CN106544184A - Glass polishing powder cleaning agent and preparation method thereof - Google Patents
Glass polishing powder cleaning agent and preparation method thereof Download PDFInfo
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- CN106544184A CN106544184A CN201610849645.1A CN201610849645A CN106544184A CN 106544184 A CN106544184 A CN 106544184A CN 201610849645 A CN201610849645 A CN 201610849645A CN 106544184 A CN106544184 A CN 106544184A
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- polishing powder
- cleaning agent
- glass polishing
- powder cleaning
- agitator
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
The invention discloses a kind of glass polishing powder cleaning agent and preparation method thereof, its each component and mass percent is as follows：Flocculant 0.16%～0.3%；Inorganic base 20%～30%；Intercalating agent 18%～30%；Deionized water 39.7%～61.84%.The formula of the glass polishing powder cleaning agent that the present invention is provided is reasonable, there is very strong chelant ability to ceria, silica, alundum (Al2O3) oxide, cleaning product qualification rate is more than 95%, cleaning performance is good, simultaneously by means of the flocculation of flocculant, so that the dust granules for departing from substrate surface are rapidly condensed into big cluster of grains in cleaning fluid, so as to reduce the dust granules solubility in cleaning fluid, greatly prolong the service life of cleaning fluid, and then reduces cost, beneficial to wide popularization and application.The preparation technology of the method that the present invention is provided is simple, be easily achieved, and production efficiency is high, can rapidly and efficiently prepare the good glass polishing powder cleaning agent product of cleaning performance.
Description
Technical field
The invention belongs to cleaning agent technical field, and in particular to a kind of glass polishing powder cleaning agent and preparation method thereof, can
Cleared off after rear, safety glass plain grinding and sapphire glass surface of polished ceria, dioxy with being widely used in CNC glass
The dust granules such as SiClx, alundum (Al2O3) dirt is cleaned.
Background technology
In recent years, with the fast development of touch screen display technologies, digital camera and high-grade wrist-watch industry, to touch-screen system
It is that touch-screen mobile phone manufacturing enterprise, computer manufacturing industry bring unlimited development space, digital camera and height especially in time to make enterprise
Shelves wrist-watch industry has also obtained fast development.Touch-screen cover plate processing enterprise is also with developing growth rapidly.However, now on the market
Without a kind of cleaning agent, can be widely applied to CNC glass clear off after, table after safety glass plain grinding and after sapphire glass polishing
The dust granules such as face ceria, silica, alundum (Al2O3) dirt is cleaned.For this reason, it may be necessary to research and develop a kind of glass polishing powder
Cleaning agent and preparation method thereof.This just brings unlimited development business opportunity to glass polishing powder cleaning agent manufacturing enterprise.
The content of the invention
For one of above-mentioned deficiency, the object of the invention be, there is provided a kind of formula is reasonable prepare it is simple, can rapidly by
The dust granules thoroughly cleanings such as the silica on ceria, sapphire glass or alundum (Al2O3) on simple glass are clean
And not corroding base material, the substrate surface after cleaning is cleaned without the dirts such as white point, watermark, and the good glass polishing powder of cleaning performance
Agent.
The object of the invention is also resided in, there is provided a kind of method for preparing above-mentioned glass polishing powder cleaning agent.The preparation of the method
Technique is simple, it is easy to accomplish, rapidly and efficiently can prepare can rapidly by the ceria on simple glass, sapphire glass
The dust granules such as silica or alundum (Al2O3) thoroughly cleaning totally and does not corrode base material, and the substrate surface after cleaning is without white
The glass polishing powder cleaning agent of the dirts such as point, watermark.
For achieving the above object, technical scheme provided by the present invention is：A kind of glass polishing powder cleaning agent, its each group
Divide and mass percent is as follows：
Flocculant 0.16%～0.3%；
Inorganic base 20%～30%；
Intercalating agent 18%～30%；
Deionized water 39.7%～61.84%.
Used as a modification of the present invention, the flocculant is PAMC.
