reach the purpose of foregoing invention, the technical solution adopted in the present invention is:A kind of replacing gasoline is provided High-octane rating vehicle fuel, it is characterised in that each component and its matter of the high-octane rating vehicle fuel Amount part is than as follows:
1 part of BTX aromatics (molecular formula is C7H8);
1 part of MTBE (chemical formula is C5H120);
1 part of propane (chemical formula is C3H8);
1 part of dichloropropane (molecular formula is C3H6CI2);
1 part of acetone (chemical formula is CH3COCH3);
1 part of 501 preservative (molecular formula is C15H240).
A kind of high-octane rating vehicle fuel and preparation method of above-mentioned replacing gasoline, it is characterised in that the side Method comprises the steps:
A, the BTX aromatics (molecular formula is C7H8) 12%, MTBE for choosing high-quality (chemical formula is C5H120) 10%th, propane (chemical formula is C3H8) 35%, dichloropropane (molecular formula is C3H6CI2) 39%, acetone (is changed Formula is CH3COCH3) 4%, 501 preservative (molecular formula is C15H240) 0.2%, it is contained in respectively each From storage tank in it is stand-by;
B, first by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank into a;Then Again successively by acetone, MTBE, BTX aromatics and 501 preservative in the lump mixing and stirring, half an hour is left Right b;And then again by dichloropropane and a mix half an hour c;Then c mixed with b again Uniformly, stand and get product fuel in 30 minutes, enter finished pot sealing standby.
Antiknock gasoline provided by the present invention is automobile-used innovative fuel, and it is with common industrial chemicals and combustion Feed additives are raw material, give full play to the performance of each component:
BTX aromatics, can be replaced with toluene:Molecular formula is:C7H8, toluene can with ethanol, ether, Acetone, chloroform, Carbon bisulfide and glacial acetic acid are miscible, atomic to be dissolved in water.Relative density 0.866.Freezing point -95℃.110.6 DEG C of boiling point.Index of refraction 1.4967.4.4 DEG C of flash-point (closed-cup).It is inflammable.Steam energy Explosive mixture, explosion limit 1.2%~7.0% (volume) are formed with air.Toluene is used as in a large number solvent It is also the important source material of organic chemical industry with high-knock rating gasoline additive, but at the same time, from coal and oil The benzene for obtaining is compared with dimethylbenzene, yield relative surplus.BTX aromatics main combust host in the fuel Effect;
Methyl tertiary butyl ether(MTBE), chemical formula is:C5H120, MTBE are a kind of high octane gasoline components, its base Plinth octane number RON:118, MON:100, it is excellent gasoline high-octane rating additive and antidetonator.MTBE Lamination can not occur so that arbitrary proportion dissolves each other with gasoline, when reconciling with gasoline component, there is good tune And effect, the octane number that reconciles is higher than its clear octane number.MTBE oxygen content is of a relatively high, can significantly improve vapour Tail gas is discharged.Methyl tertiary butyl ether(MTBE) is acted primarily as in the fuel and proposes high-octane effect;
Propane, three carbon alkanes, chemical formula is C3H8, usually gaseous state, but it is general through being compressed into liquid after Transport.After crude oil or natural gas processing, propane can be obtained from product oil.Propane be commonly used for electromotor, The fuel of baked foods and domestic heating system.Propane is used in the fuel as main fuel;
Dichloropropane, molecular formula is:C3H6CI2, is mainly used in paint, ink, for preparing paint, oil Ink, diluent and PVC adhesive, are a kind of excellent organic solvents, and the benzene class such as alternative dimethylbenzene has Closing purposes is used to make without benzene banana oil, Tianna solution, polyurethane diluent etc., organic with benzene, ketone, ester etc. Solvent mixes.The by-product of PO is produced as chlorohydrination, for the primary raw material of solvent or diluent production, as paint Diluent.Low toxic and environment-friendly replace toluene dimethylbenzene, be widely used in without benzene Tianna solution without benzene glue without Benzene is painted.Dichloropropane is mainly used as basestocks in the fuel;
