CN106566510A - Ternary combination flooding composition, and application thereof in chemical flooding - Google Patents
Ternary combination flooding composition, and application thereof in chemical flooding Download PDFInfo
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- CN106566510A CN106566510A CN201610927353.5A CN201610927353A CN106566510A CN 106566510 A CN106566510 A CN 106566510A CN 201610927353 A CN201610927353 A CN 201610927353A CN 106566510 A CN106566510 A CN 106566510A
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- ternary composite
- composite driving
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- sodium
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- 239000000126 substance Substances 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 title abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 41
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 18
- 239000011206 ternary composite Substances 0.000 claims description 84
- -1 hydroxypropyl Chemical group 0.000 claims description 67
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 57
- 229960003237 betaine Drugs 0.000 claims description 53
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 22
- 230000015784 hyperosmotic salinity response Effects 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 7
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 4
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims 2
- 210000003746 feather Anatomy 0.000 claims 1
- 244000144992 flock Species 0.000 claims 1
- 238000012360 testing method Methods 0.000 abstract description 27
- 230000000694 effects Effects 0.000 abstract description 5
- 239000002585 base Substances 0.000 description 37
- 150000003512 tertiary amines Chemical class 0.000 description 28
- 239000000543 intermediate Substances 0.000 description 27
- 239000000047 product Substances 0.000 description 25
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 24
- 239000003921 oil Substances 0.000 description 23
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 21
- 229950010007 dimantine Drugs 0.000 description 21
- 238000006073 displacement reaction Methods 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 16
- 239000000706 filtrate Substances 0.000 description 15
- 238000001914 filtration Methods 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 239000010779 crude oil Substances 0.000 description 13
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 12
- 239000003513 alkali Substances 0.000 description 12
- 239000000693 micelle Substances 0.000 description 12
- 235000015424 sodium Nutrition 0.000 description 11
- 239000012043 crude product Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 238000001953 recrystallisation Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 8
- 235000016068 Berberis vulgaris Nutrition 0.000 description 7
- 241000335053 Beta vulgaris Species 0.000 description 7
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 7
- 239000012190 activator Substances 0.000 description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 239000003208 petroleum Substances 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- GPTXEUANTKYEHV-UHFFFAOYSA-N [acetyloxy-[2-(diacetyloxyamino)ethyl]amino] acetate;sodium Chemical class [Na].[Na].[Na].[Na].CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O GPTXEUANTKYEHV-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 235000011091 sodium acetates Nutrition 0.000 description 6
- YVDSCAPXSLVWCG-UHFFFAOYSA-N OCCC[S] Chemical compound OCCC[S] YVDSCAPXSLVWCG-UHFFFAOYSA-N 0.000 description 5
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 125000001165 hydrophobic group Chemical group 0.000 description 5
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical class CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 5
- VUQPJRPDRDVQMN-UHFFFAOYSA-N 1-chlorooctadecane Chemical compound CCCCCCCCCCCCCCCCCCCl VUQPJRPDRDVQMN-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 125000001246 bromo group Chemical group Br* 0.000 description 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229960004194 lidocaine Drugs 0.000 description 3
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- ZUQSYKMMRHHLKI-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)S(CCCO)(C)C Chemical compound C(CCCCCCCCCCCCCCCCC)S(CCCO)(C)C ZUQSYKMMRHHLKI-UHFFFAOYSA-N 0.000 description 2
- MLNLHRYROOWCMV-UHFFFAOYSA-M CN(C)CC(C([O-])=O)O.[Na+] Chemical compound CN(C)CC(C([O-])=O)O.[Na+] MLNLHRYROOWCMV-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- SNRUBQQJIBEYMU-NJFSPNSNSA-N dodecane Chemical class CCCCCCCCCCC[14CH3] SNRUBQQJIBEYMU-NJFSPNSNSA-N 0.000 description 2
- 239000008398 formation water Substances 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229940038384 octadecane Drugs 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- WSULSMOGMLRGKU-UHFFFAOYSA-N 1-bromooctadecane Chemical compound CCCCCCCCCCCCCCCCCCBr WSULSMOGMLRGKU-UHFFFAOYSA-N 0.000 description 1
- KOFZTCSTGIWCQG-UHFFFAOYSA-N 1-bromotetradecane Chemical compound CCCCCCCCCCCCCCBr KOFZTCSTGIWCQG-UHFFFAOYSA-N 0.000 description 1
- 125000005999 2-bromoethyl group Chemical group 0.000 description 1
- 235000021537 Beetroot Nutrition 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- BYXIRTBGFQBYAB-UHFFFAOYSA-N BrCCC[Na] Chemical compound BrCCC[Na] BYXIRTBGFQBYAB-UHFFFAOYSA-N 0.000 description 1
- 241000372132 Hydrometridae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/588—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention provides a ternary combination flooding composition, and an application thereof in chemical flooding. The ternary combination flooding composition comprises 0.03-3.0 wt% of an alkaline substance, 0.05-0.30 wt% of a surfactant, 0.05-0.30 wt% of a polymer, and the balance of water; the surfactant is one or a combination of several of long and short chain betaines with a structure shown in the description; and in the structure, R is a C10-C24 linear or branched alkyl group, R1 is a C2-C5 linear alkyl group, R2 is a C2-C5 linear alkyl group, and X is -CH2COO-, -CH2CH2SO3, -CH2CH2CH2SO3- or -CH2CHOHCH2SO3-. A test result shows that the ternary combination flooding composition has a good oil flooding effect.
Description
Technical field
The invention belongs to oil field development technical field, and in particular to a kind of ternary composite driving compositionss and its in chemical flooding
Application.
