CN106563430A - Honeycomb ceramic monolithic photocatalyst as well as preparation method and application of honeycomb ceramic monolithic photocatalyst - Google Patents
Honeycomb ceramic monolithic photocatalyst as well as preparation method and application of honeycomb ceramic monolithic photocatalyst Download PDFInfo
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- CN106563430A CN106563430A CN201610978890.2A CN201610978890A CN106563430A CN 106563430 A CN106563430 A CN 106563430A CN 201610978890 A CN201610978890 A CN 201610978890A CN 106563430 A CN106563430 A CN 106563430A
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- monoblock type
- honey comb
- honeycomb ceramic
- type photocatalyst
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- 239000000919 ceramic Substances 0.000 title claims abstract description 35
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052878 cordierite Inorganic materials 0.000 claims abstract description 15
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 6
- 238000003618 dip coating Methods 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 4
- 241000264877 Hippospongia communis Species 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 14
- 239000011247 coating layer Substances 0.000 claims description 11
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 7
- 238000010926 purge Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 229910001593 boehmite Inorganic materials 0.000 claims description 4
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003643 water by type Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 230000007306 turnover Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011943 nanocatalyst Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910003158 γ-Al2O3 Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
The invention discloses a honeycomb ceramic monolithic photocatalyst as well as a preparation method and application of the honeycomb ceramic monolithic photocatalyst. TiO2 is immobilized on cordierite honeycomb ceramic with an activated aluminum oxide coating by using a dip-coating method, and due to the adoption of the pre-coated activated aluminum oxide coating, the acting force between activated slurry and a carrier is enhanced, the shedding rate of the monolithic catalyst is reduced, meanwhile, the usage amount of a binder used in the coating process is reduced, and the activity of the catalyst is improved because activated ingredients are more easily exposed on the surface of the catalyst. The catalyst prepared by using the preparation method has the characteristics of large specific surface area, good light transparency, low shedding rate, high mechanical strength and the like and overcomes defects of the traditional monolithic photocatalyst.
Description
Technical field
The present invention relates to nanocatalyst technical field, more particularly, to a kind of ceramic honey comb monoblock type photocatalyst and its
Preparation method and application.
Background technology
Volatile organic matter（VOC）It is a kind of widely distributed, miscellaneous atmosphere pollution, it participates in photochemical fog
Reaction, the secondary particulate participated in air is formed, while major part VOC itself has toxicity and carcinogenecity, to ecological environment
Serious harm is caused with human health.Therefore, a kind of efficient, energy-conservation of urgent needss, the VOC purification techniques of green.
At present, conventional VOC purification techniques mainly has absorption method, heat-accumulation combustion, catalysis burning, photocatalysis etc..Absorption is net
Change method, material adsorption capacity is limited, and easily generation desorption causes secondary pollution.Heat-accumulation combustion and catalysis burning etc. are general in high temperature
Lower reaction, expends substantial amounts of energy.Photocatalysis method can under mild conditions realize the efficient degradation of VOC using luminous energy,
Simultaneously secondary pollution is not produced, with good application prospect.
The integral catalyzer obtained after photocatalyst is immobilized, changes powder photocatalyst pressure drop greatly, is difficult back
The shortcomings of receipts, be to realize through engineering approaches application foundation.Conventional metal mesh carrier or the network structure of foam nickel carrier, determine it
Under conditions of light transmission is met, mechanical strength is not suitable for large-scale application than relatively low.Meanwhile, immobilized process is more multiple
Miscellaneous, immobilized rear expulsion rate is difficult to control to.
The content of the invention
For the deficiencies in the prior art, the present invention discloses a kind of ceramic honey comb monoblock type photocatalyst and preparation method thereof
With.Light can be entered by the duct of ceramic honey comb, and the catalyst surface inside duct meets photocatalysis and light transmission is wanted
Ask, and high mechanical strength.
By TiO2Photocatalyst, using on the immobilized cordierite honeycomb ceramic to active aluminum oxide coating layer of dip coating,
Prepare ceramic honey comb monoblock type photocatalyst.The active oxidation aluminized coating of pre-coated, enhances the effect of active slurry and carrier
Power, reduces the expulsion rate of integral catalyzer.Simultaneously the active oxidation aluminized coating of pre-coated, reduces in coating process and bonds
The usage amount of agent, makes active component be easier exposed to catalyst surface, improves catalyst activity.