Acetone, chemical formula is:CH3COCH3, also known as dimethyl ketone, are simplest saturated ketone.It is a kind of Colourless transparent liquid, there is special acrid odors.Soluble in water and methanol, ethanol, ether, chloroform, pyrrole The organic solvents such as pyridine.Inflammable, volatile, chemical property is more active.The commercial production of current acetone in the world Based on cumene method.Acetone industrially mainly as solvent be used for explosive, plastics, rubber, fiber, In the industries such as process hides, oils and fatss, spray painting, also can be used as synthesis ketenes, acetic anhydride, iodoform, polyisoprene rubber The important source material of the materials such as glue, methyl methacrylate, chloroform, epoxy resin.Acetone is main in the fuel Play cosolvent effect;
501 preservative, molecular formula is:C15H240, antioxidant T501 are conventional rubber antioxidants, right Heat, oxygen aging have certain protective action, can also suppress copper to do harm to.Exclusive use does not have ozone-resistant ability, but With antiozonant and wax and with can climate protection infringement of the various factors to vulcanizate.Also may be used in butadiene-styrene rubber As gelling inhibitor.This product volatility is larger.Easily disperse in rubber, rubber or work can be directly mixed with Add in latex for dispersion.Natural gum is widely used in, in various rubber polymers and its latex.This product invariant color, Also do not pollute.For manufacturing the white sidewall of tire, the transparent various rubber of white, gorgeous normal complexion and its latex Product, and the rubber such as daily, health care, adhesive plaster, rubber overshoes.This product can also be as synthetic rubber Stabilizer when rear process and storage, can be used for butadiene-styrene rubber, butadiene rubber, EP rubbers, neoprene rubber The glue kind such as glue.501 preservative act primarily as the effect of anti-corrosion and antioxygen in the fuel.
4th, specific embodiment
The specific embodiment of the present invention is described in further detail below:
Show according to relevant information, current domestic petroleum imbalance between supply and demand day is aobvious to be projected, to the interdependency of import year by year Increase, end the first half of the year in 2015, China's country's oil consumption demand broke through 5.3 hundred million tons, by 2015 Bottom will reach 5.8 hundred million tons, it is contemplated that will break through 7.2 hundred million tons to the year two thousand twenty, and will even up to break through 7.8 Hundred million tons, thus the external dependence degree of CNPC constantly expands, and is possible to be up to 70% to the year two thousand twenty, but It is that China's natural gas gross reserves is 38 tcms, coal gross reserves is 114,500,000,000 tons, therefore, push away The wide supplement for being used as petroleum resources using high-octane rating vehicle fuel, has had very important war to China Omit meaning.
A kind of automobile-used combustion of high-octane rating of replacing gasoline that the present invention is aiming at above-mentioned oily natural resources shortage and proposes Material formula, the finished fuels prepared using the formula, powerful, energy-conservation, cleaning, environmental protection, price is low Honest and clean, burning is clean.Specific embodiment provided by the present invention and experimental conditions are carried out below detailed and careful Description
Embodiment 1:
Choose high-quality BTX aromatics (molecular formula is C7H8) 12%, MTBE (chemical formula is C5H120) 10%, Propane (chemical formula is C3H8) 35%, dichloropropane (molecular formula is C3H6CI2) 39%, acetone (chemistry Formula is CH3COCH3) 4%, 501 preservative (molecular formula is C15H240) 0.2%, it is contained in respectively each Storage tank in it is stand-by;First by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank Into a;Then again successively by acetone, MTBE, BTX aromatics and 501 preservative in the lump mixing and stirring, Or so half an hour b;And then again by dichloropropane and a mix half an hour c;Then again by c Mix homogeneously with b, standing gets product fuel in 30 minutes, enter finished pot sealing standby.