Background technology
With continually developing for oil field, Chinese land main force oil field enters high recovery percent of reserves, high water cut stage.Old filed is steady
Produce, volume increase becomes the important topic put in face of oil field development worker.Chemistry with polymer flooding, ternary composite driving as representative
Drive the stable yields that raising recovery efficiency technique is domestic crude oil and be made that significant contribution.In Daqing oil field, using heavy alkylbenzene sulfonate
Strong base ternary composite driving (sodium hydroxide/heavy alkylbenzene sulfonate/polymer) technology of surfactant has been enter into expanding chemical industry
The industry application stage；Using the Weak Base ASP Flood (sodium carbonate/petroleum sulfonate/polymer) of petroleum sulfonate surfactant
The field test of technology also takes successfully and continues to expand scene applies scale.
In ternary composite driving, most representational surfactant product is heavy alkylbenzene sulfonate and petroleum sulfonate.Two
Person's production needed raw material heavy alkyl benzene, distillate are cheap and easy to get, and the relatively conventional surfactant of simple production process, cost
It is low.But, as industrial by-products heavy alkyl benzene production capacity is limited, constrain the scale of heavy alkylbenzene sulfonate scene application；And
Petroleum sulfonate is excessively complicated due to raw materials for production aromatic rich cut oil component, causes properties of product easily to receive fraction oil quality shadow
Ring, product stability has much room for improvement.And, heavy alkylbenzene sulfonate and petroleum sulfonate salt tolerant and resistance to divalent ion ability compared with
Difference, it is difficult to be applied to high salinity, the oil reservoir of high divalent ion content.
Compared with other classes of surfactant, betaine type amphoteric surfac-tant has many excellent performances, such as pole
Good stability in hard water, salt tolerance, low toxicity, easily biological-degradable, moderate performance compatibility are good etc..Additionally, beet alkali surface activator
Also there is preferable chemical stability, good emulsibility, dispersibility and antistatic behaviour, some types also have sterilization and press down mould
Property, viscoelasticity etc., range of application is quite varied.
Conventional Long carbon chain dimethyl betaine is long due to single hydrophobic chain, its dissolubility is poor have impact on it is actually used.
In the recent decade, substantial amounts of research work has been carried out in terms of displacement of reservoir oil garden beet alkaline surfactant both at home and abroad, have developed
A series of betaine type surfactant oil displacements.Such as aryl alkyl glycine betaine (CN102618244A), octadecyl hexyl first
Base carboxybetaine (Song Hongjuan, fine chemistry industry, 2015：32 (6)) and the alkyl polyoxyethylene ether Radix Betae with Ju Beite structures
Alkali (CN101745343A) etc..But, aryl alkyl glycine betaine and octadecyl hexyl carboxybetaine preparation technology compare
It is complicated；Synthesis material used by the alkyl polyoxyethylene ether glycine betaine of Ju Beite structures occupies shellfish Extra Old due to production technology and catalyst
The problems such as be difficult to obtain the large-scale raw material of industry.And, the alkyl polyoxyethylene ether glycine betaine of Ju Beite structures and octadecane
The single dose of base hexyl carboxybetaine is difficult to reach ultralow interfacial tension with crude oil.For example, cetyl Polyethylene oxide (3) ether
The ultralow interfacial tension scope that hydroxypropyl carboxybetaine could need to be reached with crude oil in the case of addition weak base sodium carbonate
(10-3The mN/m orders of magnitude and following).Octadecyl hexyl carboxybetaine need to be with hexadecyldimethyl benzyl ammonium carboxybetaine and double
Dodecyl methyl carboxybetaine compounding could reach ultralow interfacial tension with crude oil.
The content of the invention
To overcome the problems referred to above, it is an object of the invention to provide a kind of ternary composite driving compositionss, the ternary composite driving group
Compound has good oil displacement efficiency.
To reach above-mentioned purpose, the invention provides a kind of ternary composite driving compositionss, by percentage to the quality, preparing should
The component of ternary composite driving compositionss includes：
Alkaline matter 0.03wt%-3.0wt%, surfactant 0.05wt%-0.30wt%, polymer 0.05wt%-
0.30wt%, and the water of surplus；
Wherein, the surfactant is the combination of one or more in the long short chain glycine betaine with structure shown in formula I：
In the formula I, R is C10-C24Straight chained alkyl or branched alkyl, R1For C2-C5Straight chained alkyl, R2For C2-C5
Straight chained alkyl, X be-CH2COO-、-CH2CH2SO3 -、-CH2CH2CH2SO3 -Or-CH2CHOHCH2SO3 -。
In the ternary composite driving compositionss that the present invention is provided, the long short chain glycine betaine that uses (especially three alkyl bases
The chain length combination of group) branched structure with a kind of special long-chain, short chain combination is dense with relatively large critical micell
Degree, preferable dissolubility and practicality.And the hydrophobic group end of the long short chain beet alkali surface activator has multiple methyl bases
Group, so as to more effectively reduce the interfacial tension of the long short chain glycine betaine so as to excellent oil-water interfaces performance, because
This, obtained ternary composite driving composition properties are excellent, and oil displacement efficiency is high.
A kind of preparation method of above-mentioned long short chain glycine betaine is：
It is first C by organic salt and the total carbon number of alkyl3-C10Symmetrically or non-symmetrically double alkyl secondary amines press material amount ratio be 1：
(1-5) tertiary amine synthetic reaction is carried out, obtains intermediate tertiary amine；Then the intermediate tertiary amine and halogenated hydrocarbons are pressed the amount ratio of material
For 1：(0.5-2) quaterisation is carried out, long short chain glycine betaine is obtained；
Wherein, the organic salt includes 3- chlorine-2-hydroxyl propanesulfonates, 2- sodium chloroacetates, 2- bromoethyls sodium sulfonate or 3-
Bromopropyl sodium sulfonate；The halogenated hydrocarbons include chloralkane or brominated alkanes.
