CN106543829A - A kind of heat-resistant fireproof nanometer film and preparation method thereof - Google Patents
A kind of heat-resistant fireproof nanometer film and preparation method thereof Download PDFInfo
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- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
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Abstract
The invention discloses a kind of heat-resistant fireproof nanometer film, including following several compositions：Base-material emulsion：13 15 parts, deionized water：9 13 parts, filler：14 18 parts, ATO pulvis：23 25 parts, 20 epoxy resin of E：12 16 parts, anti-flash rusting agent：13 parts, coalescents：9 12 parts, mould inhibitor：24 parts；Intumescent Retardant System：15 19 parts, fluorographite：18 23 parts, ethanol：7 11 parts, dibutyl phthalate：7 10 parts, 3 methylphenols：6 10 parts, coalescents：48 parts, plasticizer：79 parts, auxiliary material：11 13 parts；Epoxy resin：11 19 parts, waterglass：9 16 parts, prodan：10 15 parts, trichloro ethylene：25 parts, styrene：6 13 parts, 2 butanone cyclohexanone：14 parts, antioxidant：10 12 parts, nano silicon：15 22 parts, ethylene glycol：10 13 parts, crosslinking agent：12 18 parts, coalescents：9 15 parts, the present invention not only increases operating efficiency, and reduces the pollution to environment, increased the life-span of product.
Description
Technical field
The present invention relates to nanometer technical field of membrane, particularly relates to a kind of heat-resistant fireproof nanometer film and its preparation side
Method.
Background technology
With the continuous development of society, nanometer technology constantly improve, increasing nanometer product listing, nanometer product can
To find application in storage sector, nanometer film of the prior art is unable to reach the effect of heat-resistant fireproof, and Long-Time Service is scrapped
Rate is higher, is to improve operating efficiency, reduces scrappage, and the present invention proposes a kind of heat-resistant fireproof nanometer film and preparation method thereof.
The content of the invention
The technical problem to be solved is to provide, and proposes a kind of resistance to height for the shortcoming that above prior art is present
Warm anti-flaming nano film, including high-temperature-resistant layer, flame-retardant layer and nanometer layer, high-temperature-resistant layer surface are coated with one layer of high-temperature resistant coating,
High-temperature resistant coating includes following several compositions：Base-material emulsion：13-15 parts, deionized water：9-13 parts, filler：14-18 parts, ATO
Pulvis：23-25 parts, E-20 epoxy resin：12-16 parts, anti-flash rusting agent：1-3 parts, coalescents：9-12 parts, mould inhibitor：2-4
Part；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：15-19
Part, fluorographite：18-23 parts, ethanol：7-11 parts, dibutyl phthalate：7-10 parts, 3- methylphenols：6-10 parts, into
Film auxiliary agent：4-8 parts, plasticizer：7-9 parts, auxiliary material：11-13 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：
11-19 parts, waterglass：9-16 parts, prodan：10-15 parts, trichloro ethylene：2-5 parts, styrene：6-13 parts, 2- butanone rings
Hexanone：1-4 parts, antioxidant：10-12 parts, nano silicon：15-22 parts, ethylene glycol：10-13 parts, crosslinking agent：12-18 parts,
Coalescents：9-15 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；Expandable flame retardant
Mixture of the system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or O-phthalic
One kind in dibutyl phthalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：10-15%,
Cerium：22-27%, praseodymium：11-13%, neodymium：2-5%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant
For phosphite ester；Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex.
The technical scheme that further limits of the present invention is：
Aforesaid heat-resistant fireproof nanometer film, high-temperature-resistant layer surface are coated with one layer of high-temperature resistant coating, high-temperature resistant coating include with
Under several compositions：Base-material emulsion：13 parts, deionized water：9 parts, filler：14 parts, ATO pulvis：23 parts, E-20 epoxy resin：12
Part, anti-flash rusting agent：1 part, coalescents：9 parts, mould inhibitor：2 parts；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：15 parts,
Fluorographite：18 parts, ethanol：7 parts, dibutyl phthalate：7 parts, 3- methylphenols：6 parts, coalescents：4 parts, plasticising
Agent：7 parts, auxiliary material：11 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：11
Part, waterglass：9 parts, prodan：10 parts, trichloro ethylene：2 parts, styrene：6 parts, 2- butanone cyclohexanone：1 part, antioxidant：
10 parts, nano silicon：15 parts, ethylene glycol：10 parts, crosslinking agent：12 parts, coalescents：9 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；Expandable flame retardant
Mixture of the system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or O-phthalic
One kind in dibutyl phthalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：10%, cerium：
22%, praseodymium：11%, neodymium：2%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant is phosphite ester；
Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex.
