CN106566355A - Protective agent for red ink handwriting on file paper sheets - Google Patents
Protective agent for red ink handwriting on file paper sheets Download PDFInfo
- Publication number
- CN106566355A CN106566355A CN201610906429.6A CN201610906429A CN106566355A CN 106566355 A CN106566355 A CN 106566355A CN 201610906429 A CN201610906429 A CN 201610906429A CN 106566355 A CN106566355 A CN 106566355A
- Authority
- CN
- China
- Prior art keywords
- red ink
- protective agent
- handwriting
- writing
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a protective agent for red ink handwriting on file paper sheets. The protective agent is prepared by uniformly mixing poly (diallyldimethylammonium chloride), absolute ethyl alcohol and distilled water according to a mass ratio of 1: (1 to 10): (0.6-4.0). The protective agent is brushed on the red ink handwriting to carry out reinforcing protection and prevent color fading. By using the protective agent to carry out brushing reinforcement on the red ink handwriting, the reinforced red ink handwriting cannot have the phenomena of spreading, color fading and the like. After test paper is soaked, the water tolerance of the red ink handwriting is enhanced, and the color fixing effect is remarkable. The color difference variation of the reinforced handwriting is small after thermal aging, the color of the handwriting cannot easily fade, and the handwriting can be kept for a long term.
Description
Technical field
The invention belongs to archives conservation repairs field, and in particular to prevent archives of paper quality during restoration and protection to one kind
Red ink dyestuff writing meets the protective agent that spreading and sinking in of water is faded.
Background technology
There is the file literature history of more than 4000 years in China, and these precious Historical Archival Documents data are due to the holding time
Long, the difference of the file literature paper that the different periods of history are formed is fine or not different with maintaining requirement, occurs in that different degrees of
Damage.Breakage have acidifying, damage by worms, tear, incomplete, discoloration, the phenomenon such as pollution.In archives restoration and protection technique, support is mounted
Contain substantial amounts of water in the paste of technique, paper deacidification technology using deacidification agent be aqueous solution deacidification agent mostly, easily cause
Dye-type writing in archives is spread after meeting water, and writing thickens unclear even disappearing completely.
The composition of writing pigment includes white carbon black, pigment and dyestuff.Wherein dyestuff is a kind of coloured organic compound, color
It is vivid, it is soluble in water, it is very unstable, belong to non-resistant pigment composition.Red ink writing primary pigments composition is dawn Y, idol
Nitrogen phloxine and methyl orange, these are organic dyestuff, and its water solublity is very strong, so red ink writing meets water seriously can spread and sink in
Change.In many archives after before the founding of the state, dye-type writing occupies very big ratio, and wherein to be even more these original for red ink writing
The important component part of files.Red ink writing archives support mount or deacidification in, writing runs into water and will fade, spread and sink in
Change, it is impossible to keep archives as former state.
In currently used protection reinforcement means, there is polymethyl methacrylate to reinforce, gelatin solution is reinforced, fluoroplastics
Method for strengthening, but these method for strengthening are directly reinforced using macromolecular material, consolidation effect is substantially and after affecting archives
Repairing quality.There is the guard method for red ink writing the country, using phosphotungstic acid, phosphoric acid, acetone, tetraethyl orthosilicate, second
The reagents such as base cellulose, barium hydroxide, methanol, ethyl cellulose Fructus Musae aqueous solution carry out three reinforcings, but cumbersome, and
And the acetone and toluene of introducing pollute the environment.
The content of the invention
The purpose of the present invention is the shortcoming for overcoming above-mentioned protection reinforcement means, there is provided a kind of red ink word prevented in archives
Mark support mount or deacidification in meet spreading and sinking in of water bleeding protective agent.This kind of protective agent can prevent red ink writing from meeting water well
Fade, and not spreading and sinking in after brushing, it is harmless.
The purpose of the present invention is achieved through the following technical solutions：
A kind of red ink writing in archives is anti-fade protective agent by diallyl dimethyl ammoniumchloride, dehydrated alcohol with
Distilled water in mass ratio 1：1～10：0.6～4.0 is uniformly mixed.