Gained catalyst of the invention has that specific surface area is big, light transmission is good, expulsion rate is low, high mechanical strength the features such as, change
It has been apt to the deficiency of traditional monoblock type photocatalyst.The technology of the present invention was not reported in pertinent literature and patent.
The technical scheme is that：
A kind of preparation method of ceramic honey comb monoblock type photocatalyst, it is characterised in that using dip coating by TiO2It is immobilized to tool
On the cordierite honeycomb ceramic of active aluminum oxide coating layer, the active oxidation aluminized coating of pre-coated enhances active slurry and carries
The active force of body, reduces the expulsion rate of integral catalyzer, while the active oxidation aluminized coating of pre-coated, reduces coated
The usage amount of binding agent in journey, makes active component be easier exposed to catalyst surface, improves catalyst activity, methods described
Comprise the following steps：
The first step, by a certain amount of TiO2It is scattered in a certain amount of deionized water with boehmite, under stirring condition, Deca
Concentrated nitric acid to pH is 3-4, continues to stir 30min, obtains active slurry；
Second step, the cordierite honeycomb ceramic carrier of active aluminum oxide coating layer vertically impregnated in above-mentioned slurry to carrier
Mid-height position, takes out after 5-10s, is inversely blown out additional size using air compressor machine purging, overturns carrier, will be untreated
Half vertically impregnated in above-mentioned slurry, take out after 5-10s, and additional size is inversely blown out；
3rd step, by gained ceramic honey comb monoblock type photocatalyst, stands a few hours under room temperature, 50 DEG C of drying, 400-550 DEG C of roasting
4h is burnt, ceramic honey comb monoblock type photocatalyst is obtained.
Cordierite carrier is impregnated in the alumina sol of solid content 28% and take out after 5-10s, blown using air compressor
Go out additional size, 50 DEG C of dryings, 550 DEG C of roastings.
TiO described in the first step2It is 1 with the mass ratio of boehmite:20~1:10；Solid content is 35% ~ 50%, and solid is accounted for
Mass ratio in total dispersion liquid.
A kind of ceramic honey comb monoblock type photocatalyst, it is characterised in that prepared according to methods described.
A kind of ceramic honey comb monoblock type photocatalyst photodegradative applications of THC at room temperature.
Using dip coating by TiO2On the immobilized cordierite honeycomb ceramic to active aluminum oxide coating layer of photocatalyst.In advance
The active oxidation aluminized coating of coating, enhances the active force of active slurry and carrier, reduces the expulsion rate of integral catalyzer.
Simultaneously the active oxidation aluminized coating of pre-coated, reduces the usage amount of binding agent in coating process, is easier active component sudden and violent
Catalyst surface is exposed to, catalyst activity is improve.Gained catalyst of the invention has that specific surface area is big, light transmission is good, comes off
Rate is low, high mechanical strength the features such as, improve the deficiency of traditional monoblock type photocatalyst.
The present invention has advantages below：
（1）Ceramic honey comb is used as carrier of photocatalyst, high mechanical strength.
（2）By the carrier of catalyst coated to active aluminum oxide coating layer, adhesiveness is good, and expulsion rate is low.
（3）Raw material is easy to get, low cost, prepares simply, reproducible.
Specific embodiment
Embodiments of the invention are elaborated below：The present embodiment is carried out under premised on technical solution of the present invention
Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following enforcements
Example.
Embodiment 1：
By 175g TiO2It is scattered in 200ml deionized waters with 25g boehmites, under stirring condition, Deca concentrated nitric acid to pH
For 3-4, continue to stir 30min, obtain active slurry.
The cordierite honeycomb ceramic carrier of the active aluminum oxide coating layer of 10 cm*10 cm*5 cm vertically impregnated in
To carrier height half position in above-mentioned slurry, take out after 5-10s, inversely blown out additional size using air compressor machine purging.Turn over
Rotaring carrier, untreated half vertically impregnated in above-mentioned slurry, take out after 5-10s, and additional size is inversely blown out.Room temperature
Lower standing a few hours, 50 DEG C of drying, 550 DEG C of roasting 4h.
Gained catalyst TiO2Loading is 18%, expulsion rate ＜ 1%, and THC the disposal efficiencies are 55% under room temperature.
Embodiment 2
By 165g TiO2It is scattered in 200ml deionized waters with 35g boehmites, under stirring condition, Deca concentrated nitric acid to pH
For 3-4, continue to stir 30min, obtain active slurry.
