CN106565896B - A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects - Google Patents
A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects Download PDFInfo
- Publication number
- CN106565896B CN106565896B CN201610982813.4A CN201610982813A CN106565896B CN 106565896 B CN106565896 B CN 106565896B CN 201610982813 A CN201610982813 A CN 201610982813A CN 106565896 B CN106565896 B CN 106565896B
- Authority
- CN
- China
- Prior art keywords
- parts
- external wall
- emulsion
- wall elastic
- kettle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000006210 lotion Substances 0.000 title claims abstract description 63
- 230000000694 effects Effects 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 239000003999 initiator Substances 0.000 claims abstract description 55
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 34
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 19
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 17
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 16
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 13
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims abstract description 10
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims description 48
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 29
- -1 hydroxyl ethyl Chemical group 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 12
- 239000012875 nonionic emulsifier Substances 0.000 claims description 12
- 150000001450 anions Chemical class 0.000 claims description 11
- 238000004945 emulsification Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 239000000908 ammonium hydroxide Substances 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229920001983 poloxamer Polymers 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- 235000019394 potassium persulphate Nutrition 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 239000011812 mixed powder Substances 0.000 claims 1
- 230000007812 deficiency Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 35
- 238000000576 coating method Methods 0.000 description 35
- 238000000034 method Methods 0.000 description 19
- 239000010408 film Substances 0.000 description 15
- 238000002310 reflectometry Methods 0.000 description 13
- 239000004816 latex Substances 0.000 description 9
- 229920000126 latex Polymers 0.000 description 9
- 230000033228 biological regulation Effects 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 description 3
- 125000005233 alkylalcohol group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The external wall elastic lotion and preparation method thereof with photic hydrophilic effects that it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of, the external wall elastic lotion not only has excellent room temperature and low temperature elasticity, but also has good stain resistance.Its raw material composition includes the component of following parts by weight：90 110 parts of deionized water；41 56 parts of Isooctyl acrylate monomer；32 45 parts of butyl acrylate；9.4 12.6 parts of styrene；8.6 12.4 parts of methyl methacrylate；0.3 1.6 parts of acrylic acid；0.6 1.9 parts of methacrylic acid；0.3 0.6 parts of acrylamide；0 0.65 parts of Methacrylamide；0.6 1.3 parts of hydroxy-ethyl acrylate；0 1.5 parts of hydroxyethyl methacrylate；17 parts of nano-titanium dioxide；1.6 7.2 parts of emulsifier；0.2 4 parts of initiator.
Description
Technical field
The present invention relates to a kind of acrylic acid ester emulsions and preparation method thereof, and in particular to a kind of with photic hydrophilic effects
External wall elastic lotion and preparation method thereof.
Background technology
Change with the alternating of environment temperature, the concrete exterior wall of building constantly can be expanded and be shunk, broken to generate
The crack of bad property.External wall elastic coating can effectively solve the problem that building substrate surface due to having the good performance expanded with heat and contract with cold
The destructive crack problem of generation and be received by the market.The main composition of external wall elastic coating is elastic emulsion, vitrifying
Temperature is less than environment temperature, is elastomer under the environment temperature used.External wall elastic coating is because having good elasticity, film
Softness, so having preferable tensile property.However external wall elastic coating causes destruction in effective protection wall from crack
The problem of stain resistance difference is concurrently there are, i.e., elastic soft film coating (especially in the summer of high temperature) surface is easy to after-tack, easily
Dust is adsorbed, the stain resistance and dicoration of external wall elastic film are greatly reduced.
In the prior art in order to improve external wall elastic coating contaminated resistance, mainly reached by following two modes：
One, the amount of filler in external wall elastic formulation for coating material is improved, the less elastic emulsion of external wall elastic coating drying and forming-film rear surface is made
Ash not easy to stick, or smaller filler is used, make the finer and close ash not easy to stick of external wall elastic coating film forming.And the method is apparent
Defect is external wall elastic coating causes its flexibility decrease, especially low temperature elasticity to decline obviously because of the raising of PVC；Two, exterior wall
The lotion of blending high rigidity in elastic coating keeps hardness higher after external wall elastic coating drying and forming-film, stain resistance more preferable.And this
The obvious shortcoming of method is external wall elastic coating causes flexibility decrease especially low temperature elasticity to decline obviously because hardness improves.Institute
To say, the contradiction between external wall elastic coating elasticity and stain resistance now cannot be all solved there are two types of widely applied technology.
Therefore, a elastic emulsion for having good stain resistance again simultaneously with excellent resilience how is developed, is current
The problem of acrylic acid ester emulsion industry.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of external wall elastics with photic hydrophilic effects
Lotion, the external wall elastic lotion not only has excellent room temperature and low temperature elasticity, but also has good stain resistance.
It is another object of the present invention to provide it is a kind of it is simple for process prepare it is above-mentioned outer with photic hydrophilic effects
The method of wall elastic emulsion.