Aforesaid heat-resistant fireproof nanometer film, high-temperature-resistant layer surface are coated with one layer of high-temperature resistant coating, high-temperature resistant coating bag
Include following several compositions：Base-material emulsion：15 parts, deionized water：13 parts, filler：18 parts, ATO pulvis：25 parts, E-20 asphalt mixtures modified by epoxy resin
Fat：16 parts, anti-flash rusting agent：3 parts, coalescents：12 parts, mould inhibitor：4 parts；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：19 parts,
Fluorographite：23 parts, ethanol：11 parts, dibutyl phthalate：10 parts, 3- methylphenols：10 parts, coalescents：8 parts, increase
Modeling agent：9 parts, auxiliary material：13 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：19
Part, waterglass：16 parts, prodan：15 parts, trichloro ethylene：5 parts, styrene：13 parts, 2- butanone cyclohexanone：4 parts, antioxygen
Agent：12 parts, nano silicon：22 parts, ethylene glycol：13 parts, crosslinking agent：18 parts, coalescents：15 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；Expandable flame retardant
Mixture of the system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or O-phthalic
One kind in dibutyl phthalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：15%, cerium：
27%, praseodymium：13%, neodymium：5%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant is phosphite ester；
Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex.
Aforesaid heat-resistant fireproof nanometer film and preparation method thereof, the method is comprised the following steps that：
（One）To stir in base-material emulsion, ATO pulvis and anti-flash rusting agent reactor of the input with agitator, the temperature of reactor
Spend for 50-55 DEG C, mixing speed is 300-350r/min, in the product input dispersion cylinder after stirring, control the temperature of dispersion cylinder
At 60-70 DEG C, deionized water, filler and E-20 epoxy resin are subsequently added into, high-speed stirred, mixing speed are 600-650r/
min；
（Two）Again to step（One）Middle addition coalescents and mould inhibitor, are stirred at normal temperatures, are adjusted to suitable glutinous
2-6min in coating is immersed by denseness, you can obtain high-temperature-resistant layer coating in high temperature resistant basic unit, and under room temperature, dry solidification is obtained
High-temperature-resistant layer is stand-by；
（Three）Fluorographite, ethanol and 3- methylphenols are added and is stirred in mixer, stir 25-30min, stirring speed
Spend for 120-130r/min, add Intumescent Retardant System and dibutyl phthalate, stir 25-30min, wait and be sufficiently mixed
Plasticizer is added after uniform, high-speed stirred 20-25min, mixing speed are 300-320r/min, finally add appropriate film forming and help
Agent and auxiliary material are filtrated to get fire-retardant coating to suitable viscosity, and flame-retardant layer basic unit is immersed dry solidification in coating can obtain
To fire-retardant stand-by layer by layer；
（Four）Epoxy resin, prodan, trichloro ethylene and 2- butanone cyclohexanone are added and is stirred in mixer, stirred
Time is 20-25min, and mixing speed is 130-140r/min, and stirring adds waterglass, styrene, nano silicon simultaneously
And ethylene glycol continue stirring 10-20min, mixing speed is 300-350r/min, be eventually adding antioxidant, crosslinking agent and into
Film auxiliary agent is stirred to suitable viscosity, is filtrated to get a nanometer coating, nanometer layer basic unit is immersed solidification in coating and is dried and can be obtained
It is stand-by to nanometer layer.
（Five）By in abovementioned steps to product according to be high-temperature-resistant layer from lower to upper, flame-retardant layer, nanometer layer overlap and be
Heat-resistant fireproof nanometer film is obtained.
