CN106542713A - A kind of method of recycling desilting sediment - Google Patents

A kind of method of recycling desilting sediment Download PDF

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Publication number
CN106542713A
CN106542713A CN201610903725.0A CN201610903725A CN106542713A CN 106542713 A CN106542713 A CN 106542713A CN 201610903725 A CN201610903725 A CN 201610903725A CN 106542713 A CN106542713 A CN 106542713A
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CN
China
Prior art keywords
soil
charcoal
desilting sediment
desilting
recycling
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Pending
Application number
CN201610903725.0A
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Chinese (zh)
Inventor
许继军
武海鹏
陈进
桑连海
刘强
代娟
殷大聪
叶玉适
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Changjiang River Scientific Research Institute Changjiang Water Resources Commission
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Changjiang River Scientific Research Institute Changjiang Water Resources Commission
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Priority to CN201610903725.0A priority Critical patent/CN106542713A/en
Publication of CN106542713A publication Critical patent/CN106542713A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/46Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Agronomy & Crop Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Soil Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of method of recycling desilting sediment, comprises the following steps:(1) water plant of desilting sediment and maturation is separately dried;(2) the dried desilting sediment and the water plant are crushed respectively;(3) by crushing after the desilting sediment and the water plant in mass ratio 1:3~5 ratio is sufficiently mixed, and obtains mixture;(4) by the mixture, high temperature pyrolysis obtain charcoal under anoxic conditions;(5) charcoal is obtained activating charcoal through acid activation, the activation charcoal is soil-repairing agent.Suitable for soil remediation and improvement.

