CN106543680A - A kind of makrolon material and its manufacture method of flame-proof abrasion-resistant - Google Patents
A kind of makrolon material and its manufacture method of flame-proof abrasion-resistant Download PDFInfo
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- CN106543680A CN106543680A CN201611054747.0A CN201611054747A CN106543680A CN 106543680 A CN106543680 A CN 106543680A CN 201611054747 A CN201611054747 A CN 201611054747A CN 106543680 A CN106543680 A CN 106543680A
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- flame
- makrolon material
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- resistant
- proof abrasion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a kind of makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：100 parts of Merlon, 0.4～0.9 part of UV resistant agent, 0.5～1 part of antioxidant, 5～7 parts of compatilizer, 0.6～1.1 part of stabilizer, 0.1～0.6 part of dispersant, 1～6 part of plasticizer, 2～7 parts of toughener, 3～3.5 parts of Organosilicon wax, be modified compound 18～24 parts of wollastonite fibre.The invention also discloses the manufacture method of the makrolon material.The anti-flammability and wearability of makrolon material provided by the present invention is stronger.
Description
Technical field
The present invention relates to a kind of macromolecular material, the makrolon material of more particularly to a kind of flame-proof abrasion-resistant and its manufacture
Method.
Background technology
Makrolon material is a kind of tasteless, odorless, nontoxic, transparent amorphous thermoplastic materials, is contained in strand
There is the general name of a family macromolecule compound of carbonic ester, abbreviation PC can be divided into aliphatic category and fragrant two kinds of the same clan, but because of product
The restriction of performance, processing characteristics and economic factor etc., only the aromatic copolycarbonate of bisphenol A-type puts into industrially scalable at present
Production and application.Bisphenol A polycarbonate is that current production rate is maximum, a kind of Merlon that purposes is most wide, is also with fastest developing speed
One of engineering plastics.Bisphenol A polycarbonate has excellent impact strength, creep resistant, heat-resisting cold resistance, ageing-resistant
Property, electrical insulating property and translucency etc., be widely used in electric and electronic parts, mechanical textile industry parts, building structural member,
Aviation transparencies material and parts, structural foam etc..
It is with the fast development of automobile industry and electron trade, unprecedentedly surging to the demand of PC in recent years, world consumption energy
Power has reached l100kt/a, and wherein domestic PC consumption has also reached 60kt/a.At present the factory of PC be mainly distributed on the U.S., West Europe and
Japan, wherein, the production capacity of GE Plastics Companies, Bayer companies and Dow Chemical Company account for the 80% of world's total productive capacity with
On.The development work of China PC is started from 1958, is succeeded in developing by Shenyang Chemical Engineering Inst first；It is developed so far, owns
, with phosgene as initiation material, production scale is less for process route.
For example, Publication No. CN102702712B, the day for announcing are 2013.12.04, the artificial University Of Ji'nan of application, Weihai prestige
High blood purification Products Co., Ltd, the Chinese invention of Changchun Inst. of Applied Chemistry, Chinese Academy of Sciences disclose a kind of " resistance to spoke
According to makrolon material and its preparation method and application ", which is by Merlon, free radical stabilizer, epoxide diluent, plasticizer
Deng composition, in formula, the quality of each composition is：100 parts of Merlon, free radical stabilizer 0.1-1.0 parts, epoxide diluent
0.1-2.0, plasticizer 0.1-2.0 parts.The invention also discloses the preparation method and application of the material, the Merlon material of preparation
After high-energy electron accelerator electron beam or 60Co gamma-radiations (dosage is not more than 40KGy) irradiation, color does not turn yellow material, can
Keep good mechanical property and the transparency, disclosure satisfy that the requirement of medical makrolon material, can be used for artificial kidney dialyzer,
Artificial lung, blood oxygenator, blood separator and anaesthetic vaporizer equipment and other needs are operated simultaneously under the conditions of transparent, directly perceived
Need the preparation of the Medical Devices of irradiation sterilization.But the makrolon material is yet suffered from two aspects of anti-flammability and wearability
Not enough defect.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of makrolon material of flame-proof abrasion-resistant, its anti-flammability and resistance to
Mill property is stronger.