Using technical scheme beneficial effect it is：High-temperature-resistant layer and nanometer layer are provided with the present invention, are increased
The anti-flammability and water proofing property of product, nanometer layer cause density increase in operation, improve operating efficiency, with common nanometer
Film compares strong applicability, pollutes little and low cost, considerably increases the protection to environment, and the method step is simple,
It is easy to operate.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of heat-resistant fireproof nanometer film, including high-temperature-resistant layer, flame-retardant layer and nanometer layer, high-temperature-resistant layer table
Face is coated with one layer of high-temperature resistant coating, and high-temperature resistant coating includes following several compositions：Base-material emulsion：13 parts, deionized water：9 parts,
Filler：14 parts, ATO pulvis：23 parts, E-20 epoxy resin：12 parts, anti-flash rusting agent：1 part, coalescents：9 parts, mould inhibitor：2
Part；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：15 parts,
Fluorographite：18 parts, ethanol：7 parts, dibutyl phthalate：7 parts, 3- methylphenols：6 parts, coalescents：4 parts, plasticising
Agent：7 parts, auxiliary material：11 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：11
Part, waterglass：9 parts, prodan：10 parts, trichloro ethylene：2 parts, styrene：6 parts, 2- butanone cyclohexanone：1 part, antioxidant：
10 parts, nano silicon：15 parts, ethylene glycol：10 parts, crosslinking agent：12 parts, coalescents：9 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；Expandable flame retardant
Mixture of the system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or O-phthalic
One kind in dibutyl phthalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：10%, cerium：
22%, praseodymium：11%, neodymium：2%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant is phosphite ester；
Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex；
Above-mentioned heat-resistant fireproof nanometer film and preparation method thereof, comprises the following steps：
（One）To stir in base-material emulsion, ATO pulvis and anti-flash rusting agent reactor of the input with agitator, the temperature of reactor
Spend for 50 DEG C, mixing speed is 300r/min, in the product input dispersion cylinder after stirring, the temperature of dispersion cylinder is controlled at 60 DEG C,
Deionized water, filler and E-20 epoxy resin are subsequently added into, high-speed stirred, mixing speed are 600r/min；
（Two）Again to step（One）Middle addition coalescents and mould inhibitor, are stirred at normal temperatures, are adjusted to suitable glutinous
2min in coating is immersed by denseness, you can obtain high-temperature-resistant layer coating in high temperature resistant basic unit, and under room temperature, dry solidification is obtained resistance to
Heat zone is stand-by；
（Three）Fluorographite, ethanol and 3- methylphenols are added and is stirred in mixer, stir 25min, mixing speed
For 120r/min, Intumescent Retardant System and dibutyl phthalate are added, stir 25min, waited
Enter plasticizer, high-speed stirred 20min, mixing speed is 300r/min, finally add appropriate coalescents and auxiliary material to conjunction
Suitable viscosity, is filtrated to get fire-retardant coating, dry solidification in flame-retardant layer basic unit immersion coating is obtained flame-retardant layer layer stand-by；
（Four）Epoxy resin, prodan, trichloro ethylene and 2- butanone cyclohexanone are added and is stirred in mixer, stirred
Time is 20min, and mixing speed is 130r/min, and stirring adds waterglass, styrene, nano silicon and second two simultaneously
Alcohol continues stirring 10min, and mixing speed is 300r/min, is eventually adding antioxidant, crosslinking agent and coalescents and stirs to conjunction
Suitable viscosity, is filtrated to get a nanometer coating, solidification drying in nanometer layer basic unit immersion coating is obtained nanometer layer stand-by.
（Five）By in abovementioned steps to product according to be high-temperature-resistant layer from lower to upper, flame-retardant layer, nanometer layer overlap and be
Heat-resistant fireproof nanometer film is obtained.
