CN106531455A - Composite electrode material with adding of polypyrrole compound rare earth modified barium nitrate - Google Patents
Composite electrode material with adding of polypyrrole compound rare earth modified barium nitrate Download PDFInfo
- Publication number
- CN106531455A CN106531455A CN201610929780.7A CN201610929780A CN106531455A CN 106531455 A CN106531455 A CN 106531455A CN 201610929780 A CN201610929780 A CN 201610929780A CN 106531455 A CN106531455 A CN 106531455A
- Authority
- CN
- China
- Prior art keywords
- parts
- electrode material
- barium nitrate
- minutes
- polypyrrole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007772 electrode material Substances 0.000 title claims abstract description 21
- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 20
- -1 compound rare earth modified barium nitrate Chemical class 0.000 title claims abstract description 13
- 239000002131 composite material Substances 0.000 title claims abstract description 12
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 14
- 229920000767 polyaniline Polymers 0.000 claims abstract description 13
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 7
- MIOPJNTWMNEORI-UHFFFAOYSA-N camphorsulfonic acid Chemical compound C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C MIOPJNTWMNEORI-UHFFFAOYSA-N 0.000 claims abstract description 7
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002048 multi walled nanotube Substances 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 238000009987 spinning Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 238000010041 electrostatic spinning Methods 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 2
- 239000003990 capacitor Substances 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 abstract 1
- 239000002041 carbon nanotube Substances 0.000 description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000005087 graphitization Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000006396 nitration reaction Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention discloses a composite electrode material with the adding of polypyrrole compound rare earth modified barium nitrate. The composite electrode material is formed by the following materials of, by weight, 10 to 12 parts of multi-wall carbon nanotubes, 1.5-1.6 parts of sodium dodecyl sulfate, an appropriate amount of deionized water, an appropriate amount of absolute ethanol, 10 to 12 parts of polyaniline, an appropriate amount of chloroform, 14 to 15 parts of polyethylene oxide, 12 to 13 parts of DL-camphor sulfonic acid, 1.2-1.4 parts of polyethylene glycol-6000, 3-4 parts of polypyrrole, 3-4 parts of barium nitrate, 2-3 parts of lanthanum nitrate, and 9-10 parts of citric acid. The electrode material prepared by the invention has the advantages of excellent electrochemical performance, fast charging and discharging, and no pollution and safety, the process is convenient for industrial control, and an assembled super capacitor has the advantages of good stability and a long service life.
Description
Technical field
The present invention relates to capacitor technology field, more particularly to a kind of addition polypyrrole compounds answering for rare earth modified barium nitrate
Composite electrode material.
Background technology
Ultracapacitor also known as electrochemical capacitor, with power density it is big, have extended cycle life, easy maintenance and cost
The features such as relative moderate.Ultracapacitor is with the energy density bigger than traditional dielectric capacitor and the power higher than battery
Density, has broad application prospects in fields such as emergency power supply, hybrid power, digital product, telecommunications.CNT since
Since 1991 are found, due to excellent mechanical property, thermal property, electric conductivity, and scientist's research is become
Focus.CNT is preferable composite addition phase, with up to more than 1000 draw ratio, simultaneously because sp2
Orbital hybridization forms a large amount of delocalization p electronics, and electric conductivity is excellent.Electricity of the polyaniline as ultracapacitor electric conductive polymer
The advantages of pole material, environmental stability, high conductivity due to being readily synthesized, good, application it has been widely studied.However, poly-
The shortcomings of aniline is because of change in volume big and poor cycle charging/discharge capability, limits which in electrode of super capacitor material
Application in terms of material.These problems can be solved by polyaniline is merged with c-based nanomaterial, so as to realize electrification
Learn the synergism of double layer capacitor and fake capacitance capacitor.Therefore, the nano-carbon material of bigger serface and satisfactory electrical conductivity
It is used as support material to obtain the combination electrode of high-performance and long circulation life.