Specifically, in the preparation method of above-mentioned long short chain betaine compound：
Double alkyl secondary amines can be diethylamine, di-n-propylamine, ethyl pentyl group secondary amine or two n-amylamines；
The step of tertiary amine synthetic reaction, is specially：The organic salt is made into aqueous solution, then at a temperature of 5 DEG C -40 DEG C
It is added in described pair of alkyl secondary amine, and 0.5h-4h is reacted at a temperature of 5 DEG C -80 DEG C and obtain mixed liquor, the mixed liquor is carried
It is pure, obtain the intermediate tertiary amine；
The step of mixed liquor is purified is specially：The mixed liquor is concentrated, addition ethanol, filtered while hot, then
By the filtrate crystallisation for obtaining, washing sucking filtration, recrystallization, the intermediate tertiary amine is obtained；
The step of quaterisation, is specially：The intermediate tertiary amine and halogenated alkane are dissolved in n-butyl alcohol, so
10h-30h being reacted at a temperature of 50 DEG C -130 DEG C afterwards, obtaining crude product, the crude product is purified, long short chain glycine betaine is obtained.
The preparation method of above-mentioned long short chain betaine compound, is first prepared in the middle of Long carbon chain tertiary amine with the synthesis of conventional glycine betaine
Body, to carry out quaterisation again different, but first with the double short chain tertiary amine intermediates of short chain secondary amine synthesis, then with long-chain halogenated alkane
Carry out quaterisation and obtain long short chain glycine betaine.Reaction is only adopted with more typical synthesis material halogenated alkane, secondary amine as raw material
Betaine type target product with branched structure is prepared just with the reaction of 2 steps.As can be seen here, the preparation of the long short chain glycine betaine
Process is simple, therefore, the popularization and application of the ternary composite driving compositionss of present invention offer are provided.
In above-mentioned ternary composite driving compositionss, it is preferable that the R is straight chain or branched-C10H21、-C11H23、-
C12H25、-C13H27、-C14H29、-C15H31、-C16H33、-C18H37、-C20H41、-C22H45Or-C24H49；The R1For straight chain-
C2H5、-C3H7、-C4H9Or-C5H11；The R2For-the C of straight chain2H5、-C3H7、-C4H9Or-C5H11。
In above-mentioned ternary composite driving compositionss, it is preferable that the long short chain glycine betaine is dodecyl diethyl hydroxypropyl
Sulfobetaines (formula A), the third sulfobetaines of dodecyl diamyl (formula B), myristyl ethyl pentyl group carboxybetaine (formula
C), octadecyldimethylamine base hydroxypropyl sulfobetaines (formula D), cetyl dipropyl carboxybetaine (formula E), cetyl second
Base butyl second sulfobetaines (formula F), octadecyl Diethlycarboxy glycine betaine (formula G) or octadecyl dipropyl hydroxypropyl sulfo group
Glycine betaine (formula H).Wherein, the third sulfobetaines of dodecyl diamyl, cetyl ethyl-butyl second sulfobetaines or ten
The using effect of eight alkyl dipropyl hydroxypropyl sulfobetaines is more excellent.The structural formula of above-mentioned each long short chain betaine compound is such as
Under：
In above-mentioned ternary composite driving compositionss, it is preferable that the R1And R2It is asynchronously C2H5。
In above-mentioned ternary composite driving compositionss, it is preferable that the polymer is hydrophobic associated polymer, star heatproof is resistance to
Salt polymer or partially hydrolyzed polyacrylamide (PHPA)；It is further preferred that the mean molecule quantity of the polymer is 12,000,000-3500
Ten thousand.
Star polymer is that possess strong salt resistance heat-resisting property by what a core and multiple super aggregate strands were constituted
Water-soluble polymer.Polymer molecule backbone starization can effectively increase the rule of the rigidity and molecular structure of polymer molecular chain
Whole property so that the curling of polymer molecular chain is difficult, the hydraulic radius increase of strand rotation, tackifying, temperature resistance, salt resistance energy
Power is significantly improved.
In above-mentioned ternary composite driving compositionss, it is preferable that the degree of hydrolysis of the star salt-tolerance is 1%-
5%；The degree of hydrolysis of the partially hydrolyzed polyacrylamide (PHPA) is 20%-30%.
In above-mentioned ternary composite driving compositionss, it is preferable that the star salt-tolerance is
The star polymer prepared in CN201010565501.6；The hydrophobic associated polymer be polymer A N125, the part water
Solution polyacrylamide is MO4000 polymer.
In above-mentioned ternary composite driving compositionss, the alkaline matter that alkaline matter is commonly used in being selected from oil displacement agent field.
Preferably, the alkaline matter includes trimethylamine, triethylamine, tetrasodium ethylenediamine tetraacetate, sodium carbonate, sodium bicarbonate, hydroxide
The combination of one or more in sodium, potassium hydroxide, sodium silicate, sodium tetraborate and sodium phosphate.Wherein, sodium carbonate, sodium tetraborate
Or the using effect of tetrasodium ethylenediamine tetraacetate is more excellent.
In above-mentioned ternary composite driving compositionss, it is preferable that the consumption of the alkaline matter is 0.05wt%-
0.20wt%, the consumption of the surfactant is 0.10wt%-0.30wt%, and the consumption of the polymer is 0.10wt%-
0.30wt%.
In above-mentioned ternary composite driving compositionss, it is preferable that the consumption of the alkaline matter be 0.20wt%, the surface
The consumption of activating agent is 0.20wt%, and the consumption of the polymer is 0.20wt%.
In above-mentioned ternary composite driving compositionss, it is preferable that the water for being adopted can be oil field injected clear water, injection sewage
With the one kind in recovered water or wherein several combinations, and the salinity of water can be 10-200000mg/L.
Present invention also offers application of the above-mentioned ternary composite driving compositionss in chemical flooding.