Embodiment 2
The present embodiment provides a kind of heat-resistant fireproof nanometer film, including high-temperature-resistant layer, flame-retardant layer and nanometer layer, high-temperature-resistant layer table
Face is coated with one layer of high-temperature resistant coating, and high-temperature resistant coating includes following several compositions：Base-material emulsion：15 parts, deionized water：13
Part, filler：18 parts, ATO pulvis：25 parts, E-20 epoxy resin：16 parts, anti-flash rusting agent：3 parts, coalescents：It is 12 parts, mould proof
Agent：4 parts；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：19 parts,
Fluorographite：23 parts, ethanol：11 parts, dibutyl phthalate：10 parts, 3- methylphenols：10 parts, coalescents：8 parts, increase
Modeling agent：9 parts, auxiliary material：13 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：19
Part, waterglass：16 parts, prodan：15 parts, trichloro ethylene：5 parts, styrene：13 parts, 2- butanone cyclohexanone：4 parts, antioxygen
Agent：12 parts, nano silicon：22 parts, ethylene glycol：13 parts, crosslinking agent：18 parts, coalescents：15 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；Expandable flame retardant
Mixture of the system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or O-phthalic
One kind in dibutyl phthalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：15%, cerium：
27%, praseodymium：13%, neodymium：5%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant is phosphite ester；
Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex；
Above-mentioned heat-resistant fireproof nanometer film and preparation method thereof, comprises the following steps：
（One）To stir in base-material emulsion, ATO pulvis and anti-flash rusting agent reactor of the input with agitator, the temperature of reactor
Spend for 55 DEG C, mixing speed is 350r/min, in the product input dispersion cylinder after stirring, the temperature of dispersion cylinder is controlled at 70 DEG C,
Deionized water, filler and E-20 epoxy resin are subsequently added into, high-speed stirred, mixing speed are 650r/min；
（Two）Again to step（One）Middle addition coalescents and mould inhibitor, are stirred at normal temperatures, are adjusted to suitable glutinous
6min in coating is immersed by denseness, you can obtain high-temperature-resistant layer coating in high temperature resistant basic unit, and under room temperature, dry solidification is obtained resistance to
Heat zone is stand-by；
（Three）Fluorographite, ethanol and 3- methylphenols are added and is stirred in mixer, stir 30min, mixing speed
For 130r/min, Intumescent Retardant System and dibutyl phthalate are added, stir 30min, waited
Enter plasticizer, high-speed stirred 25min, mixing speed is 320r/min, finally add appropriate coalescents and auxiliary material to conjunction
Suitable viscosity, is filtrated to get fire-retardant coating, dry solidification in flame-retardant layer basic unit immersion coating is obtained flame-retardant layer layer stand-by；
（Four）Epoxy resin, prodan, trichloro ethylene and 2- butanone cyclohexanone are added and is stirred in mixer, stirred
Time is 25min, and mixing speed is 140r/min, and stirring adds waterglass, styrene, nano silicon and second two simultaneously
Alcohol continues stirring 20min, and mixing speed is 350r/min, is eventually adding antioxidant, crosslinking agent and coalescents and stirs to conjunction
Suitable viscosity, is filtrated to get a nanometer coating, solidification drying in nanometer layer basic unit immersion coating is obtained nanometer layer stand-by.
（Five）By in abovementioned steps to product according to be high-temperature-resistant layer from lower to upper, flame-retardant layer, nanometer layer overlap and be
Heat-resistant fireproof nanometer film is obtained.
Embodiment 3
The present embodiment provides a kind of heat-resistant fireproof nanometer film, including high-temperature-resistant layer, flame-retardant layer and nanometer layer, high-temperature-resistant layer table
Face is coated with one layer of high-temperature resistant coating, and high-temperature resistant coating includes following several compositions：Base-material emulsion：14 parts, deionized water：12
Part, filler：15 parts, ATO pulvis：24 parts, E-20 epoxy resin：15 parts, anti-flash rusting agent：2 parts, coalescents：It is 10 parts, mould proof
Agent：3 parts；
Fire-retardant layer surface is coated with one layer of anti-flaming dope, and anti-flaming dope includes following several compositions：Intumescent Retardant System：16 parts,
Fluorographite：20 parts, ethanol：10 parts, dibutyl phthalate：8 parts, 3- methylphenols：8 parts, coalescents：5 parts, plasticising
Agent：8 parts, auxiliary material：12 parts；
Nanometer layer surface is coated with one layer of Nano waterproof paint, and Nano waterproof paint includes following several compositions：Epoxy resin：16
Part, waterglass：13 parts, prodan：13 parts, trichloro ethylene：3 parts, styrene：10 parts, 2- butanone cyclohexanone：2 parts, antioxygen
Agent：11 parts, nano silicon：18 parts, ethylene glycol：12 parts, crosslinking agent：15 parts, coalescents：13 parts；
Base-material emulsion is the one kind or several in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind；Filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；Anti- flash rusting agent is
One or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；Coalescents are second two
Alcohol；Defoamer is tributyl phosphate；Described mould inhibitor is one or more in trbasic zinc phosphate, aluminium hydroxide or Firebrake ZB；It is swollen