Used as a modification of the present invention, it is 6,500,000 cation polypropylenes that the PAMC is molecular weight
Acid amides.
Used as a modification of the present invention, the inorganic base is NaOH.
As a modification of the present invention, the intercalating agent be 1-hydroxy ethylidene-1,1-diphosphonic acid, the adjacent sodium of ethylenediamine two,
One or more mixing in sodium gluconate.
Used as a modification of the present invention, the intercalating agent is by 1-hydroxy ethylidene-1,1-diphosphonic acid, two adjacent sodium of ethylenediamine
Mix with sodium gluconate and form, wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for glass polishing powder cleaning agent mass percent 6%～10%；
Two adjacent sodium of ethylenediamine accounts for glass polishing powder cleaning agent mass percent 6%～10%；Sodium gluconate accounts for glass polishing
Powder cleaning agent mass percent 6%～10%.
Used as a modification of the present invention, the 1-hydroxy ethylidene-1,1-diphosphonic acid is 50% 1-hydroxy ethylidene-1,1-diphosphonic acid.
A kind of preparation method of above-mentioned glass polishing powder cleaning agent, which comprises the following steps：
（1）Deionized water is weighed by weight percentage, is subsequently poured into agitator, and is heated to 45～55 DEG C, then keeps constant temperature；
In weighing PAMC by weight percentage and adding deionized water, turn on agitator makes cation polypropylene acyl
Amine stops heating after being completely dissolved；
（2）NaOH is weighed by weight percentage, agitator is poured into, is stirred；
（3）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, weighs 1-hydroxy ethylidene-1,1-diphosphonic acid by weight percentage, and falls
Enter in agitator, stir；
（4）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, weighs two adjacent phenylacetic acid of ethylenediamine by weight percentage
Sodium and sodium gluconate, are subsequently poured in agitator, and stirring and dissolving makes glass polishing powder cleaning agent system into after transparent clear liquid
Product.
As a modification of the present invention, the step（1）In agitator rotating speed be 80～120 revs/min.
Beneficial effects of the present invention are：Rationally, the present invention's matches somebody with somebody the formula of the glass polishing powder cleaning agent that the present invention is provided
Fang Heli, contained intercalating agent have very strong chelant ability to ceria, silica, alundum (Al2O3) oxide, right
Thoroughly, more than 95%, cleaning performance is good for cleaning product qualification rate for the cleaning of polishing powder, while the flocculation by means of flocculant is made
With so that the dust granules for departing from substrate surface are rapidly condensed into big cluster of grains in cleaning fluid, so as to reduce in cleaning fluid
Dust granules solubility, greatly prolong the service life of cleaning fluid, and then reduces cost, beneficial to wide popularization and application, especially fit
For the ceria after under Ultrasonic Conditions, clearing off to CNC glass, after the flat film of glass tempering on surface, sapphire glass
The dust granules such as the silica or alundum (Al2O3) after grinding on surface carry out thoroughly cleaning, the substrate surface after cleaning not by
Corrosion, surface is without dirts such as white point, watermarks.The preparation technology of the method that the present invention is provided is simple, be easily achieved, production efficiency
Height, rapidly and efficiently can prepare can rapidly by the ceria on simple glass, the silica on sapphire glass or three oxygen
Change the dust granules such as two aluminium thoroughly cleaning and totally and do not corrode base material, the substrate surface after cleaning is without dirts such as white point, watermarks
Glass polishing powder cleaning agent product.
With reference to embodiment, the invention will be further described.
Specific embodiment
Embodiment 1：A kind of glass polishing powder cleaning agent is present embodiments provided, its each component and mass percent is such as
Under：Flocculant 0.3%；Inorganic base 30%；Intercalating agent 30%；Deionized water 39.7%.
Preferably, the flocculant is preferably PAMC.Further, the PAMC is excellent
Molecular weight is elected as 6,500,000 PAMCs.
Preferably, the inorganic base is NaOH.