The ternary composite driving compositionss that the present invention is provided are lived as surface using the long short chain glycine betaine with special construction
Property agent, compared with traditional single straight chained alkyl dimethyl betaine isomerss, with more preferable dissolubility, higher interface
Activity.With the alkyl polyoxyethylene ether of aryl alkyl glycine betaine, octadecyl hexyl methyl carboxybetaine and Ju Beite structures
Glycine betaine etc. is compared, and long short chain synthetic process for betaine as used in the present invention is simple, the high income of intermediate and final product
And interface performance is excellent.Compare with heavy alkylbenzene sulfonate with petroleum sulfonate surfactant, the ternary that the present invention is provided is multiple
Close and drive long short chain beet alkali surface activator salt resistant character, the excellent performance of resistance to divalent ion used by compositionss.
Core oil-displacement test result shows：After water drive terminates, using conventional octadecyldimethyl hydroxypropyl sulfobetaines
The ternary composite driving compositionss of alkali improve recovery ratio 15.72%；Under substantially same experiment condition, using comprising myristyl
The ternary composite driving compositionss provided by the present invention of dipropyl hydroxypropyl sulfobetaines improve recovery ratio and reach 20.89%.Can
See, higher oil displacement efficiency can be obtained using the ternary composite driving compositionss comprising long short chain glycine betaine provided by the present invention.
Therefore, the ternary composite driving compositionss for being provided using the present invention carry out ternary oil displacement operation advantageously.
Description of the drawings
Fig. 1 is the nmr spectrum of 3- (N, N- dipropyl the amino) -2- hydroxypropionate sodiums of embodiment 2；
Fig. 2 is the nmr spectrum of the octadecyldimethylamine base hydroxypropyl sulfobetaine surfactant of embodiment 2.
Specific embodiment
In order to be more clearly understood to the technical characteristic of the present invention, purpose and beneficial effect, now to skill of the invention
Art scheme carry out it is described further below, but it is not intended that to the present invention can practical range restriction.
In specific embodiment, involved portion of reagent and condition are as follows：
(1) alkaline matter involved in specific embodiment：
Sodium carbonate, tetrasodium ethylenediamine tetraacetate；
(2) surfactant involved in specific embodiment：
Dodecyl diamyl the third sulfobetaines (code name：C12-5S)；Octadecyldimethylamine base hydroxypropyl sulfobetaines
(code name：C14-3S)；Octadecyl Diethlycarboxy glycine betaine (code name：C18-2C)；Octadecyl dipropyl carboxybetaine
(code name：C18-3C)；Octadecyldimethyl hydroxypropyl sulfobetaines (code name：C18-1S)；Eicosyl dimethyl carboxyl is sweet
Dish alkali (code name：C20-1C)；Eicosyl dimethyl hydroxypropyl sulfobetaines (code name：C20-1S).Above surfactant is equal
To make by oneself, wherein, in the ternary composite driving compositionss that C18-5S, C14-3S, C18-2C and C18-3C are provided for the present invention
Surface active agent composition, C18-1S, C20-1C and C20-1S are with the surfactant for comparing.
(3) polymer involved in specific embodiment：
Star salt-tolerance (code name：StarPam), molecular weight 12,470,000；Polymer A N125 and MO4000 polymerizations
Thing, the physical and chemical index of above-mentioned three kinds of polymer are as shown in table 1.
1 polymer physical and chemical index of table
| Sequence number | Polymer | Molecular weight, ten thousand | Degree of hydrolysis, % | Solid content, % |
| 1 | Star salt-tolerance | 1247 | 3.28 | 90.56 |
| 2 | AN125 | 1040 | 3.76 | 85.12 |
| 3 | MO4000 | 2070 | 26.80 | 90.50 |
(4) specific embodiment median surface tension test uses TX500C rotating interfacial tensimeters, surveys under formation temperature
Determine 2h interfacial tension stationary values.
(5) Oil Reservoir Types being related in specific embodiment：
Block 1：45 DEG C of formation temperature, formation water salinity 4555mg/L；
Block 2：85 DEG C of formation temperature, formation water salinity 117000mg/L.
Embodiment 1
Present embodiments provide a kind of the third sulfobetaines of dodecyl diamyl (code name：C12-5S), it is concrete to prepare step
Suddenly it is：
(1) aqueous solution of 3- bromopropyl sodium sulfonates is added in two n-amylamines at 10 DEG C, it is then anti-at a temperature of 35 DEG C
Answer 3 hours, obtain mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off insoluble white while hot
Solid, and by the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, obtain intermediate tertiary amine 3- (N, N- diamyl amino) propane sulfonic acid
Sodium；
Wherein, the ratio of the amount of the material of the 3- bromopropyls sodium sulfonate and two n-amylamines is 1：2.5；
(2) intermediate tertiary amine 3- (N, the N- diamyl amino) propanesulfonates for obtaining step (1) and positive chlorinated dodecane are molten
In n-butyl alcohol, then react 25 hours at a temperature of 110 DEG C, obtain crude product, add ethyl acetate and dissolved, and take advantage of
Hot sucking filtration removes unreacted organic salt (3- bromopropyl sodium sulfonates), subsequently by the filtrate for obtaining concentration, evaporate into dry, obtain most
End-product dodecyl the third sulfobetaines of diamyl；
Wherein, the amount of intermediate tertiary amine 3- (N, the N- diamyl amino) propanesulfonates and the material of positive chlorinated dodecane it
Than for 1：0.9.