The cordierite honeycomb ceramic carrier of the active aluminum oxide coating layer of 10 cm*10 cm*5 cm vertically impregnated in
To carrier height half position in above-mentioned slurry, take out after 5-10s, inversely blown out additional size using air compressor machine purging.Turn over
Rotaring carrier, untreated half vertically impregnated in above-mentioned slurry, take out after 5-10s, and additional size is inversely blown out.Room temperature
Lower standing a few hours, 50 DEG C of drying, 550 DEG C of roasting 4h.
Gained catalyst TiO2Loading is 17%, expulsion rate ＜ 1%, and THC the disposal efficiencies are 45% under room temperature.
Embodiment 3
By 185g TiO2It is scattered in 200ml deionized waters with 15g boehmites, under stirring condition, Deca concentrated nitric acid to pH
For 3-4, continue to stir 30min, obtain active slurry.
The cordierite honeycomb ceramic carrier of the active aluminum oxide coating layer of 10 cm*10 cm*5 cm vertically impregnated in
To carrier height half position in above-mentioned slurry, take out after 5-10s, inversely blown out additional size using air compressor machine purging.Turn over
Rotaring carrier, untreated half vertically impregnated in above-mentioned slurry, take out after 5-10s, and additional size is inversely blown out.Room temperature
Lower standing a few hours, 50 DEG C of drying, 550 DEG C of roasting 4h.
Gained catalyst TiO2Loading is 19%, expulsion rate ＜ 1%, and THC the disposal efficiencies are 70% under room temperature.
Embodiment 4
By 185g TiO2It is scattered in 200ml deionized waters with 15g boehmites, under stirring condition, Deca concentrated nitric acid to pH
For 3-4, continue to stir 30min, obtain active slurry.
The cordierite honeycomb ceramic carrier of 10 cm*10 cm*5 cm vertically impregnated in above-mentioned slurry to carrier height
Half position, takes out after 5-10s, is inversely blown out additional size using air compressor machine purging.Upset carrier, by untreated half
In vertically impregnated in above-mentioned slurry, take out after 5-10s, additional size is inversely blown out.A few hours are stood under room temperature, 50 DEG C of bakings
It is dry, 550 DEG C of roasting 4h.
Gained catalyst TiO2Loading is 19%, expulsion rate 2%, and THC the disposal efficiencies are 64% under room temperature.
Embodiment 5：
By 70g γ-Al2O3It is scattered in 200ml deionized waters with 10g boehmites, under stirring condition, Deca concentrated nitric acid
It is 3-4 to pH, continues to stir 30min, obtains active slurry.
The cordierite honeycomb ceramic carrier of 10 cm*10 cm*5 cm vertically impregnated in above-mentioned slurry, take after 5-10s
Go out, inversely blown out additional size using air compressor machine purging.A few hours are stood under room temperature, 50 DEG C of drying, 550 DEG C of roasting 4h,
Obtain the cordierite honeycomb ceramic carrier of active aluminum oxide coating layer.
Claims (5)
1. a kind of preparation method of ceramic honey comb monoblock type photocatalyst, it is characterised in that using dip coating by TiO2It is immobilized to tool
On the cordierite honeycomb ceramic of active aluminum oxide coating layer, the active oxidation aluminized coating of pre-coated enhances active slurry and carries
The active force of body, reduces the expulsion rate of integral catalyzer, while the active oxidation aluminized coating of pre-coated, reduces coated
The usage amount of binding agent in journey, makes active component be easier exposed to catalyst surface, improves catalyst activity, methods described
Comprise the following steps：
The first step, by a certain amount of TiO2It is scattered in a certain amount of deionized water with boehmite, under stirring condition, Deca
Concentrated nitric acid to pH is 3-4, continues to stir 30min, obtains active slurry；
Second step, the cordierite honeycomb ceramic carrier of active aluminum oxide coating layer vertically impregnated in above-mentioned slurry to carrier
Mid-height position, takes out after 5-10s, is inversely blown out additional size using air compressor machine purging, overturns carrier, will be untreated
Half vertically impregnated in above-mentioned slurry, take out after 5-10s, and additional size is inversely blown out；
3rd step, by gained ceramic honey comb monoblock type photocatalyst, stands a few hours under room temperature, 50 DEG C of drying, 400-550 DEG C of roasting
4h is burnt, ceramic honey comb monoblock type photocatalyst is obtained.
