CN106552819A - A kind of soil restoring device and method - Google Patents

A kind of soil restoring device and method Download PDF

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Publication number
CN106552819A
CN106552819A CN201710056738.3A CN201710056738A CN106552819A CN 106552819 A CN106552819 A CN 106552819A CN 201710056738 A CN201710056738 A CN 201710056738A CN 106552819 A CN106552819 A CN 106552819A
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CN
China
Prior art keywords
soil
electrode
restoring device
pollution
soil restoring
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Withdrawn
Application number
CN201710056738.3A
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Chinese (zh)
Inventor
宋欢
赵飞超
阮宜武
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Individual
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Individual
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Priority to CN201710056738.3A priority Critical patent/CN106552819A/en
Publication of CN106552819A publication Critical patent/CN106552819A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • B09C1/085Reclamation of contaminated soil chemically electrochemically, e.g. by electrokinetics

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

China's soil pollution in recent years is in aggravation trend; the backwardness of soil protection work causes that some areas soil pollution is serious, pollution type is various; show as the old and new's pollutant and deposit, the situation of Inorganic whisker pollution, make soil remediation become one of environmental problem urgently to be resolved hurrily.Field coil is introduced conventional electronic soil restoring device by the present invention, there is transfer under electric field driven in heavy metal ion, 1 ions of OH and H+1, acted on by long-range navigation magnetic force in moving process, mobile route changes, and no longer concentrates on surrounding them and is generally evenly distributed in the collecting zone vertical with electric field.Pass through magnetic field simultaneously and direction of an electric field is exchanged, H+ ions can be neutralized and avoid P in soil H value from being acidified with OH ions.Therefore, polarization phenomena can be reduced by method proposed by the present invention, improves soil remediation efficiency, extend the service life of electrode.