Embodiment 2
Present embodiments provide a kind of octadecyldimethylamine base hydroxypropyl sulfobetaines (code name：C14-3S), it is concrete to prepare
Step is：
(1) aqueous solution of 3- chlorine-2-hydroxyl propanesulfonates is added in di-n-propylamine at 5 DEG C, then in 30 DEG C of temperature
Lower reaction 2.5 hours, obtains mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off while hot not
Molten white solid, and by the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, obtain intermediate tertiary amine 3- (N, N- dipropyl amino)-
2- hydroxypropionate sodiums, its nmr spectrum are as shown in Figure 1；
Wherein, the 3- chlorine-2-hydroxyls propanesulfonate and the ratio of the amount of the material of di-n-propylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, N- dipropyl the amino) -2- hydroxypropionate sodiums for step (1) being obtained and positive bromo ten
Four alkane are dissolved in n-butyl alcohol, then at a temperature of 110 DEG C react 24 hours, obtain crude product, add ethyl acetate carry out it is molten
Solution, and sucking filtration removes unreacted organic salt (3- chlorine-2-hydroxyl propanesulfonates) while hot, subsequently the filtrate for obtaining is concentrated, is waved
It is sent to dry, obtains final product octadecyldimethylamine base hydroxypropyl sulfobetaines, its nmr spectrum is as shown in Figure 2；
Wherein, the thing of intermediate tertiary amine 3- (N, N- dipropyl the amino) -2- hydroxypropionate sodiums and positive bromotetradecane
The ratio of the amount of matter is 1：0.9.
Embodiment 3
Present embodiments provide a kind of octadecyl Diethlycarboxy glycine betaine (code name：C18-2C), concrete preparation process
For：
(1) aqueous solution of 2- sodium chloroacetates is added in diethylamine at 8 DEG C, is then reacted 3 hours at a temperature of 35 DEG C,
Obtain mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off insoluble white solid while hot, and
By the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, intermediate tertiary amine 3- (N, N- lignocaine) sodium acetate is obtained；
Wherein, the 2- sodium chloroacetates and the ratio of the amount of the material of diethylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, the N- lignocaine) sodium acetates for obtaining step (1) and positive chlorooctadecane are dissolved in
In n-butyl alcohol, then react 30 hours at a temperature of 120 DEG C, obtain crude product, add ethyl acetate and dissolved, and while hot
Sucking filtration removes unreacted organic salt (2- sodium chloroacetates), subsequently by the filtrate for obtaining concentration, evaporate into dry, obtain final product
Octadecyl Diethlycarboxy glycine betaine；
Wherein, the ratio of intermediate tertiary amine 3- (N, the N- lignocaine) sodium acetates and the amount of the material of positive chlorooctadecane
For 1：0.9.
Embodiment 4
Present embodiments provide a kind of octadecyl dipropyl carboxybetaine (code name：C18-3C), concrete preparation process
For：
(1) aqueous solution of 2- sodium chloroacetates is added in di-n-propylamine at 8 DEG C, then at a temperature of 35 DEG C, reaction 3 is little
When, obtain mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off insoluble white solid while hot,
And by the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, obtain intermediate tertiary amine 3- (N, N- dipropyl amino) sodium acetate；
Wherein, the 2- sodium chloroacetates and the ratio of the amount of the material of di-n-propylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, the N- dipropyl amino) sodium acetates for obtaining step (1) and positive chlorooctadecane are dissolved in
In n-butyl alcohol, then react 30 hours at a temperature of 120 DEG C, obtain crude product, add ethyl acetate and dissolved, and while hot
Sucking filtration removes unreacted organic salt (2- sodium chloroacetates), subsequently by the filtrate for obtaining concentration, evaporate into dry, obtain final product
Octadecyl dipropyl carboxybetaine；
Wherein, the ratio of intermediate tertiary amine 3- (N, the N- dipropyl amino) sodium acetates and the amount of the material of positive chlorooctadecane
For 1：0.9.
Comparative example 1
This comparative example provides a kind of octadecyldimethyl hydroxypropyl sulfobetaines (code name：C18-1S), it is concrete to prepare
Step is：
(1) aqueous solution of 3- chlorine-2-hydroxyl propanesulfonates is added in dimethylamine at 5 DEG C, then at a temperature of 30 DEG C
Reaction 2.5 hours, obtains mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off while hot insoluble
White solid, and by the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, obtain intermediate tertiary amine 3- (N, N- dimethylamino) -2-
Hydroxypropionate sodium；
Wherein, the 3- chlorine-2-hydroxyls propanesulfonate and the ratio of the amount of the material of dimethylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, N- the dimethylamino) -2- hydroxypropionate sodiums for step (1) being obtained and positive bromo ten
Eight alkane are dissolved in n-butyl alcohol, then at a temperature of 120 DEG C react 30 hours, obtain crude product, add ethyl acetate carry out it is molten
Solution, and sucking filtration removes unreacted organic salt (3- chlorine-2-hydroxyl propanesulfonates) while hot, subsequently the filtrate for obtaining is concentrated, is waved
It is sent to dry, obtains final product octadecyldimethyl hydroxypropyl sulfobetaines；
Wherein, the thing of intermediate tertiary amine 3- (N, N- the dimethylamino) -2- hydroxypropionate sodiums and positive bromo-octadecane
The ratio of the amount of matter is 1：0.9.
Comparative example 2
This comparative example provides a kind of eicosyl dimethyl carboxybetaine (code name：C20-1C), concrete preparation process
For；
(1) aqueous solution of 2- sodium chloroacetates is added in dimethylamine at 8 DEG C, is then reacted 3 hours at a temperature of 35 DEG C,
Obtain mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off insoluble white solid while hot, and
By the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, intermediate tertiary amine 3- (N, N- dimethylamino) sodium acetate is obtained；
Wherein, the 2- sodium chloroacetates and the ratio of the amount of the material of dimethylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, the N- dimethylamino) sodium acetates for obtaining step (1) and positive bromo eicosane are dissolved in
In n-butyl alcohol, then react 28 hours at a temperature of 120 DEG C, obtain crude product, add ethyl acetate and dissolved, and while hot
Sucking filtration removes unreacted organic salt (2- sodium chloroacetates), subsequently by the filtrate for obtaining concentration, evaporate into dry, obtain final product
Eicosyl dimethyl carboxybetaine；
Wherein, the ratio of intermediate tertiary amine 3- (N, the N- dimethylamino) sodium acetates and the amount of the material of positive bromo eicosane
For 1：0.9.