《Carbon nano-tube/poly aniline/Graphene composite nanometer carbon paper and its electrochemical capacitor performance》Pass through vacuum in one text
The method of sucking filtration prepares carbon nanotube paper, and a volt-ampere electrochemicial oxidation is circulated to which, with the electrochemicial oxidation
Carbon nanotube paper based on, using electrochemical polymer deposition polyaniline, subsequently adsorb Graphene, prepare with sandwich
Carbon nano-tube/poly aniline/Graphene the composite nanometer carbon paper of sandwich structure, the compound carbon paper have good capacitance characteristic, big
Current charge-discharge electrical characteristics and good stable circulation performance.But operating procedure is complicated, it is difficult to control the structure of extrusion coating paper, with
As for being difficult to improve its specific surface area, the raising of specific capacitance is limited;And as the carbon produced in actual production process is received
Mitron can all remain the catalyst impurities of a part, and some amorphous carbon, and the presence of these impurity limits carbon nanometer
The use of pipe, using sour purifying carbon nano-tube in article, eliminates most of amorphous carbon and gold while nitration mixture process
Metal particles, but processing procedure is loaded down with trivial details, it is seriously polluted, while some functional groups are have also been introduced, the presence pair of these functional groups
The structure of CNT causes certain destruction, so as to produce certain impact to performance, limits its performance;To sum up institute
State, need certain improvement to be carried out to process meanses such that it is able to which prepared operation is controllable, and electric conductivity is strong, specific surface area is big, ratio is electric
Hold big electrode material for super capacitor, meet the demand of development in science and technology.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided a kind of addition polypyrrole compounds rare earth modified nitre
The combination electrode material of sour barium.
The present invention is achieved by the following technical solutions:
A kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, is prepared by the raw materials in:It is many
Wall carbon nano tube 10-12, sodium lauryl sulphate 1.5-1.6, appropriate deionized water, appropriate dehydrated alcohol, polyaniline 10-12,
Appropriate chloroform, polyethylene glycol oxide 14-15, DL camphorsulfonic acid 12-13, PEG-4000 1.2-1.4, polypyrrole 3-4, nitre
Sour barium 3-4, Lanthanum (III) nitrate 2-3, citric acid 9-10.
A kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, is prepared by following concrete grammar
Form:
(1)Multi-walled carbon nano-tubes is placed on into graphite crucible stove, is placed in graphitizing furnace, evacuation is carried out to which, with 10-15 DEG C/
Min is warming up to 2800 DEG C, is incubated 20-20 hours, and natural cooling obtains graphitized carbon nano pipe;By above-mentioned graphitized carbon nano
Pipe is dissolved in the 25-30 times of deionized water measured with the speed ball milling 90-120 minutes of 200-300 turn/part, addition in being put into ball mill
Sodium lauryl sulphate, after ultrasonic 20-30 minutes be spray-dried, obtain modified carbon nano-tube;
(2)Barium nitrate, Lanthanum (III) nitrate are dissolved in the 2-3 times of deionized water measured, citric acid are added, after dispersed with stirring, is added poly- second two
Alcohol -6000, stir 30-40 minutes, heat 3-4 hours, filter after the completion of reaction in 80 DEG C of water-baths, drying, by the powder for obtaining
Body calcines 60-90 minutes at 800-850 DEG C, obtains modified RE doping barium nitrate, then mixes with polypyrrole, add total amount 2-
The dehydrated alcohol of 3 times of amounts, ultrasonic disperse 30-40 minutes, is vacuum dried 10-12 hours at 50-70 DEG C, obtains modified filler;
(3)Polyaniline is dissolved in the chloroform of 100 times of amounts, DL camphorsulfonic acid is added, with 300-400 rev/min under room temperature
Speed stirs 12-14 hours, is subsequently adding step(1)Step(2)The product for obtaining, ultrasonic disperse add which after 20-30 minutes
Remaining residual componentss, continue the speed stirring 10-12 hours with 300-400 rev/min, obtain spinning liquid;
(4)Spinning liquid is drawn in syringe and spinning liquid is collected on collector metallic nickel using electrostatic spinning technique, control
Spinning solution flow processed is 0.2-0.3ml/h, and voltage is 15-20kV, and spinning distance is 8-14cm, and spinning process 5-6 hour is formed
Composite fibre electrode material with certain thickness network structure.