The protectant preparation method of described red ink, comprises the steps：At room temperature, first prepare polydiene propyl group two
Ammonio methacrylate is 1 with the mass ratio of dehydrated alcohol:1～10 mixed solution, then while stirring Deca distilled water to three-phase
Material is just balanced and is dissolved each other.
Adopt the present invention to the method for red ink writing reinforcement protection for：The simultaneous hair pen flushed with pruning dips described
Red ink writing protective agent, uniformly brushes the red ink writing part on ph test paper ph, natural air drying.
The present invention has advantages below and effect compared with prior art：The raw material polydiene dimethylamine that the present invention is adopted
Ammonium chloride safety non-toxic, changes insensitive to pH value；The protective agent formulation operations of the present invention are simple, and brush on writing not
Spreading and sinking in is faded, and will not also fade Jing after water immersion, and resistance to water strengthens, effective fixation；The present invention can be used for newspaper, rice paper etc.
Various archives paper.
Description of the drawings
Before Fig. 1 is containing four red line A4 paper immersions；
Fig. 2 is containing (left partly non-brushing protective agent after four red line A4 paper immersions；Right half brushing protective agent)；
Before the filter paper immersion of Fig. 3 red ink printing and dyeing；
(left partly non-brushing protective agent after the filter paper immersion of Fig. 4 red ink printing and dyeing；Right half brushing protective agent)；
Before Fig. 5 immersions of the rice paper containing red ink writing；
(left partly non-brushing protective agent after Fig. 6 immersions of the rice paper containing red ink writing；Right half brushing protective agent)；
Rice paper of the Fig. 7 containing red ink writing (left partly non-brushing protective agent Jing after de- acid soak；Right half brushing protective agent)
Before Fig. 8 immersions of the newspaper containing red ink writing；
(left partly non-brushing protective agent after Fig. 9 immersions of the newspaper containing red ink writing；Right half brushing protective agent)；
Newspapers of the Figure 10 containing red ink writing (left partly non-brushing protective agent Jing after de- acid soak；Right half brushing protective agent)
Before Figure 11 immersions of the composition paper containing red ink writing；
(left partly non-brushing protective agent after Figure 12 immersions of the composition paper containing red ink writing；Right half brushing protective agent)；
Composition paper of the Figure 13 containing red ink writing (left partly non-brushing protective agent Jing after de- acid soak；Right half brushes protection
Agent)
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
Embodiment 1
The described protectant preparation method of red ink writing, comprises the steps：At room temperature, first prepare polydiene third
Base alkyl dimethyl ammonium chloride is 1 with the mass ratio of dehydrated alcohol:1～10 mixed solution, then Deca distilled water is extremely while stirring
Three-phase material is just balanced and is dissolved each other.
Described red ink writing protective agent using method is as follows：
Four straight lines doubling are drawn on A4 paper with red ink pen, the simultaneous hair pen flushed with pruning dips described
Red ink writing protective agent, uniform to brush in the right side writing part of ph test paper ph, room temperature is placed, and is dried naturally, as shown in Figure 1.
Ph test paper ph after process is immersed in water, after 15min take out nature dry, as shown in Fig. 2 a left side partly do not brush it is protectant red
Color writing is wholly absent, and it is obvious that protectant red writing colour fixation is partly brushed on the right side
Qualitative filter paper is printed and dyed with red ink (such as Fig. 3), to place and filter paper is recorded with color difference meter after room temperature is dried naturally
A, b, L-value.Then by filter paper doubling, described red ink writing protective agent is uniformly brushed on the right, is dried naturally and is placed 24h
The now a of filter paper, b, L-value are recorded with color difference meter afterwards.Is soaked in water protectant filter paper 15min that brush, then dries in the air naturally
The now a of filter paper, b, L-value are recorded with color difference meter after dry 24h.The drying baker that filter paper is put into 105 DEG C is carried out artificial ageing 72h,
Filter paper after aging places room temperature 24h, then with a of color difference meter record filter paper, b, L-value.Can be calculated by value of chromatism
Go out the optimal proportioning of color fixing agent for m (diallyl dimethyl ammoniumchloride):M (dehydrated alcohol) m：(water)=1:5:2.