In the present embodiment, preferably, the intercalating agent is by 1-hydroxy ethylidene-1,1-diphosphonic acid（HEDP）, the adjacent phenylacetic acid of ethylenediamine two
Sodium（EDDHA-Na）Mix with sodium gluconate and form, wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for glass polishing powder cleaning agent quality hundred
Divide and compare 10%；Two adjacent sodium of ethylenediamine accounts for glass polishing powder cleaning agent mass percent 10%；Sodium gluconate accounts for glass
Polishing powder cleaning agent mass percent 10%.Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid is preferably 50% 1-hydroxy ethylene-1,1-diphosphonic
Acid（50%HEDP）.
In other embodiments, the intercalating agent can be 1-hydroxy ethylidene-1,1-diphosphonic acid, two adjacent sodium of ethylenediamine, grape
One or more mixing in sodium saccharate.
A kind of preparation method of above-mentioned glass polishing powder cleaning agent, which comprises the following steps：
（1）Deionized water is weighed by weight percentage, is subsequently poured into agitator, and is heated to 45～55 DEG C, preferably 50 DEG C, so
After keep constant temperature；In weighing PAMC by weight percentage and adding deionized water, turn on agitator, make sun from
Sub- polyacrylamide stops heating after being completely dissolved；Preferably, the step（1）In agitator rotating speed be 80～120 turns/
Point.
（2）NaOH is weighed by weight percentage, agitator is poured into, is stirred；
（3）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, preferably less than 50 DEG C, weighs hydroxyl by weight percentage
Ethylene-diphosphonic acid, and pour in agitator, stir；
（4）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, preferably less than 50 DEG C, weighs second two by weight percentage
Two adjacent sodium of amine and sodium gluconate, are subsequently poured in agitator, and stirring and dissolving makes glass into after transparent clear liquid
Polishing powder cleaning agent product.
The preparation technology of the method that the present invention is provided is simple, be easily achieved, and production efficiency is high, can rapidly and efficiently prepare energy
Rapidly will be the dust granules such as the ceria on simple glass, the silica on sapphire glass or alundum (Al2O3) thoroughly clear
Wash clean and do not corrode base material, glass polishing powder cleaning agent product of the substrate surface after cleaning without dirts such as white point, watermarks.
Embodiment 2, a kind of glass polishing powder cleaning agent that this enforcement is provided and preparation method thereof, which is basic with embodiment 1
Identical, difference is：The each component and its mass percent of glass polishing powder cleaning agent is as follows：Flocculant 0.16%；Inorganic base
20%；Intercalating agent 18%；Deionized water 61.84%.Wherein described intercalating agent is by 1-hydroxy ethylidene-1,1-diphosphonic acid（HEDP）, ethylenediamine two it is adjacent
Sodium（EDDHA-Na）Mix with sodium gluconate and form, wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for the cleaning of glass polishing powder
Agent mass percent 6%；Two adjacent sodium of ethylenediamine accounts for glass polishing powder cleaning agent mass percent 6%；Sodium gluconate
Account for glass polishing powder cleaning agent mass percent 6%.
Embodiment 3, a kind of glass polishing powder cleaning agent that this enforcement is provided and preparation method thereof, which is basic with embodiment 1
Identical, difference is：The each component and its mass percent of glass polishing powder cleaning agent is as follows：Flocculant 0.2%；Inorganic base
25%；Intercalating agent 24%；Deionized water 50.8%.Wherein described intercalating agent is by 1-hydroxy ethylidene-1,1-diphosphonic acid（HEDP）, the adjacent benzene of ethylenediamine two
Guanidine-acetic acid sodium（EDDHA-Na）Mix with sodium gluconate and form, wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for glass polishing powder cleaning agent
Mass percent 8%；Two adjacent sodium of ethylenediamine accounts for glass polishing powder cleaning agent mass percent 8%；Sodium gluconate is accounted for
Glass polishing powder cleaning agent mass percent 8%.