It is an advantage of the invention that:The present invention carries out the method for high temperature graphitization process to reach purification first to CNT
Effect, there is evaporation in metallic catalyst, CNT will not be destroyed simultaneously graphited, while degree of crystallinity and leading
Electrically improve;Then the CNT after graphitization, polyaniline, polyethylene glycol oxide etc. net has been made into using electrostatic spinning technique
The composite cellulosic membrane of network structure, causes the fiber of preparation thinner by controlling spinning distance, spinning flow etc., enhances which and compare table
Area, so that electrolyte ion diffusional resistance diminishes, charge transferring channel is more unobstructed, thus shows more preferable capacitive character
Can, specific capacitance is improve, and good cyclical stability is shown using ultracapacitor made by this electrode material, while
Process is simple, is easy to Industry Control.
The present invention obtains lanthanum modified barium nitrate by a series of PROCESS FOR TREATMENT, then compounds with polypyrrole, and formation has
The modified filler of good dielectric properties, is added in the preparation of the membranaceous electrode material of fiber, and rare earth ion is in polypyrrole and polyphenyl
Function served as bridge is played between amine, electric charge transfer is smoothly transmitted therebetween, be conducive to materials conductive network
Formed, improve its electrical conductivity;Electrode material excellent electrochemical performance made by the present invention, discharge and recharge are rapid, safety non-pollution, and
Technique is easy to Industry Control, the ultracapacitor good cycling stability being assembled into which, long service life.
Specific embodiment
A kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, by following weight portion(Kilogram)Original
Material is made:Multi-walled carbon nano-tubes 10, sodium lauryl sulphate 1.5, appropriate deionized water, appropriate dehydrated alcohol, polyaniline 10, chlorine
Imitative appropriate, polyethylene glycol oxide 14, DL camphorsulfonic acid 12, PEG-4000 1.2, polypyrrole 3, barium nitrate 3, Lanthanum (III) nitrate 2,
Citric acid 9.
According to claims 1, a kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, by
Following concrete grammar is prepared from:
(1)Multi-walled carbon nano-tubes is placed on into graphite crucible stove, is placed in graphitizing furnace, evacuation is carried out to which, with 10 DEG C/min
2800 DEG C are warming up to, 20 hours are incubated, natural cooling obtains graphitized carbon nano pipe;Above-mentioned graphitized carbon nano pipe is put into
With the speed ball milling 90 minutes of 200 turns/part in ball mill, addition is dissolved in the sodium lauryl sulphate of the deionized waters of 25 times of amounts,
Ultrasound was spray-dried after 20 minutes, obtained modified carbon nano-tube;
(2)Barium nitrate, Lanthanum (III) nitrate are dissolved in the deionized water of 2 times of amounts, citric acid are added, after dispersed with stirring, is added poly- second two
Alcohol -6000, stir 30 minutes, heat 3 hours in 80 DEG C of water-baths, filter after the completion of reaction, and the powder body for obtaining is existed by drying
800 DEG C are calcined 60 minutes, are obtained modified RE doping barium nitrate, are then mixed with polypyrrole, add the anhydrous second of 2 times of amounts of total amount
Alcohol, ultrasonic disperse 30 minutes are vacuum dried 10 hours at 50 DEG C, obtain modified filler;
(3)Polyaniline is dissolved in the chloroform of 100 times of amounts, DL camphorsulfonic acid is added, with 300 revs/min of speed under room temperature
Stirring 12 hours, is subsequently adding step(1)Step(2)The product for obtaining, ultrasonic disperse add remaining residual components after 20 minutes,
Continue to stir 10 hours with 300 revs/min of speed, obtain spinning liquid;
(4)Spinning liquid is drawn in syringe and spinning liquid is collected on collector metallic nickel using electrostatic spinning technique, control
Spinning solution flow processed is 0.2ml/h, and voltage is 15kV, and spinning distance is 8cm, and spinning process 5 hours, formation have certain thickness
Network structure composite fibre electrode material.
Teflon septum is immersed in polyvinyl alcohol-sulfogel electrolyte, keep 20 minutes, after taking-up
Under room temperature natural evaporation be dried, then using made by the embodiment collect composite cellulosic membrane metallic nickel as electrode material with
Polyvinyl alcohol-sulphuric acid barrier film is stacked together by sandwich structure, and which is packaged with mylar, obtains super capacitor
Device.Cyclic voltamogram curve when scanning speed is 5 mV s 1, potential region 0.8-0.2 V obtains super capacitor
The specific capacitance of device is 96F/g, and after 1 000 cycle charge discharge electrical testings, specific capacitance remains to be remained above 90%.