The purpose of the present invention is what is be achieved through the following technical solutions：
A kind of external wall elastic lotion with photic hydrophilic effects, raw material composition include the component of following parts by weight：
90-110 parts of deionized water；41-56 parts of Isooctyl acrylate monomer；32-45 parts of butyl acrylate；9.4-12.6 parts of styrene；Methyl
8.6-12.4 parts of methyl acrylate；0.3-1.6 parts of acrylic acid；0.6-1.9 parts of methacrylic acid；0.3-0.6 parts of acrylamide；First
0-0.65 parts of base acrylamide；0.6-1.3 parts of hydroxy-ethyl acrylate；0-1.5 parts of hydroxyethyl methacrylate；Nano-titanium dioxide
1-7 parts；1.6-7.2 parts of emulsifier；0.2-4 parts of initiator.
Further, the nano-titanium dioxide be rutile titanium dioxide and anatase titanium dioxide in mass ratio
(10-6):The solid powder that (0-4) is mixed, 1 μm of 99% or more particle diameter ＜.
Further, the emulsifier is anion emulsifier and nonionic emulsifier (1-10) in mass ratio：(1-10)
The compound emulsifying agent formed after mixing.Further, wherein the anion emulsifier uses C10-C20Sodium alkyl sulfate,
C10-C20Sodium alkyl sulfonate, C10-C20One or more of sodium alkyl benzene sulfonate arbitrary proportion mixture；The nonionic
Emulsifier is using octadecanoic acid ester of polyethylene glycol, alkyl alcohol ethoxylates, one kind in Pluronic PE 6800 or two
Kind any of the above scalemic thereof.
Further, the initiator is that one or more of ammonium persulfate, potassium peroxydisulfate or sodium peroxydisulfate are pressed
Arbitrary proportion mixes.
The preparation method of the above-mentioned external wall elastic lotion with photic hydrophilic effects, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, addition go from
Sub- water 40-45 parts, 0.2-1.8 parts of emulsifier, are warming up to temperature in the kettle and reach 60-90 DEG C；
B. the preparation of pre-emulsion B：It is added at normal temperatures and pressures into the pre-emulsification tank with monomer measuring tank, blender
41-56 parts of Isooctyl acrylate monomer, 32-45 parts of butyl acrylate, 9.4-12.6 parts of styrene, methyl methacrylate 8.6-12.4
Part, 0.3-1.6 parts of acrylic acid, 0.6-1.9 parts of methacrylic acid, 0.3-0.6 parts of acrylamide, Methacrylamide 0-0.65
Part, 0.6-1.3 parts of hydroxy-ethyl acrylate, 0-1.5 parts of hydroxyethyl methacrylate, 1-7 parts of nano-titanium dioxide, emulsifier 1.4-
5.4 parts, 40-45 parts of deionized water, are stirred into uniform pre-emulsion, and stir 10-50 minutes it is spare；
C. the preparation of initiator solution C：At normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
0.2-4 parts of initiator is added, 10-20 parts of deionized water stirs spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 60-90 DEG C, the 2%-8% of pre-emulsion B total amounts, initiator are added into kettle
After the 10%-90% of solution C total amount, 5-30 minutes, metering device is added dropwise simultaneously to poly- by constant flow pump feeding device and constant current
It closes and remaining pre-emulsion B and initiator solution C is added dropwise in kettle, time for adding was controlled at 180-300 minutes, and kept initiator molten
0-15 minutes more late than pre-emulsion B of liquid C is added dropwise；
E. control polymerization temperature in the kettle is in 60-90 DEG C and keeps the temperature 1-2 hours, cools down and pH is adjusted to 7-9 with ammonium hydroxide, stir
0.5-1 hours are mixed, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
The invention has the advantages that：
1) lotion of the present invention uses internal plasticization mode, that is, it is true to obtain to design very low glass transition temperature (Tg)
Elasticity, hence it is evident that better than dud lotions many on the market.Dud lotion on the market is mostly Tg between -15 DEG C~0 DEG C, and
A certain amount of coalescents are added into lotion to reduce minimum film formation temperature (MFT), and preferably elasticity is obtained under room temperature, and it is such
The elasticity that dud lotion has not had in a low temperature of really.Such as encounter -20 DEG C of environment temperature, the dud that Tg is -15 DEG C
Lotion then follows the string, and is no different with ordinary emulsion.Lotion of the present invention has the soft monomer propylene of flexible branch by improving
The dosage of acid butyl ester and Isooctyl acrylate monomer is reduced with the rigid hard monomer styrene of branch and the use of methyl methacrylate
Amount, Tg is between -45 DEG C~-30 DEG C for design, and rigidity is small between the latex particle segment prepared, in high temperature to low temperature
All there is very outstanding flexibility in wide temperature range, be true bullet lotion, there is excellent room temperature and low temperature elasticity.Simultaneously originally
The lotion is invented because adding coalescents without additional, therefore effect on environment is small, belongs to environment-friendly products.