Comparative example 3
Present embodiments provide a kind of eicosyl dimethyl hydroxypropyl sulfobetaines (code name：C20-1S), it is concrete to prepare
Step is：
(1) aqueous solution of 3- chlorine-2-hydroxyl propanesulfonates is added in dimethylamine at 5 DEG C, then at a temperature of 30 DEG C
Reaction 2.5 hours, obtains mixed liquor；The mixed liquor concentration that this is obtained, is subsequently adding ethanol and is dissolved, filter off while hot insoluble
White solid, and by the filtrate crystallisation by cooling for obtaining, sucking filtration, recrystallization, obtain intermediate tertiary amine 3- (N, N- dimethylamino) -2-
Hydroxypropionate sodium；
Wherein, the 3- chlorine-2-hydroxyls propanesulfonate and the ratio of the amount of the material of dimethylamine are 1：2.5；
(2) intermediate tertiary amine 3- (N, N- the dimethylamino) -2- hydroxypropionate sodiums for step (1) being obtained and positive bromo two
Ten alkane are dissolved in n-butyl alcohol, then at a temperature of 120 DEG C react 30 hours, obtain crude product, add ethyl acetate carry out it is molten
Solution, and sucking filtration removes unreacted organic salt (3- chlorine-2-hydroxyl propanesulfonates) while hot, subsequently the filtrate for obtaining is concentrated, is waved
It is sent to dry, obtains final product eicosyl dimethyl hydroxypropyl sulfobetaines；
Wherein, the thing of intermediate tertiary amine 3- (N, N- the dimethylamino) -2- hydroxypropionate sodiums and positive bromo eicosane
The ratio of the amount of matter is 1：0.9.
Embodiment 5
A kind of ternary composite driving compositionss A are present embodiments provided, the component of ternary composite driving compositionss A is：
0.2wt% sodium carbonate, 0.05wt% octadecyl dipropyl carboxybetaines (4 product of embodiment), 0.2wt% stars
Shape salt-tolerance, and the water (the stratum water of block 1) of surplus.
The preparation process of ternary composite driving compositionss is：Will be sodium carbonate, octadecyl dipropyl carboxybetaine, star resistance to
Warm salt tolerant polymer and water mix homogeneously, stirring obtain ternary composite driving compositionss A after a period of time.
Embodiment 6
A kind of ternary composite driving compositionss B are present embodiments provided, the component of ternary composite driving compositionss B is：
0.2wt% sodium carbonate, 0.05wt% dodecyls the third sulfobetaines of diamyl (1 product of embodiment), 0.2wt%
Star salt-tolerance, and the water (the stratum water of block 1) of surplus.
The preparation process of ternary composite driving compositionss is：Will be sodium carbonate, octadecyl dipropyl carboxybetaine, star resistance to
Warm salt tolerant polymer and water mix homogeneously, stirring obtain ternary composite driving compositionss B after a period of time.
Embodiment 7
A kind of ternary composite driving compositionss C are present embodiments provided, the component of ternary composite driving compositionss C is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.05wt% octadecyldimethylamine base hydroxypropyl sulfobetaines (embodiments 2
Product), 0.2wt% star salt-tolerances, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethylamine base hydroxypropyl sulphur
Base glycine betaine, star salt-tolerance and water mix homogeneously, stirring obtain ternary composite driving compositionss C after a period of time.
Comparative example 4
This comparative example provides a kind of three-component compound system solution M, and the component of the three-component compound system solution is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.05wt% octadecyldimethyl hydroxypropyl sulfobetaines (comparative examples 1
Product), 0.2wt% star salt-tolerances, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethyl hydroxypropyl sulphur
Base glycine betaine, star salt-tolerance and water mix homogeneously, stirring obtain three-component compound system solution M after a period of time.
Embodiment 8
A kind of ternary composite driving compositionss D are present embodiments provided, the component of ternary composite driving compositionss D is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.2wt% octadecyldimethylamine bases hydroxypropyl sulfobetaines (produce by embodiment 2
Product), 0.2wt% star salt-tolerances, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethylamine base hydroxypropyl sulphur
Base glycine betaine, star salt-tolerance and water mix homogeneously, stirring obtain ternary composite driving compositionss D after a period of time.
Embodiment 9
A kind of ternary composite driving compositionss are present embodiments provided, the component of the ternary composite driving compositionss is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.2wt% octadecyldimethylamine bases hydroxypropyl sulfobetaines (produce by embodiment 2
Product), 0.2wt% polymer As N125, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethylamine base hydroxypropyl sulphur
Base glycine betaine, polymer A N125 and water mix homogeneously, stirring obtain ternary composite driving compositionss E after a period of time.
Embodiment 10
A kind of ternary composite driving compositionss are present embodiments provided, the component of the ternary composite driving compositionss is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.2wt% octadecyldimethylamine bases hydroxypropyl sulfobetaines (produce by embodiment 2
Product), 0.2wt%MO4000 polymer, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethylamine base hydroxypropyl sulphur
Base glycine betaine, MO4000 polymer and water mix homogeneously, stirring obtain ternary composite driving compositionss F after a period of time.
Comparative example 5
This comparative example provides a kind of three-component compound system solution N, and the component of the three-component compound system solution is：
0.2wt% tetrasodium ethylenediamine tetraacetates, 0.2wt% octadecyldimethyls hydroxypropyl sulfobetaines (produce by comparative example 1
Product), 0.2wt% star salt-tolerances, and the water (the stratum water of block 2) of surplus.