(1) experimental conditions are as follows:
Experiment is 1.:25 liters of the product oil for preparing is added to into the fuel tank of the discharge capacity of Chang'an CX30 car 1.6 Interior, when travelling 296 kilometers (turn on the aircondition 50%) on a highway, averagely per liter travels 11.84 kilometers, Per 100 kilometers of 8.44 liters of oil consumptions;
Experiment is 2.:Existing 25 liters of 93# merchantable gasolines (sinopec) on the market are added with the car of discharge capacity with same car, The traveling (turn on the aircondition 50%) on same fastlink, its distance travelled is 280 kilometers, averagely per liter row 11.2 kilometers are sailed, per 100 kilometers of 8.93 liters of oil consumptions, average every liter of high-energy fuel is than showing on the market 0.64 kilometer being travelled 93# merchantable gasolines, 100 kilometers of oil consumptions save 0.49 liter than 93# merchantable gasoline more.
Embodiment 2:
Choose high-quality BTX aromatics (molecular formula is C7H8) 6%, MTBE (chemical formula is C5H120) 9%, Propane (chemical formula is C3H8) 34%, dichloropropane (molecular formula is C3H6CI2) 47%, acetone (chemistry Formula is CH3COCH3) 4%, 501 preservative (molecular formula is C15H240) 0.2%, it is contained in respectively each Storage tank in it is stand-by;First by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank Into a;Then again successively by acetone, MTBE, BTX aromatics and 501 preservative in the lump mixing and stirring, Or so half an hour b;And then again by dichloropropane and a mix half an hour c;Then again by c Mix homogeneously with b, standing gets product fuel in 30 minutes, enter finished pot sealing standby.
(2) experimental conditions are as follows:
Experiment is 1.:25 liters of the product oil for preparing is added in the fuel tank of Cadillac SRX3.0 discharge capacity, When travelling 180.5 kilometers (turning on the aircondition) on a highway, averagely per liter travels 7.22 kilometers, per 100 13.85 liters of oil consumption of kilometer;
Experiment is 2.:Existing 25 liters of (sinopecs of 97# merchantable gasolines on the market are added with the car of discharge capacity with same car Shell fuel oil), the traveling (turn on the aircondition 50%) on same fastlink, its distance travelled is 174 kilometers, is put down Per liter travel 6.96 kilometers, per 100 kilometers of 14.36 liters of oil consumptions, this high-energy fuel is than shell fuel oil Per 100 kilometers of 0.56 liter of fuel-economizings.
Embodiment 3:
Choose high-quality BTX aromatics (molecular formula is C7H8) 12%, MTBE (chemical formula is C5H120) 10%, Propane (chemical formula is C3H8) 35%, dichloropropane (molecular formula is C3H6CI2) 39%, acetone (chemistry Formula is CH3COCH3) 4%, 501 preservative (molecular formula is C15H240) 0.2%, it is contained in respectively each Storage tank in it is stand-by;First by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank Into a;Then again successively by acetone, MTBE, BTX aromatics and 501 preservative in the lump mixing and stirring, Or so half an hour b;And then again by dichloropropane and a mix half an hour c;Then again by c Mix homogeneously with b, standing gets product fuel in 30 minutes, enter finished pot sealing standby.
(3) experimental conditions are as follows:
Experiment is 1.:25 liters of the product oil for preparing is added to into the discharge capacity of Buick SCM7242ATA cars 2.4 Fuel tank in, when travelling 236 kilometers (turn on the aircondition 50%) on a highway, averagely per liter traveling 9.44 Kilometer, per 100 kilometers of 10.59 liters of oil consumptions;
Experiment is 2.:Existing 25 liters of 93# merchantable gasolines (sinopec) on the market are added with the car of discharge capacity with same car, The traveling (turn on the aircondition 50%) on same fastlink, its distance travelled is 223 kilometers, averagely per liter row Sail 8.92 kilometers, per 100 kilometers of 11.2 liters of oil consumptions, average every liter of high-energy fuel than it is existing on the market 0.52 kilometer being travelled 93# merchantable gasolines, 100 kilometers of oil consumptions save 0.61 liter than 93# merchantable gasoline more.