Mixture of the swollen flame-retardant system for dehydration catalyst, carbon forming agent and foaming agent；Plasticizer is dioctyl phthalate or neighbour
One kind in dibatyl phithalate；Auxiliary material is compound rare-earth, and compound rare-earth is by mass percentage including following components：Dysprosium：
13%, cerium：25%, praseodymium：12%, neodymium：3%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Antioxidant is Asia
Phosphate；Crosslinking agent is the one kind in polyethylene, polyvinyl chloride or haloflex；
Above-mentioned heat-resistant fireproof nanometer film and preparation method thereof, comprises the following steps：
（One）To stir in base-material emulsion, ATO pulvis and anti-flash rusting agent reactor of the input with agitator, the temperature of reactor
Spend for 53 DEG C, mixing speed is 320r/min, in the product input dispersion cylinder after stirring, the temperature of dispersion cylinder is controlled at 65 DEG C,
Deionized water, filler and E-20 epoxy resin are subsequently added into, high-speed stirred, mixing speed are 620r/min；
（Two）Again to step（One）Middle addition coalescents and mould inhibitor, are stirred at normal temperatures, are adjusted to suitable glutinous
4min in coating is immersed by denseness, you can obtain high-temperature-resistant layer coating in high temperature resistant basic unit, and under room temperature, dry solidification is obtained resistance to
Heat zone is stand-by；
（Three）Fluorographite, ethanol and 3- methylphenols are added and is stirred in mixer, stir 28min, mixing speed
For 125r/min, Intumescent Retardant System and dibutyl phthalate are added, stir 28min, waited
Enter plasticizer, high-speed stirred 23min, mixing speed is 310r/min, finally add appropriate coalescents and auxiliary material to conjunction
Suitable viscosity, is filtrated to get fire-retardant coating, dry solidification in flame-retardant layer basic unit immersion coating is obtained flame-retardant layer layer stand-by；
（Four）Epoxy resin, prodan, trichloro ethylene and 2- butanone cyclohexanone are added and is stirred in mixer, stirred
Time is 23min, and mixing speed is 135r/min, and stirring adds waterglass, styrene, nano silicon and second two simultaneously
Alcohol continues stirring 15min, and mixing speed is 320r/min, is eventually adding antioxidant, crosslinking agent and coalescents and stirs to conjunction
Suitable viscosity, is filtrated to get a nanometer coating, solidification drying in nanometer layer basic unit immersion coating is obtained nanometer layer stand-by.
（Five）By in abovementioned steps to product according to be high-temperature-resistant layer from lower to upper, flame-retardant layer, nanometer layer overlap and be
Heat-resistant fireproof nanometer film is obtained.
In addition to the implementation, the present invention can also have other embodiment.All employing equivalents or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (4)
1. a kind of heat-resistant fireproof nanometer film, including high-temperature-resistant layer, flame-retardant layer and nanometer layer, it is characterised in that：The resistance to height
Warm layer surface is coated with one layer of high-temperature resistant coating, and the high-temperature resistant coating includes following several compositions：Base-material emulsion：13-15 parts,
Deionized water：9-13 parts, filler：14-18 parts, ATO pulvis：23-25 parts, E-20 epoxy resin：12-16 parts, anti-flash rusting agent：1-
3 parts, coalescents：9-12 parts, mould inhibitor：2-4 parts；
The fire-retardant layer surface is coated with one layer of anti-flaming dope, and the anti-flaming dope includes following several compositions：Expandable flame retardant body
System：15-19 parts, fluorographite：18-23 parts, ethanol：7-11 parts, dibutyl phthalate：7-10 parts, 3- methylphenols：6-
10 parts, coalescents：4-8 parts, plasticizer：7-9 parts, auxiliary material：11-13 parts；
The nanometer layer surface is coated with one layer of Nano waterproof paint, and the Nano waterproof paint includes following several compositions：Ring
Oxygen tree fat：11-19 parts, waterglass：9-16 parts, prodan：10-15 parts, trichloro ethylene：2-5 parts, styrene：6-13 parts, 2-
Butanone cyclohexanone：1-4 parts, antioxidant：10-12 parts, nano silicon：15-22 parts, ethylene glycol：10-13 parts, crosslinking agent：
12-18 parts, coalescents：9-15 parts；
Described base-material emulsion is the one kind in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Or it is several；Described filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；
Described anti-flash rusting agent is one or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；
Described coalescents are ethylene glycol；Described defoamer is tributyl phosphate；Described mould inhibitor is trbasic zinc phosphate, hydroxide
One or more in aluminium or Firebrake ZB；Described Intumescent Retardant System is the mixed of dehydration catalyst, carbon forming agent and foaming agent
Compound；Described plasticizer is dioctyl phthalate or the one kind in dibutyl phthalate；Described auxiliary material is multiple
Rare earth is closed, the compound rare-earth includes following components by mass percentage：Dysprosium：10-15%, cerium：22-27%, praseodymium：11-13%,
Neodymium：2-5%, remaining is lanthanum element, and above lanthanide rare each component sum is 100%；Described antioxidant is phosphite ester；It is described
Crosslinking agent be polyethylene, polyvinyl chloride or haloflex in one kind.