Claims (2)
1. a kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, it is characterised in that by following weight portion
Raw material make:Multi-walled carbon nano-tubes 10-12, sodium lauryl sulphate 1.5-1.6, appropriate deionized water, appropriate dehydrated alcohol,
Polyaniline 10-12, appropriate chloroform, polyethylene glycol oxide 14-15, DL camphorsulfonic acid 12-13, PEG-4000 1.2-1.4,
Polypyrrole 3-4, barium nitrate 3-4, Lanthanum (III) nitrate 2-3, citric acid 9-10.
2. according to claims 1, a kind of addition polypyrrole compounds the combination electrode material of rare earth modified barium nitrate, and which is special
Levy and be, be prepared from by following concrete grammar:
(1)Multi-walled carbon nano-tubes is placed on into graphite crucible stove, is placed in graphitizing furnace, evacuation is carried out to which, with 10-15 DEG C/
Min is warming up to 2800 DEG C, is incubated 20-20 hours, and natural cooling obtains graphitized carbon nano pipe;By above-mentioned graphitized carbon nano
Pipe is dissolved in the 25-30 times of deionized water measured with the speed ball milling 90-120 minutes of 200-300 turn/part, addition in being put into ball mill
Sodium lauryl sulphate, after ultrasonic 20-30 minutes be spray-dried, obtain modified carbon nano-tube;
(2)Barium nitrate, Lanthanum (III) nitrate are dissolved in the 2-3 times of deionized water measured, citric acid are added, after dispersed with stirring, is added poly- second two
Alcohol -6000, stir 30-40 minutes, heat 3-4 hours, filter after the completion of reaction in 80 DEG C of water-baths, drying, by the powder for obtaining
Body calcines 60-90 minutes at 800-850 DEG C, obtains modified RE doping barium nitrate, then mixes with polypyrrole, add total amount 2-
The dehydrated alcohol of 3 times of amounts, ultrasonic disperse 30-40 minutes, is vacuum dried 10-12 hours at 50-70 DEG C, obtains modified filler;
(3)Polyaniline is dissolved in the chloroform of 100 times of amounts, DL camphorsulfonic acid is added, with 300-400 rev/min under room temperature
Speed stirs 12-14 hours, is subsequently adding step(1)Step(2)The product for obtaining, ultrasonic disperse add which after 20-30 minutes
Remaining residual componentss, continue the speed stirring 10-12 hours with 300-400 rev/min, obtain spinning liquid;
(4)Spinning liquid is drawn in syringe and spinning liquid is collected on collector metallic nickel using electrostatic spinning technique, control
Spinning solution flow processed is 0.2-0.3ml/h, and voltage is 15-20kV, and spinning distance is 8-14cm, and spinning process 5-6 hour is formed
Composite fibre electrode material with certain thickness network structure.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610929780.7A CN106531455A (en) | 2016-10-31 | 2016-10-31 | Composite electrode material with adding of polypyrrole compound rare earth modified barium nitrate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610929780.7A CN106531455A (en) | 2016-10-31 | 2016-10-31 | Composite electrode material with adding of polypyrrole compound rare earth modified barium nitrate |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106531455A true CN106531455A (en) | 2017-03-22 |
Family
ID=58291905
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610929780.7A Pending CN106531455A (en) | 2016-10-31 | 2016-10-31 | Composite electrode material with adding of polypyrrole compound rare earth modified barium nitrate |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106531455A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107365496A (en) * | 2017-04-03 | 2017-11-21 | 新沂市中诺新材料科技有限公司 | A kind of Performances of Novel Nano-Porous meter level La SnO2/ PANI composite conducting material synthetic methods |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101130431A (en) * | 2006-08-23 | 2008-02-27 | 中国科学院金属研究所 | Method for purifying nano carbon fiber of multi-wall carbon nano-tube |
CN102634016A (en) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | Preparation method of neodymium-lanthanum-doped barium ferrite-polyrrole composite microwave absorbent |
CN105977043A (en) * | 2016-04-07 | 2016-09-28 | 铜陵泰力电子有限公司 | Supercapacitor electrode material added with modified lignite and preparation method thereof |
CN105977020A (en) * | 2016-06-21 | 2016-09-28 | 闽江学院 | Fiber capacitor and preparation method thereof |
