CN1065294C - Method for manufacturing polyether type easy-dyeing spandex filament - Google Patents
Method for manufacturing polyether type easy-dyeing spandex filament Download PDFInfo
- Publication number
- CN1065294C CN1065294C CN96115991A CN96115991A CN1065294C CN 1065294 C CN1065294 C CN 1065294C CN 96115991 A CN96115991 A CN 96115991A CN 96115991 A CN96115991 A CN 96115991A CN 1065294 C CN1065294 C CN 1065294C
- Authority
- CN
- China
- Prior art keywords
- polyurethane
- polyurethanes
- manufacture method
- chromophilous
- spandex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002334 Spandex Polymers 0.000 title claims abstract description 23
- 239000004759 spandex Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 9
- 229920000570 polyether Polymers 0.000 title claims abstract description 9
- 238000004043 dyeing Methods 0.000 title abstract 4
- 239000004814 polyurethane Substances 0.000 claims abstract description 23
- 229920002635 polyurethane Polymers 0.000 claims abstract description 23
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 238000009987 spinning Methods 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000002075 main ingredient Substances 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- IPMWIVQWGGRTLD-UHFFFAOYSA-N n'-[2-(propylamino)ethyl]ethane-1,2-diamine Chemical class CCCNCCNCCN IPMWIVQWGGRTLD-UHFFFAOYSA-N 0.000 claims description 4
- KZMAWJRXKGLWGS-UHFFFAOYSA-N 2-chloro-n-[4-(4-methoxyphenyl)-1,3-thiazol-2-yl]-n-(3-methoxypropyl)acetamide Chemical compound S1C(N(C(=O)CCl)CCCOC)=NC(C=2C=CC(OC)=CC=2)=C1 KZMAWJRXKGLWGS-UHFFFAOYSA-N 0.000 claims description 3
- 150000004985 diamines Chemical class 0.000 claims description 3
- 125000005442 diisocyanate group Chemical group 0.000 claims description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 125000005263 alkylenediamine group Chemical group 0.000 claims description 2
- PWNDYKKNXVKQJO-UHFFFAOYSA-N n',n'-dibutylethane-1,2-diamine Chemical compound CCCCN(CCN)CCCC PWNDYKKNXVKQJO-UHFFFAOYSA-N 0.000 claims description 2
- UDGSVBYJWHOHNN-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 229920003226 polyurethane urea Polymers 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 10
- -1 polytetramethylene Polymers 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention relates to a method for manufacturing polyether type easily-dyed spandex fibers. It mainly solves the defect that the finished product in the prior art is not dyed by common dyes. It is mainly characterized in that the polyurethane or polyurethane solution which takes polyurethane or polyurethane urea as the main component is prepared by
Is used as an end-capping reagent, and is made into spandex fiber through spinning. It has the good effects of good dyeing property and high dyeing fastness of the finished product, and can be widely used for manufacturing spandex fibers with excellent dyeing property.
Description
The present invention relates to a kind of manufacture method of spandex fibre, particularly a kind of manufacture method with polyether-type spandex fibre of good chromatophilia energy.
Spandex is a kind of elastomeric textile fabric, now has been widely used in the knitting and woven elastic fabric.Yet because the molecular structure non-coloring gene of spandex itself, so usually dyestuff is not had the shortcoming of dying.In order to improve the dyeability of spandex silk, it is introduced that some companies contain the trivalent nitrogen compound and carry out copolymerization and improve its dyeability with adding abroad, but that this method still exists dye-uptake is big, the deficiency of dyefastness difference.Another kind method was added the trivalent nitrogen compound in the condensate in the past, but this method in the back manufacturing procedure operational problem takes place easily, produces powder, causes broken end.
Purpose of the present invention be exactly propose a kind of have good chromatophilia can the manufacture method of spandex fibre, to solve the shortcoming that existing in prior technology spandex manufactured goods dye on not common dyestuff.
Technical scheme of the present invention is achieved in that a kind of manufacture method of chromophilous polyether spandex filament, with polyurethanes or polyurethanes urea the polyurethane or the polyurethane solutions of Main Ingredients and Appearance, make spandex fibre through spinning, it is the organic compound with following structure that the end group of polyurethane blocks agent:
In the formula: R
1, R
2Alkyl or isoalkyl for C atomicity 1-4, R is the alkylene of C atomicity 1-12, it can be N, N-dimethylated propyl diethylenetriamine, N, N-diethyl propyldiamine, N, N-diethyl ethylenediamine, N, N-dibutyl propane diamine, N, N-dibutyl ethylenediamine, N, N such as N-dimethyl-ethylenediamine, N-dialkyl group alkylene diamine, particularly R are that alkylene below 4 is better for the C atomicity; Above-mentioned is that the polyurethane of Main Ingredients and Appearance is with number average molecule 1 000-4000 with polyurethanes or polyurethanes urea, and fusing point is that PTMEG below 60 ℃ and organic diisocyanate and the organic diamine of molecular weight below 400 are that raw material is made.
Advantage and good effect that the present invention had are, dyeability and dyefastness with the prepared spandex fibre of this method significantly improve, strong, also having with light stabilizer, antioxidant etc. and using has cooperative effect and the light resistance feature of fibres modified except that product dyed thereby is distinct.And have in forming process or in the process of back and do not break down, do not produce poor properties, whiteness is low, multiple advantage such as no color differnece.