The preparation process of ternary composite driving compositionss is：By tetrasodium ethylenediamine tetraacetate, octadecyldimethyl hydroxypropyl sulphur
Base glycine betaine, star salt-tolerance and water mix homogeneously, stirring obtain three-component compound system solution N after a period of time.
Test case 1
This test case provides octadecyldimethylamine base hydroxypropyl sulfobetaines (2 product of embodiment) and its isomers
Octadecyldimethyl hydroxypropyl sulfobetaines (1 product of comparative example), octadecyl Diethlycarboxy glycine betaine (produce by embodiment 3
Product) and eicosyl dimethyl carboxybetaine (2 product of comparative example) solubility property test experiments, wherein, the octadecane
Base Diethlycarboxy glycine betaine and eicosyl dimethyl carboxybetaine also isomerss each other.
This test case reflects its solubility property, critical micelle concentration by the critical micelle concentration of measure surfactant
More low then dissolubility is poorer, conversely, the more high then dissolubility of critical micelle concentration is better.This test case adopts distilled water at 30 DEG C
Octadecyldimethylamine base hydroxypropyl sulfobetaines, octadecyldimethyl hydroxypropyl sulfobetaines are tested respectively by hanging piece method
The critical micelle concentration of alkali, octadecyl Diethlycarboxy glycine betaine and eicosyl dimethyl carboxybetaine, and will be described
The critical micelle concentration of octadecyldimethylamine base hydroxypropyl sulfobetaines and the critical micelle concentration of its isomerss glycine betaine
Contrasted, its result is as shown in table 2：
2 glycine betaine isomerss critical micelle concentration of table is contrasted
| Surfactant | Critical micelle concentration/(molL-1) |
| Octadecyldimethylamine base hydroxypropyl sulfobetaines | 5.23×10-5 |
| Octadecyldimethyl hydroxypropyl sulfobetaines | 2.16×10-6 |
| Octadecyl Diethlycarboxy glycine betaine | 1.05×10-6 |
| Eicosyl dimethyl carboxybetaine | Dissolubility is too little, does not measure |
As shown in Table 2, its isomers ten of the ratio of the CMC of octadecyldimethylamine base hydroxypropyl sulfobetaines
Big 1 order of magnitude of critical micelle concentration of eight alkyl dimethyl hydroxypropyl sulfobetaines；And for eicosyl dimethyl carboxyl
For glycine betaine, the critical micelle concentration of its isomerss octadecyl Diethlycarboxy glycine betaine is 1.05 × 10-6mol·
L-1Illustrate that still there is certain dissolubility.The experimental data of above-mentioned table 2 shows：For the surface activity of same carbon number hydrophobic group
Agent, the surfactant of branched structure with the critical micelle concentration higher than its corresponding linear chain structure isomers, from
And there is more preferable water solublity；In the case of hydrophobic group carbon number identical, the Radix Betae that the long-chain with branched structure, short chain are combined
Alkali surfactant and the conventional linear alkyl dimethyl betaine surfactant isomerism with identical hydrophobic group carbon number
Body phase ratio, with relatively large critical micelle concentration, bigger dissolubility and practicality, so as to can more meet practical application
Need.
Test case 2
This test case provides embodiment 5, the interface performance test experiments of 6 ternary composite driving compositionss of embodiment.
Respectively to embodiment 5 (ternary composite driving compositionss A) and 6 (ternary composite driving compositionss B) product of embodiment and area
Interfacial tension between 1 crude oil of block.Test result is shown in Table 3.
Interfacial tension between 3 three-component compound system solution of table and crude oil
As shown in Table 3, evaluated comprising two long short chain beet alkali surface activators (C18-3C and C12-5S) with it is poly-
The three-component compound system solution of compound composition can reach ultralow interfacial tension with 1 crude oil of block, show excellent interface characteristics
Can, illustrate that the long short chain beet alkali surface activator of present invention preparation improves recovery ratio field in chemical flooding and has very big application
Potentiality.And under same experiment condition, as the dissolubility of eicosyl dimethyl hydroxypropyl sulfobetaines is too small, cannot obtain
The ternary composite driving compositionss similar with 5 components are implemented are obtained, thus its interfacial tension cannot be determined.
Test case 3
This test case provides embodiment 7, the interface performance contrast experiment of 4 product of comparative example.
Respectively to embodiment 7 (ternary composite driving compositionss C) and 4 (three-component compound system solution M) product of comparative example and area
Interfacial tension between 2 crude oil of block.Test result is shown in Table 4.
Interfacial tension between 4 three-component compound system of table and crude oil
As shown in Table 4, the equilibrium interfacial tension between octadecyldimethylamine base hydroxypropyl sulfobetaines and crude oil reaches ultralow
Scope (10-3The mN/m orders of magnitude and following) and between its isomerss octadecyldimethyl hydroxypropyl sulfobetaines and crude oil
Equilibrium interfacial tension only reaches 10-2The mN/m orders of magnitude.
As can be seen here, the hydrophobic group end of the above-mentioned long short chain beet alkali surface activator with branched structure has multiple
Methyl group, can more effectively reduce interfacial tension, the long short chain compared with the single straight chain isomerss with carbon number
Beet alkali surface activator can reach ultralow interfacial tension, oil-water interfaces excellent performance under the conditions of alkali-free with crude oil.
Test case 4
This test case provides ternary composite driving compositionss D (8 product of embodiment), ternary composite driving compositionss E (embodiment
9 products) and ternary composite driving compositionss F (10 product of embodiment) viscosity test experiment, it is specific as follows：
Viscosity test to ternary composite driving compositionss D, ternary composite driving compositionss E and ternary composite driving compositionss F.
Using U.S.'s Brookfield LVDVII rotational viscometers, from 0# rotors, rotating speed is 6RPM for viscosity test, is surveyed
Examination temperature is 95 DEG C, and as shown in table 5, viscosity unit is mPas to experimental result.
