CN106554067B - Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing - Google Patents

Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing Download PDF

Info

Publication number
CN106554067B
CN106554067B CN201611025438.0A CN201611025438A CN106554067B CN 106554067 B CN106554067 B CN 106554067B CN 201611025438 A CN201611025438 A CN 201611025438A CN 106554067 B CN106554067 B CN 106554067B
Authority
CN
China
Prior art keywords
degreaser
acrylamide
ter
oil
heat extraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611025438.0A
Other languages
Chinese (zh)
Other versions
CN106554067A (en
Inventor
赵世芬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENGLI OIL FIELD FANGYUAN CHEMICAL INDUSTRY Co.,Ltd.
Original Assignee
Yantai Zhiben Intellectual Property Operation and Management Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yantai Zhiben Intellectual Property Operation and Management Co Ltd filed Critical Yantai Zhiben Intellectual Property Operation and Management Co Ltd
Priority to CN201611025438.0A priority Critical patent/CN106554067B/en
Publication of CN106554067A publication Critical patent/CN106554067A/en
Application granted granted Critical
Publication of CN106554067B publication Critical patent/CN106554067B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/32—Hydrocarbons, e.g. oil
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/04—Surfactants, used as part of a formulation or alone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention belongs to disposing polluted water in oil technical fields, the degreaser of heavy crude heat extraction sewage processing is used for more particularly to a kind of ter-polymers, the degreaser is to be made by acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone by micellar free radical copolymerization method, its molecular weight is 10000~90000, preferably 30000~50000, the molar ratio of the acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone is 1: 0.1~1.5: 0.5~3, preferably 1: 1.1: 1.5.Degreaser of the invention is simple with preparation, heat-resistant salt-resistant performance is strong, at low cost, and oil removal rate height can reach 96% or more；And the oil recovery that separation generates does not influence subsequent crude oil dehydration.Therefore, present invention is generally applicable in the oil removing process of oil-field thick-oil thermal recovery sewage.

