CN106554748A - A kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof - Google Patents
A kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106554748A CN106554748A CN201610984788.3A CN201610984788A CN106554748A CN 106554748 A CN106554748 A CN 106554748A CN 201610984788 A CN201610984788 A CN 201610984788A CN 106554748 A CN106554748 A CN 106554748A
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- Prior art keywords
- hollow glass
- environmental protection
- glass micropearl
- type sealing
- protection type
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof, the hollow glass micropearl environmental protection type sealing adhesive includes the modified inorganic filler of the polydimethylsiloxane of 80～150 weight portions, the hollow glass micropearl of 25～40 weight portions, the antioxidant of 3～15 weight portions, the mineral oil of 5～18 weight portions, the formaldehyde absorbent of 2～8 weight portions, the thixotropic agent of 1～10 weight portion, 5～18 weight portions.In the present invention, hollow glass micro-ball has very high filling capacity, can effectively reduce VOC indexs, plays the effect of environmental protection；Through the inorganic filler being modified, its particle surface is changed into lipophile by hydrophilic, so as to improve the compatibility of the filler in hollow glass micropearl environmental protection type sealing adhesive, realizes dispersed and does not occur to reunite.The environmental protection type sealing adhesive that invention is provided produces synergism by cooperating to each component and each component content so that fluid sealant proportion compared with it is light, fillibility is good, amalgamation is good, dispersibility is excellent.
Description
Technical field
The present invention relates to fluid sealant field, more particularly to a kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof.
Background technology
Fluid sealant is that one kind deforms with sealing surface shape, is difficult trickling, has the encapsulant of certain caking property, is to use
To fill configuration gap to play the adhesive of sealing function.In many fields such as building, finishing, automobile equipment, electronic apparatus
It is required for using fluid sealant playing the purpose being bonded and sealed.But there is larger proportion, fillibility and melt in existing fluid sealant
The problem of the bad, bad dispersibility of conjunction property, how to develop a kind of proportion compared with it is light, fillibility is good, amalgamation is good, dispersibility is excellent, VOC
The low fluid sealant that can be used in building, automobile, electronic apparatus, is the problem demanding prompt solution of this area one.
The content of the invention
It is an object of the invention to provide a kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof, can solve the problem that existing
Fluid sealant proportion is larger, fillibility and amalgamation is bad, bad dispersibility technical problem.
To solve above-mentioned technical problem, the technical solution used in the present invention is：
A kind of hollow glass micropearl environmental protection type sealing adhesive, including the raw material of following parts by weight：
Preferably, the antioxidant is 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzotriazole, methylene (trihydroxy hexichol
Ketone) or poly- [(1- (β-ethyl) -2,2,6,6- tetramethyl -4- piperidyls) succinic acid] ester.
Preferably, the mineral oil is white oil.
Preferably, the formaldehyde absorbent is methylol melamine, carbamide, carbamide condensation substance, polyacrylamide
Or polyamide.
Preferably, the thixotropic agent is in aerosil, organobentonite, castor oil hydrogenated and polyamide wax
Plant or various.
Preferably, the modified inorganic filler is 1000～5000r/min in rotating speed by inorganic filler and modifying agent, temperature
Obtain to be modified under conditions of 60～120 DEG C.
Preferably, the inorganic filler is aluminium oxide, Zinc Oxide, silicon dioxide, titanium dioxide, calcium sulfate, Calcium Carbonate, height
One or more of ridge soil, clay, molybdenum bisuphide and carborundum.
Preferably, the modifying agent be vinyl three ('beta '-methoxy ethyoxyl) silane, VTES,
γ-dredge propyl trimethoxy silicane, APTES or γ-glycidyl ether oxygen propyl trimethoxy silicon
Alkane.
Preferably, the particle diameter of the hollow glass micropearl is 80～100 μm.
The invention provides a kind of preparation method of hollow glass micropearl environmental protection type sealing adhesive, comprises the following steps：
By polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, formaldehyde absorbent, thixotropic agent, modified nothing
Machine filler melting mixing, obtains hollow glass micropearl environmental protection type sealing adhesive.
The beneficial effects of the present invention is：
The invention provides a kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof, the hollow glass micropearl environmental protection
Fluid sealant includes the polydimethylsiloxane of 80～150 weight portions, the hollow glass micropearl of 25～40 weight portions, 3～15 weights
The amount antioxidant of part, the mineral oil of 5～18 weight portions, the formaldehyde absorbent of 2～8 weight portions, the thixotropic agent of 1～10 weight portion, 5
The modified inorganic filler of～18 weight portions.The present invention is with polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, first
Aldehyde absorbent, thixotropic agent, modified inorganic filler be raw material, hollow glass micro-ball have very high filling capacity, effectively can subtract
Little VOC indexs, play the effect of environmental protection；Through the inorganic filler being modified, its particle surface is changed into lipophile by hydrophilic, from
And the compatibility of the filler in hollow glass micropearl environmental protection type sealing adhesive is improved, realize dispersed and do not occur to reunite.In addition, sending out
The environmental protection type sealing adhesive of bright offer produces synergism so that fluid sealant ratio by cooperating to each component and each component content
Weight compared with it is light, fillibility is good, amalgamation is good, dispersibility is excellent, VOC is low.