Embodiment 4, a kind of glass polishing powder cleaning agent that this enforcement is provided and preparation method thereof, which is basic with embodiment 1
Identical, difference is：The each component and its mass percent of glass polishing powder cleaning agent is as follows：Flocculant 0.25%；Inorganic base
25%；Intercalating agent 28%；Deionized water 46.75%.Wherein described intercalating agent is by 1-hydroxy ethylidene-1,1-diphosphonic acid（HEDP）, ethylenediamine two it is adjacent
Sodium（EDDHA-Na）Mix with sodium gluconate and form, wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for the cleaning of glass polishing powder
Agent mass percent 8%；Two adjacent sodium of ethylenediamine accounts for glass polishing powder cleaning agent mass percent 10%；Sodium gluconate
Account for glass polishing powder cleaning agent mass percent 10%.
Rationally, its Cleaning principle is the formula of the glass polishing powder cleaning agent that the present invention is provided：Ceria, titanium dioxide
Silicon, the alundum (Al2O3) oxide bear point lotus in cleaning fluid, and flocculant PAMC positively charged, have neutralized oxygen
The negative point lotus in part in compound, under huge legendary turtle and agent effect, by means of the mechanical force of ultrasonic wave, makes dust granules depart from base material table
Face, and big cluster of grains is flocculated in cleaning fluid, so as to reach cleaning purpose.Above-described embodiment is only that the present invention is preferably real
Mode is applied, the present invention can not enumerate out the technical scheme of one of whole embodiments, all employing above-described embodiments, or root
The equivalent variations done according to above-described embodiment, in the scope of the present invention.
Compared with prior art, the invention has the advantages that：
1st, selected intercalating agent has very strong chelant ability to ceria, silica, alundum (Al2O3) oxide, to polishing
Thoroughly, cleaning product qualification rate is more than 95% for the cleaning of powder；
2nd, by means of the flocculation of PAMC so that the dust granules for departing from substrate surface are fast in cleaning fluid
Big cluster of grains is formed in rapid hardening, so as to reduce the dust granules solubility in cleaning fluid, greatly prolongs the service life of cleaning fluid.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and is changed.Therefore, specific embodiment disclosed and described above is the invention is not limited in, to the present invention's
Some modifications and changes should also be as falling in the scope of the claims of the present invention.Although additionally, used in this specification
Some specific terms, but these terms are merely for convenience of description, constitute any restriction to the present invention, adopt and which
Other cleaning agents and preparation method obtained from same or similar method and component, in the scope of the present invention.
Claims (9)
1. a kind of glass polishing powder cleaning agent, it is characterised in that its each component and mass percent is as follows：
Flocculant 0.16%～0.3%；
Inorganic base 20%～30%；
Intercalating agent 18%～30%；
Deionized water 39.7%～61.84%.
2. glass polishing powder cleaning agent according to claim 1, it is characterised in that the flocculant is cation polypropylene
Acid amides.
3. glass polishing powder cleaning agent according to claim 2, it is characterised in that the PAMC for point
Son amount is 6,500,000 PAMCs.
4. glass polishing powder cleaning agent according to claim 1, it is characterised in that the inorganic base is NaOH.
5. glass polishing powder cleaning agent according to claim 1, it is characterised in that the intercalating agent is 1-hydroxy ethylene-1,1-diphosphonic
One or more mixing in sour, two adjacent sodium of ethylenediamine, sodium gluconate.
6. glass polishing powder cleaning agent according to claim 5, it is characterised in that the intercalating agent is by 1-hydroxy ethylene-1,1-diphosphonic
Acid, two adjacent sodium of ethylenediamine and sodium gluconate are mixed and are formed, and wherein 1-hydroxy ethylidene-1,1-diphosphonic acid accounts for glass polishing powder
Cleaning agent mass percent 6%～10%；The adjacent sodium of ethylenediamine two account for glass polishing powder cleaning agent mass percent 6%～
10%；Sodium gluconate accounts for glass polishing powder cleaning agent mass percent 6%～10%.
7. the glass polishing powder cleaning agent according to claim 5 or 6, it is characterised in that the 1-hydroxy ethylidene-1,1-diphosphonic acid is
50% 1-hydroxy ethylidene-1,1-diphosphonic acid.