Description

A kind of method of recycling desilting sediment
Technical field
The present invention relates to a kind of method of recycling desilting sediment and its application, more particularly to one kind utilizes desilting The method that bed mud prepares soil-repairing agent.
Background technology
At present, with economic and society fast development, the water body such as river and lake receives different degrees of pollution And destruction.Wherein, bed mud (also referred to as mud) is derived mainly from the silt entrained by rainwash, terrestrial organism residuum, pollution Thing and aquatic animals and plants residuum etc., under each factor collective effect of water environment, precipitation is formed.Bed mud not only can river course is silted up, Reduce lake to regulate and store the ability of flood, but also water body can be become to water body release nutritive salt, heavy metal and organic pollution Endogenous pollution, feedwater ecological safety bring serious threat.
Desilting is to solve water body endogenous pollution, the effective measures of dredging channel.But, if a large amount of bed muds that desilting is produced It is mishandling, it will huge destruction is produced to ecological environment.Desilting sediment is deposited in storage mud field usually as solid waste, this Sample, does not only take up a large amount of places, and is also easy to produce secondary environmental pollution.Therefore, the recycling of desilting sediment has become system The bottleneck that about desilting engineering and black and odorous water are repaired.
In addition, the water plant in the water body such as river, lake can effectively absorb the pollutant in water body in growth period.But After its maturation, rot in water body if not gathering in and allowing, its growth period absorbs and stores the difficult degradations such as heavy metal in vivo pollution The organic matter rich in nitrogen P elements of thing and itself synthesis all will be discharged in water body, become the endogenous pollution of water body.
And with the development of science and technology, scientific research personnel is successfully prepared for having efficiently suction using biological material anaerobic pyrolysis The cheap charcoal of attached efficiency, its adsorption capacity are 2~3 times of activated carbon.The reparation for being applied to polluted-water was both solved Water pollution problem, realizes the recycling of biomass waste again.And water plant is a kind of biological material of high-quality, Desilting sediment is a kind of material rich in organic matter.This provides the possibility for solving for the problems referred to above.But have not yet to see The technology for preferably solving the above problems.
The content of the invention
The invention aims to overcome the shortcomings of above-mentioned background technology, there is provided a kind of recycling desilting sediment Method.
In order to realize object above, a kind of method of recycling desilting sediment that the present invention is provided, including following step Suddenly:
(1) water plant of desilting sediment and maturation is separately dried;
(2) the dried desilting sediment and the water plant are crushed respectively;
(3) by crushing after the desilting sediment and the water plant in mass ratio 1:3~5 ratio is sufficiently mixed, Mixture is obtained, if the water plant in material is inadequate, can be replaced with debirs such as agricultural stalk, feces of livestock and poultry;
(4) by the mixture, high temperature pyrolysis obtain charcoal under anoxic conditions;
(5) charcoal is obtained activating charcoal through acid activation, the activation charcoal is soil-repairing agent.
In such scheme, the particle diameter of the desilting sediment and the water plant after crushing is respectively less than 1mm.
In such scheme, when the organic pollution contained in the desilting sediment is exceeded, the temperature of the high temperature pyrolysis Spend for 600~800 DEG C, time of high temperature pyrolysis pyrolysis is 1~2h, the exceeded standard of the organic pollution is《Industry Enterprise's soil environment quality risk assessment benchmark》(HJ/T25-1999) soil benchmark (directly contact).
In such scheme, when the organic pollution contained in the desilting sediment is not exceeded, the high temperature pyrolysis Temperature is 400~600 DEG C, and time of high temperature pyrolysis pyrolysis is 1~2h, and the exceeded standard of the organic pollution is《Work Industry enterprise soil environment quality risk assessment benchmark》(HJ/T25-1999) soil benchmark (directly contact).
It is in such scheme, described to obtain activating concretely comprising the following steps for charcoal through acid activation by the charcoal:Will The charcoal obtains activating charcoal with hydrochloric acid solution and water washing successively.
In such scheme, the concentration of the hydrochloric acid solution is 0.5mol/L.
When the activation charcoal is used for soil pollution to be repaired, the consumption of the activation charcoal is soil dry to be repaired The 5~20% of weight.
When the activation charcoal is used for soil improvement, the consumption of the activation charcoal is to treat improved soil dry weight 1~10%.
The beneficial effect brought of technical scheme that the present invention is provided is:
1st, after the water plant of desilting sediment and maturation is separately dried and is crushed, mix in proportion, and in anoxic Under the conditions of high temperature pyrolysis obtain charcoal, and charcoal as high-performance sorbing material after acid-wash activation, its adsorptivity Can be further enhanced;