To solve above-mentioned technical problem, the technical scheme is that：
A kind of makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：100 parts of Merlon,
0.4～0.9 part of UV resistant agent, 0.5～1 part of antioxidant, 5～7 parts of compatilizer, 0.6～1.1 part of stabilizer, dispersant 0.1～
0.6 part, 1～6 part of plasticizer, 2～7 parts of toughener, 3～3.5 parts of Organosilicon wax, be modified compound 18～24 parts of wollastonite fibre.
Preferably, Merlon of the present invention is bisphenol A polycarbonate.
Preferably, UV resistant agent of the present invention is UV-326.
Preferably, antioxidant of the present invention is 2,5- ditert-butylhydro quinones.
Preferably, compatilizer of the present invention is ABS-g-MAH.
Preferably, stabilizer of the present invention is stearic acid.
Preferably, dispersant of the present invention is silicone oil.
Preferably, plasticizer of the present invention is ATBC.
Preferably, toughener of the present invention is MBS.
The invention solves the problems that another technical problem be to provide above-mentioned flame-proof abrasion-resistant makrolon material manufacture method.
To solve above-mentioned technical problem, technical scheme is：
A kind of manufacture method of the makrolon material of flame-proof abrasion-resistant, comprises the following steps：
(1) magnesium hydroxide is added in deionized water, after being stirred until homogeneous, obtains magnesium hydroxide solution, magnesium hydroxide is molten
Liquid is put in carbonization reactor, adds EDTA, wollastonite fibre, be passed through the ph values of carbon dioxide to system after opening stirring
For 7 when stop stirring, product is naturally cooled to into suction filtration after room temperature, by filter cake be placed in baking oven at 100 DEG C be dried 4 hours, turn
Compound wollastonite fibre is obtained after breaing up in entering raymond mill；
(2) the compound wollastonite fibre that step (1) is obtained is added in the watery hydrochloric acid of 8 times of weight, after being heated to 90 DEG C
Filter cake is washed with distilled water to neutrality by heat-insulation soaking 3 hours, suction filtration after taking-up, is placed in baking oven at 100 DEG C and is dried 4 hours
Obtain being acidified compound wollastonite fibre；
(3) coupling agent A151 is added to etc. in the absolute ethyl alcohol of weight, stirs to after being well mixed and add step (2)
The compound wollastonite fibre of acidifying for arriving, stirring reaction 1 hour after being heated to 90 DEG C, suction filtration after taking-up are anti-with distilled water by filter cake
After backwashing is placed in after washing in baking oven at 100 DEG C and dries, and obtains modified compound wollastonite fibre；
(4) component is weighed according to weight portion, Merlon is placed in in blast drier forced air drying 7 hours at 100 DEG C,
Dried Merlon, dispersant, Organosilicon wax are put into into high-speed mixer and mixing 10 minutes, will be except changing after being cooled to 30 DEG C
Property compound wollastonite fibre outside component input high mixer in, compound is obtained after being well mixed, by compound input double spiral shells
In the loading hopper of bar extruder, wollastonite fibre modified will be combined from extruding pelletization after side spout addition, obtain flame-proof abrasion-resistant
Makrolon material, wherein each section of temperature of double screw extruder be respectively 225 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 255 DEG C,
Head temperature is 250 DEG C, and pressure is 15MPa, and screw speed is 360rpm, and rate of feeding is 33rpm.
Compared with prior art, the invention has the advantages that：
Wollastonite fibre is a kind of inorganic mineral fiber, and which has very strong wearability and fire resistance, but its surface has
More sharp keen corner angle, and hydrophily is presented, surface chemistry can be relatively low, and the compatibility and interface between Merlon is glued
It is not good with joint efforts, thus the present invention is first by itself and magnesium hydroxide, carbon dioxide by carburizing reagent is in its surface nucleation and reacts raw
Magnesium carbonate into excellent in flame retardance has obtained compound wollastonite fibre, and the cladding of magnesium carbonate causes the corner angle of wollastonite fibre script
It is passivated, increased specific surface area and surface chemistry energy, acidification is carried out by watery hydrochloric acid then, watery hydrochloric acid is to being combined silicon ash
Mineral wool generates acid etching effect, increased surface roughness, further increases surface energy, also add the hydroxyl on surface
Number obtains being acidified compound wollastonite fibre, and process, the silicon that A151 hydrolysis is produced are modified to which by coupling agent A151 then
Alcohol can occur bonding reaction with the hydroxyl of the compound wollastonite fiber surface of acidifying, hydrophobic so as to its surface hydrophilicity is changed into
Property, its compatibility and interface binding force between Merlon is effectively increased, and then Merlon material greatly improved
The wearability and anti-flammability of material.