-
2016
- 2016-10-31 CN CN201610929780.7A patent/CN106531455A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101130431A (en) * | 2006-08-23 | 2008-02-27 | 中国科学院金属研究所 | Method for purifying nano carbon fiber of multi-wall carbon nano-tube |
CN102634016A (en) * | 2012-04-05 | 2012-08-15 | 南昌航空大学 | Preparation method of neodymium-lanthanum-doped barium ferrite-polyrrole composite microwave absorbent |
CN105977043A (en) * | 2016-04-07 | 2016-09-28 | 铜陵泰力电子有限公司 | Supercapacitor electrode material added with modified lignite and preparation method thereof |
CN105977020A (en) * | 2016-06-21 | 2016-09-28 | 闽江学院 | Fiber capacitor and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107365496A (en) * | 2017-04-03 | 2017-11-21 | 新沂市中诺新材料科技有限公司 | A kind of Performances of Novel Nano-Porous meter level La SnO2/ PANI composite conducting material synthetic methods |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Wu et al. | Carbon‐nanomaterial‐based flexible batteries for wearable electronics | |
Chen et al. | Ternary oxide nanostructured materials for supercapacitors: a review | |
Xiong et al. | Recent advances on multi-component hybrid nanostructures for electrochemical capacitors | |
Zhang et al. | Electropolymerization of graphene oxide/polyaniline composite for high-performance supercapacitor | |
He et al. | An overview of carbon materials for flexible electrochemical capacitors | |
Yao et al. | Flexible α-MnO2 paper formed by millimeter-long nanowires for supercapacitor electrodes | |
Zheng et al. | Graphene-based fibers for the energy devices application: A comprehensive review | |
Du et al. | Fabrication of hierarchical carbon layer encapsulated polyaniline core-shell structure nanotubes and application in supercapacitors | |
Guo et al. | Hybrid pseudocapacitor materials from polyaniline@ multi-walled carbon nanotube with ultrafine nanofiber-assembled network shell | |
Zhao et al. | Intercalating petroleum asphalt into electrospun ZnO/Carbon nanofibers as enhanced free-standing anode for lithium-ion batteries | |
Luo et al. | Fixing graphene-Mn3O4 nanosheets on carbon cloth by a poles repel-assisted method to prepare flexible binder-free electrodes for supercapacitors | |
CN108615865A (en) | A kind of lithium sulfur battery anode material and preparation method thereof | |
Liu et al. | Polyaniline-decorated 3D carbon porous network with excellent electrolyte wettability and high energy density for supercapacitors | |
Ji et al. | All-in-one energy storage devices supported and interfacially cross-linked by gel polymeric electrolyte | |
CN110581029A (en) | Active carbon/carbon nano tube/manganese dioxide ternary composite electrode, preparation method thereof and application thereof in electroadsorption | |
Song et al. | High flexibility and electrocatalytic activity MoS2/TiC/carbon nanofibrous film for flexible dye-sensitized solar cell based photovoltaic textile | |
Wang et al. | Towards unlocking high-performance of supercapacitors: From layered transition-metal hydroxide electrode to redox electrolyte | |
Cao et al. | Redox-active doped polypyrrole microspheres induced by phosphomolybdic acid as supercapacitor electrode materials | |
Jiang et al. | Weldable and flexible graphene ribbon@ Ni fibers with ultrahigh length capacitance for all-solid-state supercapacitors | |
Shao et al. | Binary nanosheet frameworks of graphene/polyaniline composite for high-areal flexible supercapacitors | |
Fan et al. | Asymmetric supercapacitors utilizing highly porous metal-organic framework derived Co3O4 nanosheets grown on Ni foam and polyaniline hydrogel derived N-doped nanocarbon electrode materials | |
Chen et al. | Characterisations of carbon-fenced conductive silver nanowires-supported hierarchical polyaniline nanowires | |
Faraji et al. | 2.0-V flexible all-solid-state symmetric supercapacitor device with high electrochemical performance composed of MWCNTs-WO 3-graphite sheet | |
CN106504903A (en) | A kind of nickel oxide acetylene black lifts the Static Spinning electrode material of chemical property | |
Yang et al. | A morphology control engineered strategy of Ti3C2Tx/sulfated cellulose nanofibril composite film towards high-performance flexible supercapacitor electrode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |
|
RJ01 | Rejection of invention patent application after publication |