Below with embodiment the present invention is further elaborated:
Embodiment 1: with 1950 parts of the polytetramethylene ether diols of molecular weight 1950 and 4,500 parts of 4-methyl diphenylene diisocyanates are at 70 ℃ of reaction 45min, obtain the prepolymer that two ends have isocyanate group, after adding 4487 parts of dimethyl formamide dissolving formation solution, be cooled to 8 ℃, add 74 part 1 while stirring, the 2-propane diamine is dissolved in 983 parts of dimethylformamides formed 1, and 2-propane diamine solution carries out chain propagation reaction.1,2-propane diamine solution adds 90% to, when viscosity reaches about 360PaS (20 ℃), add N, N-dimethylated propyl diethylenetriamine/dimethyl formamide be 21 parts/72 parts solution in condensate, react with free isocyanate groups.Adding acetic anhydride acid anhydride/dimethyl formamide afterwards is 10 parts/72 parts solution-stabilized viscosity.Making viscosity is that 340PaS (20 ℃) solid content is 32% polyurethane solutions.Spinning obtains the spandex fibre of 116dtex then, has good dyeability.
Embodiment 2, and with quadrat method N, the N-dimethyl-ethylenediamine substitutes N according to embodiment 1, and the N-dimethylated propyl diethylenetriamine can make the good 116dtex spandex fibre of dyeability equally.
Claims (5)
1, a kind of manufacture method of chromophilous polyether spandex filament, with polyurethanes or polyurethanes urea is the polyurethane or the polyurethane solutions of Main Ingredients and Appearance, make spandex fibre through spinning, it is characterized in that the end group blockade agent of polyurethane is the organic compound with following structure:
In the formula: R
1, R
2Be alkyl or the isoalkyl of C atomicity 1-4, R is the alkylene of C atomicity 1-12.
2,, it is characterized in that the R that end group blocks in the agent structural formula is the alkylene of C atomicity below 4 according to the manufacture method of the described a kind of chromophilous polyether spandex filament of claim 1.
3, according to the manufacture method of claim 1 or 2 described a kind of chromophilous polyether spandex filaments, it is characterized in that it can be N that end group blocks agent, N-dimethylated propyl diethylenetriamine, N, N-diethyl propyldiamine, N, N-diethyl ethylenediamine, N, N-dibutyl propane diamine, N, N-dibutyl ethylenediamine, N, N such as N-dimethyl-ethylenediamine, N-dialkyl group alkylene diamine.
4, according to the manufacture method of claim 1 or 2 described a kind of chromophilous polyether spandex filaments, it is characterized in that with polyurethanes or polyurethanes urea being that the polyurethane of Main Ingredients and Appearance is with number average molecule 1 000-4000, fusing point is that PTMEG below 60 ℃ and organic diisocyanate and the organic diamine of molecular weight below 400 are that raw material is made.
5, according to the manufacture method of the described a kind of chromophilous polyether spandex filament of claim 3, it is characterized in that with polyurethanes or polyurethanes urea being that the polyurethane of Main Ingredients and Appearance is with number average molecule 1 000-4000, fusing point is that PTMEG below 60 ℃ and organic diisocyanate and the organic diamine of molecular weight below 400 are that raw material is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96115991A CN1065294C (en) | 1996-09-24 | 1996-09-24 | Method for manufacturing polyether type easy-dyeing spandex filament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96115991A CN1065294C (en) | 1996-09-24 | 1996-09-24 | Method for manufacturing polyether type easy-dyeing spandex filament |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1187547A CN1187547A (en) | 1998-07-15 |
| CN1065294C true CN1065294C (en) | 2001-05-02 |
Family
ID=5123189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96115991A Expired - Fee Related CN1065294C (en) | 1996-09-24 | 1996-09-24 | Method for manufacturing polyether type easy-dyeing spandex filament |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1065294C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102076103B1 (en) | 2016-10-05 | 2020-02-11 | 산코 가부시키가이샤 | Method of Making Polyurethane Elastic Fiber |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994023100A1 (en) * | 1993-04-02 | 1994-10-13 | E.I. Du Pont De Nemours And Company | High-speed spun polyether-based spandex |
| WO1997018252A1 (en) * | 1995-11-16 | 1997-05-22 | E.I. Du Pont De Nemours And Company | Low temperature process for making polyurethaneureas and products thereof |
| WO1998053127A1 (en) * | 1997-05-20 | 1998-11-26 | Henkel Corporation | Polymer additive for fiber dye enhancement |
-
1996
- 1996-09-24 CN CN96115991A patent/CN1065294C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994023100A1 (en) * | 1993-04-02 | 1994-10-13 | E.I. Du Pont De Nemours And Company | High-speed spun polyether-based spandex |
| WO1997018252A1 (en) * | 1995-11-16 | 1997-05-22 | E.I. Du Pont De Nemours And Company | Low temperature process for making polyurethaneureas and products thereof |
| WO1998053127A1 (en) * | 1997-05-20 | 1998-11-26 | Henkel Corporation | Polymer additive for fiber dye enhancement |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1187547A (en) | 1998-07-15 |
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