Specific embodiment
Describe the present invention, the illustrative examples of the here present invention and explanation below in conjunction with specific embodiment in detail
It is for explaining the present invention but not as a limitation of the invention.
Embodiment 1
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.8 part of UV-326,2,5- 0.6 part of ditert-butylhydro quinones, 5.5 parts of ABS-g-MAH, 0.9 part of stearic acid, silicone oil 0.6
Part, 1 part of ATBC, 3 parts of MBS, 3 parts of Organosilicon wax, be modified compound 19 parts of wollastonite fibre.
Its manufacture method is comprised the following steps：
(1) magnesium hydroxide is added in deionized water, after being stirred until homogeneous, obtains magnesium hydroxide solution, magnesium hydroxide is molten
Liquid is put in carbonization reactor, adds EDTA, wollastonite fibre, be passed through the ph values of carbon dioxide to system after opening stirring
For 7 when stop stirring, product is naturally cooled to into suction filtration after room temperature, by filter cake be placed in baking oven at 100 DEG C be dried 4 hours, turn
Compound wollastonite fibre is obtained after breaing up in entering raymond mill；
(2) the compound wollastonite fibre that step (1) is obtained is added in the watery hydrochloric acid of 8 times of weight, after being heated to 90 DEG C
Filter cake is washed with distilled water to neutrality by heat-insulation soaking 3 hours, suction filtration after taking-up, is placed in baking oven at 100 DEG C and is dried 4 hours
Obtain being acidified compound wollastonite fibre；
(3) coupling agent A151 is added to etc. in the absolute ethyl alcohol of weight, stirs to after being well mixed and add step (2)
The compound wollastonite fibre of acidifying for arriving, stirring reaction 1 hour after being heated to 90 DEG C, suction filtration after taking-up are anti-with distilled water by filter cake
After backwashing is placed in after washing in baking oven at 100 DEG C and dries, and obtains modified compound wollastonite fibre；
(4) component is weighed according to weight portion, Merlon is placed in in blast drier forced air drying 7 hours at 100 DEG C,
Dried bisphenol A polycarbonate, silicone oil, Organosilicon wax are put into into high-speed mixer and mixing 10 minutes, will after being cooled to 30 DEG C
In component input high mixer in addition to the compound wollastonite fibre that is modified, compound is obtained after being well mixed, compound is thrown
Enter in the loading hopper of double screw extruder, wollastonite fibre modified will be combined from extruding pelletization after side spout addition, and be hindered
The wear-resisting makrolon material of combustion, wherein each section of temperature of double screw extruder be respectively 225 DEG C, 230 DEG C, 240 DEG C, 245 DEG C,
255 DEG C, head temperature is 250 DEG C, and pressure is 15MPa, and screw speed is 360rpm, and rate of feeding is 33rpm.
Embodiment 2
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.6 part of UV-326,2,5- 0.8 part of ditert-butylhydro quinones, 5 parts of ABS-g-MAH, 1.1 parts of stearic acid, silicone oil 0.4
Part, 3 parts of ATBC, 5 parts of MBS, 3.2 parts of Organosilicon wax, be modified compound 21 parts of wollastonite fibre.
The manufacture method of the makrolon material is with embodiment 1.
Embodiment 3
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.4 part of UV-326,2,5- 1 part of ditert-butylhydro quinones, 6.5 parts of ABS-g-MAH, 0.7 part of stearic acid, silicone oil 0.2
Part, 5 parts of ATBC, 7 parts of MBS, 3.4 parts of Organosilicon wax, be modified compound 20 parts of wollastonite fibre.
The manufacture method of the makrolon material is with embodiment 1.