2) lotion of the present invention adds nano-titanium dioxide to obtain photic hydrophilic effects.Under normal conditions, titanium dioxide is thin
Film surface has about 72 ° of larger contact angle with water, but when titanium dioxide surface is irradiated with, the valence band of titanium dioxide
Electronics has been excited to conduction band, generates Ti respectively3+And Lacking oxygen, the hydrone in air bond together to form surface hydroxyl with Lacking oxygen
Base forms physics adsorbed water layer, and surface just has extremely strong hydrophily, and 5 ° are reduced to hereinafter, even water with the contact angle of water
Drop can be known as Superhydrophilic with this property that complete wetting titanium deoxid film surface, film have, and titanium dioxide this
Class feature is referred to as photic hydrophilic effects.Film obtain Superhydrophilic after, because water can completely its surface spreading, can be well
Polluter is taken away, therefore there is excellent contaminated resistance.Nano-titanium dioxide is added in coating, can equally make coating
Obtain photic hydrophilic effects.And the photic hydrophilic effect of nano-titanium dioxide acquisition is added in lotion of the present invention in preparation process
It answers, hence it is evident that more excellent than traditional photic hydrophilic effects for adding nano-titanium dioxide acquisition during preparing external wall elastic coating
It is different.Traditional coating that photic hydrophilic effects are obtained using nano-titanium dioxide is all that nano-silica is added into formulation for coating material
Change titanium or nano-titanium dioxide dispersion and simple and mechanical dispersion and obtains.Such dispersing technology inefficiency, can not make
Nano-titanium dioxide is uniformly distributed in the form of nanoparticle in coating, therefore the photic hydrophilic effects performance obtained is not very
It is excellent.Lotion advantage of the present invention is that nano-titanium dioxide adds in the synthesis process, using situ aggregation method, makes monomer
It is reacted between nanometer titanium dioxide layer, TiO 2 particles are evenly coated at near-spherical polyalcohol emulsion particle in the form of nanoparticle
Sub- outer layer.The emulsion applications are in external wall elastic coating, and titanium dioxide is still with nano shape in dried coating film film forming procedure
It is coated on latex particle outer layer, after latex particle coalesces fusion film forming, nano-titanium dioxide forms uniform cause in coating surface
Close film.Therefore its nano-titanium dioxide specific surface area bigger of external wall elastic coating made from the lotion, have it is stronger
Photic hydrophilic effects, stain resistant effect are more preferable.
3) lotion of the present invention is prepared in preparation process using heating autoreaction method, and entire reaction is at 60-90 DEG C
It carries out, heating medium is hot water or vapor, and source is convenient to be can be recycled pollution-free, and entire reaction system can be relatively mild
In the environment of carry out, ensure that the stability and reproducibility of reaction.Entire reaction carries out in reaction kettle simultaneously, and need to only add
Heat and stirring can be prepared, and processing technology very simple greatly reduces the processing cost of acrylic acid ester emulsion.
Specific implementation mode
The present invention is described below by specific embodiment.Unless stated otherwise, technological means used in the present invention
It is method known in those skilled in the art.In addition, embodiment is interpreted as illustrative, it is not intended to limit the present invention
Range, the spirit and scope of the invention are limited only by the claims that follow.To those skilled in the art, without departing substantially from this
Under the premise of invention spirit and scope, various changes or change to material component and dosage progress in these embodiments
It belongs to the scope of protection of the present invention.
The percentage sign " % " arrived involved in embodiment refers to mass percent if not specified, and the percentage of solution refers to
Grams containing solute in 100mL, the percentage between liquid, refers to the volume ratio of the solution at 25 DEG C.
Technical solution of the present invention is summarized as follows：The external wall elastic lotion with photic hydrophilic effects of the present invention, raw material
Composition includes the component of following parts by weight：90-110 parts of deionized water；41-56 parts of Isooctyl acrylate monomer；Butyl acrylate 32-
45 parts；9.4-12.6 parts of styrene；8.6-12.4 parts of methyl methacrylate；0.3-1.6 parts of acrylic acid；Methacrylic acid 0.6-
1.9 part；0.3-0.6 parts of acrylamide；0-0.65 parts of Methacrylamide；0.6-1.3 parts of hydroxy-ethyl acrylate；Methacrylic acid
0-1.5 parts of hydroxyl ethyl ester；1-7 parts of nano-titanium dioxide；1.6-7.2 parts of emulsifier；0.2-4 parts of initiator.Isooctyl acrylate monomer and
Butyl acrylate can provide good flexibility as soft monomer for latex particle segment, and styrene, methyl methacrylate are made
Good rigidity, acrylic acid, methacrylic acid, acrylamide, metering system can be provided for latex particle segment for hard monomer
It is steady that amide, hydroxy-ethyl acrylate, hydroxyethyl methacrylate as function monomer can improve the mechanical stability of lotion, calcium ion
Qualitative, freeze-thaw stability, storage stability and adhesive force can be improved, improve contaminated resistance etc., nano-titanium dioxide is with it
The particularity of ingredient makes lotion obtain good photic hydrophilic effects, provides excellent contaminated resistance, emulsifier offer emulsification,
Dispersion, stabilization, initiator, which is water-soluble thermal initiator, can provide good water resistance.
The nano-titanium dioxide is that rutile titanium dioxide and anatase titanium dioxide press (10-6):(0-4) ratio
The solid powder mixed, 99% or more particle diameter<1μm.The nano-titanium dioxide adds in the synthesis process, adopts
With situ aggregation method, monomer is made to be reacted in its interlayer, it is poly- that TiO 2 particles are evenly coated at near-spherical in the form of nanoparticle
Close object latex particle outer layer.The emulsion applications are in external wall elastic coating, and titanium dioxide is still to receive during drying and forming-film
Rice form is coated on latex particle outer layer, and after latex particle, which merges, to be coalesced, nano-titanium dioxide is formed uniformly in coating surface
Fine and close film.Therefore compared with the common external wall elastic coating added with nano-titanium dioxide, lotion of the present invention is made
External wall elastic coating its nano-titanium dioxide specific surface area bigger, there are stronger photic hydrophilic effects, stain resistant effect is more
It is good.