Value of chromatism is calculated as follows：△ E=[(△ L*)2+(△a*)2+(△b*)2]1/2, in formula, △ L* are bright before and after reinforcing
Degree changing value, △ a* are that red green product are poor, △ b* are that champac chromaticity is poor, △ E are export value aberration, the bigger explanation color of △ E values
Change bigger, otherwise then illustrate that color change is less.
According to embodiment, experimental result is shown in Table 1.
Experimental result before and after the protective agent reinforcing of 1 different ratio of table
From table 1, the mass ratio of diallyl dimethyl ammoniumchloride, dehydrated alcohol and distilled water is 1:5:2 guarantor
The colour fixation of shield agent is preferable, and aberration value changes of the filter paper after treatment Jing after artificial ageing are also little.
Embodiment 2
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
On half rice paper of the right side for having red ink writing (such as Fig. 5), room temperature is placed, and after drying naturally is immersed in the rice paper of process for agent brushing
In water, nature is taken out after 15min and is dried.As a result show, left half rice paper is not brushed protectant red writing and is wholly absent, right half
The protectant red writing colour fixation of rice paper brushing is substantially (as shown in Figure 6).
Embodiment 3
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
On half rice paper of the right side for having red ink writing, room temperature is placed, and the rice paper of process is immersed in 1.5g/L after drying naturally for agent brushing
Propanoic acid calcium solution (deacidification agent) in, after 15min take out nature dry.As a result show, left half rice paper is not brushed protectant red
Color writing is wholly absent, and the protectant red writing colour fixation of right half rice paper brushing is substantially (as shown in Figure 7).
Embodiment 4
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
On half newspaper of the right side for having red ink writing (such as Fig. 8), room temperature is placed, and after drying naturally is immersed in the newspaper of process for agent brushing
In water, nature is taken out after 15min and is dried.As a result show, left half newspaper is not brushed protectant red writing and fogged, right half reports
The protectant red writing colour fixation of paper brushing is substantially (as shown in Figure 9).
Embodiment 5
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
On half newspaper of the right side for having red ink writing, room temperature is placed, and the newspaper of process is immersed in 1.5g/L after drying naturally for agent brushing
Propanoic acid calcium solution (deacidification agent) in, after 15min take out nature dry.As a result show, left half newspaper is not brushed protectant red
Color writing fogs, and the protectant red writing colour fixation of right half newspaper brushing is substantially (as shown in Figure 10).
Embodiment 6
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
On paper is write a composition on the right side for having red ink writing half (such as Figure 11), room temperature is placed, the composition paper that will be processed after drying naturally for agent brushing
It is immersed in water, nature is taken out after 15min and is dried.As a result show, it is complete that left half composition paper does not brush protectant red writing
Disappear, right half writes a composition the protectant red writing colour fixation of paper brushing substantially (as shown in figure 12).
Embodiment 7
The described protectant preparation method of red ink writing is same as Example 1, (poly- from preferably protective agent proportioning
The mass ratio of diallyldimethylammonium chloride, dehydrated alcohol and distilled water is 1:5:2).Described red ink writing is protected
Agent brushing is write a composition on paper on the right side for having red ink writing half, and room temperature is placed, and after drying naturally is immersed in the composition paper of process
In the propanoic acid calcium solution (deacidification agent) of 1.5g/L, nature is taken out after 15min and is dried.As a result show, left half composition paper does not brush guarantor
The red writing of shield agent is wholly absent, and right half writes a composition the protectant red writing colour fixation of paper brushing substantially (such as Figure 13 institutes
Show).
Conclusion
A kind of archives paper red ink writing protective agent energy effective protection red ink writing of the present invention, makes red ink writing resistance to
Aqueouss strengthen.And in the deacidification of red ink writing archives, it is prevented to a certain extent fading existing after writing meets water
The generation of elephant.
Claims (3)
1. a kind of archives paper red ink writing protective agent, it is characterised in that by diallyl dimethyl ammoniumchloride with it is anhydrous
Ethanol, distilled water in mass ratio 1：1～10：0.6～4.0 mix homogeneously.
2. red ink writing protective agent according to claim 1, it is characterised in that protective agent using method is：With pruning
Neat brush pen dips protective agent, uniformly brushes the red ink writing part on ph test paper ph, natural air drying.