8. a kind of preparation method of the glass polishing powder cleaning agent described in claim 1-7 any one, it is characterised in that its bag
Include following steps：
（1）Deionized water is weighed by weight percentage, is subsequently poured into agitator, and is heated to 45～55 DEG C, then keeps constant temperature；
In weighing PAMC by weight percentage and adding deionized water, turn on agitator makes cation polypropylene acyl
Amine stops heating after being completely dissolved；
（2）NaOH is weighed by weight percentage, agitator is poured into, is stirred；
（3）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, weighs 1-hydroxy ethylidene-1,1-diphosphonic acid by weight percentage, and falls
Enter in agitator, stir；
（4）In bucket to be mixed, solution temperature is down to less than 45～55 DEG C, weighs two adjacent phenylacetic acid of ethylenediamine by weight percentage
Sodium and sodium gluconate, are subsequently poured in agitator, and stirring and dissolving makes glass polishing powder cleaning agent system into after transparent clear liquid
Product.
9. the preparation method of glass polishing powder cleaning agent according to claim 8, it is characterised in that the step（1）In
Agitator rotating speed be 80～120 revs/min.
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| CN201610849645.1A CN106544184A (en) | 2016-09-26 | 2016-09-26 | Glass polishing powder cleaning agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610849645.1A CN106544184A (en) | 2016-09-26 | 2016-09-26 | Glass polishing powder cleaning agent and preparation method thereof |
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ID=58368009
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Cited By (7)
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| CN108929791A (en) * | 2018-08-08 | 2018-12-04 | 东莞市四辉表面处理科技有限公司 | A kind of laser carving glass-ceramic cleaning agent and preparation method thereof |
| CN108949374A (en) * | 2018-08-17 | 2018-12-07 | 深圳市海风润滑技术有限公司 | A kind of acidic glass cleaning agent |
| CN109652236A (en) * | 2019-01-21 | 2019-04-19 | 广州森波化工科技有限公司 | A kind of glass cleaning pulvis and preparation method thereof and application method |
| CN109694782A (en) * | 2017-10-24 | 2019-04-30 | 蓝思科技（长沙）有限公司 | A kind of ceramics cleaning agent and preparation method thereof |
| CN111235619A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN112812900A (en) * | 2020-12-29 | 2021-05-18 | 万津实业(赤壁)有限公司 | Foamless acidic cleaning agent and preparation method and application thereof |
| CN113773911A (en) * | 2021-09-22 | 2021-12-10 | 东莞市四辉表面处理科技有限公司 | Microcrystalline glass cleaning agent and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109694782A (en) * | 2017-10-24 | 2019-04-30 | 蓝思科技（长沙）有限公司 | A kind of ceramics cleaning agent and preparation method thereof |
| CN109694782B (en) * | 2017-10-24 | 2021-06-25 | 蓝思科技（长沙）有限公司 | Ceramic cleaning agent and preparation method thereof |
| CN108929791A (en) * | 2018-08-08 | 2018-12-04 | 东莞市四辉表面处理科技有限公司 | A kind of laser carving glass-ceramic cleaning agent and preparation method thereof |
| CN108949374A (en) * | 2018-08-17 | 2018-12-07 | 深圳市海风润滑技术有限公司 | A kind of acidic glass cleaning agent |
| CN109652236A (en) * | 2019-01-21 | 2019-04-19 | 广州森波化工科技有限公司 | A kind of glass cleaning pulvis and preparation method thereof and application method |
| CN111235619A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN111235619B (en) * | 2020-01-15 | 2022-05-31 | 东莞市四辉表面处理科技有限公司 | Efficient nickel-removing cleaning powder after hole sealing of aluminum anode and preparation method thereof |
| CN112812900A (en) * | 2020-12-29 | 2021-05-18 | 万津实业(赤壁)有限公司 | Foamless acidic cleaning agent and preparation method and application thereof |
| CN113773911A (en) * | 2021-09-22 | 2021-12-10 | 东莞市四辉表面处理科技有限公司 | Microcrystalline glass cleaning agent and preparation method thereof |
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Application publication date: 20170329 |