2nd, as the organic pollution that desilting sediment is carried is pyrolyzed during high temperature pyrolysis, and charcoal attachment Heavy metal is removed during acid-wash activation, so the activation charcoal for obtaining fullys meet safe disposal desilting sediment Requirement, and the activation charcoal can be widely used for soil pollution reparation and soil improvement;
3rd, the present invention can not only safe disposal desilting sediment, and desilting sediment and water plant can also be realized simultaneously Recycling, also reached the purpose of soil pollution reparation and soil improvement.
Description of the drawings
Fig. 1 is the flow chart of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawings and embodiment the present invention is described in further detail, but the embodiment should not be construed as it is right The restriction of the present invention.
Embodiment 1:
Referring to Fig. 1, present embodiments provide a kind of method of recycling desilting sediment, first, by desilting sediment and Ripe water plant is respectively dried, and by drying after the desilting sediment and the water plant to be crushed to particle diameter respectively little In 1mm;Then, by crushing after the desilting sediment and the water plant in mass ratio 1:4 ratio is sufficiently mixed, and obtains Mixture;Then, by the mixture 450 DEG C under anoxic conditions (organic pollution contained in desilting sediment is not exceeded) or 700 DEG C (organic pollution contained in desilting sediment is exceeded) pyrolysis 1h obtains charcoal;Finally, the charcoal is used successively The hydrochloric acid solution and water washing of 0.5mol/L obtains activating charcoal, and the activation charcoal is soil-repairing agent.
Above-mentioned soil-repairing agent does not detect the heavy metal or organic pollution of solubility.The soil-repairing agent for obtaining is used for The reparation of certain heavy metal cadmium and Pyrene contaminated soil, consumption are the 10% of soil dry weight to be repaired.Above two The soil-repairing agent that pyrolysis temperature is obtained --- soil-repairing agent (450 DEG C) and soil-repairing agent (700 DEG C) repairing polluted soil After one month, biologically effective state cadmium and pyrene in soil is determined.It was found that biologically effective state cadmium content reduces more than 76%, biology Available state pyrene content reduces more than 80%.
The present embodiment is mixed after the water plant of desilting sediment and maturation is separately dried and is crushed in proportion, and High temperature pyrolysis obtain charcoal under anoxic conditions, and charcoal as high-performance sorbing material after acid-wash activation, its Absorption property is further enhanced;Simultaneously as the organic pollution that desilting sediment is carried is warm during high temperature pyrolysis Solve, and the heavy metal of charcoal attachment is removed during acid-wash activation, so the activation charcoal for obtaining reaches completely The requirement of safe disposal desilting sediment is arrived, and the activation charcoal can be widely used for soil pollution reparation;In addition, the present embodiment Can not only safe disposal desilting sediment, and the recycling of desilting sediment and water plant can also be realized simultaneously, also Reach soil pollution and repair purpose.
The exceeded standard of above-mentioned organic pollution is《Industrial enterprise's soil environment quality risk assessment benchmark》(HJ/T25- 1999) soil benchmark (directly contact).
Embodiment 2
Two kinds of soil-repairing agents that embodiment 1 is obtained --- soil-repairing agent (450 DEG C) and soil-repairing agent (700 DEG C) For soil improvement, consumption is the 5% of soil dry weight to be repaired.Soil physico-chemical property is determined after one month, soil before and after improvement Property is as shown in table 1 below:
The physicochemical property of soil before and after the soil-repairing agent improved soil that 1 present invention of table is obtained
By above-described embodiment contrast it is found that the water plant of desilting sediment and maturation to be separately dried, crush, press Certain ratio is sufficiently mixed, and high temperature pyrolysis prepare charcoal under anoxic conditions;The charcoal of preparation after acid activation into To activate charcoal, i.e., soil-repairing agent of the invention.The soil-repairing agent for obtaining can be used for soil improvement.The present invention can not only Enough safe disposal desilting sediments, while realizing the recycling of desilting sediment and water plant, have also reached soil improvement Purpose.
Although the present invention is disclosed above with preferred embodiment, but it is not limited to the present invention.It is any to be familiar with ability The technical staff in domain, in the case of without departing from technical solution of the present invention scope, all using the technology contents pair of the disclosure above Technical solution of the present invention makes many possible variations and modification, or the Equivalent embodiments for being revised as equivalent variations.Therefore, it is every Without departing from the content of technical solution of the present invention, according to the technology of the present invention essence to any simple modification made for any of the above embodiments, Equivalent variations and modification, all should fall in the range of technical solution of the present invention protection.