Specific embodiment
In order to further appreciate that the present invention, the preferred embodiments of the invention are described with reference to embodiment, but
It is it should be appreciated that these descriptions are simply to further illustrate the features and advantages of the present invention rather than to patent requirements of the present invention
Limit.
A kind of hollow glass micropearl environmental protection type sealing adhesive that the present invention is provided, including the raw material of following parts by weight：
The present invention with polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, formaldehyde absorbent, thixotropic agent,
Modified inorganic filler be raw material, hollow glass micro-ball have very high filling capacity, VOC indexs can be effectively reduced, ring is played
The effect of guarantor；Through the inorganic filler being modified, its particle surface is changed into lipophile by hydrophilic, so as to improve filler hollow
The compatibility in glass microballoon environmental protection type sealing adhesive, realizes dispersed and does not occur to reunite.In addition, the environment-protective sealing that invention is provided
Glue produces synergism by cooperating to each component and each component content so that fluid sealant proportion is good compared with light, fillibility,
Amalgamation is good, dispersibility is excellent, VOC is low.
In the present invention, the parts by weight of polydimethylsiloxane are 80～150 parts；In an embodiment of the present invention, gather
The parts by weight of dimethyl siloxane are 100～130 parts.
Hollow glass micropearl has high filling capacity, can reduce the VOC of hollow glass micropearl environmental protection type sealing adhesive.At this
In inventive embodiment, the particle diameter of hollow glass micropearl is 80～100 μm.
In the present invention, the parts by weight of hollow glass micropearl are 25～40 parts；In an embodiment of the present invention, hollow glass
The parts by weight of glass microballon are 30～35 parts.
In order to improve the ageing-resistant performance of hollow glass micropearl environmental protection type sealing adhesive, in an embodiment of the present invention, antioxidant
For 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzotriazole, methylene (trihydroxybenzophenone) or poly- [(1- (β-ethyl) -2,2,
6,6- tetramethyl -4- piperidyls) succinic acid] ester.
In the present invention, the parts by weight of antioxidant are 3～15 parts；In an embodiment of the present invention, the weight of antioxidant
Number is 6～11 parts.
Mineral oil can adjust the properties such as hollow glass micropearl environmental protection type sealing adhesive elongation at break, elastic restoration ratio, while
The compatibility of the hollow glass micropearl in fluid sealant can also be improved；In inventive embodiment, mineral oil is white oil；At other
Embodiment mineral oil in fluid is one or more in white oil 10#, white oil 15#, white oil 26#, white oil 46# and white oil 68#.
In the present invention, the parts by weight of mineral oil are 5～18 parts；In an embodiment of the present invention, the weight of mineral oil
Number is 9～14 parts.
Formaldehyde absorbent can absorb the formaldehyde in environmental protection type sealing adhesive and in other regions, improve the feature of environmental protection of fluid sealant
Energy；In an embodiment of the present invention, formaldehyde absorbent is methylol melamine, carbamide, carbamide condensation substance, polypropylene
Amide or polyamide.
In the present invention, the parts by weight of formaldehyde absorbent are 2～8 parts；In an embodiment of the present invention, formaldehyde absorbent
Parts by weight be 4～6 parts.
Thixotropic agent is used for the viscosity for improving environmental protection type sealing adhesive, and makes environmental protection type sealing adhesive have thixotropy.In the reality of the present invention
Apply in example, thixotropic agent is one or more in aerosil, organobentonite, castor oil hydrogenated and polyamide wax；
In other embodiment, thixotropic agent is the one kind or two in aerosil, organobentonite, castor oil hydrogenated and polyamide wax
Kind.
In the present invention, the parts by weight of thixotropic agent are 1～10 part；In an embodiment of the present invention, the weight of thixotropic agent
Number is 4～7 parts.
Modified inorganic filler can its in environmental protection type sealing adhesive dispersing uniformity, the compatibility；In an embodiment of the present invention, change
Property inorganic filler be 1000～5000r/min in rotating speed by inorganic filler and modifying agent, the time is 6～12h, temperature is 60～
It is modified under conditions of 120 DEG C and obtains.