5 Na of table4EDTA/C14-3S/ polymer ternary compound system solution viscosity test results
As can be seen from Table 5, the viscosity highest of tri compound compositionss D prepared with star salt-tolerance, says
It is bright under the experiment condition, the adhesion-promoting performance of star salt-tolerance is optimal.
Test case 5
This test case provides ternary composite driving compositionss D (5 product of embodiment) and conventional three-way compound system solution N
The oil displacement efficiency evaluation experimental of (5 product of comparative example), it is specific as follows：
This test case have rated ternary composite driving compositionss D using core oil-displacement test survey and conventional three-way compound system is molten
The oil displacement efficiency of liquid N.Method of testing launches core oil-displacement test evaluation with reference to petroleum industry standard SY/T 6424-2000.
Oil displacement experiment program is：Rock core vacuumizing saturation stratum water-measure water phase permeability-saturation crude oil makes constraint
Water-carry out water drive is to aqueous up to 98%-injection ternary composite driving product slug-subsequently turn stratum water drive to aqueous up to 98%.
Experimental temperature is 90 DEG C.Core oil-displacement test result is as shown in table 6.
6 ternary composite driving compositionss oil displacement efficiency evaluation result of table
As shown in Table 6：After water drive terminates, using the conventional three-way of conventional octadecyldimethyl hydroxypropyl sulfobetaines
Compound system solution N improves recovery ratio 15.72%；Under substantially consistent experiment condition, using comprising octadecyldimethylamine
Ternary composite driving compositionss D of base hydroxypropyl sulfobetaines improve recovery ratio and reach 20.89%.It can be seen that, carried using the present invention
For the ternary composite driving compositionss ratio comprising long short chain glycine betaine it is multiple using the conventional three-way comprising conventional dimethyl betaine
Close system solution and can obtain higher oil displacement efficiency.Therefore, using present invention offer comprising octadecyldimethylamine base hydroxypropyl sulphur
The ternary composite driving compositionss of base glycine betaine carry out ternary oil displacement operation advantageously.
Claims (10)
1. a kind of ternary composite driving compositionss, by percentage to the quality, the component for preparing the ternary composite driving compositionss includes：
Alkaline matter 0.03wt%-3.0wt%, surfactant 0.05wt%-0.30wt%, polymer 0.05wt%-
0.30wt%, and the water of surplus；
Wherein, the surfactant is the combination of one or more in the long short chain glycine betaine with structure shown in formula I：
In the formula I, R is C10-C24Straight chained alkyl or branched alkyl, R1For C2-C5Straight chained alkyl, R2For C2-C5It is straight
Alkyl group, X are-CH2COO-、-CH2CH2SO3 -、-CH2CH2CH2SO3 -Or-CH2CHOHCH2SO3 -。
2. ternary composite driving compositionss according to claim 1, wherein, the R is straight chain or branched-C10H21、-
C11H23、-C12H25、-C13H27、-C14H29、-C15H31、-C16H33、-C18H37、-C20H41、-C22H45Or-C24H49；
The R1For-the C of straight chain2H5、-C3H7、-C4H9Or-C5H11；The R2For-the C of straight chain2H5、-C3H7、-C4H9Or-C5H11。
3. ternary composite driving compositionss according to claim 1, wherein, the long short chain glycine betaine is dodecyl diethyl
Base hydroxypropyl sulfobetaines, the third sulfobetaines of dodecyl diamyl, myristyl ethyl pentyl group carboxybetaine, the tetradecane
Base dipropyl hydroxypropyl sulfobetaines, cetyl dipropyl carboxybetaine, cetyl ethyl-butyl second sulfobetaines,
Octadecyl Diethlycarboxy glycine betaine or octadecyl dipropyl hydroxypropyl sulfobetaines.
4. ternary composite driving compositionss according to claim 1 and 2, wherein, the R1And R2It is asynchronously C2H5。
5. ternary composite driving compositionss according to claim 1, wherein, the polymer is hydrophobic associated polymer, star
Shape salt-tolerance or partially hydrolyzed polyacrylamide (PHPA) are birdsed of the same feather flock together compound；
Preferably, the mean molecule quantity of the polymer is 12,000,000-3,500 ten thousand.
6. ternary composite driving compositionss according to claim 4, wherein, the degree of hydrolysis of the star salt-tolerance
For 1%-5%；The degree of hydrolysis of the partially hydrolyzed polyacrylamide (PHPA) is 20%-30%；
Preferably, the star salt-tolerance is the star polymer for preparing in CN201010565501.6；It is described to dredge
Water association polymer is polymer A N125 of French Snf S. A. S.'s production, and the partially hydrolyzed polyacrylamide (PHPA) is Mitsubishi
The polymer MO4000 of chemical conversion company production.
7. ternary composite driving compositionss according to claim 1, wherein, the alkaline matter include trimethylamine, triethylamine,
In tetrasodium ethylenediamine tetraacetate, sodium carbonate, sodium bicarbonate, sodium hydroxide, potassium hydroxide, sodium silicate, sodium tetraborate and sodium phosphate
The combination of one or more；
Preferably, the alkaline matter is sodium carbonate, sodium tetraborate or tetrasodium ethylenediamine tetraacetate.
8. ternary composite driving compositionss according to any one of claim 1-7, wherein, the consumption of the alkaline matter is
0.05wt%-0.20wt%, the consumption of the surfactant is 0.10wt%-0.30wt%, and the consumption of the polymer is
0.10wt%-0.30wt%.
9. ternary composite driving compositionss according to any one of claim 1-7, wherein, the consumption of the alkaline matter is
0.20wt%, the consumption of the surfactant is 0.20wt%, and the consumption of the polymer is 0.20wt%.
10. application of the ternary composite driving compositionss described in any one of claim 1-9 in chemical flooding.
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