Embodiment 4
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.9 part of UV-326,2,5- 0.5 part of ditert-butylhydro quinones, 6 parts of ABS-g-MAH, 0.8 part of stearic acid, silicone oil 0.5
Part, 2 parts of ATBC, 6 parts of MBS, 3.1 parts of Organosilicon wax, be modified compound 24 parts of wollastonite fibre.
The manufacture method of the makrolon material is with embodiment 1.
Embodiment 5
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.7 part of UV-326,2,5- 0.7 part of ditert-butylhydro quinones, 7 parts of ABS-g-MAH, 0.6 part of stearic acid, silicone oil 0.3
Part, 4 parts of ATBC, 4 parts of MBS, 3.3 parts of Organosilicon wax, be modified compound 18 parts of wollastonite fibre.
The manufacture method of the makrolon material is with embodiment 1.
Embodiment 6
The makrolon material of flame-proof abrasion-resistant, which is made up of the component of following weight portion：Bisphenol A polycarbonate 100
Part, 0.5 part of UV-326,2,5- 0.9 part of ditert-butylhydro quinones, 6.8 parts of ABS-g-MAH, 1 part of stearic acid, silicone oil 0.1
Part, 6 parts of ATBC, 2 parts of MBS, 3.5 parts of Organosilicon wax, be modified compound 22 parts of wollastonite fibre.
The manufacture method of the makrolon material is with embodiment 1.
It is as shown in the table through the anti-flammability and wearability of test, embodiment 1-6 and comparative example, wherein, comparative example is
The Chinese invention of Publication No. CN02702712B, anti-flammability test the peak heat release of each material with reference to ASTM E-1354-90a
Speed, the burning more low then anti-flammability of HRR are stronger, wearability then by wear volume representing, wear volume more it is little then
Wearability is stronger：
Can be seen that by the table：The peak value HRR of embodiment 1-6 is significantly lower than comparative example, in terms of wear volume then
Comparative example is significantly less than, anti-flammability and wearability are stronger.
The principle and its effect of above-described embodiment only illustrative present invention, it is of the invention not for limiting.It is any ripe
The personage for knowing this technology all can carry out modifications and changes to above-described embodiment under the spirit and the scope without prejudice to the present invention.Cause
This, those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of makrolon material of flame-proof abrasion-resistant, it is characterised in which is made up of the component of following weight portion：Poly- carbonic acid
100 parts of ester, 0.4～0.9 part of UV resistant agent, 0.5～1 part of antioxidant, 5～7 parts of compatilizer, 0.6～1.1 part of stabilizer, point
0.1～0.6 part of powder, 1～6 part of plasticizer, 2～7 parts of toughener, 3～3.5 parts of Organosilicon wax, be modified compound wollastonite fibre
18～24 parts.
2. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 1, it is characterised in that：The Merlon is
Bisphenol A polycarbonate.
3. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 2, it is characterised in that：The UV resistant agent
For UV-326.
4. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 3, it is characterised in that：The antioxidant is 2,
5- ditert-butylhydro quinones.
5. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 4, it is characterised in that：The compatilizer is
ABS-g-MAH。
6. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 5, it is characterised in that：The stabilizer is hard
Resin acid.
7. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 6, it is characterised in that：The dispersant is silicon
Oil.
8. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 7, it is characterised in that：The plasticizer is lemon
Lemon acid tributyl.
