CN106566126A - Low-temperature-resistant PVC corrugated pipe - Google Patents
Low-temperature-resistant PVC corrugated pipe Download PDFInfo
- Publication number
- CN106566126A CN106566126A CN201610965009.5A CN201610965009A CN106566126A CN 106566126 A CN106566126 A CN 106566126A CN 201610965009 A CN201610965009 A CN 201610965009A CN 106566126 A CN106566126 A CN 106566126A
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- parts
- low temperature
- resistant pvc
- low
- pvc corrugated
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The invention discloses a low-temperature-resistant PVC corrugated pipe prepared from the following raw materials in parts by weight: 140-150 parts of PVC, 5-12 parts of acrylate rubber, 2-4 parts of diethylene glycol butylether acetate, 10-15 parts of alkylphenol polyethoxylates, 5-11 parts of an antioxidant, 12-15 parts of hydroxyl silicon oil, 3-10 parts of zinc p-t-butylbenzoate, 10-15 parts of a plasticizer, 3-7 parts of ethylene bisstearamide, 2-6 parts of lead oxide phosphite hydrate, 2-5 parts of thiourea, 15-28 parts of a low-temperature improver, 6-14 parts of glass fibers, 5-15 parts of dimethyldimethoxysilane and 4-7 parts of nanometer magnesia. The low-temperature-resistant PVC corrugated pipe disclosed by the invention is good in flexibility, resistant to distortion, good in bending property and capable of resisting to high and low temperatures and flex cracks.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of low temperature resistant PVC corrugated tubes.
Technical background
Plastic film capicitor is developed in the fifties earliest, and the development advanced by leaps and bounds has been obtained at nearest 20 years.Plastic film capicitor
Special " cannelure " formula special-shaped section form is adopted in structure design, this tubing is novel in design, rational in infrastructure, breaches
" board-like " traditional structure of common tubing, makes tubing both have enough resistance to compressions and an impact strength, and with good flexible
Property.Plastic film capicitor can be widely applied to draining, water-permeable pipe；Interior decoration cable conduct；Automobile electric wire sleeve pipe；Prestressed anchor
Noose pipe；Outlet pipe for air conditioner etc..Plastic film capicitor is the product that synthetic resin doping Jing melt moldings are processed.Add
Plus agent has plasticizer, stabilizer, filler, lubricant, coloring agent, UV absorbent, modifying agent etc..Development and application
In plastic film capicitor, according to the resin used by production plastic film capicitor, the corrugated tube of heterogeneity purposes is obtained, is selecting tree
During fat, should require with reference to the performance of product and moulding process.From the point of view of plastic ripple pipeline market prospect, plastic film capicitor
Road market is covered with huge business opportunity.Corrugated conduit through the expansion of nearly 20 years, at aspects such as equipment, forming technique, technique, PP Pipe Compounds
Rapid expansion is obtained all.And also lagging far behind and foreign countries in the research and development of plastic film capicitor for current China, sell on market
Plastic film capicitor compared with external product, also there are some defects, such as PVC corrugated tubes in performance：Main Ingredients and Appearance is poly-
Vinyl chloride, bright in colour, corrosion-resistant, firm and durable, with preferable tension, comprcssive strength, bonding, the connection of socket joint cushion rubber, method
Orchid is threadedly coupled for house life, industry and mining, the water supply and sewage of agricultural, irrigation, supply, aerofluxuss pipe, electric conduit, rainwater
Pipe, industrial antisepsis pipe etc..Heat resistance is projected, and heat distortion temperature is 100 DEG C, and chemical-resistance is excellent.But its flexibility is not so good as which
His plastic tube, excellent corrosion resistance, price are generally the least expensive in all types of plastic pipe but more crisp under low temperature.For this purpose, we are from product
Formula is set about, the design of the formula of plastic film capicitor will according to the compatibility of the performance of corrugated tube, structure, purposes, auxiliary agent and resin,
Influencing each other between each analog assistant and cooperative effect, and the characteristics of former, the forming factors of comprehensive each side are set
The selection of epoxy-type number and various addition auxiliary agents.In order to meet high request of the market to plastic film capicitor, develop a kind of each
Plant performance preferably PVC corrugated tubes.
The content of the invention
To achieve these goals, the invention provides a kind of low temperature resistant PVC corrugated tubes.
The purpose of the present invention is achieved through the following technical solutions：
A kind of low temperature resistant PVC corrugated tubes, are prepared by the raw materials in：PVC140-150 parts, acrylate rubber 5-12
Part, butyl acetate 2-4 parts, alkylphenol polyoxyethylene 10-15 part, antioxidant 5-11 parts, hydroxy silicon oil 12-15
Part, p-tert-butyl benzoic acid zinc 3-10 parts, plasticizer 10-15 parts, ethylene bis stearamide 3-7 parts, dibasic lead phosphite 2-6
Part, thiourea 2-5 parts, low temperature improvers 15-28 parts, glass fibre 6-14 parts, dimethyldimethoxysil,ne 5-15 part, nano oxygen
Change magnesium 4-7 parts.