3. a kind of protectant preparation method of archives paper red ink writing according to claim 1, it is characterised in that bag
Include following steps：At room temperature, the mass ratio for first preparing diallyl dimethyl ammoniumchloride with dehydrated alcohol is 1:1～10
Mixed solution, then Deca distilled water is just balanced to three-phase material and is dissolved each other while stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610906429.6A CN106566355A (en) | 2016-10-18 | 2016-10-18 | Protective agent for red ink handwriting on file paper sheets |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610906429.6A CN106566355A (en) | 2016-10-18 | 2016-10-18 | Protective agent for red ink handwriting on file paper sheets |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106566355A true CN106566355A (en) | 2017-04-19 |
Family
ID=58533630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610906429.6A Pending CN106566355A (en) | 2016-10-18 | 2016-10-18 | Protective agent for red ink handwriting on file paper sheets |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106566355A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
| CN105733368A (en) * | 2016-03-17 | 2016-07-06 | 广东工业大学 | Pure-blue ink writing anti-fading fixation accelerator for paper archives |
| CN105887566A (en) * | 2016-04-11 | 2016-08-24 | 南京工业大学 | Treating fluid for preservation of paper cultural relics, preparation method and application |
-
2016
- 2016-10-18 CN CN201610906429.6A patent/CN106566355A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
| CN105733368A (en) * | 2016-03-17 | 2016-07-06 | 广东工业大学 | Pure-blue ink writing anti-fading fixation accelerator for paper archives |
| CN105887566A (en) * | 2016-04-11 | 2016-08-24 | 南京工业大学 | Treating fluid for preservation of paper cultural relics, preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 张建功: "《聚阳离子型电解质固色剂制备工艺简化的探讨》", 《精细石油化工》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104480743A (en) | Method for printing cotton T shirt by combining traditional tie dyeing and digital printing | |
| CN107503197A (en) | A kind of chalk pretreatment fluid and preparation method thereof, direct-injection digital printing process | |
| CN103725088A (en) | Umbrella water-based ink for satin fabrics and coating method of water-based ink | |
| CN110080013A (en) | A kind of textile dispersion direct-injection ink and preparation method thereof | |
| CN103725089B (en) | A kind of umbrella use ink for percussion cloth fabric and coating method thereof | |
| CN110029512A (en) | A kind of digit printing cotton caloric transfer printing technology | |
| CN105733368A (en) | Pure-blue ink writing anti-fading fixation accelerator for paper archives | |
| CN106566355A (en) | Protective agent for red ink handwriting on file paper sheets | |
| CN103589236B (en) | Umbrella-dedicated water-based ink for terylene plain fabrics and coating method thereof | |
| CN108003703A (en) | A kind of binder for water-based ink and corresponding water-based ink | |
| CN107603344A (en) | The strengthening agent that a kind of ink writing anti-during paper deacidification fades | |
| WO2007123139A1 (en) | Ink composition for ozone detection and ozone indicator | |
| CN107286743A (en) | A kind of boiling water resistance water-based ink printed applied to PVC | |
| CN103321061B (en) | The preparation method of a kind of creative design printing dye liquor, dye liquor and application | |
| Bredereck et al. | Fixing of ink dyes as a basis for restoration and preservation techniques in archives | |
| CN106364176A (en) | Wax printing method | |
| KR20200001057A (en) | Thermal transfer paper for nylon fabric and manufactuing method thereof | |
| CN107903703A (en) | A kind of colorless and odorless fluorescence stamp-pad ink and its preparation process | |
| KR100710496B1 (en) | Paste compositions for printing fabrics | |
| CN106867310A (en) | Structure chromatic ink and preparation method thereof | |
| CN102561055B (en) | Low-permeability and high-transitivity disperse dye screen printing thickener and preparation method thereof | |
| KR100420203B1 (en) | Adhesive paste composition excellent in color and clearness and the method of printing using the same | |
| JP2001287437A (en) | Printing system | |
| KR20240079456A (en) | Digital textile printing method using natural indigo dye | |
| CN106590171A (en) | Activated dye ink as well as preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170419 |