The emulsifier is anion emulsifier and nonionic emulsifier (1-10) in mass ratio：It is formed after (1-10) mixing
Compound emulsifying agent；Further, wherein the anion emulsifier uses C10-C20Sodium alkyl sulfate, C10-C20Alkyl sulphur
Sour sodium, C10-C20One or more of sodium alkyl benzene sulfonate arbitrary proportion mixture；The nonionic emulsifier uses
One or more of octadecanoic acid ester of polyethylene glycol, alkyl alcohol ethoxylates, Pluronic PE 6800 are arbitrary
Scalemic thereof.
The initiator is that one or more of ammonium persulfate, potassium peroxydisulfate or sodium peroxydisulfate mix in any proportion
It closes.
Lotion of the present invention is by improving the soft monomer butyl acrylate and Isooctyl acrylate monomer with flexible branch
Dosage is reduced with the rigid hard monomer styrene of branch and the dosage of methyl methacrylate, designs glass transition temperature
(Tg) between -45 DEG C~-30 DEG C, rigidity is small between the latex particle segment prepared, in the extensive of high temperature to low temperature
All there is very outstanding flexibility in temperature range, be true bullet lotion, there is excellent room temperature and low temperature elasticity.
The preparation method of the external wall elastic lotion with photic hydrophilic effects of the present invention includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, addition go from
Sub- water 40-45 parts, 0.2-1.8 parts of emulsifier, are warming up to temperature in the kettle and reach 60-90 DEG C；
B. the preparation of pre-emulsion B：It is added at normal temperatures and pressures into the pre-emulsification tank with monomer measuring tank, blender
41-56 parts of Isooctyl acrylate monomer, 32-45 parts of butyl acrylate, 9.4-12.6 parts of styrene, methyl methacrylate 8.6-12.4
Part, 0.3-1.6 parts of acrylic acid, 0.6-1.9 parts of methacrylic acid, 0.3-0.6 parts of acrylamide, Methacrylamide 0-0.65
Part, 0.6-1.3 parts of hydroxy-ethyl acrylate, 0-1.5 parts of hydroxyethyl methacrylate, 1-7 parts of nano-titanium dioxide, emulsifier 1.4-
5.4 parts, 40-45 parts of deionized water, are stirred into uniform pre-emulsion, and stir 10-50 minutes it is spare；
C. the preparation of initiator solution C：At normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
0.2-4 parts of initiator is added, 10-20 parts of deionized water stirs spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 60-90 DEG C, the 2%-8% of pre-emulsion B total amounts, initiator are added into kettle
After the 10%-90% of solution C total amount, 5-30 minutes, metering device is added dropwise simultaneously to poly- by constant flow pump feeding device and constant current
It closes and remaining pre-emulsion B and initiator solution C is added dropwise in kettle, time for adding was controlled at 180-300 minutes, and kept initiator molten
0-15 minutes more late than pre-emulsion B of liquid C is added dropwise；
E. control polymerization temperature in the kettle is in 60-90 DEG C and keeps the temperature 1-2 hours, cools down and pH is adjusted to 7-9 with ammonium hydroxide, stir
0.5-1 hours are mixed, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
National standard《JG/T 172-2014 elastic building paints》The requirement of middle stain resistance is reflectivity rate of descent<25%, it
Seek elongation at break under standard state>150%, elongation at break at -10 DEG C>35%.By national standard《GB/T 9780-2013》Middle B
The regulation of method (baking oven express method) carries out the test of external wall elastic coating stain resistance, elastic emulsion reflectivity rate of descent of the invention
<15%.Model made of lotion of the present invention is placed in outdoor exposure six months, reflectivity rate of descent<10%, and be not used and receive
Rice titanium dioxide prepares model made of the lotion of gained and is placed in outdoor exposure six months, and reflectivity rate of descent is 33%.It presses
National standard《JG/T 172-2014 elastic building paints》In regulation carry out external wall elastic coating elongation at break test, the present invention
Elastic emulsion standard state under elongation at break>400%, elongation at break at -10 DEG C>120%.Therefore lotion of the present invention was both
With excellent room temperature and low temperature elasticity, and there is good stain resistance.
It is described in detail with reference to each embodiment, but does not therefore limit the invention to the scope of embodiments
It is interior.
Embodiment 1：
A kind of external wall elastic lotion with photic hydrophilic effects, raw material composition include the component of following parts by weight：
92 parts of deionized water；41 parts of Isooctyl acrylate monomer；32 parts of butyl acrylate；12.6 parts of styrene；Methyl methacrylate 12.4
Part；0.3 part of acrylic acid；1.9 parts of methacrylic acid；0.3 part of acrylamide；Methacrylamide 0.65；Hydroxy-ethyl acrylate 0.6
Part；1.5 parts of hydroxyethyl methacrylate；7 parts of nano-titanium dioxide；6.4 parts of emulsifier；0.2 part of initiator.
The nano-titanium dioxide is rutile titanium dioxide and anatase titanium dioxide in mass ratio 6:4 mix
Solid powder, 1 μm of 99% or more particle diameter ＜.