The low temperature improvers are polysiloxane copolymer, organosiloxane, benzyl silicone, at least one of silicone.
The antioxidant is at least one in 1010,1076,168.
The plasticizer be diethylene glycol, glycerol or low-molecular-weight polyisobutylene in one or two.
Preferably 1 ~ 10 micron of the diameter of the glass fibre, preferably 10 ~ 100 microns of fibre length.
Beneficial effect：The low temperature resistant PVC corrugated tubes pliability of the present invention is good, and anti-twist, good bending property can be with resistance to height
Gentle flex cracking resistance.
Specific embodiment
Embodiment 1
A kind of low temperature resistant PVC corrugated tubes, are prepared by the raw materials in：PVC140 parts, 5 parts of acrylate rubber, diethyl
2 parts of glycol monobutyl ether acetate, 10 parts of alkylphenol polyoxyethylene, 5 parts of antioxidant, 12 parts of hydroxy silicon oil, p-tert-butyl benzoic acid
3 parts of zinc, 10 parts of plasticizer, 3 parts of ethylene bis stearamide, 2 parts of dibasic lead phosphite, 2 parts of thiourea, 15 parts of low temperature improvers,
6 parts of glass fibre, 5 parts of dimethyldimethoxysil,ne, 4 parts of nano magnesia.
The low temperature improvers are polysiloxane copolymer, organosiloxane, benzyl silicone, at least one of silicone.
The antioxidant is at least one in 1010,1076,168.
The plasticizer be diethylene glycol, glycerol or low-molecular-weight polyisobutylene in one or two.
Preferably 1 ~ 10 micron of the diameter of the glass fibre, preferably 10 ~ 100 microns of fibre length.
Embodiment 2
A kind of low temperature resistant PVC corrugated tubes, are prepared by the raw materials in：PVC145 parts, 8 parts of acrylate rubber, diethyl
3 parts of glycol monobutyl ether acetate, 13 parts of alkylphenol polyoxyethylene, 8 parts of antioxidant, 13 parts of hydroxy silicon oil, p-tert-butyl benzoic acid
7 parts of zinc, 13 parts of plasticizer, 5 parts of ethylene bis stearamide, 4 parts of dibasic lead phosphite, 3 parts of thiourea, 21 parts of low temperature improvers,
10 parts of glass fibre, 9 parts of dimethyldimethoxysil,ne, 6 parts of nano magnesia.
The low temperature improvers are polysiloxane copolymer, organosiloxane, benzyl silicone, at least one of silicone.
The antioxidant is at least one in 1010,1076,168.
The plasticizer be diethylene glycol, glycerol or low-molecular-weight polyisobutylene in one or two.
Preferably 1 ~ 10 micron of the diameter of the glass fibre, preferably 10 ~ 100 microns of fibre length.
Embodiment 3
A kind of low temperature resistant PVC corrugated tubes, are prepared by the raw materials in：PVC150 parts, 12 parts of acrylate rubber, diethyl
4 parts of glycol monobutyl ether acetate, 15 parts of alkylphenol polyoxyethylene, 11 parts of antioxidant, 15 parts of hydroxy silicon oil, p-tert-butyl benzoic acid
10 parts of zinc, 15 parts of plasticizer, 7 parts of ethylene bis stearamide, 6 parts of dibasic lead phosphite, 5 parts of thiourea, 28 parts of low temperature improvers,
14 parts of glass fibre, 15 parts of dimethyldimethoxysil,ne, 7 parts of nano magnesia.
The low temperature improvers are polysiloxane copolymer, organosiloxane, benzyl silicone, at least one of silicone.
The antioxidant is at least one in 1010,1076,168.
The plasticizer be diethylene glycol, glycerol or low-molecular-weight polyisobutylene in one or two.
Preferably 1 ~ 10 micron of the diameter of the glass fibre, preferably 10 ~ 100 microns of fibre length.
Sample is made by raw material in enforcement row formula carries out testing inspection, and the performance formula in above-described embodiment 1-3 is such as
Under：Tensile strength（Mpa）35.45、34.57、33.08；Elongation at break（%）180.8、198.56、210.69；Compression
100℃*70h（%）96、96、95；- 40 DEG C of * 5h of lower temperature resistance are without fracture, without fracture, without fracture；40,000 nothings of flex cracking resistance are split
Mouthful, without breach, without breach.