Embodiment 4:
Choose high-quality BTX aromatics (molecular formula is C7H8) 6%, MTBE (chemical formula is C5H120) 9%, Propane (chemical formula is C3H8) 34%, dichloropropane (molecular formula is C3H6CI2) 47%, acetone (chemistry Formula is CH3COCH3) 4%, 501 preservative (molecular formula is C15H240) 0.2%, it is contained in respectively each Storage tank in it is stand-by;First by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank Into a;Then again successively by acetone, MTBE, BTX aromatics and 501 preservative in the lump mixing and stirring, Or so half an hour b;And then again by dichloropropane and a mix half an hour c;Then again by c Mix homogeneously with b, standing gets product fuel in 30 minutes, enter finished pot sealing standby.
(4) experimental conditions are as follows:
Experiment is 1.:25 liters of the product oil for preparing is added to into the fuel tank of the discharge capacity of BMW 740Li cars 3.0 It is interior, 175 kilometers (turning on the aircondition) is travelled on a highway, averagely per liter travels 7 kilometers, per 100 kilometers 14.28 liters of oil consumption;
Experiment is 2.:Existing 25 liters of 97# merchantable gasolines (sinopec) on the market are added with the car of discharge capacity with same car, (turning on the aircondition) is travelled on same fastlink, its distance travelled is 165 kilometers, averagely per liter traveling 6.6 kilometers, per 100 kilometers of 15.1 liters of oil consumptions, average every liter of high-energy fuel is than existing 97# on the market 0.4 kilometer being travelled merchantable gasoline, 100 kilometers of oil consumptions save 0.82 liter than 97# merchantable gasoline more.

Claims (2)

1. a kind of high-octane rating vehicle fuel of replacing gasoline, it is characterised in that the Gaoxin Each component and its mass parts of alkane value vehicle fuel is than as follows:
1 part of BTX aromatics (molecular formula is C7H8);
1 part of MTBE (chemical formula is C5H120);
1 part of propane (chemical formula is C3H8);
1 part of dichloropropane (molecular formula is C3H6CI2);
1 part of acetone (chemical formula is CH3COCH3);
1 part of 501 preservative (molecular formula is C15H240).
2. the high-octane rating vehicle fuel of replacing gasoline according to claim 1 and preparation Method, it is characterised in that methods described comprises the steps:
A, BTX aromatics (molecular formula is C7H8) 12%, MTBE (chemical formulas for choosing high-quality For C5H120) 10%, (molecular formula is propane (chemical formula is C3H8) 35%, dichloropropane C3H6CI2) the 39%, preservative (molecular formula of acetone (chemical formula is CH3COCH3) 4%, 501 For C15H240) 0.2%, it is contained in respectively stand-by in respective storage tank;
B, first by above-mentioned propane by compressor compresses into after liquid, be stored in pressurized tank Into a;Then again acetone, MTBE, BTX aromatics and 501 preservative are mixed in the lump successively Stir, or so half an hour b;And then it is little again dichloropropane to be mixed into half with a When c;Then c mixed homogeneously with b again, standing gets product fuel in 30 minutes, Enter finished pot sealing standby.
CN201510656960.8A 2015-10-13 2015-10-13 High octane number vehicle fuel capable of replacing gasoline, and preparation method thereof Pending CN106566583A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1928031A (en) * 2005-09-09 2007-03-14 上海中茂新能源应用有限公司 High-octane alcohol hydrocarbon fuel for vehicular
CN101892105A (en) * 2010-07-27 2010-11-24 邓治洲 Novel vehicular fuel
CN103122262A (en) * 2013-03-19 2013-05-29 邓治洲 Vehicle fuel
CN104694184A (en) * 2013-12-09 2015-06-10 黄慧娟 Fuel oil additive mixture

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1928031A (en) * 2005-09-09 2007-03-14 上海中茂新能源应用有限公司 High-octane alcohol hydrocarbon fuel for vehicular
CN101892105A (en) * 2010-07-27 2010-11-24 邓治洲 Novel vehicular fuel
CN103122262A (en) * 2013-03-19 2013-05-29 邓治洲 Vehicle fuel
CN104694184A (en) * 2013-12-09 2015-06-10 黄慧娟 Fuel oil additive mixture

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