Description

Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing
Technical field
The present invention relates to a kind of degreasers for disposing polluted water in oil, and in particular to a kind of ter-polymers are used for viscous crude The degreaser of thermal recovery sewage treatment.
Background technique
The viscosity of viscous crude is big, and the sewage treatment for exploiting generation is always to restrict one of the important link of its development.Crude oil warp After the heat chemistry settling processing a period of time for crossing dehydration, silt and other mechanical admixtures enter sewerage together, make dirt Total suspended matter in water reaches 20000mg/L or so.Larger difficulty is caused to sewage treatment.Meanwhile in order to enable super-viscous oil Ground is given rise to, the substances such as some surfactants, such as sulfonate are added in oil recovery process, so that Produced Liquid needs Breaking emulsion and dewatering causes a large amount of chemical agent to remain in sewage, and causing sewage, not only oil content is high, but also the stabilization of emulsion Property is strong, so that sewage oil removing and purified treatment are increasingly complex.
Conventional treatment process (natural subsidence-coagulant precipitation-filtering) is difficult to obtain heavy crude heat extraction sewage effectively at present Processing.Another method for removing oil-bearing wastewater Crude Oil is chemical method, that is, uses oil removing agent method.Degreaser substantially divides For following two categories, element of the first species's multiplicity, deoiling effect is good, but there is preparation process complexity, anti-salt property are poor, higher cost Disadvantage；Another kind of degreaser ingredient is single, and preparation method and technique are relatively simple, and the requirement to water quality is lower, but exists and remove The disadvantage of oily effect difference.It is less for the patent of condensed oil sewage processing aspect at present.
Patent ZL201410254042.8 " a kind of composite flocculation deoiling agent for oily waste water treatment " uses sulfuric acid Aluminium, magnesium chloride, magnesium hydroxide, bentonite and polyacrylamide are combined, which has dosage few, and oil removal efficiency is high, The features such as preparation is simple, at low cost, but degreaser needs are used with corrosive magnesium hydroxide, the compound is to equipment With stronger corrosiveness.
Summary of the invention
The present invention for currently available technology deficiency and a kind of ter-polymers are provided and are handled for heavy crude heat extraction sewage Degreaser, the present invention has simple process, heat-resistant salt-resistant performance strong, low in cost, and the feature that deoiling effect is good.
The invention discloses the degreasers that a kind of ter-polymers are used for heavy crude heat extraction sewage processing, which is by third Acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone are made by micellar free radical copolymerization method, molecule Amount is 10000~90000, and molecular formula is as follows:
Wherein: n=40~340, preferably 60~90；
M=2~250, preferably 30~45；
P=20~300, preferably 120~180.
The molar ratio of the acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone is 1:0.1 ~1.5:0.5~3, preferably 1:1.1:1.5.
Preferably, the degreaser molecular weight is 30000~50000.
It is a further object to provide a kind of ter-polymers to be used for the degreaser of heavy crude heat extraction sewage processing Preparation method, the preparation method include the following steps:
(1) the N- benzyl-N- second of deionized water and aforementioned proportion is added in the three-necked flask equipped with thermometer, stirring rod Base acrylamide is warming up to 30~35 DEG C, 30~60min of constant temperature under 300~500rpm stirring rate；
(2) acrylamide of aforementioned proportion is added in above-mentioned three-necked flask, and temperature is risen to 40~50 DEG C, be added Hydrophobic grouping solubilizer stirs 20~30min, and stirring rate is 500~600rpm, and after stirring, temperature rises to 65~70 DEG C, 30~50min of constant temperature obtains mixture；
(3) pH value that mixture is adjusted with the sodium hydroxide solution of 6mol/L, makes pH value between 7~8, by aforementioned proportion N-vinyl pyrrolidone be added to adjustment pH value after mixture in, adjustings stirring rate be 200~300rpm, constant temperature 50 ~60 DEG C, after stirring 30~60min, initiator is added, temperature rises to 70~80 DEG C, and stirring rate is 500~800rpm, constant temperature 3~5h is reacted, stirring is stopped, Temperature fall obtains polymer solution；
(4) polymer solution is transferred in round-bottomed flask, is evaporated under reduced pressure, gum-like product is obtained, with acetone washing 3~5 It is secondary, it is then placed in drying box dry 12~36h, finally obtains acrylamide/N- Benzyl-N-ethyl acrylamide/N- ethylene Base pyrrolidones ter-polymers.
