CN106566101B - Organo-mineral complexing flame-retardant thermal insulation material and production method - Google Patents
Organo-mineral complexing flame-retardant thermal insulation material and production method Download PDFInfo
- Publication number
- CN106566101B CN106566101B CN201610406201.0A CN201610406201A CN106566101B CN 106566101 B CN106566101 B CN 106566101B CN 201610406201 A CN201610406201 A CN 201610406201A CN 106566101 B CN106566101 B CN 106566101B
- Authority
- CN
- China
- Prior art keywords
- parts
- foam
- added
- cement slurry
- insulation material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
The present invention discloses a kind of organo-mineral complexing flame-retardant thermal insulation material and production method, the hydrophobicity of foam beads can be enhanced using interface treating agent processing organic foam particle, improve the cohesive force of foam beads and cement slurry, foam cement cladding processing organic foam particle is used later, the fire retardant processing of thermal insulation material may be implemented, the anti-flammability of thermal insulation material is improved, and greatly reduces the generation of toxic black smoke, meets the requirement of fire prevention and heat preservation；Foam cement has higher-strength, can improve the intensity of thermal insulation material；The complete foam cement system of aquation has preferable heat-insulating property, and thermal insulation material can be made to have preferable thermal and insulating performance.Foam beads are sprayed or puddled using the expandability polyurethane glue with flame retardant property, to the flame-retardant thermal insulation material that organic foam particle is dispersed phase, flame retardant polyurethane is continuous phase, therefore the performances such as good toughness, water absorption rate be low of organic insulation material are still remained, while there is the flame retardant property of part inorganic heat insulation material.
Description
Technical field
The present invention relates to building thermal insulation material preparation field, a kind of organo-mineral complexing flame-retardant thermal insulation material and production are disclosed
Method is related to polystyrene foam, phenolic resin foam or polyurethane foam by selecting the cladding processing of large dosage foam cement
Foam etc. prepares organo-mineral complexing fireproof heat-insulating material.
Background technology
Chen Xingyan discloses a kind of method manufacturing flame-retardant thermal insulation material with waste foam.The present invention is with the waste and old of recycling
Foam is as lightweight aggregate, using cement mortar as major gelled material, adds wherein mixing a certain amount of foaming agent, coupling agent, cracking resistance
Add agent, tackifier by dispensing, stir, pour into board-like new material.It is precious that Han Xinhua discloses a kind of light foaming cement expansion
Pearl rock thermal insulation material first uses water with cement mixing at cement mortar, and foaming agent is sent out into foam, and foam is added in cement mortar, is stirred
Uniformly after foam cement.Use foam cement as cementing agent again, addition expanded perlite is aggregate, stirs evenly, is put into
It is compacted in mold, through maintenance, after demoulding.Shen Fugen discloses a kind of thermal insulation material and preparation method thereof, it is characterised in that:
It does aggregate using one kind in three kinds of polystyrene plastics foam, polyurethane foam, polyvinyl chloride foam industrial chemicals, by it
It is ground into particle, then is sufficiently stirred with cement and water, at mixture after stirring, adds auxiliary agent, mixture and auxiliary agent mass ratio
It is 250~350: 0.5~1.5, auxiliary agent is made of foaming agent, foam stabilizer, foam control agent, finally castable again.
Invention content
A kind of organo-mineral complexing flame-retardant thermal insulation material disclosed by the invention, it is characterised in that be by following raw material by weight
Made of portion rate：
55 parts~160 parts of organic foam particle, the expandable glue of polyurethane of the processing of foam cement slurry and interface processing
It is 20 parts~35 parts；
The organic foam particle is selected from：Polystyrene foam, phenolic resin foam or polyurethane foam；
The foam cement slurry treatment fluid, it is characterised in that following raw material by ratio of weight and the number of copies made of：
630 parts of quick hardening sulphoaluminate cement, 40 parts of flyash, 30 parts of calcined diatomite, 100 parts of silicon ash, animal protein hair
7 parts~10 parts of infusion, 335 parts~400 parts of water, 3 parts of polycarboxylate water-reducer, 0.35 part of PP fibers.