The emulsifier is anion emulsifier and nonionic emulsifier in mass ratio 1:The composite emulsifying formed after 1 mixing
Agent；The wherein described anion emulsifier uses C10-C20Sodium alkyl sulfate and C10-C20Sodium alkyl benzene sulfonate arbitrary proportion mixture；
The nonionic emulsifier uses octadecanoic acid ester of polyethylene glycol；It is all made of common commercially available raw material of industry type.
Further, the initiator is ammonium persulfate.
The preparation method of the external wall elastic lotion with photic hydrophilic effects, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, addition go from
42 parts of sub- water, 0.7 part of emulsifier, are warming up to temperature in the kettle and reach 60 DEG C；
B. the preparation of pre-emulsion B：It is added at normal temperatures and pressures into the pre-emulsification tank with monomer measuring tank, blender
41 parts of Isooctyl acrylate monomer, 32 parts of butyl acrylate, 12.6 parts of styrene, 12.4 parts of methyl methacrylate, acrylic acid 0.3
Part, 1.9 parts of methacrylic acid, 0.3 part of acrylamide, 0.65 part of Methacrylamide, 0.6 part of hydroxy-ethyl acrylate, methyl-prop
1.5 parts of olefin(e) acid hydroxyl ethyl ester, 7 parts of nano-titanium dioxide, 5.4 parts of emulsifier, 40 parts of deionized water are stirred into uniform pre- breast
Change liquid, and stir 10 minutes it is spare；
C. the preparation of initiator solution C：At normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
0.2 part of initiator is added, 10 parts of deionized water stirs spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 60 DEG C, the 2% of pre-emulsion B total amounts is added into kettle, initiator solution C is total
The 10% of amount is added dropwise metering device by constant flow pump feeding device and constant current while being added dropwise into polymeric kettle remaining after five minutes
Pre-emulsion B and initiator solution C, time for adding was controlled at 180 minutes, and made 15 points more late than pre-emulsion B of initiator solution C
Clock is added dropwise；
E. control polymerization temperature in the kettle is in 60 DEG C and keeps the temperature 1 hour, cools down and pH is adjusted to 7 with ammonium hydroxide, stirring 0.5 is small
When, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
National standard《JG/T 172-2014 elastic building paints》The requirement of middle stain resistance is reflectivity rate of descent<25%, it
Seek elongation at break under standard state>150%, elongation at break at -10 DEG C>35%.By national standard《GB/T 9780-2013》Middle B
The regulation of method (baking oven express method) carries out the test of external wall elastic coating stain resistance, elastic emulsion reflectivity rate of descent of the invention
It is 12%.Model made of lotion of the present invention is placed in outdoor exposure six months, reflectivity rate of descent is 8%.By national standard
《JG/T 172-2014 elastic building paints》In regulation carry out external wall elastic coating elongation at break test, bullet of the invention
Property lotion standard state under elongation at break be 440%, elongation at break is 130% at -10 DEG C.Therefore lotion of the present invention both had
There are excellent room temperature and low temperature elasticity, and there is good stain resistance.
Embodiment 2
A kind of external wall elastic lotion with photic hydrophilic effects, raw material composition include the component of following parts by weight：
105 parts of deionized water；56 parts of Isooctyl acrylate monomer；45 parts of butyl acrylate；9.4 parts of styrene；Methyl methacrylate 8.6
Part；1.6 parts of acrylic acid；0.6 part of methacrylic acid；0.6 part of acrylamide；0.65 part of Methacrylamide；Hydroxy-ethyl acrylate
0.9 part；0.5 part of hydroxyethyl methacrylate；5 parts of nano-titanium dioxide；4.2 parts of emulsifier；1 part of initiator.
The nano-titanium dioxide is rutile titanium dioxide and anatase titanium dioxide in mass ratio 10:4 mixing and
At solid powder, 1 μm of 99% or more particle diameter ＜.
The emulsifier is anion emulsifier and nonionic emulsifier in mass ratio 10:The Composite Milk formed after 1 mixing
Agent；The wherein described anion emulsifier uses C10-C20Sodium alkyl sulfate and C10-C20Sodium alkyl sulfonate arbitrary proportion mixture；
The nonionic emulsifier uses Pluronic PE 6800；It is all made of common commercially available raw material of industry type.
The initiator is potassium peroxydisulfate.