2. the preparation method of ceramic honey comb monoblock type photocatalyst according to claim 1, it is characterised in that carry cordierite
Body impregnates in the alumina sol of solid content 28% and taken out after 5-10s, and using air compressor additional size is blown out, and 50 DEG C are done
It is dry, 550 DEG C of roastings.
3. the preparation method of ceramic honey comb monoblock type photocatalyst according to claim 1, it is characterised in that described in the first step
TiO2It is 1 with the mass ratio of boehmite:20~1:10；Solid content is 35% ~ 50%, the quality that solid is accounted in total dispersion liquid
Than.
4. a kind of ceramic honey comb monoblock type photocatalyst, it is characterised in that be prepared into according to the arbitrary methods described of claim 1-3
Arrive.
5. the ceramic honey comb monoblock type photocatalyst photodegradative applications of THC at room temperature according to claim 4.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610978890.2A CN106563430A (en) | 2016-11-08 | 2016-11-08 | Honeycomb ceramic monolithic photocatalyst as well as preparation method and application of honeycomb ceramic monolithic photocatalyst |
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|---|---|---|---|
| CN201610978890.2A CN106563430A (en) | 2016-11-08 | 2016-11-08 | Honeycomb ceramic monolithic photocatalyst as well as preparation method and application of honeycomb ceramic monolithic photocatalyst |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109012756A (en) * | 2018-09-17 | 2018-12-18 | 南京景铄新材料科技有限公司 | A kind of catalysis material and preparation method thereof with high stability |
| CN110662605A (en) * | 2017-05-30 | 2020-01-07 | 先技精工(日本)有限公司 | Method for producing catalyst or adsorbent carrier, and catalyst or adsorbent carrier |
| CN113318719A (en) * | 2020-02-28 | 2021-08-31 | 广东粤能净环保科技有限公司 | Photocatalytic unit and application thereof |
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| WO1999064739A1 (en) * | 1998-06-12 | 1999-12-16 | Guiterrez, Richard, N. | Method for a reduction of emissions in combustion processes |
| CN1384152A (en) * | 2001-04-28 | 2002-12-11 | 中国科学院化学研究所 | Titania nano-paint for photocatalytic decomposition of organic matter and its prepn |
| CN2533415Y (en) * | 2002-03-08 | 2003-01-29 | 戴各生 | Air cleaning device |
| JP2005254128A (en) * | 2004-03-11 | 2005-09-22 | Toshiba Ceramics Co Ltd | Photocatalyst particle and method of immobilizing it, and photocatalytic member |
| CN102180705A (en) * | 2011-02-28 | 2011-09-14 | 武汉大方机电有限公司 | Preparation method for titanium dioxide thin layer loaded on surface of inorganic ceramic matrix |
| CN104998697A (en) * | 2015-07-10 | 2015-10-28 | 上海纳米技术及应用国家工程研究中心有限公司 | Application method for integral catalyst active coating |
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2016
- 2016-11-08 CN CN201610978890.2A patent/CN106563430A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO1999064739A1 (en) * | 1998-06-12 | 1999-12-16 | Guiterrez, Richard, N. | Method for a reduction of emissions in combustion processes |
| CN1384152A (en) * | 2001-04-28 | 2002-12-11 | 中国科学院化学研究所 | Titania nano-paint for photocatalytic decomposition of organic matter and its prepn |
| CN2533415Y (en) * | 2002-03-08 | 2003-01-29 | 戴各生 | Air cleaning device |
| JP2005254128A (en) * | 2004-03-11 | 2005-09-22 | Toshiba Ceramics Co Ltd | Photocatalyst particle and method of immobilizing it, and photocatalytic member |
| CN102180705A (en) * | 2011-02-28 | 2011-09-14 | 武汉大方机电有限公司 | Preparation method for titanium dioxide thin layer loaded on surface of inorganic ceramic matrix |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110662605A (en) * | 2017-05-30 | 2020-01-07 | 先技精工(日本)有限公司 | Method for producing catalyst or adsorbent carrier, and catalyst or adsorbent carrier |
| CN109012756A (en) * | 2018-09-17 | 2018-12-18 | 南京景铄新材料科技有限公司 | A kind of catalysis material and preparation method thereof with high stability |
| CN113318719A (en) * | 2020-02-28 | 2021-08-31 | 广东粤能净环保科技有限公司 | Photocatalytic unit and application thereof |
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