2. heat-resistant fireproof nanometer film according to claim 1, it is characterised in that：The high-temperature-resistant layer surface is coated with one
Layer high-temperature resistant coating, the high-temperature resistant coating include following several compositions：Base-material emulsion：13 parts, deionized water：9 parts, filler：
14 parts, ATO pulvis：23 parts, E-20 epoxy resin：12 parts, anti-flash rusting agent：1 part, coalescents：9 parts, mould inhibitor：2 parts；
The fire-retardant layer surface is coated with one layer of anti-flaming dope, and the anti-flaming dope includes following several compositions：Expandable flame retardant body
System：15 parts, fluorographite：18 parts, ethanol：7 parts, dibutyl phthalate：7 parts, 3- methylphenols：6 parts, coalescents：4
Part, plasticizer：7 parts, auxiliary material：11 parts；
The nanometer layer surface is coated with one layer of Nano waterproof paint, and the Nano waterproof paint includes following several compositions：Ring
Oxygen tree fat：11 parts, waterglass：9 parts, prodan：10 parts, trichloro ethylene：2 parts, styrene：6 parts, 2- butanone cyclohexanone：1
Part, antioxidant：10 parts, nano silicon：15 parts, ethylene glycol：10 parts, crosslinking agent：12 parts, coalescents：9 parts；
Described base-material emulsion is the one kind in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Or it is several；Described filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；
Described anti-flash rusting agent is one or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；
Described coalescents are ethylene glycol；Described defoamer is tributyl phosphate；Described mould inhibitor is trbasic zinc phosphate, hydroxide
One or more in aluminium or Firebrake ZB；Described Intumescent Retardant System is the mixed of dehydration catalyst, carbon forming agent and foaming agent
Compound；Described plasticizer is dioctyl phthalate or the one kind in dibutyl phthalate；Described auxiliary material is multiple
Rare earth is closed, the compound rare-earth includes following components by mass percentage：Dysprosium：10%, cerium：22%, praseodymium：11%, neodymium：2%, remaining
For lanthanum element, above lanthanide rare each component sum is 100%；Described antioxidant is phosphite ester；Described crosslinking agent is poly-
One kind in ethene, polyvinyl chloride or haloflex.
3. heat-resistant fireproof nanometer film according to claim 1, it is characterised in that：The high-temperature-resistant layer surface is coated with one
Layer high-temperature resistant coating, the high-temperature resistant coating include following several compositions：Base-material emulsion：15 parts, deionized water：13 parts, filler：
18 parts, ATO pulvis：25 parts, E-20 epoxy resin：16 parts, anti-flash rusting agent：3 parts, coalescents：12 parts, mould inhibitor：4 parts；
The fire-retardant layer surface is coated with one layer of anti-flaming dope, and the anti-flaming dope includes following several compositions：Expandable flame retardant body
System：19 parts, fluorographite：23 parts, ethanol：11 parts, dibutyl phthalate：10 parts, 3- methylphenols：10 parts, film forming is helped
Agent：8 parts, plasticizer：9 parts, auxiliary material：13 parts；
The nanometer layer surface is coated with one layer of Nano waterproof paint, and the Nano waterproof paint includes following several compositions：Ring
Oxygen tree fat：19 parts, waterglass：16 parts, prodan：15 parts, trichloro ethylene：5 parts, styrene：13 parts, 2- butanone cyclohexanone：4
Part, antioxidant：12 parts, nano silicon：22 parts, ethylene glycol：13 parts, crosslinking agent：18 parts, coalescents：15 parts；
Described base-material emulsion is the one kind in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Or it is several；Described filler is one or more in glass dust, titanium white, zinc oxide, mica, diatomite, Hai Pao or calcium carbonate；
Described anti-flash rusting agent is one or more in glycol dioleate, amide imidazoline or cycloalkanes acid alkaline earth metal salt；
Described coalescents are ethylene glycol；Described defoamer is tributyl phosphate；Described mould inhibitor is trbasic zinc phosphate, hydroxide
One or more in aluminium or Firebrake ZB；Described Intumescent Retardant System is the mixed of dehydration catalyst, carbon forming agent and foaming agent
Compound；Described plasticizer is dioctyl phthalate or the one kind in dibutyl phthalate；Described auxiliary material is multiple
Rare earth is closed, the compound rare-earth includes following components by mass percentage：Dysprosium：15%, cerium：27%, praseodymium：13%, neodymium：5%, remaining
For lanthanum element, above lanthanide rare each component sum is 100%；Described antioxidant is phosphite ester；Described crosslinking agent is poly-
One kind in ethene, polyvinyl chloride or haloflex.