9. the makrolon material of a kind of flame-proof abrasion-resistant according to claim 8, it is characterised in that：The toughener is
MBS。
10. the manufacture method of the makrolon material of a kind of flame-proof abrasion-resistant according to claim 1～9 any one, its
It is characterised by, comprises the following steps：
(1) magnesium hydroxide is added in deionized water, magnesium hydroxide solution is obtained after being stirred until homogeneous, magnesium hydroxide solution is put
Enter in carbonization reactor, after opening stirring, add EDTA, wollastonite fibre, the ph values for being passed through carbon dioxide to system are 7
When stop stirring, product is naturally cooled to into suction filtration after room temperature, by filter cake be placed in baking oven at 100 DEG C be dried 4 hours, proceed to thunder
Cover and after breaing up in flour mill, obtain compound wollastonite fibre；
(2) the compound wollastonite fibre that step (1) is obtained is added in the watery hydrochloric acid of 8 times of weight, is incubated after being heated to 90 DEG C
Immersion 3 hours, filter cake is washed with distilled water to neutrality by suction filtration after taking-up, is placed in baking oven drying at 100 DEG C and is obtained for 4 hours
The compound wollastonite fibre of acidifying；
(3) coupling agent A151 is added to etc. in the absolute ethyl alcohol of weight, stirs to after being well mixed and add what step (2) was obtained
The compound wollastonite fibre of acidifying, filter cake distilled water is washed by stirring reaction 1 hour after being heated to 90 DEG C, suction filtration after taking-up repeatedly
It is placed in after washing in baking oven at 100 DEG C and dries, obtains modified compound wollastonite fibre；
(4) component is weighed according to weight portion, Merlon is placed in in blast drier forced air drying 7 hours at 100 DEG C, will be dry
Merlon, dispersant, Organosilicon wax input high-speed mixer and mixing after dry 10 minutes, will be except modified multiple after being cooled to 30 DEG C
In component input high mixer outside conjunction wollastonite fibre, compound after being well mixed, is obtained, compound input twin-screw is squeezed
Go out in the loading hopper of machine, wollastonite fibre modified will be combined from extruding pelletization after side spout addition, and obtain the poly- of flame-proof abrasion-resistant
Each section of temperature of carbonate material, wherein double screw extruder is respectively 225 DEG C, 230 DEG C, 240 DEG C, 245 DEG C, 255 DEG C, head
Temperature is 250 DEG C, and pressure is 15MPa, and screw speed is 360rpm, and rate of feeding is 33rpm.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054333A (en) * | 2018-07-24 | 2018-12-21 | 苏州环亚软管塑业有限公司 | A kind of preparation method of Domestic environment-protection type flame retardant plastics hose |
| CN109135236A (en) * | 2018-07-18 | 2019-01-04 | 望江县天长光学仪器有限公司 | A kind of polycarbonate optical lenses material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101498052A (en) * | 2009-01-04 | 2009-08-05 | 颜鑫 | Grammite raphioid fibre crystal-nano calcium carbonate micro-nano composite powder material and production method |
| CN102161820A (en) * | 2011-05-16 | 2011-08-24 | 深圳市科聚新材料有限公司 | Wollastonite enhanced polycarbonate material and preparation method thereof |
| CN102532853A (en) * | 2012-01-09 | 2012-07-04 | 东莞劲胜精密组件股份有限公司 | High-hardness and scratch-resistant modified PC (Poly Carbonate) material and preparation method thereof |
| CN102702712A (en) * | 2012-05-22 | 2012-10-03 | 济南大学 | Radiation resistant polycarbonate material, preparation method and application thereof |
| CN104672858A (en) * | 2013-12-02 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | Low-luster weather-proof scratch-resistance modified polycarbonate (PC) composite material |
-
2016
- 2016-11-25 CN CN201611054747.0A patent/CN106543680B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101498052A (en) * | 2009-01-04 | 2009-08-05 | 颜鑫 | Grammite raphioid fibre crystal-nano calcium carbonate micro-nano composite powder material and production method |
| CN102161820A (en) * | 2011-05-16 | 2011-08-24 | 深圳市科聚新材料有限公司 | Wollastonite enhanced polycarbonate material and preparation method thereof |
| CN102532853A (en) * | 2012-01-09 | 2012-07-04 | 东莞劲胜精密组件股份有限公司 | High-hardness and scratch-resistant modified PC (Poly Carbonate) material and preparation method thereof |
| CN102702712A (en) * | 2012-05-22 | 2012-10-03 | 济南大学 | Radiation resistant polycarbonate material, preparation method and application thereof |
| CN104672858A (en) * | 2013-12-02 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | Low-luster weather-proof scratch-resistance modified polycarbonate (PC) composite material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135236A (en) * | 2018-07-18 | 2019-01-04 | 望江县天长光学仪器有限公司 | A kind of polycarbonate optical lenses material |
| CN109054333A (en) * | 2018-07-24 | 2018-12-21 | 苏州环亚软管塑业有限公司 | A kind of preparation method of Domestic environment-protection type flame retardant plastics hose |
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| Publication number | Publication date |
|---|---|
| CN106543680B (en) | 2018-12-11 |
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