Claims (8)

1. a kind of method of recycling desilting sediment, it is characterised in that comprise the following steps:
(1) water plant of desilting sediment and maturation is separately dried;
(2) the dried desilting sediment and the water plant are crushed respectively;
(3) by crushing after the desilting sediment and the water plant in mass ratio 1:3~5 ratio is sufficiently mixed, and obtains Mixture;
(4) by the mixture, high temperature pyrolysis obtain charcoal under anoxic conditions;
(5) charcoal is obtained activating charcoal through acid activation, the activation charcoal is soil-repairing agent.
2. a kind of method of recycling desilting sediment as claimed in claim 1, it is characterised in that described clear after crushing The particle diameter of silt bed mud and the water plant is respectively less than 1mm.
3. a kind of method of recycling desilting sediment as claimed in claim 1, it is characterised in that when the desilting sediment In the organic pollution that contains it is exceeded when, the temperature of the high temperature pyrolysis is 600~800 DEG C, the high temperature pyrolysis pyrolysis when Between be 1~2h.
4. a kind of method of recycling desilting sediment as claimed in claim 1, it is characterised in that when the desilting sediment In the organic pollution that contains it is not exceeded when, the temperature of the high temperature pyrolysis is 400~600 DEG C, the high temperature pyrolysis pyrolysis Time is 1~2h.
5. a kind of method of recycling desilting sediment as claimed in claim 1, it is characterised in that described by the biology Charcoal obtains activating concretely comprising the following steps for charcoal through acid activation:The charcoal is obtained with hydrochloric acid solution and water washing successively Activation charcoal.
6. a kind of method of recycling desilting sediment as claimed in claim 5, it is characterised in that the hydrochloric acid solution Concentration is 0.5mol/L.
7. the application of soil-repairing agent as claimed in claim 1, it is characterised in that the soil-repairing agent is used for soil pollution During reparation, the consumption of the soil-repairing agent is the 5~20% of soil dry weight to be repaired.
8. the application of soil-repairing agent as claimed in claim 1, it is characterised in that the soil-repairing agent is used for soil improvement When, the consumption of the soil-repairing agent is treat improved soil dry weight 1~10%.
CN201610903725.0A 2016-10-17 2016-10-17 A kind of method of recycling desilting sediment Pending CN106542713A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107116096A (en) * 2017-05-16 2017-09-01 湖北加德科技股份有限公司 A kind of pyrolyzing sludge carbon and the united heavy metal soil remediation method of bioanalysis
CN107188386A (en) * 2017-07-17 2017-09-22 北京建筑大学 A kind of method that utilization sewage plant excess sludge prepares charcoal
CN108358412A (en) * 2018-04-02 2018-08-03 陈鹏 A kind of paper mill sludge treatment agent and its preparation method and application
CN108373250A (en) * 2018-04-02 2018-08-07 陈钦先 A kind of river pollution mud administers material and its preparation method and application
CN109482630A (en) * 2018-12-28 2019-03-19 北京高能时代环境修复有限公司 Repair the preparation method of the biological carbon adsorbent of heavy metals in farmland chromium-polluted soil
CN111592112A (en) * 2020-05-28 2020-08-28 盐城工学院 Method for remediation and recycling of organic pollution by mudflat plants
CN111675344A (en) * 2020-06-12 2020-09-18 广州市广绿园林绿化有限公司 Method for restoring ecological system of artificial lake
CN113042001A (en) * 2021-03-26 2021-06-29 维塔探索(广东)科技有限公司 Porous biochar for improving severe pollution and preparation method thereof
CN113171750A (en) * 2021-04-07 2021-07-27 广东工业大学 Method for preparing biochar from bottom mud and garden garbage and application of biochar
CN113735405A (en) * 2020-05-29 2021-12-03 南京林业大学 Continuous composite remediation method for heavy metal polluted bottom mud
CN114772890A (en) * 2022-04-08 2022-07-22 天津大学 Oily sludge treatment method and soil remediation method
CN116408047A (en) * 2023-03-09 2023-07-11 武汉大学 Rectorite/sediment/algae composite biochar material and preparation method and application thereof

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107116096A (en) * 2017-05-16 2017-09-01 湖北加德科技股份有限公司 A kind of pyrolyzing sludge carbon and the united heavy metal soil remediation method of bioanalysis
CN107188386A (en) * 2017-07-17 2017-09-22 北京建筑大学 A kind of method that utilization sewage plant excess sludge prepares charcoal
CN108358412A (en) * 2018-04-02 2018-08-03 陈鹏 A kind of paper mill sludge treatment agent and its preparation method and application
CN108373250A (en) * 2018-04-02 2018-08-07 陈钦先 A kind of river pollution mud administers material and its preparation method and application
CN109482630A (en) * 2018-12-28 2019-03-19 北京高能时代环境修复有限公司 Repair the preparation method of the biological carbon adsorbent of heavy metals in farmland chromium-polluted soil
CN111592112A (en) * 2020-05-28 2020-08-28 盐城工学院 Method for remediation and recycling of organic pollution by mudflat plants
CN113735405A (en) * 2020-05-29 2021-12-03 南京林业大学 Continuous composite remediation method for heavy metal polluted bottom mud
CN111675344A (en) * 2020-06-12 2020-09-18 广州市广绿园林绿化有限公司 Method for restoring ecological system of artificial lake
CN113042001A (en) * 2021-03-26 2021-06-29 维塔探索(广东)科技有限公司 Porous biochar for improving severe pollution and preparation method thereof
CN113171750A (en) * 2021-04-07 2021-07-27 广东工业大学 Method for preparing biochar from bottom mud and garden garbage and application of biochar
CN113171750B (en) * 2021-04-07 2022-03-11 广东工业大学 Method for preparing biochar from bottom mud and garden garbage and application of biochar
CN114772890A (en) * 2022-04-08 2022-07-22 天津大学 Oily sludge treatment method and soil remediation method
CN116408047A (en) * 2023-03-09 2023-07-11 武汉大学 Rectorite/sediment/algae composite biochar material and preparation method and application thereof

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Application publication date: 20170329