The dosage of the deionized water is 10~20 times of acrylamide monomer quality；The hydrophobic grouping solubilizer For lauryl sodium sulfate or dodecyl sodium sulfate, dosage is the 2~5% of acrylamide monomer quality；The initiator For K2S2O8Or NaHSO3, dosage is the 5~10% of acrylamide monomer quality.
The reaction equation is as follows:
Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing, as follows using technical process:
According to oil-containing situation in oil-field thick-oil thermal recovery sewage, degreaser of the invention is added into sewage, realize demulsification and Water-oil separating is further processed after recycling petroleum substance for subsequent technique.The specific additional amount of degreaser is as follows:
(1) when oil-containing α >=500mg/L, degreaser, which is added, makes 30~80mg/L of mass concentration of degreaser in sewage；
When (2) 500 ﹥ oil-containing α >=200mg/L, degreaser, which is added, makes 10~20mg/ of mass concentration of degreaser in sewage L；
When (3) 200 ﹥ oil-containing α >=50mg/L, degreaser, which is added, makes 5~10mg/L of mass concentration of degreaser in sewage；
(4) when oil-containing α < 50mg/L, degreaser, which is added, makes 0.1~5mg/L of mass concentration of degreaser in sewage.
The present invention provides the degreaser that ter-polymers are used for oil-field thick-oil thermal recovery sewage treatment, belongs to amphipathic polymer Molecule contains heterocyclic group, amide groups, phenyl ring and tertiary amine group on the polymer molecule, dredging in amphipathic polymer molecule Water chain is the formal distribution with block, can be adsorbed with the oil in sewage, and the polar group on side chain is then easy to be deep into In greasy dirt, it is easy to that complexing occurs with the gum asphalt in viscous crude, promotes the flocculation of greasy dirt, and then reach to condensed oil sewage The purpose of oil removal treatment.In addition, the present invention introduces pyrrolidone group when designing oil removing agent molecule, which has rigid Property structure, it is difficult to torsion and fracture, have preferable heat-resisting property；The group introduced in this molecule simultaneously belongs to nonionic Type has stronger salt-tolerant trait.
The present invention is had the following advantages and beneficial effects: compared with prior art
(1) raw material sources of degreaser of the invention are extensive, and synthesis technology is simple, and product is easily obtained and transports preservation；
(2) degreaser of the invention is adaptable, and dosage is few, can meet the needs of environmental protection and oil field development；
(3) degreaser of the invention have temperature resistance salt resistant character, can heatproof up to 250 DEG C, resistance to salinity reaches 230000mg/ L；
(4) degreaser of the invention has the characteristics that oil removal efficiency is high to condensed oil sewage processing, and condensed oil sewage processing removes For oil cut rate up to 96% or more, more existing medicament improves 45% or more, meets the pretreated requirement of oil removing of condensed oil sewage.
Specific embodiment
The present invention is described in further detail below with reference to specific embodiment, and referring to data.It should be understood that these embodiments It is of the invention solely for the purpose of illustration, rather than limit the scope of the invention in any way.
Embodiment 1: degreaser C1And preparation method thereof
(1) degreaser C1Composition, component and molecular weight it is as follows:
Degreaser C1By acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone according to 1:1.1: 1.5 molar ratios are made by micellar free radical copolymerization method, average molecular weight 42000.
(2) degreaser C1The preparation method is as follows:
1. the N- benzyl-N- of 1052g deionized water and 1.1mol is added in the three-necked flask equipped with thermometer, stirring rod Ethyl acrylamide is warming up to 32 DEG C, constant temperature 60min under 300rpm stirring rate；
2. the acrylamide of 1mol is added in above-mentioned three-necked flask, and temperature is risen to 50 DEG C, 2.55g 12 is added Sodium alkyl sulfate stirs 30min, stirring rate 550rpm, and after stirring, temperature rises to 68 DEG C, and constant temperature 50min is mixed Close object；
3. adjusting the pH value of mixture with the sodium hydroxide solution of 6mol/L, make pH value 7, by the N- vinyl of 1.5mol Pyrrolidones be added to adjustment pH value after mixture in, adjustings stirring rate be 300rpm, 50 DEG C of constant temperature, stirring 60min after, 7.11g K is added2S2O8, temperature rises to 75 DEG C, stirring rate 800rpm, isothermal reaction 5h, stops stirring, and Temperature fall obtains To polymer solution；
4. polymer solution is transferred in round-bottomed flask, it is evaporated under reduced pressure, obtains gum-like product, with acetone washing 3 times, so After be put into drying box dry 36h, finally obtain acrylamide/N- Benzyl-N-ethyl acrylamide/n-vinyl pyrrolidone Ter-polymers C1。