In an embodiment of the present invention, inorganic filler be aluminium oxide, Zinc Oxide, silicon dioxide, titanium dioxide, calcium sulfate,
One or more of Calcium Carbonate, Kaolin, clay, molybdenum bisuphide and carborundum.
In an embodiment of the present invention, modifying agent is vinyl three ('beta '-methoxy ethyoxyl) silane, three ethoxy of vinyl
Base silane, γ-dredge propyl trimethoxy silicane, APTES or γ-glycidyl ether oxygen propyl front three
TMOS.
In an embodiment of the present invention, 4～8wt% of the modifier content for inorganic filler addition.Modifier content is little
When inorganic filler 4wt%, inorganic filler fully can not be modified；Modifier content is more than inorganic filler 8wt%, makes product
Intensity and toughness reduce.
In the present invention, the parts by weight of modified inorganic filler are 5～18 parts；In an embodiment of the present invention, be modified nothing
The parts by weight of machine filler are 9～15 parts.
Present invention also offers a kind of preparation method of hollow glass micropearl environmental protection type sealing adhesive, comprises the following steps：
By polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, formaldehyde absorbent, thixotropic agent, modified nothing
Machine filler melting mixing, obtains hollow glass micropearl environmental protection type sealing adhesive.
Wherein, polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, formaldehyde absorbent, thixotropic agent and change
Property inorganic filler is same as above, will not be described here.
According to the present invention, after various raw materials are mixed, through melting mixing, you can obtain hollow glass micropearl environment-protective sealing
Glue.
Test result indicate that, the tensile strength of the hollow glass micropearl environmental protection type sealing adhesive of the present invention, elongation at break.
In order to further illustrate the present invention, a kind of hollow glass micropearl environmental protection that with reference to embodiments present invention is provided
Fluid sealant and preparation method thereof is described in detail.
Embodiment 1
Modified inorganic filler：Modified rotating speed 1000r/min, the time is 6h, 60 DEG C of modification temperature, three (beta-methoxy of vinyl
Base oxethyl) silane addition for alumina weight 2.0%；
By 80kg polydimethylsiloxane, 25kg hollow glass micropearls, 3kg 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzo
Triazole, 5kg white oil 10#, 2kg polyamide, 1kg aerosils, 5kg modified inorganic filler melting mixings, obtain hollow glass
Glass microballon environmental protection type sealing adhesive.
Embodiment 2
Modified inorganic filler：Modified rotating speed 5000r/min, the time is 8h, 120 DEG C of modification temperature, γ-dredge propyl group trimethoxy
Base silane addition is the 2.0% of Zinc Oxide and total weight of silicon dioxide amount；
By 150kg polydimethylsiloxane, 40kg hollow glass micropearls, 15kg methylene (trihydroxybenzophenone), 9kg
White oil 15#, 9kg white oil 26#, 8kg polyacrylamide, 10kg organobentonites, 18kg modified inorganic filler melting mixings, obtain
Hollow glass micropearl environmental protection type sealing adhesive.
Embodiment 3
Modified inorganic filler：Modified rotating speed 4000r/min, the time is 9h, 90 DEG C of modification temperature, vinyl triethoxyl silicon
Alkane addition for titanium dioxide, calcium sulfate and Calcium Carbonate gross weight 2.0%；
By 100kg polydimethylsiloxane, 30kg hollow glass micropearls, 6kg methylene (trihydroxybenzophenone), 4kg
White oil 46#, 5kg white oil 68#, 4kg carbamide condensation substance, 3kg castor oil hydrogenated, 4kg polyamide waxes, 9kg are modified nothing
Machine filler melting mixing, obtains hollow glass micropearl environmental protection type sealing adhesive.
Embodiment 4
Modified inorganic filler：Modified rotating speed 2000r/min, the time is 12h, 80 DEG C of modification temperature, γ-glycidyl ether oxygen
Propyl trimethoxy silicane addition for Kaolin, clay, molybdenum bisuphide and carborundum gross weight 2.0%；
By 130kg polydimethylsiloxane, 32kg hollow glass micropearls, 11kg poly- [(1- (β-ethyl) -2,2,6,6- four
Methyl -4- piperidyls) succinic acid] ester, 4kg white oil 10#, 4kg white oil 15#, 4kg white oil 26#, 5kg carbamide, 4kg thixotropic agent,
12kg modified inorganic filler melting mixings, obtain hollow glass micropearl environmental protection type sealing adhesive.