Description

A kind of soil restoring device and method
Technical field
The present invention relates to a kind of soil restoring device and method, belong to field of environment engineering technology.
Background technology
Soil is one of Main Natural Resources that people depend on for existence, and the important component part of ecological environment.Industry And the waste water,waste gas and industrial residue that life is produced enters soil by water body, air, and run up to the journey for surmounting soil self purification activity When spending, soil pollution will be caused.In recent years in aggravation trend, the backwardness of soil protection work causes some areas for China's soil pollution Soil pollution is serious, pollution type is various, show as the old and new's pollutant and deposit, Inorganic whisker pollution situation, make soil Reparation becomes one of environmental problem urgently to be resolved hurrily.
Conventional soil remediation method includes soil ablution, biological treatment, electro reclamation etc. at present.Electronic soil Repairing method has the advantages that low cost, application are wide, speed is fast, secondary pollution is few, it is adaptable to hypotonicity soil, can remove soil The heavy metals such as copper, zinc, lead, cadmium, nickel, arsenic, mercury, manganese in earth, it is also possible to which removing phenol, p- nitrophenols, hexachlorobutadiene etc. has Machine thing.There is the technical bottlenecks such as acid band migration, the control of P in soil H, polarization in application process in electronic soil remediation method, its Middle polarization problem is especially prominent.Polarization phenomena are distributed under electric field driven mainly due to cation and anion and excessively concentrate on Cause near electrode.In order to overcome this phenomenon, researcher to propose polarity switching technology, approach anode technology and inject slow Rush solution technique, although improve to some extent but still achieving no breakthrough property progress.
The present invention proposes that using a kind of composite electric soil restoring device and method that magnetic field is combined with electric field emphasis goes Except the heavy metal contaminants such as Cu2+, Pb2+, Fe3+ in soil.Compared with traditional electronic soil remediation method, prosthetic device is added Electromagnetic field generating coil, changes the mobile route of anion, cation using long-range navigation magnetic force, reduces anion, cation Concentration degree.Meanwhile, by exchanging electric field and magnetic direction respectively, H+ ions and OH-ion can be neutralized, it is to avoid soil acid Change.The enforcement of the present invention has to environmental protection to promoting the development of electronic soil restoring technology with important theory value Important actual application value.
The content of the invention
In view of the problems of prior art, the invention discloses a kind of soil restoring device and method, utilizing should Method can promote the recovery of point source soil pollution and the soil ecosystem of face source soil pollution, promote the good of degenerated soil Turn, shorten the soil remediation cycle.
Field coil is introduced conventional electronic soil restoring device by the present invention, and heavy metal ion, OH-1 ions and H+1 are in electricity Field drives lower generation transfer, is acted on by long-range navigation magnetic force in moving process, and mobile route changes, and no longer concentrates on electricity The collecting zone vertical with electric field is generally evenly distributed in around pole.Pass through the change of magnetic field and direction of an electric field simultaneously, can be with With H+ ions and OH-ion, it is to avoid P in soil H value is acidified.Therefore, polarization phenomena can be reduced by method proposed by the present invention, Soil remediation efficiency is improved, extends the service life of electrode.
Specifically, the present invention is achieved through the following technical solutions:
A kind of soil restoring device and method can be applicable to in-situ immobilization and showering.Using phenolic resin plate composition rectangle soil Earth repairs pond, and positive and negative electrode is arranged on repairs pond length direction both sides, and coil is used to produce along pond four sides uniform winding is repaired Even magnetic field.
By the improvement of said structure, negative ions are caused mobile route to be sent out by electric field force and long-range navigation magnetic force force action Fringe region that is raw to change, being no longer gathered in surrounding them and be generally evenly distributed on reparation pond width, contributes to reduction Polarization phenomena, are easy to subsequently focus on pollutant.
Wherein, positive-negative electrode plate used adopts graphite material, is powered by dc source, voltage 220V ~ 230V, changes direct current Electric both positive and negative polarity is capable of achieving the conversion of direction of an electric field.
Wherein, electromagnetic field generating coil is using the copper coil of bag paint, diameter 0.5mm ~ 1mm, the number of turn 50 ~ 200, the concrete number of turn Can require to adjust according to magnetic field intensity, magnetic field intensity 16mT ~ 50mT.
Wherein, graphite electrode plate is fastened by phenolic resin bracket clamp, and above-below direction can adjust.
Wherein, electromagnetic field generating coil is changed direct current both positive and negative polarity and is capable of achieving magnetic by powered by direct current, voltage 220V ~ 230V The conversion of field direction.
In common electric soil restoring device, due to the electrophoresis behavior of negative ions, electrode surface is made to cover pollutant And impurity, the operating efficiency and service life of electrode are seriously reduced, and electrode are no longer deposited in by above-mentioned improvement negative ions Surface and be generally evenly distributed in reparation pond both sides elongated zones, improve efficiency and life-span.
Description of the drawings
Fig. 1 is a kind of structural representation of soil restoring device in the present invention.
Fig. 2 is a kind of structural representation of soil restoring device electrode suppor in the present invention.
Fig. 3 is a kind of structural representation of soil restoring device electrode connecting end in the present invention.
Fig. 4 is a kind of soil remediation mechanism schematic diagram for not adding magnetic field in the present invention.
Fig. 5 is a kind of soil remediation mechanism schematic diagram in addition magnetic field in the present invention.
Specific embodiment
Hereinafter, the present invention is more fully described with reference to the accompanying drawings, and the present invention can come real in many different forms Apply, and should not be construed as limited to embodiment set forth herein.Conversely, thesing embodiments are provided so that the disclosure will be thorough Completely, and those skilled in the art are fully conveyed the scope of the present invention to.
Hereinafter, the exemplary embodiment of the present invention is more fully described with reference to the accompanying drawings.
With reference to Fig. 1 ~ 3, a kind of soil restoring device according to the present invention, including anode electrode connection terminal 1, electrode terminal Clamping screw 2, electrode suppor 3, graphite electrode 4, reparation pond 5, negative electrode connection terminal 6, electrode terminal locking nut 7, magnetic Field coil positive terminal 8, field coil 9, field coil negative terminal 10.
Anode electrode connection terminal:Using red copper plate stamping and forming, 10 ~ 15mm of thickness.
Electrode suppor:Shaping, plate thickness 15mm ~ 20mm are connected by screw using phenolic resin plate.
Graphite electrode:Using phosphorus content 94% ~ 99% high-carbon graphite electrode, current density be more than 10A/cm2.
Field coil positive terminal:One end is connected with field coil, and the other end is connected with DC power anode.
Field coil:Using the bag copper coil of paint, diameter 0.5mm ~ 1mm, the number of turn 50 ~ 200, the concrete number of turn can be according to will The magnetic field intensity adjustment asked, magnetic field intensity 16mT ~ 50mT.
Field coil negative terminal:One end is connected with field coil, and the other end is connected with DC power cathode.
As shown in Figure 3, it is shown that a kind of electronic soil remediation mechanism schematic diagram for not adding magnetic field, negative ions are made in electric field With lower close to positive and negative electrode, the heavy metal region of high concentration is formed about in electrode, with the increase electrode table of repair time Heavy metal is adhered in face and impurity is more and more, and the white film of formation reduces electric-field intensity, causes the drop of soil remediation efficiency It is low, it is therefore necessary to change electrode in time and could continue normal work.
As shown in Figure 4, it is shown that a kind of electronic soil remediation mechanism schematic diagram in addition magnetic field, the magnetic that field coil is produced Line of force B is vertical with ion motion direction, magnetic line of force direction ecto-entad.Ion is in motion process except being made by electric field force With also being acted on by long-range navigation magnetic force, therefore mobile route will change.By the shifting for controlling the adjustable ion of magnetic field intensity Dynamic path, makes ion no longer concentrate on electrode and is nearby generally evenly distributed in the elongated zones for repairing pond both sides.
Embodiments of the invention are the foregoing is only, the present invention is not limited to.The present invention can have various conjunctions Suitable change and change.All any modification, equivalent substitution and improvements made within the spirit and principles in the present invention etc., all should It is included within protection scope of the present invention.