Example 2: degreaser C2And preparation method thereof
(1) degreaser C2Composition, component and molecular weight it is as follows:
Degreaser C2By acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone according to 1:0.1: 0.5 molar ratio is made by micellar free radical copolymerization method, average molecular weight 12000.
(2) degreaser C2The preparation method is as follows:
1. the N- benzyl-of 710.8g deionized water and 0.1mol is added in the three-necked flask equipped with thermometer, stirring rod N- ethyl acrylamide is warming up to 30 DEG C, constant temperature 45min under 400rpm stirring rate；
2. the acrylamide of 1mol is added in above-mentioned three-necked flask, and temperature is risen to 45 DEG C, 1.42g 12 is added Sodium alkyl sulfonate stirs 25min, stirring rate 600rpm, and after stirring, temperature rises to 70 DEG C, and constant temperature 30min is mixed Close object；
3. adjusting the pH value of mixture with the sodium hydroxide solution of 6mol/L, make pH value 7, by the N- vinyl of 0.5mol Pyrrolidones be added to adjustment pH value after mixture in, adjustings stirring rate be 260rpm, 60 DEG C of constant temperature, stirring 30min after, 5.68g NaHSO is added3, temperature rises to 80 DEG C, stirring rate 500rpm, isothermal reaction 4h, stops stirring, and Temperature fall obtains To polymer solution；
4. polymer solution is transferred in round-bottomed flask, it is evaporated under reduced pressure, obtains gum-like product, with acetone washing 5 times, so After be put into drying box it is dry for 24 hours, finally obtain acrylamide/N- Benzyl-N-ethyl acrylamide/n-vinyl pyrrolidone Ter-polymers C2。
Embodiment 3: degreaser C3And preparation method thereof
(1) degreaser C3Composition, component and molecular weight it is as follows:
Degreaser C3By acrylamide, N- Benzyl-N-ethyl acrylamide and n-vinyl pyrrolidone according to 1:1.5:3 Molar ratio is made by micellar free radical copolymerization method, average molecular weight 86000.
(2) degreaser C3The preparation method is as follows:
1. the N- benzyl-of 1421.6g deionized water and 1.5mol is added in the three-necked flask equipped with thermometer, stirring rod N- ethyl acrylamide is warming up to 35 DEG C, constant temperature 30min under 500rpm stirring rate；
2. the acrylamide of 1mol is added in above-mentioned three-necked flask, and temperature is risen to 40 DEG C, 3.55g 12 is added Sodium alkyl sulfate stirs 20min, stirring rate 500rpm, and after stirring, temperature rises to 65 DEG C, and constant temperature 40min is mixed Close object；
3. adjusting the pH value of mixture with the sodium hydroxide solution of 6mol/L, make pH value 8, by the N- vinylpyridine of 3mol Pyrrolidone is added in the mixture after adjusting pH value, and adjusting stirring rate is 200rpm, 55 DEG C of constant temperature, after stirring 45min, is added Enter 3.55g K2S2O8, temperature rises to 70 DEG C, stirring rate 700rpm, isothermal reaction 3h, stops stirring, and Temperature fall obtains Polymer solution；
4. polymer solution is transferred in round-bottomed flask, it is evaporated under reduced pressure, obtains gum-like product, with acetone washing 4 times, so After be put into drying box dry 12h, finally obtain acrylamide/N- Benzyl-N-ethyl acrylamide/n-vinyl pyrrolidone Ter-polymers C3。
4 degreaser C of embodiment1Field application
Multi-purpose station T2Water be heavy crude heat extraction sewage, test process scale be 120m3/ d, water oil content 678mg/L, Sewage salinity 25680mg/L utilizes degreaser C of the invention1To multi-purpose station T2Sewage carry out oil removal treatment, add oil removing The concentration of degreaser is 45mg/L in sewage after agent, and oil content is reduced to 11.5mg/L after processing, and oil content reduces by 98.3%, removes Oil works well, and reaches technique requirement.
5 degreaser C of embodiment2Field application
Multi-purpose station T5Water be heavy crude heat extraction sewage, test process scale be 70m3/ d, water oil content 532mg/L, it is dirty Water salinity 32563mg/L utilizes degreaser C of the invention2To multi-purpose station T5Sewage carry out oil removal treatment, add degreaser The concentration of degreaser is 35mg/L in sewage afterwards, and oil content is reduced to 11.7mg/L after processing, and oil content reduces by 97.8%, oil removing It works well, and reaches technique requirement.
6 degreaser C of embodiment3Field application
Multi-purpose station T8Water be heavy crude heat extraction sewage, test process scale be 80m3/ d, water oil content 468mg/L, it is dirty Water salinity 42568mg/L utilizes degreaser C of the invention3To multi-purpose station T8Sewage carry out oil removal treatment, add degreaser The concentration of degreaser is 18mg/L in sewage afterwards, and oil content is reduced to 12.6mg/L after processing, and oil content reduces by 97.3%, oil removing It works well, and reaches technique requirement.