Claims (5)
1. a kind of low temperature resistant PVC corrugated tubes, it is characterised in that be prepared by the raw materials in：PVC140-150 parts, propylene
Acid esters rubber 5-12 parts, butyl acetate 2-4 parts, alkylphenol polyoxyethylene 10-15 part, antioxidant 5-11 parts,
Hydroxy silicon oil 12-15 parts, p-tert-butyl benzoic acid zinc 3-10 parts, plasticizer 10-15 parts, ethylene bis stearamide 3-7 parts, disalt
Base lead phosphite 2-6 parts, thiourea 2-5 parts, low temperature improvers 15-28 parts, glass fibre 6-14 parts, dimethyldimethoxysil,ne
5-15 parts, nano magnesia 4-7 parts.
2. a kind of low temperature resistant PVC corrugated tubes according to claim 1, it is characterised in that：The low temperature improvers are poly- silica
Alkyl copolymer, organosiloxane, benzyl silicone, at least one of silicone.
3. a kind of low temperature resistant PVC corrugated tubes according to claim 1, it is characterised in that：The antioxidant be 1010,1076,
At least one in 168.
4. a kind of low temperature resistant PVC corrugated tubes according to claim 1, it is characterised in that：The plasticizer be diethylene glycol, the third three
One or two in alcohol or low-molecular-weight polyisobutylene.
5. a kind of low temperature resistant PVC corrugated tubes according to claim 1, it is characterised in that：The diameter of the glass fibre is preferred
It is 1 ~ 10 micron, preferably 10 ~ 100 microns of fibre length.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965009.5A CN106566126A (en) | 2016-10-31 | 2016-10-31 | Low-temperature-resistant PVC corrugated pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965009.5A CN106566126A (en) | 2016-10-31 | 2016-10-31 | Low-temperature-resistant PVC corrugated pipe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106566126A true CN106566126A (en) | 2017-04-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610965009.5A Pending CN106566126A (en) | 2016-10-31 | 2016-10-31 | Low-temperature-resistant PVC corrugated pipe |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107963734A (en) * | 2017-11-24 | 2018-04-27 | 江苏兆盛环保股份有限公司 | A kind of aerator |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10267168A (en) * | 1997-03-26 | 1998-10-09 | Sekisui Chem Co Ltd | Corrugated tube |
| CN102775696A (en) * | 2012-07-18 | 2012-11-14 | 盐城嘉诚塑胶有限公司 | Formula and production technology of PVC (Poly Vinyl Chloride) double-wall corrugated pipe |
| CN103113725A (en) * | 2013-03-22 | 2013-05-22 | 上海顶新箱包有限公司 | PET (Polyethylene Terephthalate) resin composition as well as preparation method and application thereof |
| CN104725823A (en) * | 2013-12-24 | 2015-06-24 | 青岛万力科技有限公司 | Low-temperature-resistant flame-retardant PC (polycarbonate) composite material and preparation method thereof |
| CN105017674A (en) * | 2014-04-15 | 2015-11-04 | 绍兴文理学院 | Low-temperature anti-freezing polyvinyl chloride pipe and production method thereof |
| CN105885299A (en) * | 2016-06-23 | 2016-08-24 | 广东顺德江顺磁材有限公司 | Rubber-modified polyvinyl chloride plastic, method for preparing same and application of rubber-modified polyvinyl chloride plastic |
-
2016
- 2016-10-31 CN CN201610965009.5A patent/CN106566126A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10267168A (en) * | 1997-03-26 | 1998-10-09 | Sekisui Chem Co Ltd | Corrugated tube |
| CN102775696A (en) * | 2012-07-18 | 2012-11-14 | 盐城嘉诚塑胶有限公司 | Formula and production technology of PVC (Poly Vinyl Chloride) double-wall corrugated pipe |
| CN103113725A (en) * | 2013-03-22 | 2013-05-22 | 上海顶新箱包有限公司 | PET (Polyethylene Terephthalate) resin composition as well as preparation method and application thereof |
| CN104725823A (en) * | 2013-12-24 | 2015-06-24 | 青岛万力科技有限公司 | Low-temperature-resistant flame-retardant PC (polycarbonate) composite material and preparation method thereof |
| CN105017674A (en) * | 2014-04-15 | 2015-11-04 | 绍兴文理学院 | Low-temperature anti-freezing polyvinyl chloride pipe and production method thereof |
| CN105885299A (en) * | 2016-06-23 | 2016-08-24 | 广东顺德江顺磁材有限公司 | Rubber-modified polyvinyl chloride plastic, method for preparing same and application of rubber-modified polyvinyl chloride plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107963734A (en) * | 2017-11-24 | 2018-04-27 | 江苏兆盛环保股份有限公司 | A kind of aerator |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170419 |
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| RJ01 | Rejection of invention patent application after publication |