Claims (4)

1. a kind of soil restoring device, it is characterised in that:
A kind of described soil restoring device, it is made up of ten parts, is anode electrode connection terminal 1, electrode terminal lock respectively Tight bolt 2, electrode suppor 3, graphite electrode 4, reparation pond 5, negative electrode connection terminal 6, electrode terminal locking nut 7, magnetic field Coil electrode terminal 8, field coil 9, field coil negative terminal 10.
2. a kind of soil restoring device as claimed in claim 1, it is characterised in that:
Described electrode suppor, is connected by screw shaping, plate thickness 15mm ~ 20mm using phenolic resin plate.
3. a kind of soil restoring device as claimed in claim 1, it is characterised in that:
Described field coil, is wrapped in reparation pond outer surface, copper wire diameter 0.5mm ~ 1mm, the number of turn using the copper coil of bag paint 50 ~ 200, the magnetic field intensity adjustment that the concrete number of turn can be as requested, magnetic field intensity 16mT ~ 50mT.
4. a kind of soil restoring device as claimed in claim 1, it is characterised in that:
Described graphite electrode, using phosphorus content 94% ~ 99% high-carbon graphite electrode, current density be more than 10A/cm2.
CN201710056738.3A 2017-01-25 2017-01-25 A kind of soil restoring device and method Withdrawn CN106552819A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710056738.3A CN106552819A (en) 2017-01-25 2017-01-25 A kind of soil restoring device and method

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Application Number Priority Date Filing Date Title
CN201710056738.3A CN106552819A (en) 2017-01-25 2017-01-25 A kind of soil restoring device and method

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CN106552819A true CN106552819A (en) 2017-04-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109731902A (en) * 2019-01-17 2019-05-10 天津友爱环保科技有限公司 A kind of movable type electrochemical soil prosthetic device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102294350A (en) * 2008-12-30 2011-12-28 中国科学院沈阳应用生态研究所 System and method for resorting organic polluted soil
CN102500610A (en) * 2012-01-04 2012-06-20 大恩(天津)环境技术研发有限公司 Electrodynamic and drop-irrigation combined heavy-metal-polluted soil remediation method
CN102513344A (en) * 2012-01-04 2012-06-27 大恩(天津)环境技术研发有限公司 Novel method for remedying heavy-metal contaminated soil with electrodynamics
CN103418607A (en) * 2013-08-29 2013-12-04 江苏大学 Magnetic-assistance electrokinetic remediation device for contaminated soil
CN205762950U (en) * 2016-06-02 2016-12-07 中国石油天然气股份有限公司 The processing means of contaminated soil
CN206535858U (en) * 2017-01-25 2017-10-03 宋欢 A kind of soil electro reclamation device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102294350A (en) * 2008-12-30 2011-12-28 中国科学院沈阳应用生态研究所 System and method for resorting organic polluted soil
CN102500610A (en) * 2012-01-04 2012-06-20 大恩(天津)环境技术研发有限公司 Electrodynamic and drop-irrigation combined heavy-metal-polluted soil remediation method
CN102513344A (en) * 2012-01-04 2012-06-27 大恩(天津)环境技术研发有限公司 Novel method for remedying heavy-metal contaminated soil with electrodynamics
CN103418607A (en) * 2013-08-29 2013-12-04 江苏大学 Magnetic-assistance electrokinetic remediation device for contaminated soil
CN205762950U (en) * 2016-06-02 2016-12-07 中国石油天然气股份有限公司 The processing means of contaminated soil
CN206535858U (en) * 2017-01-25 2017-10-03 宋欢 A kind of soil electro reclamation device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109731902A (en) * 2019-01-17 2019-05-10 天津友爱环保科技有限公司 A kind of movable type electrochemical soil prosthetic device

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Application publication date: 20170405

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