The organic foam granular boundary handles glue, following raw material by ratio of weight and the number of copies made of：
500 parts of deionized water, 3 parts of styrene-acrylic emulsion, 1.5 parts of Ludox, 2.5 parts of triethanolamine.
The expandable glue of the polyurethane, following raw material by ratio of weight and the number of copies made of：
80 parts of polyether polyol, 110 parts of thick MDI, 0.1 part of triethanolamine, 0.3 part of dibutyl tin laurate, water 3.0
Part, 3.0 parts of silicone oil, 10 parts of diatomite, 10.0 parts of expansible graphite.
A kind of preparation method of organo-mineral complexing flame-retardant thermal insulation material of the present invention, includes the following steps：
1）Styrene-acrylic emulsion, Ludox, triethanolamine are added in deionized water, interface processing glue is obtained；
2）Interface processing glue and 100 parts of organic foam particles are uniformly puddled or even application is on its surface, later certainly
It so dries to drying；
3）It takes animal protein foaming agent to be dispersed in water and breaks into foam, take quick hardening sulphoaluminate cement later, flyash, forge
It burns diatomite, silicon ash, polycarboxylate water-reducer, PP fibers to be added to the water and prepare cement slurry, adds the foam broken into, puddle
At foam cement slurry, later by step 2）Treated that organic foam particle is puddled uniformly for interfacial agents, standard curing to cement
Slurry aquation is completed, and the organic foam particle of the processing of foam cement slurry and interface processing is obtained；
4）Take triethanolamine, dibutyl tin laurate, water, silicone oil, diatomite, the inflatable stone that polyether polyol is added
Ink is puddled uniformly, and thick MDI high speeds are added and puddle uniformly, obtain polyurethane foam glue；
5）By step 3）The foam cement slurry of preparation handles and the organic foam particle and step 4 of interface processing）It prepares
The expandable glue of polyurethane puddle uniformly to get.
Beneficial effects of the present invention are：The organic bubble of polystyrene foam, phenolic resin foam or polyurethane foam used
Foam particle is the leftover pieces in waste material or production process, so as to make full use of resource, avoids pollution environment.Using interface
Reason agent processing organic foam particle can enhance the hydrophobicity of foam beads, improve the cohesive force of foam beads and cement slurry,
Foam cement cladding processing organic foam particle is used later, and the fire retardant processing of thermal insulation material may be implemented, improve thermal insulation material
Anti-flammability, and greatly reduce the generation of toxic black smoke, meet the requirement of fire prevention and heat preservation；Foam cement has higher-strength,
The intensity of thermal insulation material can be improved；The complete foam cement system of aquation has preferable heat-insulating property, can make thermal insulating material
Material has preferable thermal and insulating performance.Foam is sprayed or puddled using the expandability polyurethane glue with flame retardant property
Grain to which organic foam particle is dispersed phase, flame retardant polyurethane is the flame-retardant thermal insulation material of continuous phase, therefore has still remained
The performances such as good toughness, the water absorption rate of machine thermal insulation material be low, while there is the flame retardant property of part inorganic heat insulation material.
Specific implementation mode
It further illustrates the present invention by the following examples.
Embodiment 1:
1）3 parts of newborn phenylpropyl alcohol liquid, 1.5 parts of Ludox, 2.5 parts of triethanolamine are added in 500 parts of deionized waters, and liquid obtains interface
Handle glue.
2）By step 1）Interface processing glue is made, is uniformly puddled with 100 parts of polystyrene organic foam particles or uniformly
It is sprayed on its surface, later natural drying to drying.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts of boundaries
Treated that polystyrene foam foam beads are added in foam cement slurry puddles uniformly for face agent, standard curing to cement mortar
Body aquation is completed, and the organic foam particle of foam cement slurry processing is obtained.
4）Take 80 parts of polyether polyol, 3.0 parts of 0.3 part of 0.1 part of triethanolamine, dibutyl tin laurate, the water of addition,
3.0 parts of silicone oil foam stabilizer, 10 parts of diatomite, 10.0 parts of 100 mesh expansible graphite are puddled uniformly；110 parts of thick MDI are taken, in addition
It states in component and high speed is puddled uniformly, obtain polyurethane foam glue.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 2:
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polyurethane organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 3:
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of phenolic resin organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 4
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polystyrene organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 5
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polyurethane organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described..
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 6
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of phenolic resin organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 7 parts of animal protein foaming agents to be dispersed in 135 parts of water, is added into frothing machine later and breaks into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described..
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 7
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polystyrene organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 10 parts of animal protein foaming agents to be dispersed in 200 parts of water, is added into frothing machine later and breaks into foam.
The foam just got is added in cement slurry, low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts
Treated that foam beads are added in foam cement slurry puddles uniformly for interfacial agents, and standard curing is complete to cement slurry aquation
At, obtain foam cement slurry processing organic foam particle.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 8
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polyurethane organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.10 parts of animal protein foaming agents are dispersed in 200 parts of water, are added into frothing machine later and are broken into foam.It will
The foam just got is added in cement slurry, and low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts of boundaries
Treated that foam beads are added in foam cement slurry puddles uniformly for face agent, and standard curing to cement slurry aquation is completed,
Obtain the organic foam particle of foam cement slurry processing.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 9
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of phenolic resin organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 10 parts of animal protein foaming agents to be dispersed in 200 parts of water, is added into frothing machine later and breaks into foam.
The foam just got is added in cement slurry, low speed dispersion makes foam be dispersed in cement slurry, later by 100 parts
Treated that foam beads are added in foam cement slurry puddles uniformly for interfacial agents, and standard curing is complete to cement slurry aquation
At, obtain foam cement slurry processing organic foam particle.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）160 parts of the organic foam particle of processing is added in stirred tank, the expandable glue of 35 parts of polyurethane is added
It uniformly sprays in particle surface in stirred tank or when stirring foam beads by foaming glue, is quickly mixed within the 30s times
After mixing uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 10
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polystyrene organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 10 parts of animal protein foaming agents to be dispersed in 200 parts of water, is added into frothing machine later and breaks into foam.
The foam just got is added in cement slurry, low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts
Treated that foam beads are added in foam cement slurry puddles uniformly for interfacial agents, and standard curing is complete to cement slurry aquation
At, obtain foam cement slurry processing organic foam particle.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 11
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of polyurethane organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 10 parts of animal protein foaming agents to be dispersed in 200 parts of water, is added into frothing machine later and breaks into foam.
The foam just got is added in cement slurry, low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts
Treated that foam beads are added in foam cement slurry puddles uniformly for interfacial agents, and standard curing is complete to cement slurry aquation
At, obtain foam cement slurry processing organic foam particle.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
Embodiment 12
1）Interface processing glue is prepared as 1 in embodiment 1）It is described.
2）2 in the interface processing such as embodiment 1 of phenolic resin organic foam particle）It is described.
3）200 parts of water are added in blender, No. 42.5 630 parts of quick hardening sulphoaluminate cements, flyash are sequentially added
40 parts, 30 parts of calcined diatomites, 100 parts of silicon ashes, 3 parts of polycarboxylate water-reducer, 0.35 part of 0.5mm~1.5mmPP fibers, by its point
Dissipate into cement slurry.It takes 10 parts of animal protein foaming agents to be dispersed in 200 parts of water, is added into frothing machine later and breaks into foam.
The foam just got is added in cement slurry, low speed dispersion makes foam be dispersed in cement slurry, later by 400 parts
Treated that foam beads are added in foam cement slurry puddles uniformly for interfacial agents, and standard curing is complete to cement slurry aquation
At, obtain foam cement slurry processing organic foam particle.
4）Polyurethane foam glue is prepared as 4 in embodiment 1）It is described.
5）55 parts of the organic foam particle of processing is added in stirred tank, the expandable glue addition of 20 parts of polyurethane is stirred
It mixes in kettle or is uniformly sprayed in particle surface when stirring foam beads by foaming glue, quickly puddled within the 30s times
After uniformly in injection mold, rear closed foaming is vacuumized at room temperature, and the fire-retardant organic heat-insulating material of multicomponent is made after reacting 30min
Material.
The performance data of embodiment 1-12 is shown in Table 1
The performance data of 1 embodiment 1-12 of table
。
Claims (1)
1. a kind of preparation method of organo-mineral complexing flame-retardant thermal insulation material, includes the following steps：
1）35 parts of styrene-acrylic emulsion, 1.5 parts of Ludox, 2.5 parts of triethanolamine are added in 500 parts of deionized waters, interface processing is obtained
Glue；
2）Interface processing glue and 100 parts of organic foam particles are uniformly puddled or even application is on its surface, is dried in the air naturally later
It shines to drying；
3）It takes 7 parts~10 parts of animal protein foaming agent to be dispersed in 335 parts~400 parts water and breaks into foam, take fast hard sulphur aluminium later
630 parts of acid salt cement, 40 parts of flyash, 30 parts of calcined diatomite, 100 parts of silicon ash, 3 parts of polycarboxylate water-reducer, PP fibers 0.35
Part, which is added to the water, prepares cement slurry, adds the foam broken into, puddles into foam cement slurry, later by step 2）Interface
Treated that organic foam particle is puddled uniformly for agent, and standard curing to cement slurry aquation is completed, and is obtained at foam cement slurry
The organic foam particle of reason and interface processing；
4）Take 80 parts of polyether polyol that 0.1 part of triethanolamine, 0.3 part of dibutyl tin laurate, 3.0 parts of water, silicone oil 3.0 is added
Part, 10 parts of diatomite, 10.0 parts of expansible graphite are puddled uniformly, and 110 parts of high speeds of thick MDI are added and puddle uniformly, obtain polyurethane hair
Steep glue；
5）By step 3）The foam cement slurry of preparation handles and 55 parts~160 parts of the organic foam particle and step of interface processing
4）20 parts~35 parts of the expandable glue of polyurethane of preparation is puddled uniformly, is added in mold, is vacuumized rear closed hair at room temperature
Organo-mineral complexing thermal insulation material is made after reacting 30min in bubble；
Wherein, the organic foam particle is selected from：Polystyrene foam, phenolic resin foam or polyurethane foam.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610406201.0A CN106566101B (en) | 2016-06-12 | 2016-06-12 | Organo-mineral complexing flame-retardant thermal insulation material and production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610406201.0A CN106566101B (en) | 2016-06-12 | 2016-06-12 | Organo-mineral complexing flame-retardant thermal insulation material and production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106566101A CN106566101A (en) | 2017-04-19 |
| CN106566101B true CN106566101B (en) | 2018-08-14 |
Family
ID=58532146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610406201.0A Active CN106566101B (en) | 2016-06-12 | 2016-06-12 | Organo-mineral complexing flame-retardant thermal insulation material and production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106566101B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109020358A (en) * | 2017-06-08 | 2018-12-18 | 韩洪博 | It is a kind of to use general-purpose cement modified flame-retardant polystyrene foam insulation board |
| CN107778025B (en) * | 2017-11-17 | 2021-02-19 | 吉林建筑大学 | Preparation method of high-shock-resistance cement polyphenyl formwork concrete wall |
| CN108752772A (en) * | 2018-05-25 | 2018-11-06 | 成都固迪建材有限公司 | Modified polystyrene material and preparation method thereof and thermoset foam material and preparation method thereof and thermosetting composite polyphenylene plate |
| CN112777962B (en) * | 2020-12-23 | 2022-06-07 | 北华大学 | Method for manufacturing waste polyurethane foam concrete thermal insulation wall material |
| CN112661477B (en) * | 2021-01-09 | 2022-05-20 | 山西大学 | Preparation method of modified polystyrene-basic magnesium sulfate cement composite thermal insulation material |
| CN113511832A (en) * | 2021-06-03 | 2021-10-19 | 青岛理工大学 | Heterogeneous solution method for preparing polymer-coated inorganic particles and application thereof |
| CN113831074A (en) * | 2021-10-22 | 2021-12-24 | 武汉盛大长青建材有限公司 | Light sound-insulation terrace slurry containing polyurethane particles, preparation method and light sound-insulation terrace |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103145384A (en) * | 2013-04-09 | 2013-06-12 | 戚永明 | Light environment-friendly foaming cement thermal insulation material |
| CN103232203A (en) * | 2013-04-27 | 2013-08-07 | 苏州市德莱尔建材科技有限公司 | Foam heat insulation plate and preparation method thereof |
| CN103755289A (en) * | 2013-11-01 | 2014-04-30 | 西安理工大学 | Ultra-light cement based microporous insulation material and preparation method thereof |
-
2016
- 2016-06-12 CN CN201610406201.0A patent/CN106566101B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103145384A (en) * | 2013-04-09 | 2013-06-12 | 戚永明 | Light environment-friendly foaming cement thermal insulation material |
| CN103232203A (en) * | 2013-04-27 | 2013-08-07 | 苏州市德莱尔建材科技有限公司 | Foam heat insulation plate and preparation method thereof |
| CN103755289A (en) * | 2013-11-01 | 2014-04-30 | 西安理工大学 | Ultra-light cement based microporous insulation material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106566101A (en) | 2017-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106566101B (en) | Organo-mineral complexing flame-retardant thermal insulation material and production method | |
| CN103964774A (en) | Autoclaved aerated concrete block and manufacturing method thereof | |
| CN104844263A (en) | Thermal insulation material | |
| CN105314998B (en) | A kind of entringite colloid is thermal insulation mortar of template and preparation method thereof | |
| CN103992086B (en) | A kind of fire-resistant water-fast aerated bricks and preparation method thereof | |
| WO2016168810A1 (en) | Magnesium-based cements and slurry precursors for the same | |
| US11224894B2 (en) | System and method for making and applying a non-Portland cement-based material | |
| CN108751827A (en) | A kind of dry mixing combined lightweight aggregate concrete based on inorganic modified polyurethane particles | |
| CN107556036A (en) | Warming plate and preparation method thereof | |
| MX2014006238A (en) | Cement composition. | |
| CN107089841A (en) | A kind of low-cost high-strength foam concrete and preparation method thereof | |
| JP2021181402A (en) | System and method for preparing and applying non-portland cement-based material | |
| CN108546151B (en) | Light steam-curing-free foaming wall material and preparation method thereof | |
| CN105924122A (en) | Lightweight waterproof modified expanded perlite insulation board and production method thereof | |
| CN107382193A (en) | A kind of preparation method of fireproofing and heat resistant light cellular partition board | |
| CN102898088A (en) | Heat-insulation sound-insulation light-weight high-strength aerated concrete building block and producing method thereof | |
| CN106186921A (en) | A kind of mineral fibre enhancement mode modified expanded perlite insulation board and production method thereof | |
| CN106082884A (en) | A kind of insulating light wall slab containing solid waste cinder and preparation technology | |
| CN105884295B (en) | A kind of floor heating high-strength foamed concrete material and preparation method thereof | |
| KR20130092929A (en) | High strenth concrete and high strenth concrete construction method | |
| JP2017210407A (en) | Polymer cement mortar and method using polymer cement mortar | |
| CN106146005A (en) | A kind of high-strength light steaming-free air-adding brick and preparation method thereof | |
| CN108298941A (en) | A kind of anti-fire door core board and preparation method thereof | |
| CN105000905B (en) | A kind of non-ignitable compound insulating material and preparation method thereof | |
| CN105418033A (en) | Pearly sand concrete and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191114 Address after: Room 708, building 49, Huafu international, No. 88, Yanshan Avenue, Pukou District, Nanjing, Jiangsu Patentee after: Chen Zhou Address before: 130118 No. 5088 Xincheng street, Jilin, Changchun Patentee before: Jilin Jianzhu University |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200429 Address after: 241000 No.1 Longtang Road, green food Park, economic development zone, Sanshan District, Wuhu City, Anhui Province Patentee after: Wuhu Ju Innovative Materials Co.,Ltd. Address before: Room 708, building 49, Huafu international, No. 88, Yanshan Avenue, Pukou District, Nanjing, Jiangsu Patentee before: Chen Zhou |
|
| TR01 | Transfer of patent right |