The preparation method of the external wall elastic lotion with photic hydrophilic effects, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, addition go from
45 parts of sub- water, 1.8 parts of emulsifier, are warming up to temperature in the kettle and reach 70 DEG C；
B. the preparation of pre-emulsion B：It is added at normal temperatures and pressures into the pre-emulsification tank with monomer measuring tank, blender
56 parts of Isooctyl acrylate monomer, 45 parts of butyl acrylate, 9.4 parts of styrene, 8.6 parts of methyl methacrylate, 1.6 parts of acrylic acid,
0.6 part of methacrylic acid, 0.6 part of acrylamide, 0.35 part of Methacrylamide, 0.9 part of hydroxy-ethyl acrylate, methacrylic acid
0.5 part of hydroxyl ethyl ester, 5 parts of nano-titanium dioxide, 2.4 parts of emulsifier, 45 parts of deionized water, are stirred into uniform pre-emulsification
Liquid, and stir 20 minutes it is spare；
C. the preparation of initiator solution C：At normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
1 part of initiator is added, 15 parts of deionized water stirs spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 70 DEG C, the 4% of pre-emulsion B total amounts is added into kettle, initiator solution C is total
The 30% of amount is added dropwise metering device by constant flow pump feeding device and constant current and residue is added dropwise into polymeric kettle simultaneously after ten minutes
Pre-emulsion B and initiator solution C, time for adding control at 240 minutes, and make initiator solution C more late than pre-emulsion B 5
Minute is added dropwise；
E. control polymerization temperature in the kettle is in 70 DEG C and keeps the temperature 1.5 hours, cools down and pH is adjusted to 7.5 with ammonium hydroxide, stirring
0.5 hour, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
National standard《JG/T 172-2014 elastic building paints》The requirement of middle stain resistance is reflectivity rate of descent<25%, it
Seek elongation at break under standard state>150%, elongation at break at -10 DEG C>35%.By national standard《GB/T 9780-2013》Middle B
The regulation of method (baking oven express method) carries out the test of external wall elastic coating stain resistance, elastic emulsion reflectivity rate of descent of the invention
It is 10%.Model made of lotion of the present invention is placed in outdoor exposure six months, reflectivity rate of descent is 6%.By national standard
《JG/T 172-2014 elastic building paints》In regulation carry out external wall elastic coating elongation at break test, bullet of the invention
Property lotion standard state under elongation at break be 480%, elongation at break is 140% at -10 DEG C.Therefore lotion of the present invention both had
There are excellent room temperature and low temperature elasticity, and there is good stain resistance.
Embodiment 3
A kind of external wall elastic lotion with photic hydrophilic effects, raw material composition include the component of following parts by weight：
100 parts of deionized water；50 parts of Isooctyl acrylate monomer；38 parts of butyl acrylate；10.8 parts of styrene；Methyl methacrylate 10.2
Part；1.0 parts of acrylic acid；1.2 parts of methacrylic acid；0.5 part of acrylamide；1.3 parts of hydroxy-ethyl acrylate；Nano-titanium dioxide 1
Part；1.6 parts of emulsifier；4 parts of initiator.
The nano-titanium dioxide is the solid powder of rutile titanium dioxide, 1 μm of 99% or more particle diameter ＜.
The emulsifier is anion emulsifier and nonionic emulsifier in mass ratio 1:The Composite Milk formed after 10 mixing
Agent；The wherein described anion emulsifier uses C10-C20Sodium alkyl benzene sulfonate；The nonionic emulsifier uses polyoxyethylene
Sorbitol monooleate, alkyl alcohol ethoxylates arbitrary proportion mixture；It is all made of common commercially available raw material of industry type.
The initiator is sodium peroxydisulfate.
The preparation method of the external wall elastic lotion with photic hydrophilic effects, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, addition go from
40 parts of sub- water, 0.2 part of emulsifier, are warming up to temperature in the kettle and reach 90 DEG C；
B. the preparation of pre-emulsion B：It is added at normal temperatures and pressures into the pre-emulsification tank with monomer measuring tank, blender
50 parts of Isooctyl acrylate monomer, 38 parts of butyl acrylate, 10.8 parts of styrene, 10.2 parts of methyl methacrylate, acrylic acid 1.0
Part, 1.2 parts of methacrylic acid, 0.5 part of acrylamide, 1.3 parts of hydroxy-ethyl acrylate, 1 part of nano-titanium dioxide, emulsifier 1.4
Part, 40 parts of deionized water, be stirred into uniform pre-emulsion, and stir 20 minutes it is spare；
C. the preparation of initiator solution C：At normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
4 parts of initiator is added, 20 parts of deionized water stirs spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 90 DEG C, the 8% of pre-emulsion B total amounts is added into kettle, initiator solution C is total
After the 90%, 30 minutes of amount, metering device is added dropwise by constant flow pump feeding device and constant current, residue is added dropwise into polymeric kettle simultaneously
Pre-emulsion B and initiator solution C, time for adding control at 180 minutes；
E. control polymerization temperature in the kettle is in 90 DEG C and keeps the temperature 2 hours, cools down and pH is adjusted to 9 with ammonium hydroxide, stirring 1 is small
When, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
National standard《JG/T 172-2014 elastic building paints》The requirement of middle stain resistance is reflectivity rate of descent<25%, it
Seek elongation at break under standard state>150%, elongation at break at -10 DEG C>35%.By national standard《GB/T 9780-2013》Middle B
The regulation of method (baking oven express method) carries out the test of external wall elastic coating stain resistance, elastic emulsion reflectivity rate of descent of the invention
It is 13%.Model made of lotion of the present invention is placed in outdoor exposure six months, reflectivity rate of descent is 9%.By national standard
《JG/T 172-2014 elastic building paints》In regulation carry out external wall elastic coating elongation at break test, bullet of the invention
Property lotion standard state under elongation at break be 430%, elongation at break is 125% at -10 DEG C.Therefore lotion of the present invention both had
There are excellent room temperature and low temperature elasticity, and there is good stain resistance.