Embodiment 5
Modified inorganic filler：Modified rotating speed 3000r/min, the time is 10h, 100 DEG C of modification temperature, three second of 3- aminopropyls
TMOS addition for silicon dioxide, titanium dioxide, Kaolin and clay gross weight 2.0%；
By 120kg polydimethylsiloxane, 35kg hollow glass micropearls, 9kg2- (2 '-hydroxyl -5 '-aminomethyl phenyl) benzo
Triazole, 7kg white oil 26#, 7kg white oil 46#, 6kg methylol melamines, 3kg aerosils, 3kg organobentonites, 13kg change
Property inorganic filler melting mixing, obtains hollow glass micropearl environmental protection type sealing adhesive.
The density of the hollow glass micropearl environmental protection type sealing adhesive prepared by embodiment 1～5, hardness, tensile strength, fracture
The test of percentage elongation, abnormal smells from the patient, the results are shown in Table 1.
The test result of 1 embodiment 1～5 of table
Disclosed above is only specific implementation of the patent example, but this patent is not limited to this, general for this area
For logical technical staff, under the premise without departing from the principles of the invention, the deformation made should be regarded as belonging to the scope of the present invention.
Claims (10)
1. a kind of hollow glass micropearl environmental protection type sealing adhesive, it is characterised in that including the raw material of following parts by weight：
2. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the antioxidant is 2- (2 '-hydroxyls
Base -5 '-aminomethyl phenyl) benzotriazole, methylene (trihydroxybenzophenone) or poly- [(1- (β-ethyl) -2,2,6,6- tetramethyls
Base -4- piperidyls) succinic acid] ester.
3. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the mineral oil is white oil.
4. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the formaldehyde absorbent is hydroxyl first
Base melamine, carbamide, carbamide condensation substance, polyacrylamide or polyamide.
5. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the thixotropic agent is gas phase dioxy
One or more in SiClx, organobentonite, castor oil hydrogenated and polyamide wax.
6. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the modified inorganic filler is by nothing
Machine filler and modifying agent are 1000～5000r/min in rotating speed, and temperature is to be modified under conditions of 60～120 DEG C to obtain.
7. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 6, it is characterised in that the inorganic filler is oxidation
Aluminum, Zinc Oxide, silicon dioxide, titanium dioxide, calcium sulfate, Calcium Carbonate, Kaolin, clay, molybdenum bisuphide and carborundum it is a kind of or
It is various.
8. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 6, it is characterised in that the modifying agent is vinyl three
('beta '-methoxy ethyoxyl) silane, VTES, γ-dredge propyl trimethoxy silicane, three second of 3- aminopropyls
TMOS or γ-glycidyl ether oxygen propyl trimethoxy silicane.
9. hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that the grain of the hollow glass micropearl
Footpath is 80～100 μm.
10. a kind of preparation method of hollow glass micropearl environmental protection type sealing adhesive as claimed in claim 1, it is characterised in that include
Following steps：
Polydimethylsiloxane, hollow glass micropearl, antioxidant, mineral oil, formaldehyde absorbent, thixotropic agent, modified inorganic are filled out
Material melting mixing, obtains hollow glass micropearl environmental protection type sealing adhesive.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610984788.3A CN106554748A (en) | 2016-11-09 | 2016-11-09 | A kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof |
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| CN201610984788.3A CN106554748A (en) | 2016-11-09 | 2016-11-09 | A kind of hollow glass micropearl environmental protection type sealing adhesive and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107163907A (en) * | 2017-05-23 | 2017-09-15 | 句容耀皮节能玻璃科技发展有限公司 | A kind of double glazing environmental protection type sealing adhesive and preparation method thereof |
| CN110117477A (en) * | 2018-02-06 | 2019-08-13 | 上杭鑫昌龙实业有限公司 | Silicone sealant and preparation method thereof |
| CN111849388A (en) * | 2020-07-31 | 2020-10-30 | 南京大学 | High-voltage-resistant insulating non-drying waterproof sealant |
| CN112680174A (en) * | 2020-12-25 | 2021-04-20 | 郑州圣莱特空心微珠新材料有限公司 | Modified silicone adhesive, preparation method and application thereof, and vacuum glass |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163907A (en) * | 2017-05-23 | 2017-09-15 | 句容耀皮节能玻璃科技发展有限公司 | A kind of double glazing environmental protection type sealing adhesive and preparation method thereof |
| CN110117477A (en) * | 2018-02-06 | 2019-08-13 | 上杭鑫昌龙实业有限公司 | Silicone sealant and preparation method thereof |
| CN111849388A (en) * | 2020-07-31 | 2020-10-30 | 南京大学 | High-voltage-resistant insulating non-drying waterproof sealant |
| CN112680174A (en) * | 2020-12-25 | 2021-04-20 | 郑州圣莱特空心微珠新材料有限公司 | Modified silicone adhesive, preparation method and application thereof, and vacuum glass |
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