Claims (8)

1. ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing, which is by acrylamide, N- benzyl-N- second Base acrylamide and n-vinyl pyrrolidone are made by micellar free radical copolymerization method, and molecular weight is 10000~ 90000, molecular formula is as follows:
Wherein: n=40~340；
M=2~250；
P=20~300.
2. the degreaser that ter-polymers according to claim 1 are used for heavy crude heat extraction sewage processing, which is characterized in that institute The molar ratio of acrylamide, N- Benzyl-N-ethyl acrylamide and the n-vinyl pyrrolidone stated is 1:0.1~1.5:0.5 ~3.
3. the degreaser that ter-polymers according to claim 2 are used for heavy crude heat extraction sewage processing, which is characterized in that institute The molar ratio of acrylamide, N- Benzyl-N-ethyl acrylamide and the n-vinyl pyrrolidone stated is 1:1.1:1.5.
4. ter-polymers according to claim 1 or 2 are used for the degreaser of heavy crude heat extraction sewage processing, feature exists In the degreaser molecular weight is 30000~50000.
5. preparation method of the ter-polymers according to claim 1 for the degreaser of heavy crude heat extraction sewage processing, Be characterized in that, the preparation method specifically includes the following steps:
(1) the N- Benzyl-N-ethyl third of deionized water and aforementioned proportion is added in the three-necked flask equipped with thermometer, stirring rod Acrylamide is warming up to 30~35 DEG C, 30~60min of constant temperature under 300~500rpm stirring rate；
(2) acrylamide of aforementioned proportion is added in above-mentioned three-necked flask, and temperature is risen to 40~50 DEG C, be added hydrophobic Group solubilizer stirs 20~30min, and stirring rate is 500~600rpm, and after stirring, temperature rises to 65~70 DEG C, perseverance 30~50min of temperature obtains mixture；
(3) pH value that mixture is adjusted with the sodium hydroxide solution of 6mol/L, makes pH value between 7~8, by the N- of aforementioned proportion Vinyl pyrrolidone is added in the mixture after adjusting pH value, and adjusting stirring rate is 200~300rpm, constant temperature 50~60 DEG C, after stirring 30~60min, initiator is added, temperature rises to 70~80 DEG C, and stirring rate is 500~800rpm, isothermal reaction 3~5h, stops stirring, and Temperature fall obtains polymer solution；
(4) polymer solution is transferred in round-bottomed flask, is evaporated under reduced pressure, obtains gum-like product, with acetone washing 3~5 times, so After be put into drying box dry 12~36h, finally obtain acrylamide/N- Benzyl-N-ethyl acrylamide/N- vinyl pyrrole Alkanone ter-polymers.
6. preparation method of the ter-polymers according to claim 5 for the degreaser of heavy crude heat extraction sewage processing, It is characterized in that, the dosage of the deionized water is 10~20 times of acrylamide monomer quality.
7. preparation method of the ter-polymers according to claim 5 or 6 for the degreaser of heavy crude heat extraction sewage processing, It is characterized in that, the hydrophobic grouping solubilizer is lauryl sodium sulfate or dodecyl sodium sulfate, dosage is propylene The 2~5% of amide monomer quality.
8. preparation method of the ter-polymers according to claim 5 or 6 for the degreaser of heavy crude heat extraction sewage processing, It is characterized in that, the initiator is K2S2O8Or NaHSO3, dosage is the 5~10% of acrylamide monomer quality.
CN201611025438.0A 2016-11-17 2016-11-17 Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing Active CN106554067B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611025438.0A CN106554067B (en) 2016-11-17 2016-11-17 Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611025438.0A CN106554067B (en) 2016-11-17 2016-11-17 Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing

Publications (2)