4. a kind of preparation method of heat-resistant fireproof nanometer film, the preparation method are provided with any claim in claim 1-3
Described heat-resistant fireproof nanometer film, it is characterised in that the preparation method is comprised the following steps：
（One）To stir in base-material emulsion, ATO pulvis and anti-flash rusting agent reactor of the input with agitator, the temperature of reactor
Spend for 50-55 DEG C, mixing speed is 300-350r/min, in the product input dispersion cylinder after stirring, control the temperature of dispersion cylinder
At 60-70 DEG C, deionized water, filler and E-20 epoxy resin are subsequently added into, high-speed stirred, mixing speed are 600-650r/
min；
（Two）Again to step（One）Middle addition coalescents and mould inhibitor, are stirred at normal temperatures, are adjusted to suitable glutinous
2-6min in coating is immersed by denseness, you can obtain high-temperature-resistant layer coating in high temperature resistant basic unit, and under room temperature, dry solidification is obtained
High-temperature-resistant layer is stand-by；
（Three）Fluorographite, ethanol and 3- methylphenols are added and is stirred in mixer, stir 25-30min, stirring speed
Spend for 120-130r/min, add Intumescent Retardant System and dibutyl phthalate, stir 25-30min, wait and be sufficiently mixed
Plasticizer is added after uniform, high-speed stirred 20-25min, mixing speed are 300-320r/min, finally add appropriate film forming and help
Agent and auxiliary material are filtrated to get fire-retardant coating to suitable viscosity, and flame-retardant layer basic unit is immersed dry solidification in coating can obtain
To fire-retardant stand-by layer by layer；
（Four）Epoxy resin, prodan, trichloro ethylene and 2- butanone cyclohexanone are added and is stirred in mixer, stirred
Time is 20-25min, and mixing speed is 130-140r/min, and stirring adds waterglass, styrene, nano silicon simultaneously
And ethylene glycol continue stirring 10-20min, mixing speed is 300-350r/min, be eventually adding antioxidant, crosslinking agent and into
Film auxiliary agent is stirred to suitable viscosity, is filtrated to get a nanometer coating, nanometer layer basic unit is immersed solidification in coating and is dried and can be obtained
It is stand-by to nanometer layer；
（Five）By the product for arriving in abovementioned steps according to from lower to upper for high-temperature-resistant layer, flame-retardant layer, nanometer layer overlap can must
To heat-resistant fireproof nanometer film.
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| CN108003678A (en) * | 2017-12-06 | 2018-05-08 | 博维恩冷冻科技（苏州）有限公司 | A kind for the treatment of process of wear-resistant instrument valve |
| CN109054577A (en) * | 2018-06-06 | 2018-12-21 | 江苏大印电子科技有限公司 | A kind of high pressure common phase water proof bus bar slot |
| CN109251566A (en) * | 2018-09-05 | 2019-01-22 | 江苏叙然信息科技有限公司 | A kind of waterproof easy to clean nano material and its preparation process |
| CN111117407A (en) * | 2020-01-22 | 2020-05-08 | 姹ゅ姜 | Super-hydrophobic coating with flame retardant effect and preparation method thereof |
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