Claims (6)
1. a kind of external wall elastic lotion with photic hydrophilic effects, which is characterized in that its raw material composition includes following parts by weight
Several components：90-110 parts of deionized water；41-56 parts of Isooctyl acrylate monomer；32-45 parts of butyl acrylate；Styrene 9.4-
12.6 parts；8.6-12.4 parts of methyl methacrylate；0.3-1.6 parts of acrylic acid；0.6-1.9 parts of methacrylic acid；Acrylamide
0.3-0.6 parts；0-0.65 parts of Methacrylamide；0.6-1.3 parts of hydroxy-ethyl acrylate；0-1.5 parts of hydroxyethyl methacrylate；
1-7 parts of nano-titanium dioxide；1.6-7.2 parts of emulsifier；0.2-4 parts of initiator；
The preparation method of the above-mentioned external wall elastic lotion with photic hydrophilic effects, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, be added deionized water
40-45 parts, 0.2-1.8 parts of emulsifier, are warming up to temperature in the kettle and reach 60-90 DEG C；
B. the preparation of pre-emulsion B：Propylene is added into the pre-emulsification tank with monomer measuring tank, blender at normal temperatures and pressures
Acid it is different monooctyl ester 41-56 parts, 32-45 parts of butyl acrylate, 9.4-12.6 parts of styrene, 8.6-12.4 parts of methyl methacrylate,
0.3-1.6 parts of acrylic acid, 0.6-1.9 parts of methacrylic acid, 0.3-0.6 parts of acrylamide, 0-0.65 parts of Methacrylamide, third
0.6-1.3 parts of olefin(e) acid hydroxyl ethyl ester, 0-1.5 parts of hydroxyethyl methacrylate, 1-7 parts of nano-titanium dioxide, emulsifier 1.4-5.4
Part, 40-45 parts of deionized water, be stirred into uniform pre-emulsion, and stir 10-50 minutes it is spare；
C. the preparation of initiator solution C：It is added at normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
0.2-4 parts of initiator, 10-20 parts of deionized water, stirring are spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 60-90 DEG C, the 2%-8%, initiator solution C of pre-emulsion B total amounts are added into kettle
After the 10%-90% of total amount, 5-30 minutes, metering device is added dropwise by constant flow pump feeding device and constant current and is dripped simultaneously into polymeric kettle
Add remaining pre-emulsion B and initiator solution C, time for adding to control at 180-300 minutes, and makes initiator solution C than pre-
0-15 minutes emulsion B evenings were added dropwise；
Control polymerization temperature in the kettle is in 60-90 DEG C and keeps the temperature 1-2 hours, cools down and pH is adjusted to 7-9 with ammonium hydroxide, stir 0.5-
1 hour, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
2. a kind of external wall elastic lotion with photic hydrophilic effects as described in claim 1, which is characterized in that the nanometer
Titanium dioxide be rutile titanium dioxide and anatase titanium dioxide in mass ratio（10-6）:（0-4）The solid mixed
Powder, 1 μm of 99% or more particle diameter ＜.
3. a kind of external wall elastic lotion with photic hydrophilic effects as described in claim 1, which is characterized in that the emulsification
Agent be anion emulsifier and nonionic emulsifier in mass ratio（1-10）：（1-10）The compound emulsifying agent formed after mixing.
4. a kind of external wall elastic lotion with photic hydrophilic effects as claimed in claim 3, which is characterized in that described the moon from
Sub- emulsifier uses C10-C20Sodium alkyl sulfate, C10-C20Sodium alkyl sulfonate, C10-C20One or both of sodium alkyl benzene sulfonate
Any of the above scalemic thereof；The nonionic emulsifier is using octadecanoic acid ester of polyethylene glycol, alkylol polyoxyethylene
One or more of ether, Pluronic PE 6800 arbitrary proportion mixture.
5. a kind of external wall elastic lotion with photic hydrophilic effects as described in claim 1, which is characterized in that the initiation
Agent is that one or more of ammonium persulfate, potassium peroxydisulfate or sodium peroxydisulfate mix in any proportion.
6. a kind of preparation method of any external wall elastic lotions with photic hydrophilic effects of claim 1-5, special
Sign is, includes the following steps：
A. the preparation of bottom material liquid A：To with blender, condenser, constant flow pump feeding device polymeric kettle in, be added deionized water
40-45 parts, 0.2-1.8 parts of emulsifier, are warming up to temperature in the kettle and reach 60-90 DEG C；
B. the preparation of pre-emulsion B：Propylene is added into the pre-emulsification tank with monomer measuring tank, blender at normal temperatures and pressures
Acid it is different monooctyl ester 41-56 parts, 32-45 parts of butyl acrylate, 9.4-12.6 parts of styrene, 8.6-12.4 parts of methyl methacrylate,
0.3-1.6 parts of acrylic acid, 0.6-1.9 parts of methacrylic acid, 0.3-0.6 parts of acrylamide, 0-0.65 parts of Methacrylamide, third
0.6-1.3 parts of olefin(e) acid hydroxyl ethyl ester, 0-1.5 parts of hydroxyethyl methacrylate, 1-7 parts of nano-titanium dioxide, emulsifier 1.4-5.4
Part, 40-45 parts of deionized water, be stirred into uniform pre-emulsion, and stir 10-50 minutes it is spare；
C. the preparation of initiator solution C：It is added at normal temperatures and pressures into the initiator tank with blender, constant current Dropping feeder
0.2-4 parts of initiator, 10-20 parts of deionized water, stirring are spare to being completely dissolved；
D. when polymerization temperature in the kettle reaches 60-90 DEG C, the 2%-8%, initiator solution C of pre-emulsion B total amounts are added into kettle