Publication Number Publication Date
CN106554067A CN106554067A (en) 2017-04-05
CN106554067B true CN106554067B (en) 2019-05-17

Family

ID=58443427

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611025438.0A Active CN106554067B (en) 2016-11-17 2016-11-17 Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing

Country Status (1)

Country Link
CN (1) CN106554067B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108623740B (en) * 2018-05-18 2020-03-27 中国石油化工股份有限公司 Temperature-resistant oil removing agent for oily sewage in oil field and preparation method thereof
CN111592120A (en) * 2020-06-19 2020-08-28 华辰环保能源(广州)有限责任公司 Sulfide ecological inhibitor for reducing viscosity loss of oil field polymer and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464798A (en) * 2010-11-05 2012-05-23 中国石油化工股份有限公司 Amide macromonomer, thermothickening copolymer, preparation methods and application thereof
CN104558407B (en) * 2013-10-24 2017-02-15 中国石油化工股份有限公司 Temperature-resistant salt-resistant water-soluble polymer, and preparation and application method thereof

Also Published As

Publication number Publication date
CN106554067A (en) 2017-04-05

Similar Documents

Publication Publication Date Title
CN104176788B (en) A kind of degreaser for oil field binary combination flooding produced sewerage and preparation method thereof
DK2738237T3 (en) Amphiphilic macromolecule and its use
CN106348362B (en) A kind of heavy crude heat extraction sewage degreaser of resisting high temperature, high salt and preparation method thereof
EP2738191B1 (en) Amphiphilic macromolecule and use
CN100554191C (en) Process for the treatment of ternary combination flooding sewage
CN106554067B (en) Ter-polymers are used for the degreaser of heavy crude heat extraction sewage processing
EP2738190B1 (en) Amphiphilic macromolecule and use
Ren et al. Preparation of a novel zwitterion flocculant with the characteristics of quaternary ammonium salt cation and dithiocarbamate anion and its application in produced water treatment
CN106749892B (en) A kind of degreaser of heavy crude heat extraction sewage and preparation method thereof
US20190375665A1 (en) Sludge dehydrating agent and sludge dehydrating method
CN107235529A (en) A kind of degreaser handled for oil-contaminated water of oil field and preparation method thereof
CN106587245B (en) Degreaser and preparation method thereof for heavy crude heat extraction sewage processing
CN106145257A (en) A kind of condensed oil sewage inorganic agent and its preparation method and application
CN106335968A (en) Demulsifier for sewage high in thickened oil content and preparation method
CN104479659A (en) Method of cleaning oil-based drilling cuttings and recovering base oil
CN106495270B (en) A kind of degreaser for polymer flooding water processing
CN106946768B (en) A kind of oily wastewater degreaser and preparation method thereof
CN106542604A (en) Degradable heavy crude heat extraction sewage degreaser and preparation method thereof
CN106495242B (en) A kind of degreaser and preparation method thereof of salt tolerant polymer flooding water
CN106495272B (en) A kind of binary combination flooding sewage water degreaser and preparation method thereof
CN107298470A (en) A kind of degreaser of oil field binary combination flooding output water
CN106542608A (en) A kind of degreaser for heavy crude heat extraction sewage process
CN106395962A (en) Flotation agent for oily sewage treatment and preparation method thereof
CN106749123B (en) A kind of degreaser and preparation method thereof of the binary of quaternary amine containing heterocycle combination flooding sewage
CN106543116B (en) A kind of degreaser of amphoteric ion type ternary composite flooding water extraction

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20200323

Address after: 257000 West Fourth Road and North zero row Road, Dongying District, Dongying City, Shandong Province

Patentee after: SHENGLI OIL FIELD FANGYUAN CHEMICAL INDUSTRY Co.,Ltd.

Address before: Zhaoyuan City, Shandong province 265400 Yantai City Shing Road No. 108 Building No. 1

Patentee before: YANTAI ZHIBEN INTELLECTUAL PROPERTY MANAGEMENT Co.,Ltd.

TR01 Transfer of patent right