After the 10%-90% of total amount, 5-30 minutes, metering device is added dropwise by constant flow pump feeding device and constant current and is dripped simultaneously into polymeric kettle
Add remaining pre-emulsion B and initiator solution C, time for adding to control at 180-300 minutes, and makes initiator solution C than pre-
0-15 minutes emulsion B evenings were added dropwise；
E. control polymerization temperature in the kettle is in 60-90 DEG C and keeps the temperature 1-2 hours, cools down and pH is adjusted to 7-9 with ammonium hydroxide, stirs
0.5-1 hours, filtering and discharging, you can obtain the external wall elastic lotion with photic hydrophilic effects.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610982813.4A CN106565896B (en) | 2016-11-09 | 2016-11-09 | A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610982813.4A CN106565896B (en) | 2016-11-09 | 2016-11-09 | A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106565896A CN106565896A (en) | 2017-04-19 |
| CN106565896B true CN106565896B (en) | 2018-09-25 |
Family
ID=58540595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610982813.4A Active CN106565896B (en) | 2016-11-09 | 2016-11-09 | A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106565896B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108239220B (en) * | 2018-02-08 | 2021-08-27 | 上海昱邦化工科技有限公司 | Water-based acrylic emulsion and preparation method thereof |
| CN113831448A (en) * | 2021-10-27 | 2021-12-24 | 上海保立佳新材料有限公司 | Pure acrylic emulsion, raw material composition thereof, preparation method and application thereof |
| CN115785331B (en) * | 2022-12-26 | 2024-02-27 | 万华化学集团股份有限公司 | Preparation method and application of acrylate emulsion |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102516477A (en) * | 2011-11-23 | 2012-06-27 | 华南理工大学 | Nano titanium dioxide/ acrylate composite emulsion and preparation method thereof |
| CN103073669B (en) * | 2013-01-11 | 2015-06-03 | 华南理工大学 | Method for preparing nano titanium dioxide/polyacrylate compound emulsion |
| CN104610832B (en) * | 2015-01-22 | 2017-01-11 | 南阳师范学院 | Nano TiO2 modified polyacrylate coating agent |
| CN104974289A (en) * | 2015-07-13 | 2015-10-14 | 华南理工大学 | Nanometer titanium dioxide/acrylate polymer composite emulsion and preparation method thereof |
-
2016
- 2016-11-09 CN CN201610982813.4A patent/CN106565896B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106565896A (en) | 2017-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106565897B (en) | A kind of external wall elastic lotion and preparation method thereof with lotus leaf effect | |
| CN104277172B (en) | Water-based waterproof acrylate emulsion and preparation method thereof | |
| CN106565909B (en) | A kind of external wall elastic lotion and preparation method thereof with ultraviolet light cross-linking effect | |
| CN106565896B (en) | A kind of external wall elastic lotion and preparation method thereof with photic hydrophilic effects | |
| CN101173021A (en) | Acrylic acid series nucleocapsid polymer emulsion and re-dispersible emulsion powder, and method for producing thereof | |
| CN103242007B (en) | Preparation method of graphene oxide modified polymer cement waterproof coating | |
| CN105531340A (en) | Acrylic emulsion adhesive, and production method for same | |
| CN109705692A (en) | A kind of elastic compounded emulsion and preparation method thereof with super contaminated resistance | |
| WO2009139314A1 (en) | Emulsion composition for vibration damping material | |
| CN107629499A (en) | A kind of elastic polymer waterproof paint and preparation method thereof | |
| CN1966569A (en) | Dispersion powders stabilized by protective colloids | |
| CN107083215A (en) | A kind of ceramic tile gum produced by pure acrylate elastic emulsion and styrene-acrylic emulsion and technique | |
| CN105254799A (en) | Acrylate emulsion with high-gloss blackspot type raindrop imprint resistance and preparation method of acrylate emulsion | |
| CN105732878A (en) | Core-shell type emulsion with PTFE (polytetrafluoroethylene) as core and preparation method thereof | |
| JP2009270063A (en) | Emulsion composition for damping material | |
| CN105085779B (en) | With the high-solid-content and low-viscosity high stability polyacrylate dispersion and method of the preparation of double polymerisable emulsifiers | |
| JP2006347797A (en) | Mortar, structure covered with the same and working method of the same | |
| JPS60127371A (en) | Inorganic coating material composed mainly of colloidal silica | |
| CN100467416C (en) | Redispersible polymer viscose glue powder and preparation method thereof | |
| CN107285664B (en) | A kind of preparation method of no cement high strong water resistant type ceramic tile adhesive | |
| JP5260187B2 (en) | Emulsion composition for damping material and damping material composition | |
| CN104610834B (en) | A kind of preparation method of the super hydrophobic coating for producing anion | |
| CN104558453A (en) | Method for preparing cationic fluorine-containing amphiphilic block copolymer micelles | |
| JP5031222B2 (en) | Polymer cement compositions, these mortars, mortar coated structures | |
| JPWO2005010095A1 (en) | Two-component plastisol composition and method of use thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A kind of exterior wall elastic lotion with photohydrophilic effect and its preparation method Granted publication date: 20180925 Pledgee: Foshan Shunde Sub branch of Postal Savings Bank of China Co.,Ltd. Pledgor: FOSHAN CITY SHUNDE DISTRICT BATF INDUSTRY Co.,Ltd. Registration number: Y2024980006686 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |